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By J Wen, P Hou, W Yu, M Hu, Z Jiang, C Bai

Vanadium titano-magnetite (VTM) is one of the important iron ore resources in the world. High viscosity and low fluidity are the basic characteristics of hot metal containing vanadium and titanium during the ironmaking process. Clarifying the influencing mechanism of the melt viscosity would be a significant issue for the high efficiency smelting of VTM. In this paper, a self-developed melt viscometer based on the principle of torsional vibration theory was employed to measure the viscosity of hot metal accurately. Simultaneously, the thermodynamic calculations and some modern detection methods were also used to investigate the precipitation behaviour of high-melting-point phases in hot metal containing vanadium and titanium. The measuring results show that the viscosity of molten iron gradually increases with the increase of titanium content when the mass fraction of titanium is between 0.09 wt per cent – 0.50 wt per cent. Meanwhile, the viscosity of the hot metal was affected significantly by the vanadium content. When the vanadium mass fraction was higher than 0.30 wt per cent, the viscosity of hot metal increased sharply, which will have a serious impact on the fluidity of the hot metal. Furthermore, it was revealed by thermodynamic calculations that an increase in titanium and vanadium content would result in the precipitation of high melting point phases such as TiC, TiN, VC, and VN in the molten iron, ultimately resulting in a decrease in its fluidity. Meanwhile, it was confirmed by Scanning Electron Microscope (SEM) observation that the precipitates in the hot metal were compounds consisting of V, Ti, C, and N elements, which agrees well with the thermodynamic analysis results.

Aug 21, 2024

By S-C Shim, H-R Lee, Y Kang, H Shin

Since iron oxide and silicon oxide are major gangue components in various types of ore, FeO-SiO2 base slag, ie fayalite slag, has been often encountered in pyrometallurgical processes of non-ferrous metals. During most matte production processes such as the smelting of Cu, Pb, and Ni, the FeOSiO2 based slag is inevitably formed and plays an important role in refining crude metal as well as engineering aspects. Recently, similar pyrometallurgical approaches have been attempted in the recovery of valuable metals (Ni, Co, Cr) from wasted secondary batteries. Thus, the viscosity of the FeO-SiO2 based slag has great significance in properly controlling smelting processes. However, when molten metal or matte does not coexist with the slag during the measurement, there has been a serious difficulty in maintaining Fe valance and consequently, the slag composition. In the present research, the viscosity of molten FeO-SiO2 slag was measured in 1573~1673 K using a rotational viscometer. In order to keep the state of iron oxides, the oxygen partial pressure was controlled using CO/CO2 gas mixture. The optimised ratio of CO/CO2 could be calculated using Fe/Fe2+ and Fe2+/Fe3+ equilibria at each temperature. The composition of the slag, particularly Fe valance, after the measurement was analysed with the aid of an inductively coupled plasma – optical emission spectroscopy (ICP-OES) and an automatic potentiometric titrator. The measurement showed that the FeO-SiO2 slag has considerably low viscosity values in the molten state, and it sharply increases as the temperature decreases. In spite of the careful oxygen partial pressure control, a part of Fe2+ was found to be oxidised to Fe3+, with a maximal case reaching about 20 per cent. The increase in viscosity of FeO-SiO2 at low temperatures can be attributed to the composition change due to an unavoidable Fe2+ oxidation. In addition, the relationship between the change in the viscosity and the liquidus temperature of FeO-SiO2 based slag was discussed to understand the composition dependence of viscosity.

Jun 19, 2024

By E Jak

A viscosity model has been developed for both completely liquid and heterogeneous, partly crystallised slags in the Al2O3-CaO-æFeOÆ-SiO2 system in equilibrium with metallic iron. The Urbain formalism has been modified to describe the viscosities of the liquid slag phase over the complete range of compositions and a wide range of temperatures. The Roscoe equation has been used to describe the effect of presence of solid suspension (slurry effect) on the viscosity. The parameters of the viscosity model were optimised to describe large experimental data set in the low-order subsystems, as well as in the multi-component system. The computer package FACT was used for prediction of the proportion of solids and the composition of the remaining liquid phase. The model provides a good description of the experimental data (over four thousand experimental points) in liquid phase, and liquid + solid mixtures, over the complete range of compositions and a wide range of temperatures. This model can now be used for viscosity predictions in industrial slag systems. An example of the application of the new model to slag cleaning and reduction smelting processes is given in this paper.

Jan 1, 2000

By R G. Reddy, Z Zhang

Viscosities of CaO-aluminosilicate ternary melts were estimated using a structure-based model. The model considers depolymerisation effects and related breakdown of the silicate network structure on the addition of metal oxides to the melts. The predicted values are in good agreement with the experimental values over the whole temperature and composition range.

Aug 21, 2024

By Y Mita, T Iwama, R Inoue, S Ueda

In the iron and steel manufacturing industries, efforts are being made to achieve carbon neutrality by 2050, and the transition from a coal-based steelmaking process to that utilising renewable energy is being pursued. An alternative process in which directly hydrogen-reduced iron is melted in an electric furnace is being investigated. It is known that foaming slag reduces heat loss from the steel bath in electric arc furnace, but iron loss due to the suspension of steel particles in the slag is indispensable. To improve the separation of steel particles from the slag, the control of the slag viscosity is important. Although the slag viscosity has been extensively studied, in those studies the slag was considered to be a simple liquid. However, in actual operations, slag is a multiphase fluid consisting of solid, gas and liquid phases. Therefore, in this study, by measuring the sedimentation velocity of titanium, stainless steel and glass spheres in an aqueous glycerin solution containing bubbles generated by the reaction between NaHCO3 and C2H2O4, the apparent viscosity of the gas-liquid fluid was evaluated based on Stoke’s law. It was found that the apparent viscosity of the gas-liquid fluid is larger than the viscosity of liquid phase and depends on both the bubble volume ratio in solution and the density of the falling solid sphere, and the apparent viscosity was different from that previously obtained by the rotation method. The apparent viscosity derived from the sedimentation velocity of solid spheres changed depending on the specific gravity of the ball. This is because the apparent viscosity is derived from the velocity of a ball falling in a static bubble in this method, whereas that is derived from the force applied by a stationary flow in the rotational method.

Aug 21, 2024

By D Giurco

This paper presents the results from research undertaken in the CSIRO-funded Mineral Futures Collaboration Cluster on developing a future vision for the mining and minerals industry – Vision 2040 – in which the industry proactively contributes to long-term benefit for communities and the nation. Our research finds that Australia is currently experiencing mining-led prosperity due to high commodity prices, yet underlying this are challenges for maintaining market share due to lower productivity from extracting lower grade, more remote and complex ores. Whilst much focus has been on developing new technologies for finding and processing such ores, this paper assesses these activities, together with policy and market innovations in the context of needing to strengthen social, environmental and financial capital for long-term benefit. Vision 2010 sees mining activities linked to systems that are net providers of clean water, energy and ecosystem services, rather than minimising negative impacts alone; sovereign wealth funds are used to harness current prosperity for future innovation. Using a case study in lithium and comparisons to iron/steel, coal and copper – we illustrate the opportunities for new technology, policy and market innovations to link the mining and minerals sector in Australia to more sustainable patterns of production, consumption and prosperity.

Nov 22, 2011

To carry out its responsibilities the SECV needs to manage the visual environment effectively. Every land oriented decision effects what we see and the value in pursuing visual excellence is supported by informed opinion, widespread community interest and evidence of cost- effectiveness.By knowing how we perceive the landscape and then changing or conserving it we can assist in fostering a positive mental image of a countyside which is welcomed by the local and regional community.It is useful to examine key design elements and the value we place on visual impressions in relation to three significant SECV rehabilitation projects, at Loy Yang, Newport and Morwell Open Cut.

Jan 1, 1992

By J Seery, N Savage, A Wilson, L Nicholas

Geological modelling provides a means of spatially representing the three dimensional distribution of geological information to downstream stakeholders. The geologist completing the modelling work intimately understands the varying degrees of confidence, assumptions and extrapolation required to honour the data. Geological models are often taken and used by stakeholders without fully understanding this modelling process. This can lead to confusion amongst stakeholders when the geological model shows variable reconciliation. A method for visually communicating the confidence of the spatial distribution of geological models has been created by the Rio Tinto Iron Ore structural geology group for use primarily in geotechnical engineering investigations. A numeric confidence rating is assigned to each geological data point used in the creation of a geological surface. This is based on data type, collection method and reliability to indicate potential error in distance from its modelled location. In regions of sparse data, confidence ratings are inserted based upon the geologistÆs experience and knowledge of the geology, whereas mapped geological contacts or drill hole intersections are assigned a higher confidence rating. A regular grid of points is registered to the geological surface and each of these grid points is assigned a confidence rating using an inverse distance weighting using a nearest neighbour approach. The resulting grid is colour coded according to the confidence rating to provide a visual representation of the variable confidence of the geological surface in three dimensions. Subjectivity and bias from the geologist is minimised by critically analysing the input geological data and then applying this methodology to represent the confidence in the spatial characteristics of geological models. Understanding of this confidence enables mining professionals to make informed decisions and identify areas that require further geological investigative work. CITATION:Savage, N, Nicholas, L, Wilson, A and Seery, J, 2013. Visual communication of geological confidence - a move toward a less subjective approach, in Proceedings Iron Ore 2013 , pp 169-174 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

Visual computing opens the design process to a wider audience and allows rapid communication of mine plans to all stakeholders. The integration of software and hardware technologies that take advantage of a graphical environment will continue to improve both long-term and short-term mine design (Figure 1). A good design must be adaptive to respond to decision changes as the mine develops and more information becomes available. The constraints on mine design predicate careful analysis in order to operate the mine as efficiently and safely as possible.Continuous improvement in mining is assured by developing innovative technologies that target mine survey, drill and blast, modelling, short-term design and pit and stope optimisers. The design life of a mine has to be sufficiently long to ensure the mine is commercially successful, justifying the high start-up capital costs. Being able to execute a plan so that it honours the design realises the rewards of computerised mine planning and the long-term investment in data acquisition.

Sep 26, 2011

By S Mitra, D O’Dea, N Barrett, T Honeyands, E Copland

This work describes a novel mapping technique that allows the direct overlay of calculated local phase equilibria on micrographs of the physical system. The technique demonstrated integrates FactSage™, ver 8.2 (by Thermfact Ltd. and GTT-Technologies) phase equilibria calculations with mapped compositions determined by Scanning Electron Microscope – Energy Dispersive X-ray Spectroscopy (SEM-EDS) to visually express calculated properties while preserving the spatial information of the sample. The developed methodology is used to analyse interrupted blast furnace softening and melting tests containing mixed burdens of lump and sinter. Tests are interrupted at 1300C and cooled to room temperature for analysis. Phases present at room temperature are analysed to infer the liquid fraction and phases present at high temperature. Analysis of the interface regions between the dissimilar burdens allows insights to be gained into the interaction mechanism. During the transition from solid to liquid, migration and interaction of liquid oxide across the interfaces of the dissimilar burdens has been observed and demonstrated to impact softening and melting performance. Specifically, interaction of the oxides generated by lump (primarily FeO, SiO2 and Al2O3) and sinter (primarily FeO, CaO, SiO2, Al2O3 and MgO) are analysed, and the occurrence of a range of new mineral phases such as merwinite, melilite, olivine and bredigite observed.

Jun 19, 2024

By S Withell, K Sheehan

Whitehaven Coal (WHC) is undergoing a transformative journey, deeply committed to the principles of a High Reliability Organisation (HRO) and the establishment of a mature, interdependent culture founded on psychological safety. This ongoing commitment is not merely aspirational but is supported by performance improvements backed by both quantitative performance data and qualitative evidence of cultural progression. WHC has strategically integrated leading and lagging indicators to target fatal risk. WHC focus areas include an emphasis on strategy and risk appetite, targeted data, informed learning, proactive addressing of fatal risk and the integration of data management and technology.

Apr 16, 2024

By H Mali, B Kain-Bückner

Different types of lump iron ore-bearing particles were investigated in terms of their raw material properties depending on their behaviour during reduction. To predict the reduction behaviour different types of lump iron ore and pellet brands were characterised by their mineral abundance, texture and pore size. The image processing software VisuMet was developed to semi-automate the evaluation of photomicrographs from polished sections of lumpy iron particles. The results were compared to the standard reducibility test after ISO 4695. The evaluation of lump iron ores is based on the simulation of the transformation of the different iron minerals due to their sequence of reducibility. The progress of the reduction front is simulated and the result is a degradation curve. Pellets were also investigated due to their different pore size distribution. The results indicate that the pore size influences the reducibility in addition to mineral abundance. The evaluation with VisuMet of the lump iron ore and pellet samples correlates with the reducibility provided by the ISO 4695 test. The determination of the mineral abundance by VisuMet is comparable to common point counting with a correlation coefficient of 99.67 per cent.CITATION:Kain-Bückner, B and Mali, H, 2017. VisuMet – analyses of lumpy iron carriers with image processing, in Proceedings Iron Ore 2017, pp 557–560 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Paterson M. R, Spencer P. A

Vitrokele technology is a resin process that can be applied in gold plants to reduce both capital and operating costs. The Vitrokele resin can be used for both precious metal recovery and for recovering free and combined cyanide from effluent streams. Vitrokele resin has been extensively tested at pilot plant level and is now applied successfully at a commercial heap leach facility in Zimbabwe where it is used in place of activated carbon for recovery of gold from pregnant leach solution. Significant capital cost savings were achieved by installation of a resin plant instead of a conventional carbon adsorption plant. Operation to-date has not seen any significant physical or chemical degradation of the resin either in terms of adsorption capacity/kinetics or physical appearance/size. This gold recovery process is equally applicable to slurry streams where it would be implemented in stirred tanks with interstage screens in a similar manner to a conventional carbon adsorption plant.

Jan 1, 1996

By J Player, P Mikula, G Sweby

A numerical modelling back-analysis exercise was carried out at a WA gold mine at which early signs of seismicity (rock noise, scatts from active faces) were becoming apparent as depth of mining increased towards the 500 m mark. Some strain bursting had occurred and it was necessary to discover what the implications of this were for greater depth. The aim of the modelling was to: 1. Establish a correlation between observed ground conditions and model predicted damage, in overstressed areas of the mine. 2. Use this correlation to forecast rock mass damage and ground control requirements for proposed future stoping panels at greater depth. Good correlation has been achieved between observed rock mass damage, and a 3D Finite-Element RS3 model, run in elastic mode. Two candidate stress field orientations were modelled. The model parameter best fitting the observations was the Strength Factor (SF), the ratio of strength/stress. The good match (correlation coefficient of 0.7) between observed and modelled suggests that the elastic approach is justified for the depth range and rock mass properties analysed. The correlation also enabled a link between observed damage and installed ground support performance. Using the linear best-fit between observed and modelled, a forecasting exercise was carried out using the same RS3 model, modified to include future stoping. The resulting damage and ground support categories were obtained from the modelled SF for each proposed stoping level. Also, a series of generic geometries was assessed to investigate the impact of varying stope face lead/lag distance, sill pillar height and stope pillar size, on ground conditions. The key finding of the generic geometries were: • Ground support schemes have been defined for the expected conditions. • All ore drives are expected to have significant damage in the backs and rehabilitation. • Lead/lag distance not to exceed 10 m. • Sill pillar/level intervals of less than 20 m require an increase in ground support scheme. • Pillar sizes for maintaining footwall and hanging wall stability should be at least 10 m × 5 m.

Nov 29, 2022

By Finlayson EJ

Epithermal gold is hosted by late Middle Miocene Okiduse Volcanics on Woodlark Island. Dating of associated alteration minerals indicate mineralisation to be broadly contemporaneous with volcanism (12.2 - 12.5 m.y.) and is probably related to subduction of the Solomon Sea plate along the Trobriand Trench. Mineralisation is polymetallic and structurally controlled. Pyrite, sphalerite, galena and minor chalcopyrite occur in steeply dipping fracture zones and/or hydrothermal breccia bodies associated with mixed clay-pyrite alteration envelopes. These envelopes occur within a terrane of regionally propylitised high-K, calc-alkaline andesites and related epizonal subvolcanics. Gangue minerals include quartz, calcite, dolomite and minor anhydrite. High level advanced argillic alteration and siliceous cap rocks are not present but may have been eroded off the top of the system. Fluid inclusion and stable isotope data suggest that the carbonates and paragenetically associated auriferous base metal sulphides probably deposited from an isotopically evolved (+8%. 180) reduced hydrothermal fluid sourced from underlying sedimentary rocks. The fluid was predominantly of low salinity (0-4 wt % NaCl equivalent) and had a temperature of about 270¦C at the time of boiling and mineral deposition.

Jan 1, 1987

By C J. N Wilson

The central Taupo Volcanic Zone is a region of intense Quaternary silicic volcanism accompanying rapid crustal extension. Modem central TVZ is the most frequently active and productive silicic volcanic system on Earth, erupting rhyolite at c.0.28 m3 s-1. The rhyolites show no major compositional changes with time, but the total extent of magma chamber zonation has changed with the advent of rifting and crustal extension at c.0.7 Ma. At least 34 caldera-forming ignimbrite eruptions have formed a complex sequence of relatively short-lived, nested and/or overlapping volcanic centres in central TVZ. Taupo contrasts with other large silicic magmatic systems in the exceptionally high frequency, but small size, of caldera forming eruptions. This contrast reflects the thin, rifted nature of the TVZ crust that precludes the development of long term magmatic cycles at Taupo. Within central TVZ, non-rhyolitic compositions have been erupted apparently irregularly in time and space; in particular there is no evidence for a geographic separation of basalts from andesites. TVZ is a rifted arc, but its segmented nature, high thermal flux and voluminous rhyolitic volcanism make it unique on Earth.

Jan 1, 1995

By Wilson CJN

The central Taupo Volcanic Zone is a region of intense Quaternary silicic volcanism accompanying rapid crustal extension. Modem central TVZ is the most frequently active and productive silicic volcanic system on Earth, erupting rhyolite at c. 0.28 m' s'. The rhyolites show no major compositional changes with time, but the total extent of magma chamber zonation has changed with the advent of rifting and crustal extension at c.0.7 Ma. At least 34 caldera-forming ignimbrite eruptions have formed a complex sequence of relatively short-lived, nested and/or overlapping volcanic centres in central TVZ. Taupo contrasts with other large silicic magmatic systems in the exceptionally high frequency, but small size, of caldera- forming eruptions. This contrast reflects the thin, rifted nature of the TVZ crust, that precludes the development of long- term magmatic cycles at Taupo.Within central TVZ, non-rhyolitic compositions have been erupted apparently irregularly in time and space; in particular there is no evidence for a geographic separation of basalts from andesites. TVZ is a rifted arc, but its segmented nature, high thermal flux and voluminous rhyolitic volcanism make it unique on Earth.

Jan 1, 1995

By D M. Aranha, A R. Cabral

Theories on the origin of the Itabira iron formation (itabirite) in Quadrilßtero Ferrffero (QF), as elsewhere in the world, are restricted by the apparent lack of adjoining volcanic units, severe syndeformational metamorphism and deep weathering. Besides the three types of iron formations at QF (siliceous, dolomitic and amphibolitic; Dorr, 1969) we include a fourth type initially described as ocherous, goethitic, limonitic or even yellow iron formation. Considering its high magnetite content, it has been described as yellow magnetite itabirite (Pires, 1979). It was reported as formed by the alteration of the dolomitic itabirite (Dorr, 1969) although the anomalous Al2O3 contents are high for normal weathered itabirite. The yellowish magnetitic itabirite occurs at the bottom of the Itabira Iron formation, along the contact with the Batatal schists, and at the top units of the Itabira, within the Gandarela Formation. Within the magnetitic itabirite at the Tamanduß iron ore mine there are metric zones, concordant to the bedding of pillow-like structures, exhibiting a porous core, surrounded by an intermediate, more granular zone with numerous, minute rounded cavities grading to an external, fine-grained zone with much less minute cavities. In the external portions of some pillows a breadcrust type structure, derived by quenching with the water can be observed. In some other zones, such as the Barreiro hill, an outer, vesicular, whitish yellow, 5 - 10 mm thick, band grades to an aphanitic, isotropic band. The vesicles are slightly flattened against the band surfaces. The existence of fragmental layers showing flowage and fragment alignment, kaolinitic laminas and vesicles filled with kaolinite at Barreiro Hill and Capitpo do Mato Mine represent mesoscopic structures, indicators of a possible volcanic origin. Chemical compositions of the magnetitic itabirite from a wide area in QF revealed a relatively high Al2O3 content, consistent with a volcanic origin.

Jan 1, 2005

By Whitford DJ

A distinct zonation occurs in the nature of submarine volcanic activity associated with westwards propagation of the Woodlark spreading system into continental crust. Olivine tholeiites (Type I MORB) flooring one spreading segment in the Eastern Sector of the Western Woodlark Basin are accompanied by more evolved "ferrobasalts". Basaltic andesites and Mg-poor andesite-dacites occur on axial and flanking seamounts respectively. In the Western Sector, Mg- and K-rich olivine andesites occur in a rift valley and on an axial seamount near the tip of the propMr/8 tig rift. Observed correlations between 6Sr ratios (0.7028-0.7041), REE patterns and K contents imply a complex petro- genesis with the relative importance of mantle heterogeneity and crustal contamination difficult to resolve.

Jan 1, 1987

By P G. Rutherford, A W. McOnie

A volcanic sequence is described from the Golden Cross Mine, Waihi, New Zealand. The sequence includes seven lithostratigraphic units comprising flow and pyroclastic units of Coromandel Group andesite and dacite and overlying Whitianga Group dacite and rhyolite which is intruded by the Golden Cross dacite porphyry and rhyolite dykes. The sequence is mineralised and is unconformably overlain by two post-mineral units, the lacustrine Waitekauri beds and Omahine Subgroup andesite.   Detailed structural analysis of mine data has identified four deformational events (D 1-D4) and related these to the gold-silver mineralising events. Faulting was coeval with the mineralization and directly controlled the development, localisation, style and geometry of the ore shoots. Mineralization developed in competent lithologies where dilation occurred during faulting. The Empire Fault is the master shear which controlled fluid flow. Mineralised veining developed in response to tectonic pulses occurring at slightly different stages as represented by the underground Empire vein complex and the open pit vein array. The mineralising events culminated with the deposition of barren calcite veins. Post-mineral movement along the Western Boundary fault appears to have offset the orebody.

Jan 1, 1995