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By F P. Hao

Organo-sulphur-based collectors (eg xanthates, dithiocarbamates and dithiophosphates) are widely used in the flotation of sulphide minerals. Xanthates (ROC(=S)Sû), for example, adsorb strongly at sulphide mineral surfaces, in a reaction that is electrochemically coupled with the reduction of dissolved oxygen. One of the oxygen reduction products, hydrogen peroxide, reacts directly with dissolved xanthate, leading to its oxidative decomposition. Experimental work has been conducted, using ethyl xanthate, to understand the molecular mechanism by which hydrogen peroxide reacts with xanthates. A number of degradation products have been identified, some of which have not been reported previously. This oxidative decomposition reaction pathway is discussed in the broader context of xanthate decomposition in flotation systems. One of the identified ethyl xanthate decomposition products, ethyl perxanthate (ROC(=S)SOû), has been observed in the process water of a number of mineral processing operations. The interaction of this molecule with goethite (α-FeOOH) particles, typical of that found in tailings dams, has been studied in more detail using attenuated total reflectance (ATR)-FTIR. The ethyl perxanthate molecule has been found to coordinate to iron (FeIII) at the goethite surface, and undergo a surface-catalysed decomposition process. In the presence of both PbII and goethite, a ternary surface complex is formed, where ethyl perxanthate is coordinated directly to surface adsorbed PbII atoms. The results obtained give some insight into the environmental fate of ethyl xanthate in tailings streams, and a basis on which to consider the environmental importance of such species in tailings dams. Strategies for the destruction of residual xanthate levels in waste water streams are discussed in terms of the likely reaction products.

Jan 1, 2002

Generation and Attachment of Submicron Size Bubbles to Colloidal Solids

Sep 13, 2010

On Kinetic Coupling in Meso-Scale Phenomena in Mineral Froth Flotation

Sep 13, 2010

By M Simpson

Greywackes of the greater Auckland Region (Brynderwyn Hills to Hamilton), when considered on a regional scale, have characteristic ranges of physical, mineralogical and other properties. Some properties (eg density, porosity, crushing resistance, clay index) generally cluster and correlate with the basement greywacke facies, regions and terranes recognised by geologists, and their diagenetic/metamorphic level. Other local factors, particularly variations in mineralogical composition, nature of matrix cement, grain size, and degree of weathering may produce aberrant properties. Some of these local variations, when extreme, have the potential to affect the aggregateÆs performance in roading or the concrete industries.   Smectite and the zeolite laumontite are the major deleterious minerals occurring in fresh greywacke rocks of the Auckland region, although weathered rocks may contain halloysite, an expanding member of the kaolin clay mineral group. These minerals, when found in abnormally high levels in greywackes cause expansion effects in the aggregate. Currently there are inconsistencies in the detailed correlation of shrinkage, clay index, clay mineral content and intrinsic expansion data that need further research to resolve them.  

Jan 1, 2007

The Australian Mineral Industry's growth in the last two decades is directly related to the skill and experience of its consultants in mining, metallurgy, geology, finance, management, marketing, and engineering. The role of mining consultants needs to be re-examined, so that the quality of the service they deliver will continue to be adequate for the 1990's. One means of this evaluation is by examining Case Studies in the strategies and difficulties of developing contract and entrepreneurial research.

Jan 1, 1986

By A Murphy, I Samsonova, N Eastwood, D Whittle

Part XI of the United Nations Convention on the Law of the Sea (UNCLOS or the Convention) (United Nations (UN) Division for Ocean Affairs and the Law of the Sea, 1982) establishes a comprehensive regulatory framework for the conduct of deep seabed mining (DSM) activities of mineral resources in the Area (defined in Article 1(1) of UNCLOS as ‘the seabed and ocean floor and subsoil thereof, beyond the limits of national jurisdiction’). Under that framework, DSM activities can only take place in the Area pursuant to an approved Plan of Work in the form of a contract with the International Seabed Authority (ISA) (the Authority), a 168-member international body created under UNCLOS to administer the Area. Private contractors can undertake DSM activities if they are sponsored by Member States of UNCLOS, providing a dual system of international and domestic regulatory control and oversight for activities in the Area.

Sep 1, 2024

By R L. Brathwaite

The gold-scheelite-quartz lodes of the Wakamarina valley were the most productive of the mesothermal gold-bearing areas in the Marlborough Schist. Most of the production came from the Empire City and Golden Bar mines which worked the Golden Bar lode. Only 134 m of its 1800 m strike length are accessible, in the No.2 level of the Golden Bar Mine. A fault has downthrown the Golden Bar Mine section by = 47 m and displaced it left-laterally by 18 m. The lode is a typical ribbon-banded mesothermal vein, averaging c. 1.75 m wide, and enclosing narrow horses of schist country rock. It is composed of bands of milky æbuckÆ quartz with thin laminae of schist. Scheelite occurs in short strings of grains within quartz on the footwall side of the lode and also in small quartz-carbonate veinlets in the foot wall and hanging wall schist. The lode quartz contains only localised traces of pyrite and arsenopyrite. They are more abundant in the wall-rock schist.   The Golden Bar lode lies within a steeply dipping normal fault, which, on its footwall side, is adjacent to a 40 m-wide, shallow-dipping mylonite shear zone. Within 1 m of the lode, the shear foliation has been dragged down to nearly parallel the lode footwall. Wall rock alteration is manifested by a marked increase in K and Rb, which correlate with abundant illite/muscovite and K-feldspar within 2 m of the footwall of the lode. Amphibole, stilpnomelane, and pumpellyite show a progressive decrease towards the lode. As and Sb increase close to the lode, but are at background levels within the lode itself. Enhanced Cr (150-430 ppm) in the quartz, relative to the schists (~40 ppm), suggests that the source hydrothermal fluids passed through and leached mafic rocks, such as the metabasites from the hanging wall of the lode (~400 ppm Cr).

Jan 1, 1995

FOR many years past it has been the practice at the Bairnsdale School of Mines to treat any parcels of auriferous concentrates sent in from the surrounding district by roasting them in a handworked reverberatory, and then chlorinating or cyaniding the product. According to Donald CIark, who has done a large amount of work on these ores, the results obtained were fairly satisfactory extractions of over 90 per cent being claimed. With some modifications, the method has been very generally adopted, not only in Gippsland but throughout Victoria. It is, however, difficult to get exact information as to the extractions actually obtained, and unfortunately no records of working results have been kept at the Bairnsdale School of Mines.Having treated several lots of ore by this method during 1907 and 1908 with unsatisfactory results, the writers thought it desirable to make a detailed investigation on some particular ore, both in the laboratory and on a working scale. The ore selectedwas a parcel of low-grade concentrates from Stirling, a small mining field situated about forty miles to the east of Bairnsdale. This ore was chosen chiefly on account of the heavy and inexplicable volatilization loss which took place even on roasting with the greatest care; the loss amounting to between 10 and 15 per cent. In the experiments here related, three main objects were kept in view:-1. To determine with what mineral 01' minerals the gold and silver were associated...

Jan 1, 1909

The magnesite deposits near Young, N.S.W., occur in decomposed serpentine rock below a soil. and alluvial cover. They show considerable variation in both quality and depth which greatly hampers mining operations. Seismic refraction techniques afford methods of conducting detailed and reconnaissance surveys which yield a depth and velocity analysis of the serpentine/magnesite refractor. The measured seismic velocities may be used as an index of the presence and quality of the deposits. The Seismic Timer which was used in the test surveys is a simplified seismograph which makes use of seismic reciprocity by replacing the conventional seismic shotpoints with geophone stations and the conventional geophone stations with impact points of a sledge hammer. Thi,s enables the use of detailed seismic refraction techniques which yield the depth and velocity analysis of the refractor.INTRODUCTIONThe magnesite deposits near Young, N.S.W., were produced by a process of leaching and enrichment of magnesium in serpentine rock. The magnesite occurs in nodular form emplaced in decomposed rock at shallow depths below soil and alluvium. The depth ranges from close to the surface down to some tens of feet. The deposits are patchy and show considerable variation in both quality and depth, giving riseto considerable difficulties in mining operations.Due to the thorough leaching of the surface material, geochemical tests carried out so far have not proved satisfactory for locating the pockets of magnesite enrichment.It was decided to test the application of detailed shallow seismic refraction methods to the investigation of both the depth and quality of the deposits. The tests were carried out...

Jan 1, 1962

Study on a Novel Polymer/Bentonite Compound Adsorbent for Removal of Cu(II) from Aqueous Solution

Sep 13, 2010

By A Giblett, T J. Napier-Munn

This paper presents the results of a test program evaluating the impact of sample mass on the precision of Stage 1 gravity recoverable gold (GRG) test results. Four ore types ranging from low to high GRG contents were the focus of testing. A method to predict the influence of sample mass on the confidence limits of the Stage 1 GRG test result is demonstrated. The results suggest that although small samples tend to overestimate Stage 1 GRG in samples with low gravity gold values due to higher mass pull to concentrate, such samples can give acceptable estimates of the Stage 1 GRG content with focussed sample treatment protocols.CITATION:Giblett, A and Napier-Munn, T J, 2015. Measuring the influence of sample size on the precision and accuracy of gravity gold estimation, in Proceedings MetPlant 2015, pp 367–372 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

Recovery of Vanadium from Stone Coal Through an Environmentally Friendly Acid Leaching Technology

Sep 13, 2010

In the first half of this century a mining industry was developed in Indonesia under Dutch colonial rule. World War II and the subsequent struggle for independence resulted in the destruction of most of the infras- tructure and much of the data. After independence, restrictions on for- eign investment and internal turmoil prevented re-establishment of a viable mining industry until the formation of the present Government after 1965 and the enactment of sound laws in 1967 to encourage foreign investment. Rebirth of the mining industry was followed initially by slow growth, but in the 1980's, spurred by the worldwide interest in gold, Indonesia has become the focus of an intense exploration boom for gold and other precious metals. 103 Contracts of Work for gold have been awarded since 1985 with Australian companies being the most predominant. Since 1985 three new gold operations have been commissioned and another two are nearing completion. Several more are undergoing feasi- bility studies. There is reason to predict that Indonesian gold produc- tion will grow to place the country in the ranks of significant producers during the 1990's.

Jan 1, 1988

By J E. Lynch

The Weda Bay nickel and cobalt laterite deposits on Halmahera Island, Republic of Indonesia were first drilled in May 1996 by Strand Minerals Pte Ltd (Strand). Subsequent exploration has delineated four large laterite provinces, parts of which have been diamond drilled to outline an indicated nickel resource of 59.9 Mt of 1.51 per cent Ni and 0.09 per cent Co within a total indicated and inferred resource of 117 Mt of 1.36 per cent Ni and 0.12 per cent Co. The project is held as a Seventh Generation Contract of Work (COW) by PT Weda Bay Nickel, which is jointly owned by Strand (90 per cent) and PT Aneka Tambang (ten per cent). Strand is a wholly owned subsidiary of Weda Bay Minerals Inc, a company listed on the Toronto and Alberta Stock Exchanges in Canada. Halmahera is located in the north-eastern part of the Indonesian archipelago at the convergent junction of three major plates and is a region of considerable tectonic and geological complexity. The western arms of Halmahera form a classic volcanic island arc while the central region and eastern arms contain ophiolite complexes and interlayered sediments. The extensive areas of laterite discovered at Weda Bay have developed over serpentinised harzburgites and dunites of pre-Cretaceous age. Weathering of these rocks has produced laterite profiles that are enriched in nickel and cobalt. There are three economically mineralised laterite types, namely limonites, ferruginous saprolites and saprolites and all are amenable to rapid pressure acid leaching with recoveries of 98 per cent nickel and 94 per cent cobalt in less than 20 minutes.

Jan 1, 1999

The Role of Mineral Processing in the Development of Cement with Low Carbon Emissions

Sep 13, 2010

By K Cameron, S Strohmayr, J Wallace

In 2012, a single module heavy medium cyclone plant (HMP) was installed at the Glencore Zinc’s (then Xstrata Zinc) McArthur River lead zinc mine. The HMP formed the first part of the MRM Phase 3 Project to increase run of mine (ROM) capacity from 2.4 to 5.5 Mt/a.The purpose of the HMP is to remove liberated gangue from the crusher product at minimal loss of valuable mineral. The McArthur ores are very finely disseminated requiring a fine primary grind size prior to rougher flotation. Rejecting waste prior to grinding therefore offers significant power and grinding media savings. The plant was designed to treat only those ores with a reasonable upgrade ratio at the target zinc recovery across the HMP of 95%.On this basis, a 1.8 Mt/a single module plant was built based on 250 t/h feed rate and 82% availability. In contrast to existing base metal heavy medium plants in Australia, the MRM Flow sheet utilised the principles in modern coal heavy medium cyclone plant design. Since commissioning, the plant feed rate has been significantly increased and is now normally operated up to 540 t/h (dry basis).Although this throughput increase is partially due to debottlenecking work, it is also attributable to the conservative design parameters for base metal heavy medium cyclone circuits in comparison to those used in equivalent coal circuits.This paper discusses Flow sheet design and compares traditional base metal design parameters with those achieved at MRM and those of modern coal plants. It provides information on plant capital and operating costs and the net savings realised by its installation. In addition to power and grinding cost savings, the paper also highlights the savings in water through rejection of near dry waste and reduction of tailings pumped to the storage dam.CITATION:Wallace, J, Strohmayr, S and Cameron, K, 2015. McArthur River Mine heavy medium plant – the benefits of applying modern coal plant design principles to base metal heavy medium separation, in Proceedings MetPlant 2015, pp 311–323 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

By Trutwin W, Tracz J

The outbreak of open fires underground cause disturbances to the conditions of the mine ventilation process. Thermal and chemical effects due to fire create unsteady, transient states in airflow and the spread of combustion products in the mine ventilation network. Changes in airflow have an influence on the fire, constituting a sort of feed-back between the fire and the ventilation process. This paper deals with a numerical simulation method, which enables the determination of transients caused by fires. The mathematical model, of the simulation method considered, has been based upon a: simple model of combustion of fuel in the airway, unsteady exchange of heat between the fire, airflow and surrounding rocks, airflow in mine ventilation networks and the theory of heatflow in the rocks. Initial and boundary conditions allow the determination of a set of parameters describing the airflow, the propagation of combustion products, the tempera- ture of the fire and flow etc. due to the fire. The simulation method, facilitates a graphical presentation of the spread of combustion products throughout the network. The simulation method has been prepared for an IBM PC/AT Computer.

Jan 1, 1988

Optical sensors have emerged during the telecom boom in the late 1900s, due to the availability to low-cost telecom-grade optical components. It's only after the telecom industry's fall in 2004 that optical sensors became sufficiently developed to be a viable technology for real-world applications. Geotechnical applications have long relied on electrical sensors such as thermocouples, strain, and the venerable vibrating wire to measure physical phenomena. Although these are well suited for a large variety of applications, electrical sensors cannot be used for all applications: these are vulnerable to noise, hazardous voltages and corrosion, limiting the environments in which they can be used. In addition, electrical wires can also become an issue when sensors require external excitation or are distant from the measurement system. Finally, changes in physical properties of electrical sensors and systems over time makes regular calibration a necessity - not easy to do when these are permanently mounted on structures. Optical sensing systems are non-conducting and use light to perform various measurements. There are several optical sensor technologies available, each with different strengths and weaknesses. In addition, there are different methods of interrogating optical sensors, each of which also present different strengths and weaknesses. To make matters worse, configuring the interrogation and scaling to physical units can also be challenging to the unprepared engineer. This paper will present a holistic view of optical sensing, presenting the different optical sensor technologies and interrogation techniques. Sample optical sensing systems will be revealed and top considerations for optical sensing will be presented.

Nov 25, 2010

The transgressive sedimentary sequence of the Noumea Basin contains rhyolitic lavas and less voluminous mafic and intermediate volcanics of shoshonitic affinities which erupted simultaneously during the late Cretaceous. The shoshonitic volcanism shows a trend froIn early mafic to younger evolved intermediate lithologies. The rhyolites are consistently calcalkaline. There is no evidence of mixing of the two magma types. The shoshonitic volcanism is the result of a short-lived subduction event related to spreading in the New Caledonia Basin and involved reactivation of an earlier esozoic subduction zone.

Jan 1, 1995

Andesites are a major source of aggregate for much of the North Island of New Zealand. There are regional differences with respect to some important properties of the andesites. Some are reactive with cement and are designated as potentially deleterious or deleterious by the concrete industry. Other andesites, particularly those that are slightly altered or weathered, have rather high Plasticity or Clay Indices and perform poorly in road construction.   The performance of the andesites has been investigated and can be shown to be determined by: +        the chemistry of the rock which in turn determines the chemistry of the glass in the rock; +        the presence of large amounts of groundmass glass in the rock; and +        the nature of the superimposed alteration processes. Environment of extrusion and how rapidly the rock has been cooled or chilled are also important as they determine the fabric of the rock and how much glass will be present in the rock.   There are three main types of alteration that affect the quality of the aggregate: 1.   hydrothermal alteration, 2.   late magmatic alteration associated with the devitrification of glass, and 3.   weathering.   Each of these alteration types produces different alteration minerals. In fresh andesites the devitrification of glass has an important affect on the rockÆs properties. The Taranaki andesites are shown to have unusually (in comparison with other North Island andesites) high Na2O contents, held in the groundmass glass, which is the fundamental reason for the high alkali û silica reactivity of these andesites.

Jan 1, 2005