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By D Lau

Traditionally X-ray diffraction (XRD) has not been significantly used by the cultural heritage sector, as the most commonly used technique, X-ray powder diffraction (XRPD), requires sample removal from the artwork or artefact, followed by grinding of the sample to a fine powder. With the development of micro-X-ray diffraction (micro-XRD) and other associated advances, non-destructive, in situ analysis of crystalline pigments on micro-areas of paintings and artefacts has become possible. This is illustrated with the application of this technique to the in situ analysis of propriety paints, paint cross-sections and small paintings. However, workers have noted that XRD can be insufficiently sensitive with pigment mixtures, due to matrix effects. This study obtained X-ray diffractograms of 17 single pigment preparations and determined relative amounts of crystalline content. The purity of single pigments was compared with Joint Committee on Powder Diffraction Standards (JCPDS) database diffractograms. The impact of pigments with high X-ray absorption coefficients on the detection limits of pigments with low X-ray absorption coefficients was further investigated by building on work done with the chromium oxide-zinc oxide series with the preparation of a second series of binary mixtures of zinc oxide (which has a high absorption coefficient and is almost fully crystalline) and ultramarine blue, which has a lower absorption coefficient but which is more crystalline. Semi-quantitative analysis, where baseline and absorption factor corrections are made, confirm detection limits as low as five per cent for chromium oxide and ultramarine blue when in a binary matrix with zinc oxide. However, this type of analysis is very time consuming. So in order to theoretically simulate issues that will be encountered with binary pigment mixtures, the single phase diffractograms were used to theoretically investigate the matrix effects of the three white pigments with the various coloured pigments. This illustrated that detection limits can be as low as five per cent or in non-ideal conditions, such as with partial peak clashes or where there are large differences in relative peak intensity, as high as 50 per cent. These results have significant implications for the analysis of painted surfaces on artworks or artefacts. It has been demonstrated that ideally this method is more suited to the investigation of surfaces where there is minimal mixing of pigments or where there is not a significant difference between the absorption coefficients of the mixed pigments.

Jan 1, 2008

By W Potma, C Brauhart, S Halley, S Urbisinov, A Scogings

Truly integrated, quantitative, 3D GEOmetallurgical (or mineral system) characterisation, classification and 3D modelling should provide a cradle to grave unifying link across the exploration and mining value chain. All too often, spatially representative (quantitative) characterisation and modelling of a mineral system is delayed until feasibility stage, incurring a significant opportunity cost. The application of robust GEOmet characterisation methods early in the project lifecycle (at exploration stage) improves ground selection, exploration, and Mineral Resource estimation outcomes, long before there is a need for metallurgical test work. The value of this early provision of quantitative 3D mineralogy models is compounded at project feasibility stage, and continues to accrue over the entire project lifecycle, delivering cost savings, improved decision making and early warning of issues and opportunities.CITATION: Potma, W, Halley, S, Scogings, A, Urbisinov, S and Brauhart, C, 2018. Putting the ‘GEO’ back in front of GEOmetallurgy: importance of early implementation of quantitative mineral system characterisation, classification and modelling, in Proceedings Complex Orebodies Conference 2018, pp 55–57 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By Gonzalez JM

The Pao gold prospect in N. Luzon, is an example of a high sulphidation epithermal gold system hosted in Mid-Tertiary alkaline volcanics, in the Philippine Arc. Styles of mineralization include: quartz-enargite veins, vuggy silica alteration bodies, and pervasive low grade (0.5ppm) gold mineralization, associated with kaolinite-pyrite-quartz alteration, and geochemically characterized by high As and Hg. Early magnetite-epidote-chlorite alteration linked to an unexposed granitoid is overprinted by an extensive zone of advanced argillic alteration (kaolinite-pyrite-quartz). No alunite is recorded. Important controls of mineralization include; a broad anticline intersected by axial faults, permeable pyroclastic units, and upward confinement of the alteration system by a highly impermeable, clay-rich volcanic unit. At this stratigraphic position the most important mineralization waz developed. The Pao high sulphidation system is not closely related to a stratovolcanic centre, and has formed subsequent to deformation of the volcanic field. It may, however, be related to an unexposed comagmatic intrusion.

Jan 1, 1990

By Duniam P

Sequencing of large underground firings is a critical aspect of blast performance. Using theory developed in open cut operations, where blast results are easier to quantify, a new technique for sequencing underground mass blasts has been developed. The basis for the technique is to identify timing regimes to control fragmentation and relief then apply non-electrics to fit these criteria. The use of computer software to graphically interpret delay statistics enables the evaluation of designs in a realistic manner.

Jan 1, 1995

Based on the idea to copy crystallisation and precipitation phenomena occurring in nature, a new technology was developed allowing the preparation of metastable, mineral forming solutions. If these solutions are brought into soil or rock formations, directed precipitation of slightly soluble minerals takes place. Immobilisation of dissolved heavy metals as well as overlaying of reactive mineral surfaces with insoluble minerals can be achieved. It is possible to prepare solutions leading to the formation of gypsum, BaSO4, CaCO3, Ca(OH)2, Al(OH)3 or Fe(OH)3. The successful large-scale application of BaSO4 forming solutions was demonstrated in the former uranium mine Koenigstein of Wismut GmbH, (Germany).

Jan 1, 2003

By Krokhmai VS, Sayko OP

The paper summarises the theoretical and experimental studies which led to the development of new industrial equipment designed to recover liberated gold from placer gravity concentrates. The new technology is based on environmentally clean magnetic methods, which avoids use of mercury in the production process and obtains higher gold recoveries compared to the amalgamation technique, and which can reach 98.6 - 99.5 per cent. The complex of equipment thus developed is now commercially used at nine Russian gold mining operations. Six more such complexes are due to come on stream in 1993, some of them outside the CIS. The new technology appears to hold much promise for the recovery of precious stones (diamonds, rubies etc) semi-precious stones (pyropes, chrysolites etc) and also artificial diamonds, for which case there are encouraging laboratory results.

Jan 1, 1993

By Burman B. C

This paper describes studies into two particular aspects of the Lochiel deposit which formed part of feasibility level geot2chnical and hydrogeological investigations for proposed open cut mine development. The two aspects were depressurisation of thick beds of silt located through the profile and the determination of characteristics and origins of soil structure and their effect on pit stability. The studies were very detailed and multi disciplinary and highlight the integration of geology, geotechnics, hydrogeology and mining that is required for mine development studies. It is considered that as more marginal deposits are developed throughout the world the demands for efficient economic mining together with in- creasing scales of operation will require simi- lar types of studies. As such the studies pre- sented herein are likely to be a forerunner to a,emerging trend for development of open pit mines in difficult ground and water conditions.

Jan 1, 1986

Drill blasting is a widely used method for rock fragmentation in mining, quarrying and construction industries. Environmental effects such as air shocks, dust, flying rocks and ground vibration are unavoidable results and undesired effects of blasting. Among these ground vibrations can have a damaging effect and may influence on long distances. Therefore various researchers have developed mathematical models to predict ground vibration after blasting. These models take into account the amount of explosive, distance and several coefficients related to the field under investigation. The developed models to predict ground vibration may yield different results for the same case. Selection of the most suitable model requires engineering judgment and evaluation of models. At this point, a computerised system helps the engineer to evaluate and select the most suitable model in order to design and plan a blasting pattern. The safe charge of explosive and magnitude of vibration after blasting should be predicted beforehand. Therefore a computer program namely 'prediction of blast induced vibration' (P-BIV) has been developed. This paper introduces and presents a computer program (P-BIV) which includes the set of models developed to estimate ground vibration to provide blasting engineers a tool to determine the amount of explosive for safe blasting.

Dec 6, 2010

By DAVID C LAURENCE

The richer, shallower sapphire deposits of the New England region of New South Wales which have been traditionally mined by the small miner are almost worked out. Larger mining and exploration companies are replacing the small miner and exploring for the primary source of sapphire or lower grade alluvial deposits.Although in recent years considerable exploration effort has been directed at locating the primary source, commercial exploitation of sapphire is still restricted to the working of alluvial deposits.If the Australian industry is to compete against Asian and African producers it must use cost effective exploration, mining, processing and marketing methods.

Jan 1, 1990

By S Latchireddi

Close circuiting autogenous and semi-autogenous mills is an energy efficient way of grinding and a number of operations have utilised this in the design of their comminution circuits. Owing to the large flow of slurry through the mill that results from operating this way the grates and pulp lifters have to be designed to cope. However, the literature has little or no information on how grate and pulp lifter size and design are related to their ability to remove slurry from the mill. Over the last few years the JKMRC has been researching this area and has developed relationships between grate/pulp lifter design and flowrate capacity. At the same time it has determined the major causes of pulp lifter inefficiency and a solution to preventing this inefficiency (the Twin Chamber Pulp Lifter). This paper describes the models that have been developed through this program and uses industrial scale data to illustrate their accuracy. Results from the industrial trials of the Twin Chamber Pulp Lifter are also presented.

Jan 1, 2000

By M N. Ingham

X-ray fluorescence (XRF) spectrometry has always been considered to be a comparative method of analysis. Reference materials are required to calibrate the analytical system. This paper describes the use of a set of æsyntheticÆ oxide standards, made from commercially available high purity compounds, to calibrate a spectrometer for 21 major and minor oxides. The spectrometer software uses simple methods of background correction, and a fundamental parameter method of matrix correction. Sample preparation is by fusion in 66 per cent lithium tetraborate, 34 per cent lithium metaborate. The use of synthetic standards, made from traceable compounds, brings XRF significantly closer to being a primary rather than a comparative method. Reference materials were used to validate the method described and examples of accuracy for major constituents are given using ores and other minerals. This method has successfully been used to analyse a wide variety of minerals and ores, as validation data shows. A titanium process example clearly shows the benefits of highest accuracy analysis.

Jan 1, 2008

By Taylor R. G

This paper reports a biogeochemical study of the Siberia lode of the Herberton tin field. Soil near the orebody contained high levels of Fe, Cu, Pb, Sn, As, Mld Mn. Polycarpaea spirostylis and Indigofera dominii were associated with these high levels but several other species apparently could not tolerate them. The potential of these species as indicator plants is discussed.

Jan 1, 1975

By Eggins SM, Crawford AJ, Maillet P

The Fiji Islands are remnants of a once continuous Solomon-Vanuatu-Fiji-Tonga volcanic arc (the Vitiaz arc), located at the boundary between the Indian-Australian and Pacific plates. They record a history of (i) arc volcanism the late Eocene to late Miocene, (ii) an extensive magmatic response to arc rifting (5.5-3.OMa) during which volcanism was dominated by shoshonitic to tholeiitic basalts, and as rifting continued, (iii) a transition from arc to intraplate volcanism. The Hunter Ridge-Hunter Fracture Zone separates the inactive South Fiji Basin from the actively spreading North Fiji Basin, and has been considered to be a transform zone, almost parallel to the motion vector of the Australian plate. However rocks dredged during the 1993 `Alize' cruise, from along the northern part of the Hunter Ridge are typical arc tholeiites, and therefore demand that subduction has occurred beneath the Hunter Ridge sometime during the last û 5Ma.

Jan 1, 1995

By V Sanmartfn, J Torracchi

The broad biodiversity of our country is manifested through several different biological forms. From the villages of Portovelo and San Gerardo in the southern part of Ecuador, some samples of water and rocks were taken in order to identify the native micro-organisms which take part in the natural processes of leaching of sulfurous minerals. The presence of Spp Thiobacillus ferrooxidans was determined together with a fungi sample which has not yet been characterised by the current workers. These have been isolated, grown, experimented and conserved in appropriate cryogenic environments. The present research intends to study the individual and group adaptation of the bacteria and the fungi upon suitable systems of agitation and ventilation, in combination with several different concentrations of refractory auriferous samples. These refractory samples were derived from old mine workings and the experiments were performed to test the effectiveness of the isolated species in bioleaching as pre-treatments upon the cyaniding processes. The capability of these bacteria to develop in environments with high concentrations of cyanide has also been studied, to investigate the possible use of bacteria in the biodegradation of cyanide. The presence of Thiobacillus ferrooxidans in acid conditions has already been tested in advance, however, the presence of fungi species in these conditions are studied to prove their efficiency as another alternative for the bioleaching of refractory auriferous minerals and Baptista, 1998).

Jan 1, 2004

By J P. Hsi

Recent increase in the development of underground space in urban areas in Australia has included soft ground tunnel construction. The ground movements associated with soft ground tunnel construction may present risk to other existing and proposed structures in the nearby vicinity. Much experience has been gained both in the UK and Asia in recent years in the engineering evaluation of this risk. The paper presents a procedure to assess these aspects of soft ground tunnel construction with reference to recent projects.

Jan 1, 1999

This paper reviews the geochemistry of weathered nickeliferous sulphidic and lateritic profiles, the supergene behaviour of nickel and ore-associated elements, and their implications for exploration in an attempt to distinguish between barren and mineralised nickeliferous profiles. Nickel is an abundant accessory element in ultramafic rocks with background concentrations in some units up to 0.25 weight per cent. Ore-grades in fresh rock are mostly associated with massive and disseminated sulphide zones within magnesium-rich layered ultramafic sequences. In lateritic weathered terrain, nickel is also concentrated in the regolith profile. This process not only upgrades nickel in the gossanous weathered product of sulphidic deposits, but for sub-economic sulphide zones and some ultramafic rocks, is sufficient to result in a supergene resource. Ore-grade accumulations of nickel in regolith after sulphide-poor ultramafic rocks are referred to as lateritic deposits. Nickel sulphide zones and their ferruginous weathering products are collectively referred to as sulphidic deposits and are the major source of nickel in Western Australia. Mineral exploration in the Yilgam Block is hampered by deep lateritic weathered profiles (eg Butt and Sheppy, 1975; Smith, 1977; 1982). During the nickel boom of 1967 - 1972, most discoveries resulted from the location of outcropping nickeliferous gossan and ironstone. Exposed ultramafic terrain with nickel sulphide potential were explored intensively, mostly by gossan and soil sampling. However, up to 85 per cent of the area of the Yilgarn Block is buried by transported regolith. In these covered areas, barren and mineralised rock responses at the surface are similar and soil sampling produced unreliable results due to many false anomalies. A statistical, multi-element approach to regional geochemical exploration has evolved. Potential trace element indicators investigated, include Co, Cr, Cu, Ir, Mn, Pb, Pd, Pt, Sc, Se, and Zn. In recent years, trace element ratios have also been tested with varying degrees of Success.

Jan 1, 1996

The relative importance of magmatic and metamorphic fluids in Archaean gold mineralisation has long been a subject of debate. Computer simulations can be used to explore the interaction between competing fluid flow drivers, thus providing insight into their role in mineralisation. This approach has been applied to Archaean gold mineralisation in the Yilgarn craton, Western Australia. A simple model representing regional metamorphism in a granite-greenstone terrane indicates that fluid produced during a regional metamorphic event in the Yilgarn was unlikely to have been involved in mineralisation, because it would have escaped from the crust long before the main gold event. Another model illustrates the competition between magmatic fluid production, convection, and deformation. The model shows that the timing of deformation relative to fluid production is important in determining the fate of magmatic and metamorphic fluids, and hence their potential to play a role in mineralisation. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Mishra S. N, Mishra R, Sen P. K

Control of silicon in produced through the submerged-arc furnace can result in reduced power and coke consumption in addition to improving the quality of the hot metal. A thermo-chemical analysis of the production of ferro-chromium was carried out to devise strategies to control the recovery of silicon during the manufacture of ferro-chromium. The presence of three thermochemical zones in the furnace with respect to the reduction of silica was recognised from this analysis. Any strategy for the control of silicon recovery has to take cognizance of these thermochemical zones. The effect of various strategies on the silicon level in the hot metal have been evaluated. Possible strategies, such as the reduction of coke level in the charge; the replacement of quartz; pre-reduction of the ore and the control of the temperature profile are discussed in this paper.

Jan 1, 1999

The geologic settings, geochemistry of host rocks, mineralogy and metal values in modern back-arc volcanic-hosted massive sulphide (VHMS) mineralisation are very similar to those in many ancient polymetallic VHMS deposits. The geology, distribution and styles of seafloor mineralisation in modem back-arc basins, especially the eastern Manus and Lau Basins, southwest Pacific, are compared to VHMS deposits in the Mount Read and Mount Windsor districts of Australia . Based on exploration and research in modem back-arc settings, geologists are now observing the direct analogues of the polymetallic VHMS deposits currently being exploited in ancient back-arc volcanic belts throughout Australia and the world.

Jan 1, 1995

By Waters JC

Pseudoclastic hydrothermal alteration textures occur within quenched coherent dykes forming part of a subaqueous dome complex (-4 Ma) on Ponza Island, Italy. These textures are similar to those observed in considerably older (-500 Ma) subaqueous volcanic rocks at a number of localities throughout the Mount Read Volcanics in Tasmania and elsewhere in ancient volcanic sequences of this type in Australia. This is significant because the processes of formation, hydrothermal alteration and secondary mineralisation of ancient volcanic sequences may be better understood if we can make comparisons with modern analogues. Observations at Ponza imply that these pseudoclastic alteration features form synvolcanically or immediately after dyke emplacement and lava extrusion. This is compatible with scenarios presented for their formation in ancient sequences in the Mount Read Volcanics, Tasmania.

Jan 1, 1995