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By P Wollants, B Blanpain, R Ding

Vacuum oxygen decarburisation (VOD) is the refining process used by ALZ (Genk, Belgium) for their production of stainless steels. The process consists of three stages: oxygen blowing at a pressure of 100 mbar, degassing, and reduction of the slag with ferrosilicon at 5 mbar. The magnesia-chromite bricks used in the slag zone of the ladles suffer from acute wear. In this paper results obtained from a program to improve the refractory life span are presented. The dominant wear phenomena were identified with an electron microscopy study of bricks taken from different locations in the ladle. Concurrently a dynamic model for the vacuum oxygen decarburisation (VOD) refining process was developed. The model calculates the elementsÆ oxidation rate during the blowing oxygen stage and allows the continuous calculation of the change of the metal, slag and gas composition throughout the VOD process. From these activities a general scheme of the refractory wear was worked out and measures to improve the refractory life were proposed and implemented.

Jan 1, 2000

By C D. Ogg, P B. Pope, K M. Lynch, B K. C

Iron-reducing bacteria are able to couple the oxidation of an electron donor to the reduction of Fe(III) to Fe(II) under anaerobic conditions in the generation of cellular energy. Recent evidence suggests that these bacteria are phylogenetically diverse and widely distributed in nature. Our laboratory has isolated thermophilic, thermotolerant and mesophilic iron-reducing bacteria from numerous petroleum reservoirs with varying conditions, groundwaters of the Great Artesian Basin (GAB), and petroleum-contaminated soils. Some of these isolates have been identified as novel species and from genera such as Deferribacter, Bacillus, Alkaliphilus, Clostridium and Thermoanaerobacter. Further investigations have shown that these bacteria are metabolically diverse, not only capable of reducing different metal species but also able to use a range of organic compounds, including polycyclic aromatic hydrocarbons, for growth. Due to their abundance and metabolic capabilities, it is possible that iron-reducing bacteria may be important in microbially-enhanced oil recovery processes and in the bioremediation of contaminated soils and aquifers, particularly in anaerobic zones.

Jan 1, 2004

Classifications of Ni-Cu deposits are based on petrology, geochemistry and the geotectonic setting of host igneous bodies (Naldrett and Cabri, 1976; Besson et al, 1979; Nadrett, 1989). The four major classes in Naldrett's (1989) division rest on the geotectonic setting of the igneous complexes and the classes are further subdivided on the basis of the petrology and geochemistry of the intrusion. A more common subdivision of mafic and ultramafic igneous rocks is based on the environment of rock-forming processes, endogenic or exogenic, intrusive or extrusive, and this subdivision has been applied, in practice, to the classification of sulphide Ni-Cu deposits, too. The extrusive deposits, Class I in Naldrett's (1989) classification, are directly related to volcanic processes whereas all the others refer to the intrusive environment. This paper looks at the differences between the extrusive and intrusive groups of Ni-Cu deposits and presents generic, genetic and structural features of the intrusive group.

Jan 1, 1996

My paper presents a discussion of the legislative and departmental requirements in connection with the acquisition of exploration rights for minerals (other than petroleum and coal) in the Independant State of Papua New Guinea, the Solomon Islands and Queensland and he practical problems associated with land entry and land ownership associated therewith. In general there are many similarities in the methodology and philosophy behind the legislation in each country and the contractual requirements established thereby between the exploration company (the explorer) and the government and the mines department or equivalent in each place. There are also a number of differences. I have prepared the paper on the basis that my audience will largely consist of -experienced explorers and the paper is intended to act as a brief refresher and a guide to the philosophy and the practicalities behind the legislation and practices in ground entry in each case. I will deal in turn with New Guinea, the Solomon Islands and then Queensland.

Jan 1, 1987

Financial theory often takes some time to penetrate industry and when it does it can result in a paradigm shift in valuations and mental models. The Black Scholes option valuation was first published in 1973, although the authors were only awarded a Nobel Prize in 1997. The valuation of real options has been applied to the oil and gas industry for some time, however it has only recently been more widely applied to the non-oil, mineral resource sector. The use of real option valuation (ROV) for the valuation of marginal and short mine life resource projects is a more useful valuation tool than the conventional DCF, NPV valuation tool. The application of ROV has major implications for corporate strategy. It generally favours equity over debt funding and non-hedging over hedging. A retrospective assessment of the successful development of the Lennard Shelf Operations demonstrates the concepts of implementing real options and the value destruction of limiting operational flexibility through debt and hedging activities.

Jan 1, 2003

By E House, V Lisitsin

Recent whole-rock geochemical data from nearly 900 fresh drill core and underground samples taken from seven central Victorian gold deposits confirm the presence of distinct and identifiable primary alteration haloes surrounding the deposits. Ferroan carbonate alteration extends for up to several hundred metres away from turbidite-hosted gold mineralisation outside of contact metamorphic aureoles. A less distinct phyllic alteration zone can be identified using geochemical molar ratios or short wave infrared analysis. It generally overlaps a sulfidic halo characterised by disseminated pyrite and in close proximity to mineralised structures, arsenopyrite. The extent of the sulfidic halo can be traced using low-level analysis of pathfinder elements such as S, Au, As and Sb. Recognition of these alteration features enlarges the target for exploration and provides a tool by which drilling can be directed towards mineralised structures. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

Geological models for the exploration and evaluation of epithermal Au and porphyry Cu-Au deposits rely upon a classification of different deposit styles and an understanding of the evolutionary processes of deposit formation. These models guide the interpretation of subsurface deposit anatomy in order to target drill testing and assist the explorationist to focus on the more prospective projects. It is important for the explorationist to distinguish between different styles of magmatic arc Au deposits as each style displays distinctive characteristics with exploration implications. Magmatic arc Au deposits are distinguished as porphyry Cu-Au formed at depths of 1 - 2 km at the apophysis to larger, buried, magmatic sources which are also the ultimate metal sources for the varying styles of shallower level epithermal Au deposits. Low sulfidation epithermal Au deposits characteristically develop from dilute circulating meteoric waters and are distinguished as the group with a closer relationship to intrusive source rocks, and slightly higher sulfide contents (still generally

Jan 1, 2004

By Massacci P

A review has been made of the studies focusing on methods for the description of grain -size distribution after breakage and, separa- tely, of the degree of liberation of the miner- al species making up the various grain-size classes of comminution products. The purpose of the study has been to de- velop an overall model of the phenomenon which, owing to the very effect of comminution, leads to the formation of grains that are generally of mixed composition. A calculation procedure has thus been de- veloped for the liberation function taken as the assessment of the distribution of mix com- ponents in the products obtained after a commi- nution process. The aim is to identify a func- tion which may, to a certain extent, simulate the variation of the grade-recovery function of an ore in relation to its degree of comminu- tion. The numerical model thus obtained has been tested out on results obtained experimentally.

Jan 1, 1986

By Thomas R. J

Following asmallnumberofpollutionincidents involving the death of cattle from ingestion of cyanide that had escaped from gold processing plants, the Queensland Government undertook to develop competent guidelines addressing this problem. These guidelines, "Queensland Government Guidelines on Prevention of Water Pollution from Cyanide Use in Gold Ore Processing", issued by the Department of Environment and Heritage, Department of Resource Industries and Water Resources Commission, cover hydrology and general house-keeping intended to reduce the likelihood of significant impact from a spill or unintentional dis- charge of contaminated material. There are three major advances for Queensland embodied in this Guideline: ò the use of a design approach that gives site specific standards rather than trying to give a multitude of standards broad enough to cover all situations, ò the use of hazard assessment and a "critical period" hydrologi- cal design technique, and ò new monitoring and reporting requirements. The guideline is presented here in a summary form:

Jan 1, 1991

By M Wortley, J McKay, D La Rosa, O Guyo

It has been a generally held concept that crushing operations were, by their nature, too simple to benefit from the implementation of advanced process control. The commissioning of an OCS¬ expert control system and image-based oversize detection system, VisioRock, at the Pilbara Iron Tom Price facility are dispelling these notions. A constraint-based OCS¬ expert control system has been designed and commissioned on the high-grade crushing and screening plant along with a vision-based oversize detection system functioning on six product conveyor belts. To date, the expert control has demonstrated the ability to increase production by maximising dynamic constraint utilisation. Dynamic constraint utilisation is a concept developed by Rio Tinto Technical Services for effectively evaluating constraint-based control logic performance. The VisioRock system has been installed and configured and has been operating for a period of several months. Currently, Tom Price and Metso personnel are working to define correct oversize detection thresholds. Details of the plant implementation are discussed.

Jan 1, 2005

Underground mine ventilation is now com monly simulated on a digital computer. Such a programme, incorporating natural ventilation has been modified by others to account for methane emission and elevated local tempera- tures. At Wollongong University, the pro- gramme was further developed and extensive interactive graphics incorporated such that any view of the three dimensional mine could be viewed, and superimposed upon that view are areas where a nominated parameter has exceeded a particular value - generally at a nominated time after a particular event and usually a fire/explosion of one type or another. A further programme was developed such that up to 20 'times' could be examined at a particu- lar location after say, a fuel rich fire at some other place in the mine. The output from this programme includes a plot of methane 1, smoke 1, temperature, pressure and air flow versus time - a most useful graphic to observe the limits of safe attendance in a particular Airway.

Jan 1, 1983

The geographical and geological situations of the two mineral sand deposits currently being mined by Western Titanium Limited and the mining methods in use are briefly described. Production scheduling involving the ability to vary the proportions of the major minerals produced, together with maintaining a constant feed grade to the wet concentrator has been assuming greater importance to the company in recent years as the relative value of these minerals, due mainly to technological advances and environmental considerations, is subject to significant and rapid change. Manual calculation, even using a programmable calculator, became a trade-off between man hours and data usage. Schedules were updated infrequently and only a fraction of the avail- able data was used. In July 1975 a Data General NOVA 2/10 minicomputer with a 24K word core and three cassette drives was purchased. A suite of programmes was developed using BASIC to assist in production scheduling and these were opera- tional early in 1976.

Jan 1, 1977

By Woodcock J. T, Millett R. N

It was shown that manganese dioxide could be used as an oxidant in acid thiourea leaching of a gold ore. Manganese dioxide could generate high redox potentials and was as effective as hydrogen peroxide in the leaching process. Results obtained under closely controlled leaching conditions confirmed that high redox potentials enabled faster dissolution of gold to be obtained but led to extremely high reagent consumptions (thiourea, acid, and manganese dioxide). Additions of sodium sulphite solution in an attempt to lower thiourea consumption by reducing formamidine disulphide back to thiourea were only marginally successful. Although thio- urea consumption was slightly decreased, the consumption of acid and manganese dioxide was substantially increased and there was no net benefit in using sulphite. Tests in which a single addition of mangan- ese dioxide was made before addition of thiourea minimized overall reagent consumption and gave only a slightly lower dissolution rate of gold. This is a promising technique for further Investigation.

Jan 1, 1987

By Matsushita Y, Maeda M, Sano N

The present study was carried out to explore the possible separate recovery of iron and phosphorus (as gas) from BOF slag using graphite crucibles or graphite powders in the presence of a tin bath. The last is consider- ed to enhance the activity of phosphorus in iron reduced from slag or not to absorb the phosphorus vapour readily. When the slag was reduced in a graphite crucible in contact with a tin bath, the phosphorus reduced from the slag was carried away in CO explosively generated by the reduc- tion of iron oxide. When graphite powder was used as the reductant instead, 78% of the phosphorus was removed from slag, only 3% of which was absorb- ed into the tin bath. The rest left the system as gas. Gaseous dephosphorization depends on the area of contact between slag and reductant as cll n.u the amount of the latter. the reduction behaviour was directly observed, using an X ray transmission technique, to conlirm the reaction mechanism.

Jan 1, 1980

By Zingano A, Costa J. F

Brazilian amethyst production is mostly obtained from underground mines in the southernmost part of the country, involving approximately 6000 miners and generating an income of US$ 20 million per year. Amethyst-bearing geodes are hosted by Cretaceous continental flood basalts of the Serra Geral Formation. The economic zone occurs in the massive (colonnade) intermediary section of the Sao Gabriel Basalto. The tunnels and stopes follow the occurrence of geodes leading to an erratic and complex layout. A ground control survey revealed excessive roof convergence. Topographic results show excessive roof deformation and some roof falls have already been reported. To understand the ground conditions, prevent roof falls and better define the pillar dimensions detailed geomechanical mapping was carried out using the scanline method. Uniaxial compressive strength tests provided complementary information for rock mass classification. Results of the geomechanical classification were used to modify the mining layout taking into account the roof and pillar geomechanical characteristics. Retreat pillar mining minimised ground instability.

Jan 1, 1997

By McKenzie C, Michaux S

Modern quarrying operations focus attention on blasting operations as a critical component in the overall cost-effectiveness of quarrying. Generally, optimisation of blasting has been linked to the processes of drilling, explosive consumption, secondary breakage, and product haulage to the primary crusher. This approach gives no consideration to the impact of primary crusher feed size distribution on downstream processes, or on the quality (ie shape and strength) of the final product. Blasting operations can be manipulated to produce a wide range of muckpile size distribution. This paper presents the results of studies into the impact of muckpile fragmentation on downstream crushing and screening operations, and includes measurements of primary blast oversize and muckpile fragmentation, together with measurements of size distribution, circulating loads and flakiness for various process streams throughout a quarry processing plant. This paper is an extension of other studies investigating the prediction and control of fragmentation from blasting, and the role of explosive performance in controlling muckpile fragmentation.

Jan 1, 1995

Underground mine ventilation is now com monly simulated on a digital computer. Such a programme, incorporating natural ventilation has been modified by others to account for methane emission and elevated local tempera- tures. At Wollongong University, the pro- gramme was further developed and extensive interactive graphics incorporated such that any view of the three dimensional mine could be viewed, and superimposed upon that view are areas where a nominated parameter has exceeded a particular value - generally at a nominated time after a particular event and usually a fire/explosion of one type or another. A further programme was developed such that up to 20 'times' could be examined at a particu- lar location after say, a fuel rich fire at some other place in the mine. The output from this programme includes a plot of methane 1, smoke 1, temperature, pressure and air flow versus time - a most useful graphic to observe the limits of safe attendance in a particular Airway.

Jan 1, 1983

The main aim of the conference is to work towards improved useage of steelplant slags which have largely been considered waste mater- ials, This paper summarised investigations carried out on the suitability of air cooled blast furnace slag, blast furnace granulated slag and basic oxygen steelmaking slag as road base materials. All slag samples were obtained from the PortòKembla Works of Australian-Iron and Steel Pty Ltd. Since road making materials are increas- ingly being characterised by use of resilient moduli, the compressive strengths and resilient moduli were determined for road base of the following slags. 1 Air cooled crushed blast furnace slag 2 mixes of air cooled blast furnace slag, granulated slag, and lime 3 mixes of air cooled blast furnace slag,-granulated slag and basic oxygen steelmaking slag. Evaluation of a local dacite (dense medium grained igneous rock, classification rhyolite), generally considered an excellent road base course material, was carried out for use as a reference material.

Jan 1, 1979

By Johnson N. W, Ralston J, Lauder D. W, Smart St C R

The flotation behaviour of the Hilton ore of Mount Isa Mines has been examined in the presence of two collectors (sodium ethyl xanthate (Ex) and sodium diisobutyldithiophosphinate (3418A)) over a range of flotation Eh values and collector additions. Tests were also conducted in the absence of collector to determine the relative contributions of natural and self-induced floatability of the major minerals in the feed. In these tests the influence of metabisulphite on the self-induced floatability of the minerals was also determined. Attention focussed on optimising the selectivity of galena flotation. It is shown that the Hilton ore sample contained lower levels of naturally hydrophobic iron sulphide minerals than are generally contained in the Mount Isa lead-zinc ore. Furthermore, the self-induced floatability of galena was less than that exhibited by the galena in the Mount Isa lead-zinc ore. Sodium metabisulphite (MBS) reduced the self-induced flotation of galena but had no effect on the natural floatability of the iron sulphide minerals.

Jan 1, 1991

In dense medium processes for the beneficiation of minerals the consumption of medium (generally ferrosilicon) represents a major component of the operating cost. This provides a strong incentive for improvements in heavy medium recovery circuit design and operation. A major thrust in heavy medium plant design over the past decade has therefore been towards circuits which reduce medium losses. In this paper recent trends in plant design are examined in relation to the factors infl uencing circuit performance and medium losses. Operational details ' which have a significant effect on losses are discussed and illustrated by means of plant and pilot plant test data, with particular emphasis on the performance of wet drum magnetic separators. While the emphasis is on reducing the consumption of the high-cost ferrosilicon medium used in minerals beneficiation, most of the principles described in this paper are equally relevant to the design and operation of magnetite recovery circuits for coal preparation plants.

Jan 1, 1987