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By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022

By B A. Webler, P Su, P C. Pistorius

Advanced high-strength steels (AHSS) typically have much higher aluminium concentrations (by an order of magnitude or more) than conventional low-carbon aluminium-killed steels. The resulting lower oxygen activity at the steel-slag interface changes the kinetics and thermodynamics of steelslag reactions. Previous work showed that the rapid transformation of alumina inclusions to spinel inclusions, and spinel to periclase, occurs because of the relatively high concentration of dissolved magnesium. In this paper, experimental results on nitrogen removal by ladle slag are compared with predictions based on the available thermodynamic databases. As in previous work, the kinetics was modelled by assuming mass transfer control, with steel or slag mass transfer limiting. The results show that significant removal of nitrogen by steel-slag reaction is possible.

Aug 21, 2024

The State of Western Australia has a land area of 2 525 000 km2, and is well endowed with minerals and petroleum products. In 1989 - 90 these products were valued at nearly A$10 500 million.

Jan 1, 1992

By W Curlewis, D Hake, Z Cuthbert

The South Island Line (East) will be a medium-capacity railway covering approximately 7 km from Admiralty Station to South Horizons Station on the south side of Aberdeen Harbour in Hong Kong, with intermediate stations at Ocean Park, Wong Chuk Hang and Lei Tung.South Island Line (East) Contract 904 project is located on the island of Ap Lei Chau at the southern side of Hong Kong island and requires extensive construction works to be completed in close proximity to the existing residential estates of South Horizons and Lei Tung. The project also has areas of significant cultural heritage, including 18th and 19th century temples and historical gravesites. Owing to the site access constraints and location for the project, detailed planning and methodology innovations have been required to ensure the most effective and responsible means of delivering the project works. To excavate the tunnels using drill-and-blast techniques in these restricted locations, the maximum instantaneous charge weight that could be fired while blasting was severely limited. To overcome these restrictions, the project team developed and pioneered the use of ‘deck loading’ in Hong Kong to minimise the impact of blasting operations and has successfully implemented double- and triple-deck blasting operations during the completion of tunnel excavation works.Upon completion of the drill-and-blast excavation, the tunnel lining works were completed using both in situ concrete lining with travelling forms and permanent shotcrete works.CITATION:Curlewis, W, Cuthbert, Z and Hake, D, 2014. SIL904 Hong Kong – Drill and Blast Tunnels, station blasting innovations (double- and triple-deck blasting) and lining solutions, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 21–28 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By A E. Petts

Record iron ore prices and a renaissance of infrastructure in the Pilbara have Flinders Mines poised to move from explorer/developer to an iron ore producer. The potential of the company’s Pilbara Iron Ore Project was first highlighted by the announcement of Rio Tinto’s Caliwingina North deposit to the north and the Fortescue Metals group’s Serenity deposit in the southeast. The success of Flinders Mines’ exploration has been based on incorporating landscape studies into an existing geological framework, and using this to understand the iron-rich materials that were emplaced during the Tertiary. The development of the Delta and Eagle deposit resource models highlights this process. There are three main mineralisation styles at the project; detrital iron, channel iron and bedded iron deposits. They have textural and mineralogical similarities with comparative deposits in the region. Gaining an insight into the geological processes unique to detrital iron deposits and more distal channel iron deposits has been important to understanding the geometallurgy of the mineralisation. The model sits comfortably with other regional oregenesis models and allows a contextual framework to be developed around the timing of deposition of the Fe-rich detritus and pisolitic nodules that dominate the deposits. The exploration model also allows Flinders to explore more effectively for bedded iron mineralisation developed prior to, and since the development of the Tertiary weathering landscape.

Jul 11, 2011

By M Suzuki

Although several models for the surface tension of molten oxide slag have been proposed, suitably accurate predictions of this property are not yet possible. The surface tension, or surface excess free energy, of molten oxides is largely determined by the ionic coordination induced by surface relaxation. However, the associated mechanism of surface structural relaxation for molten oxide mixtures such as slag is complex and not yet fully understood. To allow a better evaluation of surface relaxation characteristics, the present work analysed the ionic coordination associated with the surface-relaxed states of several oxide mixtures. This work especially focused on calcium aluminate slags because these materials exhibit complex relationships between composition and surface tension. The effects of incorporating low concentrations of SiO2 as a surface active component on the surface ionic coordination were also examined. X-ray absorption techniques were used to assess oxygen and cationic elements in glassy samples after surface relaxation treatments, and molecular dynamics simulations based on a polarisable ion model of molten slag with vacuum/melt interfaces were also performed. The X-ray absorption techniques provided data related to electron yields (which are primarily associated with surface features) and fluorescence yields (which evaluate the bulk material). Thus, the ionic coordination characteristics of both regions were investigated. The results of molecular dynamics calculations allowed statistical analysis of the distributions of Al- or Sicentred polymorphs as well as the bond angles between cations and oxygen anions in the vacuumexposed and bulk regions in the equilibrated melt. The results indicated that bridging oxygen ions were preferentially distributed in the relaxed surface region rather than non-bridging oxygens. These bridging oxygen ions represented vertex connections between AlO4 or SiO4 tetrahedra. In the case of the calcium aluminate slags, the addition of one Ca2+ ion as charge compensation for two Al3+ ions was found to be necessary to form two AlO4 tetrahedra. This specific feature of surface ionic coordination could be responsible for the complex trends observed in surface tension data. The incorporation of low concentrations of SiO2 reduced the proportion of tetrahedrally-coordinated Al ions such that higher coordination states become dominant in the bulk of the material, whereas AlO4 tetrahedra were preferentially distributed in the surface region. SiO4 tetrahedra were the preferred Si-centred polymorph and were likely connected to one another to form bridging oxygen ions at the surface. On the basis of these results, a model to predict slag surface tension was proposed, and the energy of the formation of the ionic clusters resulting from surface relaxation was taken into account.

Aug 21, 2024

The task of designing stable high walls and spoil piles in strip coal mines, and stable openings with controlled roofs and floors in underground collieries - within the constraints normally imposed by economics - depends upon a reliable assessment of rock mass strengths and rock mass reactions under a variety of stress conditions. Of the geological factors influencing internal friction and cohesion within rock masses, many may be determined qualitatively or empirically from bore-hole evidence. Rock types, descriptions and properties of intact rocks, location of boundaries, limits and degrees of weathering, potential for slaking or decomposition of rocks when exposed, bedding characteristics, the nature of rock anisotropy and the likely effects of water on rock mass properties can be assessed from bore- hole data. Discontinuities, whether they be major such as faults and dykes, or minor such as joints and fractures, present a greater problem, and in most instances the mine geologist must resort to additional techniques to describe or predict their occurrence, nature, frequency, intensity or physical properties. Information on ground water and seam gas is available from bore-holes within certain levels of reliability.

Jan 1, 1977

Sapporo-Iwanai district is located at the intersection of the northeast Japan arc and Kuril arc, associated with the subduction zone. This area is characterized by Miocene submarine volcanism followed by Plio-Pleistocene subaerial volcanism.   Koryu, a small epithermal Au-Ag deposit, occurred in Pleistocene (1.4 - 0.85 Ma) within Miocene sedimentary rocks near a subaerial andesitic volcano, while Toyoha, a large epithermal Pb-Zn-Ag (-Au) deposit, also occurred near a subaerial andesitic volcano. Although most of the base metal deposits formed in middle-late Miocene, Toyoha formed in Plio-Pleistocene (2.93 - 1.60 Ma) within Miocene volcanic and sedimentary rocks. This epithermal mineralization was partly overprinted by xenothermal Cu-Sn-In(-Au) mineralization (2.68 - 0.49 Ma).   Hydrothermal alteration differs vastly between Koryu and Toyoha: host rocks at Koryu were not intensively altered, although wall rocks adjacent to veins were silicified, while those at Toyoha show intensive and extensive neutral-pH alterations. Geological and chronological studies show that middle~late Miocene (12.5 - 8.4 Ma) alteration was pervasive and overprinted by Plio-Pleistocene (2.93 - 0.49 Ma) alteration. The base metal veins in the middle-late Miocene were not well developed, but were large in number with great depth.   These studies show that the hydrothermal activity at Koryu is rather small and short-lived, while that at Toyoha is large, long-lived and characterized by overprinting of different hydrothermal systems. The subaerial magmatic activities yielded not only the andesite lavas, but also generated hydrothermal solutions for the formation of both Koryu and Toyoha. The metals were possibly derived from such magma. At Toyoha, the hydrothermal solutions could also remobilize metals from old ores.   The size, life span of magmatic-hydrothermal system, and overprinting on the old mineralizing systems could constrain the type of metal deposits (precious and polymetallic deposits) nearby subaerial andesitic volcanoes in Plio-Pleistocene.

Jan 1, 2005

Perhaps the only thing certain about an address that purports to look into the future of any human endeavour is that time will prove it :.o be inaccurate. In undertaking the dubious, but oft-times necessary business of prediction, thr, historian will base his/her forecasts on tr-ands of the past, the speculator on current events, and the politician on what he/she would dearly like to see happen. The thoughts expressed in this address seem to have arisen through exercising a combination of all three of those philosophies but, hopefully, with a smat- tering of pragmatism.

Jan 1, 1988

By D Semini, B Newcombe

Base-metal sulfide refractory gold ores often contain a portion of ‘free’ gold that is amenable to recovery using gravity concentration methods, whilst the refractory portion of the gold is better recovered using flotation. The decision as to whether a plant treating a refractory gold ore should utilise gravity concentration or a flash flotation circuit (or a combination of both) within the grinding circuit is usually made at the design stage of flow sheet development. Very limited data is available in the published literature which provides an industrial scale comparison on which to base such a decision and conventional laboratory testing methods are often the only way of obtaining such data. The optimum processing route will also be mineralogy dependent.This paper presents the findings of operating a refractory gold plant with either flash flotation (normal operation) or a combination of flash and gravity recovery methods treating the cyclone underflow stream and will demonstrate the regions of the recovery profile that each contributes to. Size-by-assay analysis has been performed on a number of streams around the operating plant to gain an insight into the changes that occur when the gravity circuit is in operation in addition to the flash flotation circuit. A discussion around the implications to overall plant operation in combining the use of a batch process (gravity concentration) with a continuous process (flotation) is presented.CITATION:Newcombe, B and Semini, D, 2014. Interactions between flash flotation and gravity concentration – an industrial case study of a refractory gold concentrator, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 427–436 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By F Radke, P A. Tilyard

Determination of the mineralogical location (deportment) of minor and trace elements (including credit and penalty elements) in base metal concentrates can indicate whether further processing is likely to (a) reduce the levels of the penalty elements, and/or (b) direct selected elements into other plant products, thereby increasing current concentrate grade or increasing payment for credit elements. To determine the deportment of elements requires knowledge of the proportions of the minerals present and their individual element contents. In addition, knowledge of the liberation and locking is important, as this can affect any possible further processing. Mineral proportions can be determined by a variety of methods including chemical analysis, point-counting, area-counting, QEM*SEM, image analysis and mineral separation. In the case of a Broken Hill zinc concentrate, several of these methods were used and gave consistent results.

Jan 1, 1998

By Dawes S

Efficient roof control in colliery operation is a factor that must be maintained for· the maximum reQovery and economic extraction of the mineral. It must be carefully considered in each of the following stages in the life of a mine.1. The primary development and the first working of the mine.2. The maintenance of access roads, intake and return airways.3. The extraction of pillars.FACTORS IN ROOF CONTROLThe main objects of roof control are: The support of the roof in working places, the relief of roof pressure from the workings during pillar extraction, and in some instances the prevention of subsidence of the surface.The support of the roof during development operations and first working, and the subsequent maintenance of these is influenced by:-1. The depth of the seam below the surface.2. The thickness of the seam.3. The dip of the seam.4. The condition of the roof and floor.5. The method of extraction-mechanical or by hand.6. The method of. working-Iongwall or bord and pillar.7. The availability of material.As a general rule, the pressure exerted by the superincumbent strata may be taken as one pound per square inch for each foot of cover, and the crushing strength of coal as 1,500 to 2,000 lb. per square inch; this, of course, varies, but from these figures it may be assumed that seams below 2,000ft. in depth are liable to crush. If any part of the seam is removed, added weight is thrown onto the remaining coal. It is therefpre essential that for effective working this extra weight must be removed or supported as soon as possible.The outstanding principle in the support of mining excavations is to ensure that the supports are set as soon as possible after the natural support has been removed.Where a system of bord and pillar is applied, the early setting of supports reduces the extent to which the roof bends, thereby reducing the liability to ·tension fractures at the centre of the road.

Jan 1, 1947

By Hayes J. A

The satisfactory ventilation of an extensive coal mine is a subject which requires continual attention from all concerned.It must be remembered that a colliery contains many miles of workings, extending in all directions and throughout which noxious gases may be given off either naturally or by oxidation of the coal; fumes from explosives will be produced, dust will be gathered and carried in suspension, and water will be evaporated, producing a high humidity. Hence a considerable quantity of air in movement must be available to provide sufficient oxygen for men and horses, as well as to dilute and sweep away impurities, and maintain a tolerable degree of coolness.To maintain these conditions a modern colliery is divided up from the main ventilation shafts or adits (as the case may be) into a system of main airways, and in the working districts is further subdivided into district splits. To initiate the air movement, large centrifugal fans with a displacement capacity of up to 400,000 cu. ft. of air per minute are installed, generally in drifts off the upcast shaft, or adit, and at the return end of the ventilating circuit. These fans are thus exhausting fans and by producing a region of low density bring the heavier air at the other extremity of the circuit into movement to correct the difference in density, so far as it is not prevented by the frictional resistance of the airways. A flow of air is thus established, and it is obvious that to enable this volume of air to be as great as possible, the frictional resistance of the mine airways should be maintained at the lowest practicable figure. To this end, main airways should be as large as possible, have sides as smooth as practicable, and be straight, any necessary bends being of large radius.REQUIREMENTS OF THE VENTILATION SYSTEMThe New South Wales Coal Mines Regulation Act contains stringent provisions on requirements of the ventilation system. The main points are expressed in the following extracts:"In every mine which is in operation, unless a certificate of exemption from compliance with this rule has been granted by the Minister, whether any person employed therein shall be...

Jan 1, 1947

A contract for three 20 ft diameter vertically mounted axial flow fans of the same aerodynamic design, was placed by Mount ]sa Mines Limited in 1963. The hydraulic blade pitch changing mechanism, the method of blade fabrication, and the roll out centre casings are features of these fans. Protection devices and fan control are designed for unattended operation and remote control. The erection and commissioning of the fans during 1964-65 is described.

Jan 1, 1967

By Campbell Brown GA

IN 1904-5 diamond drilling operations in the Mount Morgan mine proved the presence of some inillioils of tons of rich, copper-gold ore, averaging about 45% to 50% silica and 22%Fe as sulphide. To smelt this ore in blast furnaces, without previous concentration, large quantities of basic flux.were required. Unlimited quantities of cheap, limestone, were available at Marmor, on the GladstoneRockhampton railway, 50 miles from Mount Morgan, but the supply of iron flux was a more difficult problem. Smelting operations started, with one' furnace in January, 1906, using as flux low-grade sulphide ore fro:m. the mine, containing very little silica. When the second, furnace was blown in this was supplemented by ironstone from, small aeposits in the immediate district. It was recognized that these sources of supply would be insufficient to keep the full plant going after the third furnace had been blown in. Accordingly, the deposits at Eabra and Mount Etna were opened, neither of which proved capable of supplying the quantity required viz, 1000 tons per week. Negotiations were meanwhile being conducted with the Marble Island Iron and Limestone Co. to obtain the right to mine at Iron Island, where a sufficiently large deposit was known to exist. Shipments from this source commenced in January, 1907, and ceased at the end of July of this year, when the metallic flux from...

Jan 1, 1912

By C Li, K McDonald an, T Nicholson, C Brown

The relative reactivities of chars prepared from different coal samples at temperatures in the range 500 to 1150¦C were determined by measuring the rates of metallisation of a standard ilmenite concentrate. The results have been interpreted in relation to different measured physical and chemical properties of the chars. Char reactivities were found to correlate with the maximum specific surface area (SSA) of the chars, obtained from plots of SSA versus temperature. Weathering of coal samples gave higher reactivities which correlated with higher SSAs. Experiments using recycled chars showed that the high internal SSAs developed during earlier reduction reactions provide no benefit in terms of increased metallisations. The important role of char hydrogen contents in controlling low temperature metallisation rates was demonstrated. Chars prepared from different rank coals had the same hydrogen content when prepared at the same temperature. Ilmenite metallisation rates had a linear dependence on the hydrogen content of the chars. Large differences in the slopes of the metallisation versus H2 content curves for different chars were interpreted in terms of SSA variations and catalysis of the gas reactions by dispersed metallic iron particles in the chars. A simple test based on magnetic separation of the char was shown to give an indication of enhanced reactivity due to contained metallic iron.

Jan 1, 2001

By Carthew SJ

The early period of South Australia's mining history was dominated by Cornishmen as large numbers of miners and their families migrated to escape closure of the Cornish copper mines. Records show that Carthew families migrated from Kent and Cornwall to South Australia. Those from Redruth, Cornwall, were miners and their family history provides an insight into the condi- tions under which early miners lived and worked. Carthews are one of the oldest surviving mining families in South Australia and their movement pattern has been typical of many other early Cor- nish mining families.

Jan 1, 1987

By D Head

IonicRE acknowledges within our mining industry, there is a common belief that workplace health and safety, often referred to as safety, is just a matter of ‘common sense’ – something obvious and easy. However, at IonicRE, we hold a different perspective. We understand that safety is far from easy. We recognise the need to emphasise the importance of understanding and conveying the inherent difficulties of working safely. We are committed to implementing processes that support individuals in achieving our safety objective of eliminating fatalities and permanently disabling injuries. To build resilience and sustainability into safety performance, we draw parallels with the principles underpinning sustainable and exceptional production performance. Achieving sustainable safety performance demands effective leadership, meticulous planning, adept management, genuine care and unwavering commitment. We’ve leveraged various tools and techniques, such as DISC theory, Maslow’s hierarchy, process control, Kaizen, Six Sigma and Kirkpatrick’s 4 levels, among others, to facilitate this improvement. There methods play a pivotal role in developing a Safety Blueprint for enhanced safety performance. This paper provides an overview of IonicRE’s Safety Blueprint, a strategic framework for developing our safety capability. Our capability is underpinned by three key pillars. Firstly, a comprehensive risk management approach is imperative, encompassing the understanding of hazards, the identification of threats to our people and the associated risks. Secondly, it entails providing and enforcing accountability to sustain our safety capability. Lastly, it involves constructing an effective defence system against threats and harm. Implementing these pillars requires a meticulously devised change process. Anticipating resistance and potential setbacks, we underscore the importance of having the right people and a wellcommunicated vision for safety at IonicRE. A Safety Blueprint serves as a detailed plan outlining the path toward a future goal. At IonicRE, we contend that safety in the mining industry has generally lacked a coherent and effective Safety Blueprint – a comprehensive plan to navigate the journey toward a destination. Drawing parallels with NASA’s detailed plan for landing a man on the moon safely, we question why, as an industry, we cannot similarly eliminate fatalities. While progress has been made in the last century, we must not wait another 50 years to eradicate fatalities from our industry. Examining Safe Work Australia data from 2008 reveals that 47 per cent of mining fatalities result from vehicle activity and 40 per cent stem from individuals being struck by an object. As of December 7, 2023, seven lives have been lost in the mining industry in Australia this year, indicating a stubborn trend mirroring 2022, with limited improvement over the past 25 years. These incidents are not isolated or unexpected. We understand the hazards and controls, yet fatalities persist. IonicRE considers that the mining industry stands at a critical juncture – do we accept a plateau in mining safety performance, or do we rethink our approach? At IonicRE, we are thoroughly reassessing the hazards that threaten our people, systematically redefining effective risk control measures and establishing a robust framework to hold individuals accountable for the effective implementation of the control measure.

Apr 16, 2024

By M Balamurali

In mining, grade control generally focuses on blasthole sampling and the estimation of ore control block models with little or no attention given to how the materials are being excavated from the ground. In the process of loading trucks, the underlying variability of the individual bucket load will determine the variability of truck payload. Hence, accurate material movement demands a good knowledge of the excavation process and the buckets’ interaction with the environment. However, equipment frequently goes into off-nominal states due to unexpected delays, disturbances or faults. The large amount of such disturbances causes information loss that reduces the statistical power and biases estimates, leading to increased uncertainty in the production. A reliable method that inferences the missing knowledge about the interaction between the machine and the environment from the available data sources, is vital to accurately model the material movement. In this study, a twostep method was implemented that performed unsupervised clustering and then predicted the missing information. The first method is Density-based spatial clustering of applications with noise (DBSCAN) based spatial clustering which divides the diggers’ and buckets’ positional data into connected loading segments. Clear patterns of segmented bucket dig positions were observed. The second model utilised Gaussian process regression which was trained with the clustered data and the model was then used to infer the mean locations of the test clusters. Bucket dig locations were then simulated at the inferred mean locations for different durations and compared against the known bucket dig locations. This method was tested at an open pit mine in the Pilbara region of Western Australia. The experimental results demonstrate the advantage of the proposed method in inferencing the missing information of bucket-environment interactions and therefore enables miners to continuously track the material movement.

Jun 22, 2022

The commercial outcomes from new mining projects or brownfields expansions often fall short of feasibility study forecasts because of technical under-performance. This paper: reviews past feasibility study performance; identifies the key drivers of underperformance; and proposes actions that can be taken to manage the risk of underperformance. There have been a number of published reviews of feasibility study performance since the 1970s. The results of these studies are summarised together with recent unpublished data. Key drivers of underperformance include inadequate metallurgical testing, simultaneously pushing a number of project parameters beyond comfortable limits and a failure to recognise the linkage between mining rate and head grade. Actions can be taken during the data acquisition phase and during the feasibility study to manage project technical risks. These generally require a more flexible approach to study management than can be achieved under a ælump sumÆ contract.

Jan 1, 2003