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By B. Wilshire, P. W. Davis

It has been shown that grain-boundary migration during high-temperature creep can reduce or even prevent the formation of intercrystalline voids, giving a considerable increase in ductility.' A similar observation has been made in a recent investigation of the creep properties of various grades of nickel and nickel alloys. The results can be illustrated by the observations made on: a) Pure vacuum-cast nickel (99.993 pct Ni) b) Impure vacuum-cast nickel (99.97 pct Ni) c) Pure nickel containing internal voids (produced by a process of intering). d) A substitutional solid solution alloy of pure nickel containing 1.16 pct Sn. All the materials were given a high-temperature anneal (>850°C) to produce a stable grain size of 7 to 10 grains per linear mm. The apparatus and techniques used to obtain the present results have been described elsewhere.' In this series, grain growth was observed only in the highest-purity, vacuum-cast metal. Thus we may consider that in the other materials grain-boundary migration was prevented by either preexisting voids or solute atoms. The effect of migration on the creep ductility of the above materials can be seen from Fig. 1, which

Jan 1, 1962

By C. E. Shoenfelt, E. W. Krampert

The major oil discovery in 1938 for Wyoming was the General Petroleum Corporation's So. 1 Government, C.NW.SE. of sec. 21-35N-77W, on the Cole Creek structure in central Wyoming, 14 miles northeast of Casper. This well found commercial oil production in basal Cloverly sand (Lakota) at 7978 ft. and was completed on May 28, 1938, at 8019 ft., 3 ft. in Morrison shale. It had an initial produrtion of 10 bbl. of oil an hour but at the end of a 7-day test made 336 bbl. of oil in 24 hr. During 1938, the well produced a total of 23,161 bbl. of oil. It has been agitated about 10 days out of each month to provide fuel for lease and drilling operations, the balance of the time it has been shut in pending the completion of the second well on the structure. The Cole Creek oil is of intermediate base and has an A.P.I. gravity of 32.7". The record of the well contains the "tops" listed in the accompanying tabulation. Tops in General Petroleum Corporation's No. 1 Government Well Feet 2210 Top of the Mesa Verde (Teapot sandstone) 2960 Top Steele shale 4500 Shannon sand; good show of oil and gas 6740 Top Frontier sand; some oil saturation 6840 Halliburton test of Froutier did not show much oil, but at 6878 ft. the oil showing amounted to 50 barrels 6878-7051 Shale 7051-7062 Sand with some oil saturation 7062-7920 Shale (sandy phase of Thermopolis shale 7779 to 7788 ft.) 7920-7926 Sand (Muddy); oil-saturated 7926-7974 Shale 7974-7979 Hard, coarse, limy sand (Dakota); some oil saturation 7979-7997 Soft sand; high oil saturation 7997-8002 Shale with pyrites 8002-8016 Sand (Lakota) 8016-8019 Variegated Morrison shale 5600 Elevation Lance Creek Field.—Important extensions to the Lance Creek field in eastern Wyoming were made in 1938 by the completion of a number of

Jan 1, 1939

By C. E. Shoenfelt, E. W. Krampert

The major oil discovery in 1938 for Wyoming was the General Petroleum Corporation's So. 1 Government, C.NW.SE. of sec. 21-35N-77W, on the Cole Creek structure in central Wyoming, 14 miles northeast of Casper. This well found commercial oil production in basal Cloverly sand (Lakota) at 7978 ft. and was completed on May 28, 1938, at 8019 ft., 3 ft. in Morrison shale. It had an initial produrtion of 10 bbl. of oil an hour but at the end of a 7-day test made 336 bbl. of oil in 24 hr. During 1938, the well produced a total of 23,161 bbl. of oil. It has been agitated about 10 days out of each month to provide fuel for lease and drilling operations, the balance of the time it has been shut in pending the completion of the second well on the structure. The Cole Creek oil is of intermediate base and has an A.P.I. gravity of 32.7". The record of the well contains the "tops" listed in the accompanying tabulation. Tops in General Petroleum Corporation's No. 1 Government Well Feet 2210 Top of the Mesa Verde (Teapot sandstone) 2960 Top Steele shale 4500 Shannon sand; good show of oil and gas 6740 Top Frontier sand; some oil saturation 6840 Halliburton test of Froutier did not show much oil, but at 6878 ft. the oil showing amounted to 50 barrels 6878-7051 Shale 7051-7062 Sand with some oil saturation 7062-7920 Shale (sandy phase of Thermopolis shale 7779 to 7788 ft.) 7920-7926 Sand (Muddy); oil-saturated 7926-7974 Shale 7974-7979 Hard, coarse, limy sand (Dakota); some oil saturation 7979-7997 Soft sand; high oil saturation 7997-8002 Shale with pyrites 8002-8016 Sand (Lakota) 8016-8019 Variegated Morrison shale 5600 Elevation Lance Creek Field.—Important extensions to the Lance Creek field in eastern Wyoming were made in 1938 by the completion of a number of

Jan 1, 1939

By Richard A. Conkling

D. W. OHERN, Oklahoma, Okla. (communication to the Secretary*). -The author states: "A shale layer buried beneath 2,000 or 3,000 ft. of strata, in some instances, will upon folding become thicker in the synclines and thinner on top of the anticlines." In any series of folded strata there is a level of no strain. Provided the strata do not slip on each other, there would be above this level a thickening of strata in the synclines and a thinning on the anticlines, as the author states, while the converse would obtain below this level. In order that the author's

Jan 3, 1917

By A. B. Wood

In welding and metal working by electricity, two systems are in use,—the so-called. incandescent system, in which the material operated upon is traversed by currents of large volume and low electro-motive force, the current having a continuous metallic circuit during the welding operation, and the arc system, in which the electric arc is utilized. It is the purpose of the present paper to call attention to this last

Jan 1, 1892

By G. Donald Sherman

THE intense chemical weathering of geological materials in the tropical regions has produced soils that are very rich in their content of iron and aluminum oxides. These soils are commonly referred to as laterites. There is considerable confusion as to the definition of a laterite, since there are workers who consider it to be entirely a ferruginous horizon and others who insist that laterite must have a high content of free aluminum oxide. How¬ever, in general the former is the accepted definition. The indurated ferruginous clay was given the name "laterite" by Buchanan,' not because of its bricklike appearance but rather because bricks were cut from it and used as a building material. Many of the temples of India and Siam are built of this material. This term has come to mean to the geologist a material that includes hard masses of concretionary, cellular, pisolitic ironstones. The soil scientists have deviated from the original meaning of the word and their writings show very little respect for Buchanan's definition or an understanding of the ma¬terial described by him. Pendleton," a life-long student of tropical soils, has insisted that the term laterite be restricted to Buchanan's definition; namely, an alluvial horizon, largely of iron oxides, with a slaglike, cellular or pisolitic structure, and of such a degree of hardness that it may be quarried out and used for building construction. More recently DuPreez2 and Sherman" have eliminated from Buchanan's definition the requirement of a hardness for building construction purposes. In doing this they eliminate the lithological implications in favor of a description of a product, soil, which originates and is developed by pedogenic processes. The confusion of the definition of a laterite is made greater by workers who insist that it must contain bauxite of different degrees of purity. Many of the tropical soils are rich in aluminum oxides. It is natural for the workers who have studied these tropical soils to emphasize the importance of the hydrated aluminum oxides. Hollands reported that the alumina in a laterite existed as bauxite. Fermor3 insisted that a laterite must have a high content of aluminum oxide hydrate, and Fox,4 in 1923, made the suggestion that if a laterite contained enough hydrated aluminum oxide to be used as an aluminum

Jan 1, 1952

By H. C. Heard

The review by Professor J. C. Jaeger (Chapter 1) briefly summarizes and discusses a select group of papers by various workers dealing primarily with aspects of fracture in brittle rock materials. Professor Jaeger's treatment is primarily concerned with the correlation of phenomenological and theoretical failure criteria with empirical results from short duration tests at ambient temperatures and generally at low lithostatic and interstitial fluid pressures. As engineering rock mechanics becomes more concerned with new techniques of mineral exploration and production at increasingly greater depths in the crust, it is well to be aware of the effect of the environment -that of the superposed stress field upon the lithostatic and interstitial fluid pressure, the temperature and the duration of the loading upon the failure of rocks either by fracture or flow. All results to be discussed here are from laboratory tests on small homogeneous samples, thus caution should be used in the direct extrapolation of these results to large inhomogeneous rock masses having quite different boundary conditions in the earth. The purpose of this supplement is to briefly point out the major effects of these parameters as examined singly, with all others held constant, and to cite some recent results which apply to the main theme on the brittle failure of rocks. The total stress field imposed upon a small volume of porous and permeable rock in the earth's crust may be thought of as the sum of an applied differential stress, plus a lithostatic pressure, plus an interstitial fluid pressure. The differential stress portion may be completely specified by nine components, six shear and three normal. If the small volume element is in rotational equilibrium, by suitably choosing our coordinate axes we may resolve these nine components into the three principal com-

Jan 1, 1967

By G. E. Karantzavelos

Although jigging has been the subject of extensive studies, evaluation of the effect of various jigging factors on the efficiency of separation has been less comprehensive. The basic factors that affect jigging separation are reviewed, a mathematical model describing jigging kinetics is presented, and attention is focussed on the mechanisms of the stratification process. The parameters of the kinetic model (the Wei- bull distribution function) are redefined in a gravity concentration technological sense, and their values are estimated for a wide range of jigging conditions. Several mathematical relationships (regression models) are also formulated which express the dependence of total time required for the complete stratifaction of mineral particles on the operating jigging variables.

Jan 1, 1984

By George Rice

INSTANTANEOUS outbursts of gas in underground workings are similar in effect to great blasts of explosives, but without heat effects. Fortunately they occur only in a few localities in exceptional coal fields of the world and under exceptional geologic conditions. Such violent outbursts should not be compared with the ordinary outflows of gas into coal mines or with explosions of gas and dust. The phenomenon is essentially one of gas held in circumscribed areas under very high pressure and as a mining face or heading approaches such a place and the mining excavation sufficiently weakens the natural surrounding dam or shell, this is burst by the pressure just as by the discharge of a mass of explosives. The outbursts, so far as known to the writer, have been confined to coal beds and have not occurred in other mineral deposits. Hence, as discussed later, he believes that it is the relation of the gases to the coal material that is a factor in conjunction with others in producing conditions which permit the phenomena to occur when mining is done. The gases in most instantaneous outbursts have been hydrocarbon gases but in two coal fields they have been definitely found to be chiefly or wholly carbon dioxide. One of these localities in which CO2 outbursts have been frequent and have caused loss of life is in the southern part of the Gard basin, near Alais, in southern France. In 1919, the writer visited the Fontaine mine in this field the day following the occurrence of an outburst by which two men were smothered by carbon dioxide and fine dust. After 24 hr. the CO2 had not been entirely removed by the ventilating current. Occasional outbursts of CO2 have also occurred in other small basins in France, causing accidents, as in Puy-de-Dome. However, mines in the Gard basin, north of those in which CO2 outbursts have occurred, have experienced hydrocarbon gas outbursts.

Jan 1, 1931

By Fred Wright

IN A recent paper1 a detailed discussion is given of the possibilities. of using polarized light in the examination of opaque substances. The factors underlying the problem .are there treated from the viewpoint of the electromagnetic theory of light and the presentation is necessarily mathematical in form. The practical methods resulting from the discussion are, however, relatively simple and promise to be of value in the determination of certain ores and metals when studied in reflected light under the microscope. The results of the theoretical investigation referred to may be summarized by stating that in general the optical constants, such as refractive indices and absorption indices, cannot be satisfactorily ascertained on small, random, polished sections; that the use of polarized light enables. the observer ordinarily to determine whether the crystal plate is isotropic or anisotropic, and also to ascertain the degree of anisotropism; that for this purpose methods based either on the contrast in intensity between the two reflected components of non-polarized light, or on the amount of rotation of the plane of polarization, on reflection, of vertically incident, plane-polarized light, may be employed; that methods based on the phase difference between the two reflected components are in general of little value because of the small differences in phase which ordinarily result for a relatively large change in birefringence or biabsorption. The measurement of the optical properties of transparent minerals, even in minute irregular grains, is a simple task with modern petrographic microscope methods and is accomplished by petrologists as part of their ordinary routine work. But the determination of the optical constants of opaque substances is difficult and is rarely attempted; all observations are necessarily made in reflected light and are restricted commonly to the determination of color, of hardness, of the character of crystallization, and

Jan 2, 1920

Jan 1, 1922

Jan 1, 1922

By H. Ries

THE stabilization of a gravel road with soil is a method of treatment developed in recent years by the United States Bureau of Public Roads for the purpose of binding the constituents together better, and maintain-ing a more durable surface. The process consists in adding to the gravel or crushed stone and sand, a soil mortar, so-called, of fine sand, silt and clay, mixed in the proper proportions. The coarse gravel and sand supply structural strength and hardness; the fine sand adds embedment support to the coarse sand; the silt acts as a filler to prevent the granular particles from rocking; while the clay serves not only as a binder but also provides pores minute enough to cause connecting moisture films which are supposed to have high cohesive properties1. It will be recognized that the clay is an important ingredient both when wet and dry, and should not show excessive expansion when wet, nor correspondingly high shrinkage in drying, as otherwise there is danger of unseating the nonplastic particles. Such a stabilized road, although an improvement on one with a floating surface, will in course of time be subject to wear, and become dusty when the clay dries out and breaks up. It has been found that if some salts are added to the road mixture they tend to maintain the soil moisture and prevent dustiness of the road or raveling of the road surface. In addition to this, it is claimed that these dissolved salts cause a thinning of the moisture films on the particles, thus permitting greater compaction of the road mixture, and thereby increasing its density. This fact can be proved by noting the increased compaction which a road mixture shows when certain salts are added to the soil water. Since certain chemical substances such as sodium chloride are electro-lytes, the question arises whether they cannot have some effect on. the qualities of the clay in the soil mortar, and perhaps improve them. In view of the fact that certain salts seem to exert a favorable effect on the road mixture it is desirable that they be held in the road soil as long a time as possible.

Jan 1, 1936

By Malcolm V. Lowry

At Balmat in northern New York State, the St. Joseph Lead Co.'s 2100-tpd zinc mining and milling operation is utilizing a unique thickener in conjunction with conventional crushing, grinding and flotation methods. From 1930 through 1962, zinc concentrates went directly from flotation to the filtering, drying and loading facilities, all of which had to operate 24 hr per day. Wide fluctuations in tonnage also had to be accommodated due to variations in the grade of ore. Many problems were thus encountered in filtering and drying, but the cost of installing a conventional, large diameter thickener could never be justified. In 1963, after thorough investigation, an unconventional thickener that is unusual in several respects was installed at Balmat. The tank depth is 16 ft instead of the normal 8 ft. The rakes are raised and lowered by having the main drive gear located on a movable platform. Automatic controls are programmed to raise the drive platform and rakes during one shift of storage. During the next two shifts of withdrawal, the controls are programmed to lower the drive platform and rakes.

Jan 5, 1966

By A. S. Michaels, M. C. Porter, A. Stancell

Previous laboratory studies have demonstrated that the injection of small quantities of reverse wetting agents during water displacement can increase oil recovery from unconsolidated porous media.9 In the present investigation, an attempt has been made to determine more fully the effects of reverse wetting treatments and to clarify the mechanism by which increased oil recovery is effected. Water-oil displacements were performed in beds of 140-200 mesh silica sand. Hexylamine slugs (injected after 0.25 pore volume of water throughput), when adequate in size and concentration, were effective in promoting additional oil recovery. Their effectiveness increased with the quantity of amine injected. However, slugs of sufficient size and concentration to stimulate oil production at water flow rates of 34 ft/day did not do so at 4 ft/day. Visual studies in a glass grid micromodel have shown that the stimulation of oil production, via ayueous hexylamine, is a result of transient changes in the oil wettability of the pore walls. if the amine slug is of sufficient size and concentration to induce significant changes in the adhesion-tension, large continuous oil masses will be formed. if the superficial water velocity is high enough to result in rapid desorption of the amine, a favorable "wettobility gradient" may be established across the masses; under such conditions, high oil mobility is observed, and increased oil recovery results. INTRODUCTION It is generally agreed that the efficiency of oil displacement by water in porous media is limited in part by capillary forces which cause the retention of isolated masses of oil — resulting in the so-called "irreducible minimum oil saturation". Recent estimates10 indicate that there are about 220 billion bbl of petroleum in United States reservoirs which are not economically recoverable with present techniques (such as water flooding). This amounts to almost five times the known recoverable reserves. It has been recognized for some time that a suitable alteration in the water-oil interfacial tension and/or the contact angle, as measured between the water-oil interface and the solid surface, should result in better displacement efficiency. Surface active agents can be used as interfacial tension depressants to accomplish this objective,1,2,7 but unfortunately, the additional oil recovery is seldom commensurate with the treatment cost. In contrast to interfacial tension depressants, the effect of contact angle alterations on water-oil displacements has received relatively little attention in the literature. It is known that the wettability affects the displacement process.3,4,11 Displacements in water-wet systems generally result in lower residual oil saturations than those in oil-wet systems. The effect of "'transient" wettability alterations concurrent with the displacement process have been investigated by Wagner, Leach and coworkers,4,11 wherein it has been demonstrated that the establishment of water-wet conditions during water flooding of oil-wet, oil-saturated porous media is accompanied by significant increase in oil displacement efficiency. Michaels and Timminss studied the effects of transient contact angle alterations resulting from chromatographic transport of reverse wetting agents through unconsolidated sand. It was demonstrated that chromatographic transport of short-chain (C4 through C8) primary aliphatic amines can improve oil recovery and that the recovery increases with the quantity of amine injected (i.e., with either the amine concentration or the volume of the slug injected). Circumstantial evidence indicated that the increased displacement efficiency resulted primarily from transient changes in wettability of the porous medium. In the Present investigation. additional information has been obtained on the effects of reverse wetting treatments and the mechanism by which increased oil recovery is accomplished. Hexylamine slugs of varying size and concentration were chromato-

Jan 1, 1965

By R. R. Spencer, C. A. Campbell, R. J. Marcotte, A. S. Kromer, P. H. Ostlender

Calumet Div. of Calumet & Hecla Inc. is engaged primarily in mining, milling, and smelting the native copper ores of northern Michigan. The copper occurs in fragmental tops of lava flows and in certain interbedded felsitic conglomerates of Pre- Cambrian age. The most famous native copper ore- body in world history is the Calumet conglomerate, which outcrops between the villages of Calumet and Laurium for a distance of about 2 miles. The Osceola lode parallels the conglomerate lode and is mineralized for about 3 miles. Horizontal distance between the two is 750 ft. In 1932 the price of copper dropped to 54 per lb. Coupled with the high cost of obtaining copper from extreme depths, this low price made the venture un- profitable, and the mining unit was abandoned. After the shaft pillar copper was removed from several of the conglomerate shafts in a retreating operation, the mine was allowed to fill with water. In post-depression years, when the price of copper stabilized at about 12¢, Calumet Div. found it profitable to operate its remaining mines on other lodes, as well as its tailings reclamation plants.

Apr 1, 1956

By Nev A. Gokcen

DISCREPANCIES and scattering in the equilibrium data on the reactions of hydrogen, and CO with dissolved oxygen in liquid iron are un- duly large. Available experimental results on the reduction of liquid ferrous oxide, i.e., wüs-tite, with hydrogen and CO are questionable, as pointed Out by Darken and Gurry'l Direct determinations of the solubility of oxygen in liquid iron are subject to errors which cannot be easily reduced by further experimental refinements, and therefore an accurate but indirect method is highly desirable. The purpose of this investigation was, therefore, 1)

Jan 1, 1957

By Robert Lepsoe

IT is generally realized that in cyaniding the precipitation efficiency of zinc dust is due to the fine division or extended surface of its metallic particles; but frequently it is thought that the presence of other, metals, say 2-3 per cent. lead, is advantageous,. causing more complete precipitation. The results of testing about fifty brands of commercial zinc .dust have led to the conclusion that there is a distinct relation of precipitation efficiency to fineness and that the effect generally can be estimated by examining the size of metallic particles. The presence of lead was not found to be of any importance. SPECIFICATIONS Generally the term "97 percent. to pass a 350-mesh screen, 95-97 per cent. uncombined metallic zinc" is used by the leading European exporters. Among the many methods of determination of metallic zinc, I have found the iodine test (iodine in potassium iodide) very satisfactory and rapid. It has been controlled by the other methods, samples of the same product having been sent to three different analysts: Iodine method 98. 11 per cent. metallic zinc, Volumetric method 97.63 per cent. metallic zinc, Ledoux Co., New York Bichromate method 98.16 per cent. metallic zinc, Watson Gray, Liverpool, England Bichromate method 98.20 per cent. metallic zinc, Norway Inst. of Tech., Trondhjem

Jan 2, 1925

The new saw mill at Cache Bay of the Geo. Gordon & Co., Ltd., a subsidiary of International Nickel Co., of Canada, is equipped with the first fully electric saw carriage drives in Ontario. It has a capacity of 120,000 ft of lumber in an 8-hr shift. About half of the mill's production is high grade white pine lumber which is shipped to the general market. The other half, red pine is used in the mining operations of International Nickel in the Sudbury district, 55 miles west of Cache Bay. [ ] Inco with a potential need of 77 million board ft a year, gets only part of its supply from the new mill. The milling firm became an Inco subsidiary Jan. 1, 1948.

Jan 1, 1952

By J. W. Bolton

PRODUCTION of sound bronze castings is a matter of great practical interest to users and manufacturers of high-grade non-ferrous engineering specialties. Although there has been much excellent research in this field, there still remains some confusion regarding the fundamental principles underlying production of really sound bronze. The literature of the past 20 years on this subject indicates that the prevailing opinion of metallurgists and foundrymen has been that unsoundness in bronze is due generally to oxidation. The following references are typical.

Jan 1, 1929