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By Kim M

Mukuk gold mine in South Korea produces a pyrite concentrate containing gold associated with arsenopyrite as a gangue mineral. The effects of Portland cement as a depressant on the flotability of arsenopyrite were studied to improve the separation of arsenopyrite from pyrite concentrate containing gold. A series of the fundamental flotation tests were performed using Portland cement as a function of pH and concentration of the collector. Flotation recovery of pyrite and arsenopyrite in the fundamental tests with amyl xanthate showed that arsenopyrite was depressed by the addition of a moderate amount of Portland cement, but pyrite was not depressed by it. In the flotation tests of the artificial mixture samples with arsenopyrite and pyrite, following pH were adjusted to be 10.5 by Portland cement, different amount of amyl xanthate was added. The results from these studies showed that flotation recovery of pyrite was 100 per cent under the condition of some addition of amyl xanthate, but arsenopyrite was not floating at all. Portland cement shows remarkable depression of galena, but its effect on the flotability of chalcopyrite is not as clear. In the pulp under Portland cement addition, chalcopyrite can be easily activated by the addition of sodium bisulphite, whereas galena is depressed more effectively. From the batch flotation tests with the pyrite concentrate, the galena concentrate and the Cu-Pb bulk concentrate from the mines, it was confirmed that the results of the batch flotation tests agree with the results of the fundamental flotation tests. The effects of depression by Portland cement on pyrrhotite, marmatite and stibnite are also discussed briefly.

Jan 1, 1993

By C Smith, D Lilly

The Lafarge Marblehead Plant in Marblehead, Ohio, USA produces 4.2 million tonnes of sized aggregate yearly. In 1997, a program was instituted to maximise primary crusher productivity through the optimisation of blasting variables and procedures. A proprietary blasting shot report database and the Lafarge production database was statistically analysed to provide guidance in the program. Blasting powder factor (kg/m3) was the main control variable utilised to increase crusher throughput. In 2005, the program was refined to increase the production of certain high margin aggregate sizes and the reduction of fines. The principal blasting component affecting the percentage of high margin size production appears to be pattern area (burden and spacing area). This can be coupled with powder factor to optimise the production rate of high margin aggregate sizes. The size optimisation program incorporates the blasting shot report database, Lafarge production database, statistical analysis and aggregate sampling. A preliminary indication is that the production of high margin sizes (12.7 mm X 4.8 mm, 24.4 mm X 12.7 mm, and 50 mm X 25.4 mm) has been increased seven to 12 per cent utilising these techniques. As an added benefit, blasting costs have been reduced linearly as burden û spacing pattern areas have increased and powder factors have decreased. The program is ongoing and will investigate other blasting procedures and variables including electronic blasting caps to further increase the production of high margin products. The statistical methods involved in the analysis are described in this article for use in other mines and situations. The methods described can be used to optimise crusher throughput, digging rates and product size.

Jan 1, 2007

Aspects of the formation, decomposition and acid solubility of zinc ferrite were examined to find potential ways of increasing the recovery of zinc from a calcination process of mineral concentrates. Ferrite can begin to form within 2 hours at 450¦C. while complete reaction can occur after 35 minutes at 700¦C. The nature of the starting materials has a pronounced effect on the rate of formation and below 700¦C. ZnSO4 and Fe2O3 proved to be the least reactive of the materials investigated. It is possible that iron in a mineral admixed h sphalerite can be converted to a relatively inactive form, however, it does not seem possible to prevent zince f formation when iron is in the sphalerite lattice. At the two temperatures examined, 650¦C. and 700¦C, the presence of SO2 in the atmosphere accelerate .e formation of ferrite. Prolonged exposure to such atmospheres, however, caused the ferrite to decompose to ZnSO4 and Fe203. The optimum temperature for decomposition was 650¦C. and it was virtually complete within 2 hours in an atmosphere of 10% SO2 in air. Zinc ferrite was also decomposed by CO at low concentrations, and by heating with limestone at 1000¦C. for at least 2 hours. The solubility of zinc ferrite in acid was influenced by the starting materials used. As both the reaction temperature and the time at temperature increased the acid solubility decreased. The acid solubility was a minimum when the ___i_.. n - I -r~...................c -..... F, fe..i+e --A frn... A01- +^ Z(lo/

Jan 1, 1970

By S Paciornik

The traditional trading of iron ores is based on chemical specifications and particle size distribution. However, recent characterisation studies, that bring additional information like mineralogical composition and microstructural (textural) aspects, have become important. They contribute to determination of the iron ores downstream beneficiation operations and subsequent steelmaking processing, allowing improvements on both new and existing processes. Despite progress in commercial scanning electron microscope/energy dispersive spectrometer (SEM/EDS) automatic instruments in the last decade, these systems are not capable of performing the identification and discrimination of major iron ore minerals (haematite and magnetite) and the consequent description of its microstructure. On the other hand, reflected light microscopy (RLM) can easily distinguish the iron oxides by their reflectancies, but it cannot discriminate quartz and epoxy resin, which present similar colour on images. The present work proposes an innovative method to perform a quantitative mineralogy characterisation of iron ore based on RLM-SEM co-site microscopy. This technique combines images obtained by RLM and SEM through an automatic registration procedure that accurately aligns the two kinds of images of each field. In fact, it creates multi-dimensional images, which are then analysed using image processing and pattern recognition techniques. The case study is an itabiritic iron ore from Quadrilßtero Ferrffero (Brazil) which contains mainly quartz, goethite, magnetite and haematite. The discrimination of phases that are not distinguishable with either RLM (epoxy resin and quartz) or SEM (haematite and magnetite) can be performed through this multimodal approach, allowing the subsequent mineralogical quantification. The mineralogical quantification computed by image analysis was consistent with independently obtained results based on the Rietveld technique.

Jan 1, 2008

Placer Dome Asia Pacific operates eight mines in the region and has two closed operations that are either under rehabilitation or at the latter stage of care, monitoring and maintenance. All operating mines are scheduled to close within the next ten years based on current proven reserves. Mine closure planning and associated risk assessments are integrated into both strategic planning and day-to-day operations within the Placer Dome group. Mine closure is all about predicting the potential risks and Placer DomeÆs knowledge has improved following the planned closure at Kidston Gold mine in North Queensland. Planning for closure commenced in earnest in 1994, and focused on identifying the issues and associated potential risk to the environment, and ensuring that the most suitable control measures were implemented leading up to and following closure in July 2001. At all times during the process of planning, implementation, safety contractor management and post closure, the identification of risk and potential threats to the business have been identified and managed. Post closure risk assessment of rehabilitation strategies potential to fail has been completed in conjunction with URS and opportunities to manage these potential failures in perpetuity will be discussed along with lease surrender. Misima Mines is currently processing low-grade ore and plans to close in 2004. Planning for closure has been ongoing for several years with a focus on the social aspects and the impact of the mine closing on a remote island community. Misima Mines has assessed the risk profiles using a community closure focus group, to identify both the biophysical and social aspects for closure.

Jan 1, 2003

By V Lickfold, A J. Crawford, A J. Wilson

A total of 12 alkalic porphyry centres of Late Ordovician age have been discovered in two mineral districts within NSW. The alkalic porphyry deposits are hosted within shoshonitic volcanic centres that formed where a major cross-arc basement structure (the Lachlan Transverse Zone) cut the Ordovician Macquarie Arc. The Macquarie Arc was amalgamated with the back-arc basin sediments of the Wagga Marginal Basin and with the proto-Pacific margin of Gondwanaland to form the Lachlan Fold Belt after the cessation of arc magmatism in the Late Ordovician. Within the Ordovician volcanic belts of NSW, the alkalic porphyries are the most significant mineral deposits economically. The combined resource of the Cadia district porphyries (729 Mt @ 0.79 g/t Au and 0.30 per cent Cu) makes Cadia the worldÆs seventh largest known porphyry gold system and the largest known gold resource in an alkalic porphyry system (574 t Au). Hydrothermal alteration in the alkalic porphyries comprises a complex sequence of potassic, calc-potassic, sodic, calc-sodic, propylitic and late-stage, typically fault-controlled phyllic assemblages. Hematite dusting is common in many of these alteration assemblages, giving the intrusions and the altered volcano-sedimentary host sequences a distinctive pink-orange colouration. Intensely developed hydrothermal alteration assemblages are localised to within a few hundred metres of the composite intrusions that sourced the mineralising fluids, making these deposits difficult exploration targets. Sulfides are typically zoned, with several of the deposits having bornite-rich cores, chalcopyrite-dominant annuluses and pyritic outer haloes. Gold is well correlated with bornite in most of the deposits, and with chalcopyrite at Cadia Hill.

Jan 1, 2002

The common notion that the Box Hole Bore mineralization represents a variant of the Mississippi Valley type, has not been supported by the present investigation. Most of the common characteristics of Mississippi Valley type, namely 1. saturated saline brines; 2. low temperature domain; 3. mineralization in intraformational breccias and collapsed anticlinal structures; 4. hydrocarbon-rich or foetid carbonates, and 5. very simple geochemistry seem not to be applicable. The Box Hole Bore mineralization features: 1. moderately saline brines (18% NaCl); 2. very high temperature (495¦-520¦C) and low density brines, of critical vapour:water ratio and low pressure of formation (700 bars); 3. mineralization confined by faults and ex- tending laterally into carbonates of high pore volume such as stromatolitic dolo- mites; 4. ore environment characterized by oxidizing conditions, such as ferruginous carbonate and silica sands of high energy environment (heavy mineral banding) and 5. more complex geochemistry than is normal for Mississippi Valley type deposits (copper sulphosalts, and appreciable silver content). Additionally, the ore has un- usual textures formed by the replacement of carbonates and barite by large idiomorphic galena crystals. The pressure and temperature domains of the Box Hole Bore mineralization indicate post- Devonian emplacement and local high heat flow, possibly related to the Alice Springs Orogeny. Because of high lead and zinc trace element con- tents (100-600 ppm) of the carbonates, even out- side mineralized areas, it is possible that the mineralizing fluids have derived their metal con- tent from a local source, possibly aided by evap- oritic concentrations of the tidal to supratidal sequences. The new model for Box Hole Bore gives treater importance to the confining faults.

Jan 1, 1984

This paper is written as a supplement to that of Edwards, Baker and Knight on "The Geology of the Wonthaggi Coalfield" 1, the West Area pit being in an early developmental stage at the time of their paper. The thin seams to the west of Dudley Basin 2 had beenknown for many years but it was not until 1935 that it became necessary to work them. The West Area Pit came into production as Dudley Area Pit approached exhaustion in 1937. From available information it was estimated that early work would be in a 36in. bottom seam. The present top seam was not included in the reserves, but it was to be extracted where it proved thick enough for economical working.THE SEAMSEdwards, Baker and :Knight (1944) had insufficient information to correlate positively the West Area seams with those in the Dudley Basin. Their opinion was, however, that they were a westerly extension of the Bottom Seam. Since then the driving of the present north-east heading towards No. 4 Bench McBride Tunnel has established that the West Area seams are those worked as Bottom Seam in the Dudley Basin. West Area Top Seam is a seam that occurred above the Bottom Seam in the Dudley Basin. Only sporadic attempts have been made to work it in Central Area, because 30in. was considered an economic minimum height until recent times. This seam should not be confused with Top Seam, Dudley Basin, which lies some 300ft. above the bottom seam measures and except in isolated areas over deeper workings has been eroded away in West Area.

Jan 1, 1953

The purpose of this paper is to present a detailed account of the development of the Blasthole Diamond Drilling method of stoping now used at the property of Big Bell Mines Limited, in Western Australia.The ore body is one of the large low grade gold deposits of this State, being a continuous lens 1,850 ft. long and ranging in width from 15 ft. at the ends to 120 ft. at the widest part, the average width being 59 ft. It was first worked in 1913 by a local syndicate, and up to 1924, when operations ceased, 64,448 tons of 3.4 dwt. ore were mined from a shallow open cut. Between 1928 and 1932, 15 deep diamond drill holes were put down to test the ore body at vertical depths ranging from 100 to 700 ft. On the information gained from these drill holes, Premier Gold Mining Co. Ltd. began underground explQration. A level was driven at a depth of 253 ft. and crosscuts put out to the full width of the, orebody at intervals of 100 ft. along the strike, all ore broken being put through a sampling plant. On completion of this sampling,' Big Bell Mines Limited was formed as the operating company, and a plant with a capacity of 1,000 long tons per day was erected and mining and milling operations were commenced in 1937. Ore was first mined from glory hole stopes, 65 ft. long, separated by 35 ft. pillars, by benching using conventional steel with changes up to 20 ft., all broken ore being hauled to the main shaft on the...

Jan 1, 1948

By Lee M. F, Guilfoyle K

A large hard rock rib pillar was recently preconditioned at Mt Charlotte mine using a novel blasting technique. The motivation for trialling this procedure was a history of past pillar failures, with associated seismicity. Design studies had shown that a new proposed pillar would be at risk of violent failure, and preconditioning was used in an attempt to reduce this risk. Preconditioning by blasting involves physically modifying a selected zone of ground in advance of mining, then forming the pillar so that it incorporates that zone of ground. The modified rock in the zone is intended to allow extra closure (yield) of the pillar in response to mining-induced stress changes. The ground modification was done by tight firing a blasthole array to fracture the rock. The blast design comprised pairs of pre-split blastholes to create a series of short cracks across the target zone, followed by main blastholes to fracture the rockmass between each pair of cracks. A monitoring program was used to establish whether or not the preconditioning was effective. It included conventional extensometers, stress change cells and closure stations, plus a seismic monitoring system. To-date, stoping is complete on one side of the pillar and has just commenced on the other. Results show significant movements within the preconditioned zone and on geological structures in the pillar, as well as lower stress in the pillar compared to an adjacent non-preconditioned site. The preconditioning technique can be applied elsewhere, provided its purpose, mechanism and side effects are understood. Benefits are likely to include more assured production, and successful pillar recovery even in high stress situations.

Jan 1, 1995

Large GDP increases in the Pacific Rim countries have been accompanied by similarly large increases in demand for oil products. In the case of residual fuels, this demand has been tempered by the substitution of other energy products such as coal or gas.In the region's developing and newly industrialised nations, it has not been possible to make the very large investements in infrastructure which allow other energy sources to be used for transportation. As a result, GDP growth has been mirrored in the demand growth for automotive fuels. Other non-sustitutable products such as lubricants have also benefitted by the region's GDP growth.The combination of a number of years of sustained growth, coupled with increasing quality requirements is now stretching the upgrading capacity of the region's refineries. If, as seems likely, the region continues to enjoy a high GDP growth rate, then this will be accompanied by increasing reliance on finished products coming out of the Middle East. The owners of the most simple form of refinery in which crude is simply distilled and the naphtha reformed into petrol will face major capital investments. If they decide not to bear this cost, they will face increasing problems in selling their surplus residual fuel oil at an economic price. Quality will become an increasingly important issue. Not only in the well publicised areas such as unleaded petrol, but also for products such as lubricants which play a major role in the efficiency of modem equipment. Quality of service such as hours of opening, ease of access, and service station facilities will also become increasingly important as the oil companies use these to attract customers and gain brand differentiation.

Jan 1, 1990

Models of the genesis of existing ore oodles and targetting of exploration for new mines are greatly enhanced by an-understanding of the plate tectonic environment existing at the time of mineral emplacement. In areas of recent or active tectonism, a study of the present-day crustal and upper mantle structure is an obvious starting point in unravelling the evolution of the accessible upper crust. Bougainville is the northern-most island in the Solomon Islands arc. A 7km deep trench almost 100km off its western coast marks the commencement of subduction of the Solomon Sea plate beneath the Pacific plate. As outlined by the seismicity, the subducted crustal slab under the southern half of Bougainville reaches the axis of the island at about 100km depth, from which point it dips near vertically another 300km into the upper mantle. Large surface blasts at the Bougainville Copper Mine at Panguna, Bougainville, Papua New Guinea were used to derive an unreversed upper crustal profile of the island. The crust appears to be relatively simple, being comprised of a 5km deep layer with a P-wave velocity of 4.5km/sec, overlying a l0km thick layer with a P-wave velocity of 7.2km/sec. Constraints on the 15km mantle depth were provided by the identification of both P to and S to P phase conversions of seismic waves from local shallow earthquakes at the Moho boundary. An upper mantle velocity of 7.95(¦ 0.15) km/sec was measured from travel times of selected shallow earthquakes along the strike of the island arc.

Jan 1, 1987

By A W. Bewsher, T C. McCu, D B. Mapleson

The Miitel nickel sulfide deposit has been overprinted by a family of late stage structures that have acted as conduits for fluids that have contaminated the orebody with arsenic minerals. This has resulted in highly variable and unpredictable arsenic grades throughout the Miitel orebody. The ore produced from Miitel is processed under a toll-treatment agreement with Western Mining Resources Kambalda Nickel Concentrator. Part of this arrangement includes a financial penalty if monthly average arsenic grades in ore delivered exceed 800 ppm. This constraint has provided an extra challenge to the Miitel mine geologist in addition to daily underground duties. Routine development and stope mapping, close spaced sampling and cross-sectional interpretation were used in building an understanding of the structural controls of arsenic mineralisation and ore repetition at the Miitel nickel mine, and in providing maximum input to mine planning and scheduling. The distribution of structures responsible for arsenic introduction is now well understood from detailed mapping, sampling, and interpretation. By applying these insights to mine scheduling, the operation has successfully managed arsenic levels within the required specifications. Geological mapping has also improved the understanding of the structural complexity of the ore deposit, leading to the addition of ore tonnes and an increased confidence in resource modelling. Regular sampling and tight controls on data quality provided confidence in a strongly skewed arsenic data set. Multiple Indicator Kriging has been used for resource estimation of the arsenic contaminated nickel ore since it allows explicit control of the spatial influence of extreme grades in the positively skewed arsenic sample population. Both the grade control and exploration data sets are used to model the arsenic distribution.

Jan 1, 2003

By M Wen, J Gerit, C A. Pelletier, D Muggli

On-land waste rock dumps at BHP Billiton Base MetalsÆ Island Copper Mine (ICM) near the northern end of Vancouver Island, B.C. continue to discharge ARD. These waters, which amount to approximately five million cubic metres each year, are injected into a three-layer, meromictic pit lake for treatment. The top layer is brackish water, replenished by each yearÆs rainfall (amounting to nearly 2 m/year). This top layer of water must meet effluent permit limits for heavy metals. This water eventually exfiltrates through a æbeachÆ waste rock dump, which is 93 per cent submerged along the north shore of Rupert Inlet. The middle and bottom layers of the Pit Lake are saline and currently oxic (2 mg/L dissolved oxygen) and anoxic (0.03 mg/L dissolved oxygen), respectively. Spreading of a liquid fertilizer every ten days throughout the top layer results in plankton and bacterial blooms that scavenge zinc, copper and cadmium out of this layer eventually to become mineral sediment in the bottom of the pit lake. Adsorption on planktonic skeletons and mineral precipitates also scavenges these dissolved metals from the middle and bottom layers to form bottom sediment. Sulfate reduction has recently begun in the bottom sediments. Diagenetic processes in the bottom sediments will eventually transform most of the dissolved heavy metals into insoluble sulfides. Cycling of ferric iron between the sediment and the water column and back seems to contribute dramatically to the biogeochemical metal removal processes. This biogeochemical system serves to maintain the top-layer water well within permit limits for discharge to the environment.

Jan 1, 2003

The ore deposits investigated are composed primarily of hcmatite and can be grouped into three categories depending on the amount of leaching of silica and carbonate which has occurred from the original iron formation, and on the amount of recrystallization of the hematite. Minor constituents are magnetite. goethite, and quartz.Texturally. there are five different types of hematite, formed at different stages during the genesis of the ores.These are1. anhedral hematite grains formed by recrystallization of hematite already present in the original iron formation.2. hematite formed by martitization of euhedral magnetite, 3. massive aggregates of fine- to medium-grain hematite formed by recrystallization of (l) and (2).4. tabular or prismatic hematite grains occurring around the boundaries of the massive aggregates or martite euhedra. and in fractures and5. specular hematite. which is present in fractures in ore types (l) to (4).Minor and trace-element analyses, determined using an electron-probe microanalyser. indicated that only silica (less than 0·01 per cent) and cobalt (less than 0·002 per cent) were present in the magnetite and hematite from unaltered iron formation and in the hematite from the ores. Low concentrations of trace elements are typical of magnetite in ores formed as marine precipitates. On the basis of the analyses alone. it proved impossible to distinguish between the five hematite types. A determination of the variation in rare-earth trace element contents between iron oxides in the iron formation and iron oxides in the ores indicates that the rare earths were depleted during ore formation. A possible explanation is that they were removed in solution with silica as it was leached from the iron formation.

Jan 1, 1971

By Christie AB, Bull VH

The geological environments of gold deposits are reviewed in relation to the strong resurgence in exploration for gold since 1979. The resurgence is due mainly to New Zealand's geological endowment with gold and its history as a gold producer. Major past production was from Cenozoic placers of Otago and Westland, late Cenozoic epithermal deposits of the Hauraki Goldfield, and the respective Paleozoic and Mesozoic lode deposits of the Reefton and Otago Goldfields. These same geological environments are the targets of current exploration, mainly in extensions of previously mined deposits. On the Westland and Otago Goldfields alluvial and fluvioglacial gravel placers, mainly representing lateral and depth extensions of previously worked ground, are being mined and prospected. Gold production in 1984 was exclusively from these deposits, and the development of mobile concentration plants has resulted in a great increase in mining activity. Mineralised zones adjacent to previously mined lodes in the Hauraki Goldfield, Reefton Goldfield, and at Macraes Flat (Otago Goldfield) are being intensively explored. At Waihi (Hauraki), an open-pittable resource of about 10 million tonnes of ore has recently been delineated. Some new deposit types and little explored environments are also receiving attention. They include: gold-sulphide quartz veins hosted in an alkaline granite dike in west Nelson; hot spring type gold deposits in fossil geothermal (epithermal) systems of Northland, the Hauraki Goldfield and the Taupo Volcanic Zone; and marine placers off the West Coast where an area of auriferous gravels has been outlined near Hokitika. There is potential in known deposits and prospects currently being evaluated for a large increase in gold production by the early 1990s.

Jan 1, 1986

By Kadoya H, Kondo Y

The Harima works were established in 1964 and started operation in 1966. The initial capacity was 3500 t/month of zinc and 1500 t/month of lead. Until 1990 a lot of improvements had been made and the capacity had increased 6600 t/month of zinc and 2200 t/month of lead without enlarging the furnace size. During the ten weeks campaign shut-down at the end of 1990, many modifications were carried out including the enlargement of the furnace shaft area. By these changes, the capacity has gone up to 7500 t/month of zinc and 2500 t/month of lead. In the sinter plant, the amount of SO2 rich gas supplied to the acid plant was raised to 50 000 Nm3/h from 43 500 Nm3/h. An electrostatic precipitator was adopted instead of a venturi scrubber to clean the rich gas. Oxygen enrichment has been continuously operated since August 1991, because the furnace capacity is more than the rate of sinter production. Utilisation of the sinter plant is high being as much as 97 per cent and the sulphur burning rate has been increased. In 1990 the furnace was replaced except the hearth. The shaft area was enlarged to 19.4 m2 from 15.3 m2. The target blast was designed to be more than 36 000 Nm3/h. Tuyere layout was changed to prevent slag breakouts. Due to these modifications shaft condition has been very good. Automatic launder jacket cleaners were installed to increase the lead cooling efficiency. Many other improvements and developments were also made. Coke powder injection from the tuyeres has been successfully operated since April 1987.

Jan 1, 1993

By G Yeowart, P D. Munro

The Prominent Hill copper-gold concentrator of OZ Minerals Limited in South Australia was built in 2008 and commenced commercial production in early 2009. It has a design ore throughput of eight million tonnes per year (Mt/yr). While the flow sheet has many items in common with other plants treating ores from iron oxide-hosted copper-gold deposits, the Prominent Hill concentrator also has some unique features. Plant design has been based on a 'template' of the very successful Ernest Henry concentrator. Initial options considered for processing Prominent Hill copper-gold ore are briefly examined as well as potential complications arising from the presence of a considerable tonnage of 'gold-only' material present in the deposit. Metallurgical test work and the subsequent decisions leading to the selection of a conventional crushing, semi-autogenous grinding (SAG) and rougher flotation circuit is discussed. One particular difference with other plants treating this ore type is that metallurgical tests and mineralogical studies identified that rougher concentrate had to be reground to a P80 of 20 - 25 microns or finer for adequate liberation of fluorine-bearing minerals. Subsequent satisfactory separation of fluorine-rich gangue material from the valuable copper sulfides requires highly efficient cleaner flotation to make a commercial quality copper-gold concentrate. Xstrata Technology's IsaMillÖ and Jameson Cell technologies developed to meet similar taxing fine grinding and flotation duties for the treatment of the refractory zinc-lead-silver ores of the Carpentaria-Mount Isa Mineral Province were selected for regrinding and cleaner flotation. Plant design has features aiding ergonomics for ease of operation and maintenance not commonly seen in recent projects with large sulfide flotation concentrators.

Jan 1, 2009

By Rospigliosi RT, Krouse HR

The San Vicente stratabound zinc-lead rhythmite deposit, Peru, is hosted in carbonates of the Late Triassic - Early Jurassic Pucara Group. These strata were deposited in a large, shallow water, carbonate platform which extended nearly continuously for 150 kilometers (north-south) in the eastern part of the Pucara basin.The distinctive sulfide-bearing rhythmites occur in three dolomite units which, from bottom to top, include the San Judas horizon with one sulfide-bearing manto; the San Vicente horizon with seven sulfide-bearing mantos including the main ore horizon; and the Alfonso horizon with three sulfide-bearing mantos. The dark gray sulfide-bearing dolostone layers range in thickness from a few millimeters to a few centimeters and contain variable amounts of carbonaceous material, pyrite, quartz, fine-grained sphalerite and galena. They are bordered on each side by selvages of yellow to red-brown coarse-grained sphalerite containing minor amounts of galena. Coarsely crystalline white or gray sparry dolomite is found between the coarse-grained sphalerite layers. Although commonly stratiform and uniform in thickness, the dark layers curve, "pinch out," coalesce, and form "islands" and "peninsulas."Mineral replacement textures, the paragenetic sequence, and presence of sparry dolomite, bitumen, intraformational breccias and isotope data support a hydrothermal replacement origin by metal-bearing solutions that deposited the ore and related minerals in space previously occupied by dolomite and evaporite minerals. The alignment of the Zn -Pb deposits, and at San Vicente the orientation of the mantos, the spatially and temporally associated igneous sills and the tourmaline-bearing sandstone support hydrothermal mineralization driven by a magmatic heat source in a tensional regime.

Jan 1, 1990

By E Ferrow, R Herbert, M E. Malmstr, M Fuchs

The study of microbial sulfide oxidation and oxidation rates of tailings requires the use of sterile control samples in laboratory experiments for comparison purposes. The need for sterile tailings sand is also apparent in the study of microbial communities and processes. This study compares six different methods with regard to sterilisation efficiency and investigates chemical and mineralogical changes in the samples as the result of sample treatment. In addition, the effect of sterilisation on mineral weathering rates is also studied. The efficiency of the different methods with regard to sterility is estimated by most probable numbers (MPN) of both sulfur and iron oxidising bacteria. The sterilisation methods that were compared are: washing with sterile water, washing with ethanol, applying antibiotics, repeated heating to 70¦C, autoclaving, and γ-irradiation. There are several possible drawbacks with the different methods, including the risk of an applied chemical acting as a substrate for micro-organisms in the system, and the risk of altering the tailings. The results show a substantial difference in sterilisation efficiency between the treatments. For example, autoclaving, repeated heating, ethanol and irradiation efficiently kill micro-organisms, rendering an undetectable amount of bacteria after one month of incubation, whilst washing with water exhibits virtually no microbiological effect, with a bacterial content comparable to the control. The use of antibiotics for sterilisation ranks intermediate: the lag-phase was twice as long in the antibiotics treatment compared with the controls. X-ray diffraction, optical and electron microscopy, M÷ssbauer spectroscopy, and mineral magnetism indicate no significant change in the bulk mineralogical composition. However, X-ray photoelectron spectroscopy analyses show that with some of the treatments, sulfides are partially oxidised, as indicated by the formation of sulfate and partially û oxidised sulfur species at the tailings surfaces. Aerated batch weathering experiments performed on sterilised tailings samples and untreated controls indicated that while the initial rates of element (S, Fe, Cu, Zn, Mg, Na, K, Ca) release may differ between the samples, over the course of ~100 days of experiment at pH 2 and room temperature, the rates declined toward a similar value for all samples. To conclude, there does not appear to be one perfect method for tailings sterilisation. Autoclaving and heating damage the mineral grain structure and oxidise the sulfide surfaces. Ethanol, antibiotics and rinsing greatly alter the pore water chemistry through the washing procedure. In addition, ethanol and denatured antibiotics might serve as a substrate and also, in the case of antibiotics, adhere to mineral surfaces thus obstructing chemical reactions. Irradiation seems to be the preferable method on an overall basis, although the formation of surface Fe3+ was suggested by M÷ssbauer spectroscopy.

Jan 1, 2003