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By Parker A. J, Ruane M, Wadley L. G B

Copper, sulphur, nickel, cobalt, palladium, silver, and gold can be recovered from the copper sulphide precipitated from the "copper boil" of the Sherritt-Gordon nickel process used at Western Mining Corporation's Kwinana nickel <refinery. The method is based on an oxidative ammonia leach of copper, nickel, and the precious metals at temperatures below 40°C to produce, in part, elemental sulphur, in the residue. This is followed by heating to decompose thiosulphate and remove some ammonia with precipitation of some of the copper, palladium, gold, and silver. Addition of sulphur dioxide to pregnant liquor precipitates copper, as either Chevreul's salt or copper(I) ammonium sulphite, together with the remaining gold and silver. Less than 10 per cent of the dissolved palladium and less than 1 per cent of nickel and cobalt precipitate to this stage.In one option, the Chevreul's salt is dissolved in a solution of copper(II) sulphate, acetonitrile, and water to generate a solution of copper(I) sulphate. Gold and silver do not dissolve. The solution of copper(I) sulphate is thermally disproportionated by distilling acetonitrile to give exceptionally pure copper powder, with desirable characteristics for powder metallUrgy. Nickel, cobalt, and ammonium sulphate are recovered from the motherliquor of the Chevreul's salt precipitation by return to the Sherritt-Gordon process, where recovery procedures already exist. Palladium is recycled for eventual removal as a sulphide with the gold and silver.In the other option, solid copper(I) ammonium-sulphite is <thermally disproportionated in water at 150°C to copper powder.

Jan 1, 1978

By Boland J

Prediction of rock cuttability by various excavation machines such as tunnel boring machines, road headers, rippers, picks, roller disc cutters, excavators, etc is of major concern to both civil and mining engineers and rock mechanics. In principle, the design of a rock cutting tool is based on achieving maximum excavation with minimum input energy, minimum applied force, minimum equipment weight and volume and, more importantly, minimum tool wear. When a rock material is indented by the force of a cutting tool and then unloaded several material zones form underneath and around the tool. As the tool moves into the rock the volume of its associated rock cavity (ie volume of displaced rock) expands and depending on the indenter's shape various phenomena may occur. Immediately beneath the tool a small zone in which the stress state is more or less hydrostatic, is formed which is underlain by an inelastic, or damaged, material zone. Both size and shape of this damaged zone control the magnitude of the indentation force and the chip formation mechanism during unloading. The rock is unable to store the whole strain energy induced by the tool and consequently the extra energy is expended either in forming new fracture surfaces and/or in plastic deformation in the damaged zone. Therefore, it is not surprising to see that both perfect-elastic and rigid-plastic constitutive models are not generally suitable for modelling indentation of rocks. In contrast elastoplastic constitutive models are more appropriate as they can include both elastic and plastic deformations (Kral et al, 1993). Elastic solutions for several half-space indentation problems can be found in most text books on elasticity and in particular in Timoshenko and Goodier (1951), Sneddon, (1951), Poulos and Davis (1974) and Johnson (1985a). If a failure criterion, eg the Mohr-Coulomb failure criterion, is applied to delimit elastic solutions for indentation problems, a lower bound limit of the applied indentation force (for a given indentation depth) can be estimated. It may be noted that elastic analyses, without any delimiting failure criteria, normally overestimate the indentation force. Plastic solutions for a few indentation problems may be found in Hill (1950), Johnson, (1985a) and Alehossein et al (1992). When analysing the behaviour of indented rocks the choice of an appropriate constitutive model describing effectively the behaviour of the rock at various stages and phases during indentation is a challenging issue. Several questions need to be answered before starting an effective analysis. The first question is of course: Which one of these is more appropriate for modelling zones underneath and around a cutter, elasticity or plasticity theory, continuum damage mechanics or fracture mechanics, and what is the bridging link between these various theories? Which mode is more dominant in fracturing rock, tensile or shear mode? What governs the mechanism of chip formation? What is the function, shape and the behaviour of the pulverised zone that forms just underneath a cutter? Is the hydrostatic stress state assumption reasonable for this zone? How does the rock change during the absorption and dissipation of the input energy and how does the indentation energy vary with rock type and depth of penetration? How can we model the damaged zone under the indenter? Furthermore does a plastic material form beneath the pulverised zone? When and how do radial and ring cracks form around and under an indenter?

Jan 1, 1995

THE reduction of iron from the ferric to the ferrous state prior to its titration by permanganate or dichromate may give erroneous results in the presence of other reducible metals such as titanium. Stannous chloride and metallic zinc both reduce tetravalent titanium to a lower form, and so increase the consumption of the oxidizing standard: solution. Sulphuretted hydrogen and sulphurous acid do not reduce titanium, but are slow in action and troublesome to manipulate.Sulphuretted hydrogen is considered to be the best reducing agent for iron in the presence of titanium.* In the method to be described the advantages of the H 2S reduction are retained without the disadvantages of using the gas. The reduction is carried out by the action of a metallic sulphide having a solubility product of such a value that the sulphide iom, are utilized as fast as they are formed, and but little free sulphuretted hydrogen is given off.Cadmium sulphide was the first to be tried, but its solubility product (3.6 x 10 - 2~)t was apparently too low. The reduction was satisfactory, but the excess was very difficult to remove. Zinc sulphide (S.P. = 1.2 x 10 - 23) was found to be quite satisfactoryin both respects. The zinc sulphide is preferably used in the form of an emulsion prepared from pure zinc sulphate as follows: About 100 grm. of ZnS047H20 is dissolved in 2 litres of water. H2S is passed until no further precipitate is obtained, the acid formed being barely neutralized from time to time by the addition of ammonia. The precipitation of the sulphide in a slightly acid solution gives a finer emulsion than that prepared in an alkaline solution, and any iron present remains dissolved. The precipitate is allowed to settle and the clear liquid decanted. The precipitate is then shaken up with more water, acidified with a little sulphuric acid, allowed to...

Jan 1, 1922

By Ward B

Central Colliery was developed to exploit large underground reserves in the German Creek lease. It was planned from the outset as a retreating longwall operation and is the first longwall mine in Queensland. Longwall mining is not new to Australia but all previous experience has been confined to the coalfields of New South Wales. There was no precedent for longwall extraction in the markedly different geological setting of the Bowen Basin in Central Queensland. Various investigations were thus carried out during the initial development of Central Colliery, prior to the installation of the longwall, to ascertain the geotechnical characteristics of the coal seam and the adjacent strata and to predict the performance of the heading and pillar design as mining proceeds to depth. Laboratory tests showed the coal to be weak with an unconfined compressive strength of 9.6 MN/m2. Site inspection and geophysical correlation revealed a shear zone and extensive intraformational shear planes in the seam. The latter were found to exert a controlling influence on rib reaction in the headings. This behaviour was predicted by finite element modelling of the development headings which indicated that mining induced stresses in the coal would be relieved by block movement of the ribs. A chain pillar width versus depth curve was established for yielding pillar design based on empirical and computational methods. This gave pillar widths from 25m to 48m over the proposed depth range of 150m to 300m. Finite element modelling of the 25m pillars chosen for the first gateroads confirmed the overall stability of the design but suggested that rib spall could be significant in the adjacent tailgate. (1) Chief Mining Engineer, Capricorn Coal Management Pty. Ltd., German Creek Mine, Queensland (2) Senior Engineering Geologist, Coal Division, The Shell Company of Australia Limited, Melbourne

Jan 1, 1986

The ultraviolet spectrum of isopropyl ethylthionocarbamate (the principal constituent of Dow flotation collector Z-200) in water and of Z-200 itself in water was found to have an absorption peak at 242 nanometers(nm). The height of this peak was found to be directly proportional to isopropyl ethylthionocarbamate concentrations up to 15 p.p.m. Z-200 contains about 90 per cent isopropyl ethylthionocarbamate and the heightof the peak was proportionately lower, but obeyed the straight line relationship up to 15 p.p.m. This showed the potential value of spectrophotometric measurements for the determination of Z-200 residuals in flotation liquors.Methyl ethyldithiocarbamate (an impurity in Z-200) increased the peak height slightly, but other impurities in Z-200, xanthates, and most inorganic salts present in flotation liquors do not interfere. However nitrate ion and thiosulphate ion have absorption peaks which overlap the isopropyl ethylthionocarbamate peak.The simplest general method to overcome this effect is to extract the isopropyl ethylthionocarbamate into cyclohexane and to measure the absorbance of the extract.The maximum absorbance of the cydohexane extract was at 247 nm and the peak height at this wavelength was found to be directly proportional to the isopropyl ethylthionocarbamate or Z-200 concentration in the original aqueous solution. An alternative method is to measure the spectrum of the original aqueous solution using the aqueous raffinate from extraction as a reference solution. This gives the spectrum due to isopropyl ethylthionocarbamate alone and measurement of the absorbance at 242 nm gives the concentration in the original aqueous solution. Both methods give the same value for the concentration of isopropyl ethylthionocarbamate in the original solution.

Jan 1, 1969

This paper discusses support requirements for the proposed monorail system to be used in decline development. The monorail drilling and loading systems are systems that move on the rail (monorail) installed in the roof of the decline and supported by roof bolts, suspension chains and steel supports. However, due to the weight of the components of the two systems, it is imperative that the force in each roof bolt, suspension chain and steel support capable of suspending the weight of the heaviest component is determined. Numerical models that relate the weight of the monorail drilling and loading components to the required strength in the support system have been developed. Using these developed models, numerical values of the forces in each roof bolt, suspension chain and steel support, required to suspend the weight of the heaviest component of the monorail drilling and loading systems are determined.

Dec 6, 2010

Forecasting, particularly when applied to meaningful issues, is known irreverently as 'futurology'. There is quite a range of opinion ext.ant in the world when mineral resources are looked at. The opinions range from the doomsday view that there will be acute shortages of all essential commodities, to the optimistic outlook that new 'discoveries will prevent any possibility of shortages. The environment is, as yet, only studied locally and quite parochially; surprisingly there is little integration when considering the spatial atmosphere, the seas in depth and the earth's crust.

Jan 1, 1981

By T S. Giraudo

The Macraes Gold Project, operated by GRD Macraes Limited, engaged GRD Minproc Limited to assist with the evaluation of a pressure oxidation circuit, this being the key component of a recovery enhancement project. The initial study gave sufficient confidence in the process to enter into project execution. GRD Macraes Limited was the first company to license Newmont Mining Corporation's pressure oxidation technology, which aims to improve gold recovery from the carbonaceous sulfidic flotation concentrate. This paper outlines the fundamental chemistry of the process followed by a description of the plant that was ultimately installed. A summary of the commissioning is given together with an overview of the production results to date. The project ramp-up was rapid, with design temperature and throughput being achieved within days of hot commissioning. Gold recoveries have exceeded expectations, improving from around 70% prior to the installation of pressure oxidation to above 84%. The project has increased the nominal gold output at Macraes from 120,000 oz/y to 170,000 oz/y. On-going plant optimisation for process parameters is discussed, giving rise to flexibility in gold production, with key controlling parameters exceeding design.

Jan 1, 2000

By M P. Simpson

Forty one whole rock samples from the Gold Cross low-sulfidation epithermal Au-Ag deposit have d18O values that range from 4.4 to 9.3 per mil, with an average value of 7.0 per mil. Unaltered and weakly altered rocks have d18O values greater than eight per mil, and the orebody is surrounded by samples that are depleted in 18O. A strongly silicified sample adjacent to the Empire Vein System has a d18O value of 9.0 per mil, similar to previously reported analyses of vein quartz (7.0 to 11.7ë, average 9.4ë). This suggests that, in detail, Golden Cross may have a zone of 18O-enriched wall rocks in the core of the deposit, adjacent to the main underground veins. Although some workers have suggested that stable isotope geochemistry may provide useful information for epithermal mineral deposit exploration, at Golden Cross this is not the case. Alteration minerals, major elements and trace elements all define larger, less ambiguous halos than the zone of 18O-depleted wall rocks.

Jan 1, 2001

The reasons for selecting two stage pebble milling in preference to conventional methods of grinding are discussed. Commissioning of the first section was completed in October, 1969. Improvements in both the operating and engineering aspects were then incorporated in the section commiss ioned in March, 1971.

Jan 1, 1975

By Maconochie A. P

The copper-gold orebodies of the Ok Tedi project and located in an area of climatic and topographic extremes, where both the landforms and the rocks from which they have developed are so young that it may be said that geological and engineering processes are coincident.

Jan 1, 1990

The paper describes the reasons for the development and for the selection of systems which were finally adopted; further estima- tion and design engineering problems, as well as experience with large screens in operation. Advantages, disadvantages and the final li- mits of screen dimensions are indicated.

Jan 1, 1984

By Y Chen, G Xu, B Albijanic

High concentrations of airborne coal particles is the main reason leading to health and safety hazards in underground coalmines. Water spray is one of the effective methods to suppress coal particles in mine sites, but the use of plain water is not effective enough to capture coal particles. By adding surfactants, coal wettability can be improved which will increase the coal dust suppression efficiency. In this study, a modified sink test was employed to evaluate coal wettability in the presence of two anionic surfactants: sodium dodecyl sulfate (SDS) and sodium dodecyl benzene sulfonate (SDBS). Sink rates were calculated by measuring sink weight over test time. Different surfactant concentrations (0.01 per cent, 0.05 per cent, 0.1 per cent, 0.2 per cent and 0.4 per cent) and two types of water (tap water and deionised water) were selected to investigate coal wettability over three size ranges (0–38, 53–75 and 75–90 µm). The results show that both SDS and SDBS surfactants can lower the water surface tension and improve coal wetting performance. Sink rates increased as the surfactant concentration increased, and surfactant solutions prepared by tap water performed better than deionised water in enhancing coal wettability. Also, coal wettability varied for different coal particle sizes; the smaller coal particles were, the worse the wettability they possessed.CITATION:Chen, Y, Xu, G, Wang, R and Albijanic, B, 2017. Study on coal wettability for dust suppression in the presence of surfactants by sink test, in Proceedings Australian Mine Vent Conference 2017, pp 105–110 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

By Lewis PC, Carr GR, Dean JA, Glen RA

The Lachlan Fold Belt (LFB) is a complex orogenic belt which developed in Early to Mid Palaeozoic time. A number of orogenies and more localised deformational events affected the region. A simplified classification scheme for the diverse gold deposit types is proposed, subdividing primary mineralizing processes into four categories: volcanism (epithermal and volcanogenic deposits), igneous intrusion (subvolcanic/porphyry style, skarn and magmatic deposits), metahydrothermal processes (deposits generated during metamorphism and regional deformation) and hydrothermal-distal processes (deposits generated by poorly understood, generally remote large scale hydrothermal processes). Major gold deposit associations include epithermal and porphyry style deposits in Ordovician-Early Silurian shoshonitic andesite sequences; volcanogenic base metal-gold deposits in Silurian rift or basin felsic sequences; vein deposits in Late Silurian and Early Devonian S and I-type granitoids; deposits in Early Devonian sedimentary rocks of the Cobar Basin probably generated by metahydrothermal processes during basin closure and cleavage formation; deposits associated with serpentinite; and metahydrothermal quartz vein deposits in folded sedimentary rocks.Studies of host rock geochemistry suggest a relationship between magma types, gold enrichment and mineralization particularly in shoshonitic sequences and Early Devonian granitoids of the Boggy Plain Supersuite. Structural studies indicate the importance of thrust type structures and detachment faults in generation and location of gold mineralization. Lead isotope initial ratios help define metallogenic associations and a number of distinctive isotope "signatures" have been established.

Jan 1, 1990

Open pit mine plans define the complex strategy of displacement of ore and waste over the mine life. Various mixed integer linear programming (MILP) formulations have been used for production scheduling of open pit mines. The main problem with these models is the inability to solve real size mining problems. We present a mixed integer linear programming formulation for the open pit long-term production scheduling problem. To reduce the number of binary integer variables in the formulation, we aggregate blocks into larger units referred to as mining-cuts. We present a semi-supervised clustering algorithm which aggregates smaller blocks based on rock types and grade ranges into mining-cuts without introducing an error in the grade estimated values. The cluster-based aggregation algorithm is fully integrated into an MILP mine production scheduling prototype software. We have implemented, verified, and validated our models. The efficiency of the new platform is evaluated through iron ore mine case study.

Dec 6, 2010

By S M. Zhang, Y X. Han, J Liu, Y J. Li

"Compared with conventional roasting and magnetic separation processes, higher reduction temperatures and stronger reducing atmospheres are used in reduction technologies to reduce iron oxides to metallic iron, which is often liberated during reduction and amenable to magnetic separation. Reduction and magnetic separation of an Australian refractory iron ore was therefore studied as a function of reduction temperature, time and coal addition. It was found that during reduction, the particle size of the reduced iron increased with reduction temperature and time. Subsequent magnetic separation tests were further conducted on the reduction products. A reduced iron powder with a Fe grade of 85.67 per cent was obtained at a Fe recovery of 87.82 per cent under optimum reduction conditions where a metallisation rate of 85.82 per cent was achieved. The mechanism involved in reduction is discussed based on XRD and SEM examinations.CITATION:Han, Y X, Liu, J, Li, Y J and Zhang, S M, 2013. Upgrading an Australian iron ore by reduction and efficient magnetic separation, in Proceedings Iron Ore 2013, pp 397-402 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

It's long been suspected that there has been an increase in the incidence of premature failure of rock bolts in underground coal mines over the past ten years. As far back as 2002 a study found a possible contributor to such premature failure in some Australian coal mines might be linked to stress corrosion cracking (SCC) (Crosky et al, 2002). That study suggested the low impact toughness could be a major influence on the susceptibility to SCC of different steel compositions. A subsequent study involving laboratory corrosion tests however failed to confirm any link with metallurgical factors (Villalba and Atrens, 2007), a finding that is at odds with field experience. Some mine sites today are still reporting prematurely failed rock bolts to the rock bolt manufacturers; the failures are being identified at SCC induced. To this end a research project has recently been commissioned at University of New South Wales (UNSW), which aims to identify the environmental factors causing SCC, through field test sites and simulating the conditions within an accelerated corrosion laboratory. This paper outlines the methodology that will be used in this study.

Nov 25, 2010

By S Winter, G Klenowski

During longwall mining in the Bowen Basin, open tension cracks formed by overburden subsidence occur to a height of about 175 m above the mining horizon. Within this zone, water in aquifers or inundated workings will flow into the mine.At the Oaky Creek mines Aquila seam, open cut pits containing pit water overlie German Creek seam longwall panels at a height of about 105 m. The highly saline water is classified as contaminated and cannot be discharged off-site. Because alternative water storage facilities were not available, innovative water management solutions were needed to allow longwall mining to proceed without underground flooding.Computer modelling and underground inflow measurements have been completed to accurately determine inflow rates into longwall mines from overlying water sources at increasing overburden heights. Research work has also included determining cost-effective blanket treatment of final voids and reshaping spoil piles to minimise downward seepage.Ponded water overlying the Aquila low, Grasstree south and A6 pits required remedial works prior to longwall undermining to prevent flooding. In the Aquila low pit it was necessary to partition the pit and remove water overlying longwall 32. Two in-pit bridges were constructed by dozing and track compacting low wall spoil. The final void above the longwall panel was kept dry during undermining. Maximum recorded underground inflow rate was 30.0 L/s.The Grasstree south pit final void, part of the ramp and much of the spoil piles were inundated prior to undermining of 308 panel. A bridge and blanket were required to prevent ponding above the longwall. Maximum recorded inflow during undermining was 23.2 L/s.The pit A6 south final void, which contained dumped, saturated rejects and inundated highwall mining entries was undermined by longwall 36 at the Oaky No 1 underground mine. Because mapping of highwall entries was not available, the maximum calculated inflow rate of 73.0 L/s was based on all design entries being fully inundated. The actual inflow rate during longwall mining ranged up to 20.0 L/s.Water management improvements that have been implemented include greater use of contaminated pit water to wash coal, use of evaporation fans, and installation of a 6 ML/day reverse osmosis plant for water purification.CITATION:Klenowski, G and Winter, S, 2017. Inflows into longwall mines from inundated overlying workings, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 183–190 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By A T. Job, M L. Edgar, P R. McAree

Characterising ores in-pit and in real-time presents a significant value opportunity for the mining industry. Hyperspectral imaging systems are proposed as an enabling technology to achieve this real-time characterisation. This paper considers the application of a hyperspectral imaging spectrometer mounted on a shovel. We define the performance requirements for such a spectrometer and associated subsystems during a typical dig-load cycle. The relatively high swing rotation speed of the shovel requires approximately video-rate exposure times to achieve good spatial resolution. We analyse a selection of components against these requirements and find that suitable commercial spectrometers, detectors and optics appear fit-for-purpose. Automated, real-time spectral classification systems are also available, with only relatively modest requirements for processing power. The paper argues that at near peak solar illumination, a system for field deployment at the required sensitivity is viable using only commercial off-the-shelf components.CITATION:Job, A T, Edgar, M L and McAree, P R, 2017. Real-time shovel-mounted coal or ore sensing, in Proceedings Iron Ore 2017, pp 397–406 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By J Elsen, R Snellings, K Van Balen

This research concerns the mineralogical study of the physico-chemical reactions taking place at the pozzolan-binder interface. Lime binder/ pozzolan mixtures have been prepared for different natural zeolites. Analcime, phillipsite, chabazite, erionite, mordenite and clinoptilolite were mixed with portlandite and water, after which the progress in the reaction was quantitatively determined by thermogravimetrical analyses from three to 180 days. A first and important step was the thorough characterisation of the raw materials by quantitative X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscope energy- dispersive X-ray (SEM-EDX) measurements of the zeolite minerals, Brunauer-Emmet-Teller (BET) specific surface area measurements, grain-size analyses and cation exchange capacity measurements. Beside these zeolite samples with varying Si/Al ratios, two clinoptilolite samples exchanged to the calcium, potassium and sodium form were studied and the difference in their short- and long-term reactivity was assessed. Also the difference in reactivity between identical clinoptilolite samples ground to different grain sizes, obviously having different specific surface areas, was determined experimentally. The results indicate that the external surface area only influences the short-term reactivity, whereas the cation content has effect on both long- and short-term. Na-exchanged samples combine clearly more portlandite in the first few days, whereas the reaction slows down afterwards compared to K- and Ca-exchanged samples. The early reactivity of the unexchanged zeolite samples could be explained by these two parameters, but their long-term reactivity seemed to be related to their Si/Al ratio. Samples with zeolites rich in Si reacted faster then their Al-rich counterparts.

Jan 1, 2008