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By Moinpour M

The kinetics of reduction of copper (cuprous) sulphide with CO-CO2-He gas mixtures, using an excess of CaO(s) as a sulphur-scavenging substance were investigated in the temperature range 855° - 950°C by a thermogravimetric method. Several gas compositions were employed at each temperature. Potential carbon deposition was overcome by preheating the reducing gas mixture. The phase-composition and the morphology of partially reactedsamples were analysed by a SEMlEDAX unit. The reduction rates showed strong dependence on the bulk gas compositions (CO, CO2) and, in most cases, the rate declined with rising temperature. The rate-controlling step appears to be the diffusion of CO2 gaseous species through the micropores of the CaS(s) - product layer which builds up around the CaOcore.

Jan 1, 1989

The operation of quarries for the production of crushed stone and aggregates, depends heavily on rock blasting efficiency, which usually represents a major share of total production costs. After investigating the causes of this situation, a series of technical aspects have been detected, and they are described for the purpose of contributing to the minimization of costs, which also reduces the effects of blasting on the environment. Utilization of empirical design methods, of inadequate explosive types, and of erroneous drilling pauems with respect to rock properties, are the main factors to be corrected, as a consequence of poor engineering criteria, with scarce use of computational methods and field instrumentation. Several concepts of blasting optimization are pointed out, and their application to industrial operations in a Portuguese limestone quarry indicated clear trends for the reduction of production costs, as well as some of the deleterious consequences of blasting on the environment.

Jan 1, 1990

The international scientific and engineer-ing community is being challenged to take advantage of the opportunity offered by the U.N. International Decade for Natural Disaster Reduction (IDNDR) program to reduce rapid onset geological hazards along the Pacific Rim. Natural disasters observe no national boundaries; international cooperation offers the best opportunity to reduce the losses these catastrophic events create.

Jan 1, 1990

By Reid A. F

Since early 1971 Western Titanium N.L. has been operating an ilmenite upgrading plant on a commercial basis at Capel, Western Australia. In their process ilmenite is pre- oxidized, then reduced in a rotary kiln to a mixture of metallic iron and titanium oxides. The iron is leached out by accelerated rusting in aerated water, leaving a product with titanium content, expressed as Ti02, of about 92%. Samples from different stages of the up- grading process, representing operations over the last two years, have been studied in detail by X-ray diffraction methods, and the sequences of phases and reactions occurring have been determined. Quantitative X-ray studies showed the ilmenite feed materials to consist of a mixture of ilmenite and pseudo- rutile. Pre-oxidation of the ilmenite at =1000¦C leads to the formation of rutile plus a Fe2TiO5-FeTi205-Mn2TiO5 solid solution. The final reduction product consisted of a mixture of metallic iron, reduced rutile and a FeTi05-MnTi205-Ti305 solid solution. The relative amounts of these reduction products were very sensitive to the initial concentra- tions of the minor constituents manganese and magnesium. The effects of variation of ilmenite feed rate, reducing atmosphere,- reduction temperature and controlled addition of magnesium were also studied.

Jan 1, 1973

Reduction of Iron Content from Silica by Gravitational Processes In this research work, it was attempted to reduce the iron contents (Fe2O3) in silica sample which was provided from Shenin silica mine using gravitational processes including jig machine, multi gravity separator (MGS), shaking table and spiral. The silica sample contains 93.75 per cent SiO2, 0.44 per cent Fe2O3, 2.78 per cent Al2O3, and 0.08 per cent TiO2 and the Fe2O3 has to be reduced to about 0.1 per cent or less than 0.02 per cent. Mineralogical studies and XRD analysis indicated the presence of haematite, pyrite and goethite as the major iron impurity phases. Mineralogical studies of polished and thin sections yielded that the degree of freedom of silica is more than 80 per cent in the range of -300 +212 mm. After elimination of fine particles, at first nine tests were carried out on crusher product (in two size fractions), wet rod mil product and scrubber product by means of Jig Machine. The best results were obtained with about 0.15 per cent Fe2O3 on rod mill and scrubber product which was not desirable. Thereafter 7 tests were carried out using shaking table; the best results were obtained with about 0.14 per cent Fe2O3 on rod mill and scrubber product which was not desirable. MGS showed the worst result in order to iron removal from silica which was not desirable. Finally 9 testes were carried out using spiral whish is the best gravitational separator for elimination of iron impurities from silica. The best result of spiral tests were achieved on scrubber product. In this test concentrate weight percent and its Fe2O3 grade were 82.32 per cent and 0.085 per cent respectively. Finally a test was carried out using 2 stages of spiral in order to develop flow sheet. In this test concentrate weight percent and its Fe2O3 grade were 78.8 per cent and 0.1 per cent respectively. This product can be used to produce float (clear flat) glass.

Sep 13, 2010

By Whitehead A. B

INTRODUCTIONDuring the past few years there has been considerable interest in developing the so-called direct reduction processes for treating iron oxides. The various methods proposed were recently reviewed by Scortecci and Palazzi (1960).In particular the application of fluidized bed techniques received considerable attention and, on first examination, this seems to be the ideal method 'of dealing with fine iron oxides. Several difficulties (e.g. product agglomeration) require the method to be investigated further before its potentialities can be fully assessed.PROPOSED FLUIDIZED BED REDUCTION PROCESSESBrassert and De Jahn (1951) were among the earliest to suggest the use of fluidized beds for the reduction of iron ore to metallic iron. Their patent was followed by many others proposing similar concepts, mainly from Lewis (1955), Ogorzaly (19.56), Shipley (1956), Agarwal (1960'), Osborn (1958), Texaco Development Corporation (1956) and Stelling (1957).The H-iron process (Squires and J ohnson, 1957; Lubker and Bruland, 1960) is the only scheme that has been an economic success. This process, mentioned later, manufactures a 'premium quality product in the form of sized iron powder.AIM OF THE PRESENT WORKThe work reported here was performed to assist in the formulation of a comprehensive pl'ogramme of research into fluidized bed reduction processes to be undertaken at the...

Jan 1, 1962

By Y Peng, D Wannas

In the fine particle flotation technologies being developed today the fine hydrophilic (gangue) particles are usually well dispersed. These highly dispersed fine particles can be recovered into the flotation froth product by mechanical entrainment. Flocculation of hydrophilic particles caused by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxylapatite, galena and sphalerite, as well as on a relatively coarse quartz sample (-75+38 ¦m). Dodecylamine was used as a collector for the quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, potassium dichromate, corn starch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700 000 and 80 000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 ml flotation column. Both water and solid recoveries were recorded. The degree of flocculation and dispersion was determined by settling tests in 250 ml graduated cylinders. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of artificial mixtures of the -75+38 ¦m quartz and fine iron oxide or hydroxylapatite, polymer depressants that caused flocculation were found to perform better than the ones that did not cause flocculation.

Jan 1, 2005

By Henderson J

Iron ore samples selected from the Deepdale, Iron Prince and Mt. Newman ore bodies have been pelletised on a pilot scale plant and subsequently reduced under laboratory conditions by hydrogen or carbon monoxide. Pellets approximately 1 cm in diameter have been reduced by hydrogen over the temperature range 5000- 900¦C and the results examined by thermogravimetric, microscopic, electron probe and x-ray techniques. After an initial time delay it was found that up to 95% reduction the rate of reduction could be described by a transport con- trolled porous model, in which the effective diffusivities of hydrogen in theòpr¦duct layer and the reaction zone are filar. Independent measurements of effective diffusivity supported the values obtained from the reduction data. ve 95% reduction the rate decreased markedly due to the formation_of retained wustite or fayalite. Comparison with reduction by carbon monoxide over the temperature range 7500 - 900¦C showed that the rate eduction by carbon monoxide was approximately five times slower than the rate by hydrogen. The rate of reduction was found to be a function of the properties of the pellets, which may account for the ely conflicting results that have been obtained in previous investigation on porous pellets.

Jan 1, 1970

Hydrogen and carbon monoxide reduction data were obtained on pelletized materials of the type currently being prepared commercially in Australia.Pellets, approximately 1 cm diameter, made from Deepdale, Iron Prince, and Mt. Newman iron ore were reduced by hydrogen over the temperature range 500°-900°C and the reduced pellets were examined by thermogravimetric, microscopic, electron probe, and x-ray techniques. After an initial time delay it was found that up to 95 per cent reduction the data could be described by a porous model where gaseous diffusion through the solid is rate controlling. Independent measurements of effective diffusivity supported the values obtained from the reduction data. Above 95 per cent reduction the rate decreased markedly due to the formation of retained wustite or fayalite.Comparison with reduction by carbon monoxide over the temperature range 750°-900°C showed that the rate of reduction was approximately five times slower than for reduction by hydrogen.The rate of reduction was found to be a function of the initial properties of the pellets which may account for the widely conflicting results that have been obtained with previous investigations on porous pellets.

Jan 1, 1971

By J Moncrieff, P Bellairs

The Black Star Open Cut is located immediately adjacent to the township of Mt Isa and is situated in the middle of extensive pre-existing infrastructure including two concentrators, two smelters, a wet fill plant and two shafts. At any one time there are in excess of 500 people working on the surface within an industry-accepted 600 m exclusion zone from Black Star blasts. Apart from the surface operations there are also the underground operations including the lead mine (closed in December 2005) and the Enterprise and X-41 mines that must clear for all Black Star blasts. The application of industry standard blasting exclusion zones (600 m) was risk assessed as imposing operationally prohibitive constraints which could cause significant business interruption due to the logistical challenges required to ensure that all personnel from surface plants were evacuated for each blast and potential for lost production whilst these personnel were not operating the plant. In was therefore an imperative for the blast exclusion zone to be reduced. This was achieved by the: use of a QA/QC team to ensure that relevant drill and blast implementation is within an acceptable tolerance (KPIs) from design; use of high-quality stemming material called HMR, which is a by- product of the concentrating process and is generally sized at -14 mm with very little fines; implementation of appropriate training and support to Black StarÆs own blast crews, reinforcing the need to achieve the designed amount of stemming in every hole; and provision of appropriate support from Black StarÆs management for additional resources to ensure that every blast achieves design within the KPIs but especially in high-risk areas. The blast exclusion zone was successfully reduced after monitoring the flyrock results from more than 176 blasts. Black Star Open Cut now maintains a minimum blast exclusion of 200 m in critical areas; however, general blasting currently uses a 250 m exclusion as this provides additional risk management whilst still minimising the logistics associated with clearing and securing the slightly increased area.

Jan 1, 2007

By Parida K. M, Paramguru R. K

Laboratory-scale studies aimed at developing a process for solubilising manganese values from a low grade pyrolusite containing material using low grade pyrite, both available in India, are described. Leaching 21 parts by mole of pyrolusite with 6 and 26 parts by mole of pyrite and sulphuric acid respectively results in good manganese dissolution (98 per cent) at 100°C within one hour. The probable kinetics of the leaching process has also been given.

Jan 1, 1995

The Bowen Basin of Queensland and the Hunter Valley of New South Wales are the two largest black coal producing areas in Australia. Mining activities require the availability of large on-lease storages for water and tailings. The legislative framework for the regulation of large dams is slightly different between the states. The paper provides a broad outline of the regulatory framework in each state, with particular reference to Queensland and New South Wales. In New South Wales, water storages and tailings dams are treated similarly by the regulator. Under the Queensland Water Act 2000, now proclaimed, referable dams are restricted to water supply dams the failure of which involves population at risk downstream. Tailings dams are excluded, being deemed hazardous waste dams regulated under the Environment Protection Act 1994. These storage facilities are required to include a ædesign storage allowanceÆ so that the possibility of spillway discharges is minimised. New South Wales is moving toward this requirement. A curious anomaly is emerging in Queensland: the legislative definition of hazardous waste û material resulting from the processing of minerals û does not extend to coal tailings since coal is not included in the definition of a mineral. The paper explores this and other ramifications for mining operations of the new legislation as well as general trends in criteria affecting the cost of providing water and tailings storages.

Jan 1, 2003

Production of refined zinc (99.95 per cent) at the minesite without increasing greenhouse gas emissions is considered. As an example, exploitation of the full reserve of the McArthur River orebody is proposed, using the existing concentrator, whilst introducing radically innovative smelting technology. Bulk flotation of all the sulphide minerals is followed by smelting in a melt circulation reactor with tonnage oxygen. By smelting the high-energy pyritic concentrate and reacting the evolved sulphur dioxide with near-mine dolomite, a large amount of electricity can be generated. This is enough to supply all the requirements for the smelter itself, an air separation plant and a facility for compressing and liquefying carbon dioxide. Carbon dioxide is disposed of off-shore for enhanced oil recovery or by other means. The reacted dolomite fixes sulphur as an inert and environmentally acceptable solid residue. Treatment by these means leads to virtually zero gas emission smelting. The paper concludes with a vision for the future in which expansion of zinc smelting capacity is seen to be definitely needed.

Jan 1, 1998

This paper examines the properties of Australian indigenous crude oil and the changes to Australian refinery process- ing required after the Gippsland crude finds in the late '60s. In addition the paper details the dif- ferent crudes available to Australian ref ineries and the relative product yields in relation to Australian crudes. Market demand for petroleum products both now and in the future is then related to the products yields. The paper also examines the impact of the OPEC induced crude price spiral and the subsequent changes in refinery engineering, current and projected market demands, and energy conservation measures both inside and outside the industry.

Jan 1, 1982

FOR some years after the erection of the first chlorination plant at Mount Morgan the ore sent to the works for treatment was mined entirely from the oxidized zone; consequently, the bullion recovered at the refinery was of unusual purity, averaging about 972 in fineness, and, as no impurity in any way detrimental to the softness or toughness of the bullion was present, there was no necessity to subject it to any refining process.The charcoal from the filters was calcined to ash in small reverberatory furnaces of the usual type. The ash was mixed with suitable proportions of soda and borax to form a good liquid slag. This' mixture was then charged into salamander cruciblesand run to metal and slag in the ordinary wind furnaces-a slow and tedious proceeding in the Mount Morgan climate. The bullion, cleaned of slag, was re-melted under borax and poured into bars weighing from 350 to 400 oz.; these bars, after being dipped while hot into dilute sulphuric acid, were packed and sent to the mint. Of late years, however, the ore coming from the deeper ground of the oxidized zone became much lower in gold values, and contained variable but increasing quantities of sulphides, sulphates...

Jan 1, 1911

By Robins R. G

The dissolution of metallic copper powder in aqueous solutions of cupric sulphate under the influence of ethylene gas was investigated. The dissolution reaction stoichiometry obtained was: Cue+(aq) + Cu(s) + 2C2H4(g) = 2(CuC2H4)+(aq) The rate of formation of the copper (I)-ethylene complex in the above reaction was studied in a laboratory autoclave and the effect pH, temperature, ethylene partial pressure and initial concentration on the dissolution rate was measured experimentally and expressed theoretically in terms of several simple conceptual kinetic models. The results led to the selection of optimum conditions for the reaction and the suggestion of an "ion-molecule reaction" mechanism to explain the very low activation energies for the reaction system. The area of application of this reaction lies in the direction of refining impure copper such as cement copper. Several experiments were performed in which an acidified solution of cupric sulphate under ethylene pressure was used to dissolve copper from the cement copper powder in the form of the copper (I)-ethylene complex, followed by the release of gas pressure to disproportionate the complex and precipitate a purer metallic copper.

Jan 1, 1987

ecent work on decoppering lead is reviewed; CuS is formed rapidly even from dilute solutions of copper in lead. he mechanism of decoppering is discussed, and an explanation for the retention of metals such as silver in lead is dvanced. As decoppering tin appears to be an analogous process, the Cu-Sn-S system is studied at 300¦C. CuS, hich is not, an equilibrium product, is found in decoppering drosses. In the removal of nickel from lead, Ni3pb2S2 formed; preliminary measurements show the equilibrium nickel content to be greater than that obtained by tirring in sulphur. Decoppering bismuth is thermodynamically favoured, but is complicated by the occurrence of uBiS2. The Cu-Pb-S system is the only one of the four studied where the equilibrium can be calculated simply, as ' resence of ternary sulphide or other phases invalidates calculations based on binary data.

Jan 1, 1970

Recent work on decoppering lead is reviewed CUS is formed rapidly even from dilute solutions of copper in lead. The mechanism of decoppering is discussed and an explanation for the retention of metals such as silver in lead is advanced. As decoppering tin appears to be an analogous process, the, Cu-Sn-S system is studied at 300°C.. CuS, which is not an equilibrium product, is found m decoppermg drosses. In the removal of nickel from lead, Ni3Pb2S2 is formed; preliminary measurements show the equilibrium nickel content to be greater than that obtained by stirring in sulphur. Decoppering bIsmuth IS thermodynamically favoured, but is complicated by the occurrence of CuBiS2 The Cu-Pb-S system IS the only one of the four studied where the equilibrium can be calculated simply, as the presence of ternary sulphIde or other phases invalidates calculations based on binary data.

Jan 1, 1971

By Senanayake G

A sample of crude copper powder produced by the CLEAR Process was refined by dissolution and recovery in sulfate media using the Parker Process. The Parker Process offers an alternative method of copper recovery to electrorefining and allows a range of Eh and pH conditions to be used to provide further discrimination of impurities. High purity copper powder was recovered by the Parker Process even in the presence of added impurities when the Eh and pH was maintained near constant throughout the refining step.

Jan 1, 1984

By Kajioka H, Nakamura Y

Na2CO3 is a powerful flux for both dephosphorization and desulphurization in oxidizing atmospheres. In order to study refining with Na2CO3 and the nature of the Na2CO3 slag itself, hot metal (4Kg) was melted in Al203 crucibles in a high frequency induction furnace and oxidised with oxygen under Na2CO3 slag. The behaviour of Na2CO3 at high temperature was observed by thermobalance. It was found that dephosphorization ceases in a few minutes and [,P] after refining is easily lowered to less than 0.010%. [%P] after refining is affected by [Si], [P] of hot metal, the refining temperature and the consumption of Na2CO3. Desulphurization also ceases in a few minutes but it shows curious behaviour, increase of [S], decrease of (S) and increase in sulphur lost, during the latter half of run. [%S] after refining is also affected by [P] of hot metal, the refining temperature and the consumption of Na2C03o

Jan 1, 1980