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By R F. Johnston, I D. Sommerville

This paper presents an overview of the researches carried out in our laboratory on the application of plasma in recovery of alloy elements from waste slags and the treatment of lean ores, which are examples of advanced materials processing. After briefly reviewing the early work on the reduction of nickel, chromium, manganese, vanadium and titanium oxides, and a short investigation of the reduction of titanium oxide from the slag resulting from the blast furnace smelting of a titanomagnetite ore, the paper concentrates on the more recent studies on the reduction of an Australian scheelite. In some of these experiments, aluminium was used in addition to carbon as a reductant, in virtually all cases complete reduction was achieved within a relatively few minutes even with carbon alone during plasma processing. It therefore appears that this technique provides a possible processing route to facilitate the recovery of valuable alloying elements from non-traditional sources, or to permit process step elimination.

Jan 1, 2000

ecent work on decoppering lead is reviewed; CuS is formed rapidly even from dilute solutions of copper in lead. he mechanism of decoppering is discussed, and an explanation for the retention of metals such as silver in lead is dvanced. As decoppering tin appears to be an analogous process, the Cu-Sn-S system is studied at 300¦C. CuS, hich is not, an equilibrium product, is found in decoppering drosses. In the removal of nickel from lead, Ni3pb2S2 formed; preliminary measurements show the equilibrium nickel content to be greater than that obtained by tirring in sulphur. Decoppering bismuth is thermodynamically favoured, but is complicated by the occurrence of uBiS2. The Cu-Pb-S system is the only one of the four studied where the equilibrium can be calculated simply, as ' resence of ternary sulphide or other phases invalidates calculations based on binary data.

Jan 1, 1970

By M Magee, D Way

The Mount Isa Copper Concentrator was commissioned in 1973. In 1991, two autogenous grinding mills were installed replacing two stages of crushing, one stage of rod milling and one stage of primary ball milling. The cyclone overflow P80 of the secondary ball milling circuit was reduced to 120 microns due to the increased operating power in the AG/SAG mill circuits. A study of the mineralogy of the milled products and the plant flotation recovery indicated that the installed secondary grinding energy was more than what was required for adequate liberation of the chalcopyrite and half of it had potential for more effective use elsewhere. Halving the secondary grinding energy meant only one of the two secondary ball mills would be needed. The predicted saving in operating cost of one less ball mill was more than two million dollars per annum. This paper summarises various plant trials that were conducted in the Copper Concentrator to decommission one of the two secondary ball mills.

Jan 1, 2004

The Tregoora Gold Project is centred around the old Mitchell River Antimony Field located 100 kilometres west-northwest of Cairns, North Queensland. The project is currently the subject of a joint venture between Strategic Minerals Corporation N.L. and Hawk Investments Limited.Historical BackgroundThe Tregoora area was first prospected for antimony and gold around 1890. During the periods 1905 to 1914 and 1937 and 1944 approximately 100 tonnes of antimony and an unknown quantity of gold were won from a number of small mines the principal one being the "Retina". A strong increase in the demand for antimony in the early 1970's resulted in renewed exploration activity in the region and the re-development of the Retina Mine. Despite the intermittent interest in the region for antimony it was not until 1984 that the potential of the area for hosting gold resources was realised with the delineation by Strategic Minerals Corporation N.L. of a significant gold deposit now referred to as the Black Knight.

Jan 1, 1986

Synthetic and commercial activated carbons are characterised for several chemical and physical properties. A range of techniques is used to establish correlations between physicochemical parameters and gold- adsorption activities. The most important parameter in the carbon activation process for a product with a high gold-adsorption activity is the activation temperature. High activation temperatures yield products with large micropore volumes which provides sites that are ideal in size for adsorption. The surface area of an activated carbon is not necessarily a good measure of its adsorption activity. Surface oxygen-containing functional groups are identified by Fourier transform infrared spectrophotometry to be comprised mainly of ethers and hydroxyls. These functional groups line the edges of the micropores imparting a polar character to the pore and aid in the solvation of the adsorbate. Oxidants such as nitric acid result in a proliferation of surface carboxyl groups. resulting in a negatively- charged surface that is not conducive to the adsorption of gold.

Jan 1, 1993

The Permo-Triassic Bowen Basin developed during the final stages of the Tasman Orogenic Phase in eastern Australia. The basin has considerable economic value as a source of coal, natural gas and precious metals. The basin, which is of controversial origin, is preserved as a north-south trending, asymmetrical syncline bounded in places by faults. It is here interpreted as a retroarc foreland basin which developed on the landward (west) side of a continental arc associated with continent-ocean plate convergence. Initiation of the basin occurred via back-arc extension in Early Permian times, coincident with a phase of talc-alkaline arc volcanism. Early Permian, mostly marine sedimentation gave away to extensive coastal and alluvial plain depositional systems in Late Permian times, coincident with a resurgence of arc volcanism. Triassic sedimentation was almost entirely alluvial and coeval with westward propagation of thrust sheets from the eastern basin margin. Compressive tectonics climaxed in Middle to Late Triassic times, terminating sediment accumulation and uplifting the entire area.

Jan 1, 1990

Major exploration companies can have a problem with what to do with small precious metal ore bodies located through exploration programmes. Low tonnage, but high grade, ore bodies too small to justify in-house development.1.2 Ban Ban Mining is a Sunshine Coast based partnership with considerable expertise in mining and earthmoving which specializes in the mining of small/medium size ore bodies on behalf of the tenement holder on a profit sharing or royalty basis.1.3 The partnership's first successful venture has been the mining and vat leaching of a small 40,000 tonne ore body with a head grade of 5 gm/tonne gold and 32 gms/tonne silver, situated near Ban Ban Springs in southeast Queensland.1.4 This paper looks at the low cost vat leaching method of treatment, as an alternative to CIP and CIL in the processing of low tonnage/high grade precious metal ore bodies.

Jan 1, 1990

By Sakurai F

Akita Zinc Refinery of Mitsubishi Metal Corporation (MMC) started operation in 1953 with a capacity of 560 tons of electrolytic zinc per month. Its capacity has been expanded gradually and reached 8,100 tons per month in 1973. However, present production level is about 6,500 tons per month due to the depressed zinc market. In 1963, newly developed sulphate roasting was incorporated for residue treatment. Since 1973, electric power from Ohnuma geothermal power station of MMC has been supplied in addition to hydroelectric power from Komata power station of MMC. At present, about 40% of power is supplied from our company's power station and the rest is from the power company. Recent customers' demands for zinc prod- ucts include various kinds of shape, weight and chemical composition of galvanizing zinc alloy. It is necessary for zinc producer not only to meet the requirements of customers but also to enhance the value of zinc product in order to expand the market of zinc.

Jan 1, 1987

The demands of the economy require larger manufacturing facilities using greater quantit- ies of raw materials which must be mined, handl- ed, stockpiled and recovered with efficiency and dependability. All over the world, mining com- panies, steel manufacturers, power stations and process plants are not only seeking but finding methods of increasing outputs and'reducing costs in the field of materials handling. In mining bigger continuous mining machines and shovels, larger trucks and crushers are digging and processing greater quantities of differing materials which have to be handled and shipped at rates once thought to be impossible. To implement such schemes demands the blending of a lot of diverse-equipment, mining machinery, bins, feeders, reclaimers and it is here that the belt conveyor assumes a role of ever increas- ing importance. Significant developments have taken place in the seventies with respect to conveyor belt transportation; not only in the systems but also in the components which combine to make such systems work efficiently.

Jan 1, 1976

The initiation of cast Pentolite primers by detonating cord has been examined by the combination of two different experimental techniques with computer simulation by the finite element hydrodynamic code DYNA2D. In the first type of experiment, the cord/primer system was placed in a water aquarium, and photographed using a high-speed image converter camera. This highlighted the emergence of the detonation front through the primer surface and the generation of shock waves in the surround- ings. Numerical simulation was used to interpret the experimental record, establishing where the cord had induced buildup to detonation inside the primer. The second experiment used the plate dent test, where the primer was placed in contact with a block of metal (here aluminium), with the resul- tant dent in the metal surface being a measure of primer output. Detailed numerical simulation of this test confirmed that the observed dent was caused by the development of a complex series of shock waves inside the Primer.

Jan 1, 1988

By Armstrong ME

The gas bubble energy generated by an explosive plays a major part. in the fragmentation, muckpile movement and damage produced. Previously, the interaction between gas pressure and the rock has been interpreted from a theoretical basis or a qualitative study of breakage mechanisms. A method to measure the fluctuations in gas pressure in rock adjacent to the blast has been developed. This peak pressure will vary with structure, as well as with distance and explosive type. The technique is simple to apply and can be used to observe the flow rate of gas at. varying distances. The apparent velocity of penetration is an indication of whether gas has travelled through pre-existing or blast induced cracks. The technique provides a ?n:eans of determining the suitability of an explosive for a given rock type, depending on the amount of displacement desired. The technique has application in optimir.irig throw blasting and predicting and controlling damage, particularly in highly structured rock masses.

Jan 1, 1986

By Stanton G

The Department of Mapping and Surveying (DMS), the Australian Key Centre in Land Information Studies (AKCLIS), the Department of Industry Development (DID) and the State Government Computer Centre (SGCC) are testing a regional information network in northern Queensland. Several study sites have been chosen by different groups of participants. The members of each common-interest group share their data for the site. They can also access datasets supplied by other organisations that are not directly involved in the particular study being undertaken. The participants include state government departments, local authorities, fed- eral organisations and the private sector. The participants communicate with computer systems in Brisbane via Q-Net. Q-Net is a pilot State government tele- communications network, established by the Department of Industry Development. Q-Net uses the communications sat- ellite AUSSAT 1 as the primary instrument of data transfer. The Q-Net network is a star system, with a Master Earth Station in Brisbane acting as a hub for radial earth stations, located throughout Queensland.

Jan 1, 1987

The geographical and geological situations of the two mineral sand deposits currently being mined by Western Titanium Limited and the mining methods in use are briefly described. Production scheduling involving the ability to vary the proportions of the major minerals produced, together with maintaining a constant feed grade to the wet concentrator has been assuming greater importance to the company in recent years as the relative value of these minerals, due mainly to technological advances and environmental considerations, is subject to significant and rapid change. Manual calculation, even using a programmable calculator, became a trade-off between man hours and data usage. Schedules were updated infrequently and only a fraction of the avail- able data was used. In July 1975 a Data General NOVA 2/10 minicomputer with a 24K word core and three cassette drives was purchased. A suite of programmes was developed using BASIC to assist in production scheduling and these were opera- tional early in 1976.

Jan 1, 1977

By Houlihan RN, Landau J

A reciprocating plate column is described in which two sets of perforated plates are mounted alternately on two shafts and are reciprocated with a phase difference of 1800 between them. It is shown that such a column is mechanically superior to the previously proposed types: under practical operating conditions the pressure fluctuations at the base of the column are only a small fraction of the static head. Furthermore, mass transfer experiments with the system tributyl phosphate in kerosene- acid aqueous solutions of uranyl nitrate show that both high specific throughputs and reason- ably good efficiencies can be attained in this type of column. A comparison with the more conventional extraction equipment (mixer -settlers, pulsed columns) on the basis of residence time per equilibrium stage indicates the potential of reciprocating plate columns in hydrometallurg- ical application, especially in which the requirements of separation efficiency are modest while the scale of operation is large.

Jan 1, 1975

By Woodcock J. T, Millett R. N

It was shown that manganese dioxide could be used as an oxidant in acid thiourea leaching of a gold ore. Manganese dioxide could generate high redox potentials and was as effective as hydrogen peroxide in the leaching process. Results obtained under closely controlled leaching conditions confirmed that high redox potentials enabled faster dissolution of gold to be obtained but led to extremely high reagent consumptions (thiourea, acid, and manganese dioxide). Additions of sodium sulphite solution in an attempt to lower thiourea consumption by reducing formamidine disulphide back to thiourea were only marginally successful. Although thio- urea consumption was slightly decreased, the consumption of acid and manganese dioxide was substantially increased and there was no net benefit in using sulphite. Tests in which a single addition of mangan- ese dioxide was made before addition of thiourea minimized overall reagent consumption and gave only a slightly lower dissolution rate of gold. This is a promising technique for further Investigation.

Jan 1, 1987

By Gleadow AJW, Foster DA, Kohn BP, Raza A

A large and increasing data base of apatite fission track results from sedimentary and granitic rocks exposed within the southeastern highlands and along the continental margin of Australia provides constraints for the tectonic development of the southeastern passive margin. The fission track results suggest that many regions of the southeastern margin of Australia experienced distinct episodes of relatively rapid cooling during the middle Cretaceous to early Tertiary that can be attributed to the effects of rifting. One cooling episode is middle Cretaceous in age and related to denudation of the southeastern highlands from Tasmania to northern New South Wales between -90-100 Ma. Rocks exposed along the present coast line record a later episode of rapid cooling, which is diachronous and decreases in age northward from -80 to 90 Ma in northern Tasmania to southern New South Wales, -60-80 Ma in central and northern New South Wales, and to -50-60 Ma in southern Queensland.

Jan 1, 1995

I WISH to express to the members of the Institute my sincere appreciation of the distinction which they have conferred upon me by again making me their president. It also gives me great pleasure to once more welcome the Institute to Mount Lyell.Since your last visit certain improvements in plant have been made, which I trust you will have found interesting, and which show that, though located in a remote corner of the world, we are abreast of the times.The opportunities which a recent lengthy trip to America has given me to observe the degree of interest which our local smelting practice continues to arouse in metallurgical circles make it seem appropriate that I should take advantage of your visit to lay before you some detailed information on the more practical features of pyrite smelting, particularly as carried out at Mount Lyell. There are only a few places in the world where the method is now being practised in approximate purity-only about half...

Jan 1, 1915

By Walton M. C

A combination of flotation and smelting technologies is proposed as a cost-effective means to maximise the revenue of base metal operations. The proposed treatment route breaks the grade - recovery nexus associated with the treatment of ores exhibiting difficult mineralogy in conventional plants. Aspects of the two technologies are reviewed and typical capital and operating costs presented. A significant improvement in revenue is demonstrated in a worked example, where a copper-lead-zinc operation is examined in terms of the conventional and proposed treatment options. For the selected ore, the net smelter return per tonne of mill feed improved 57 per cent, from US$89.70 to US$141.10 with the proposed treatment option. This represents an additional US$51.4 million in annual revenue. Metallurgical operating costs increased by US$20.12 per tonne of mill feed for an incremental capital requirement of US$30.3 million for an existing operation.

Jan 1, 1992

By Torckler L, Brathwaite R. L

At Neavesville gold-silver (electrum) mineralization occurs in steeply-dipping zones of intense fracturing, brecciation and quartz veining within rhyolitic pyroclastics, carbohaceous shales and andesites. Hydro- thermal alteration extends over an area of greater than 3 by 1.5 km. In rhyolitic tuffs, highly silicified zones containing quartz- adularia-illite assemblages are flanked by less silicified assemblages composed of albite, illite-montmorillonite and chlorite. The mineralogy ana sequence of alteration are comparable with the alteration zones which envelop the steam-producing fissures of the active Wairakei and Broadlands geothermal fields. Primary fluid inclusions in quartz from five fissure veins in the Neavesville field show maximum homogenisation temperatures ranging from 220 - 260¦C and salinities of 0.0 - 1.1 wt. % NaCl equivalent, which cover a similar range to actual measured temperatures and salinities in geothermal fluids at Wairakei aria riroaolan¦s. The age of the rhyolitic pyroclastics and related alteration and mineralization is probably Pliocene and Neavesville therefore represents a fossil geothermal system.

Jan 1, 1980

By Matsushita Y, Maeda M, Sano N

The present study was carried out to explore the possible separate recovery of iron and phosphorus (as gas) from BOF slag using graphite crucibles or graphite powders in the presence of a tin bath. The last is consider- ed to enhance the activity of phosphorus in iron reduced from slag or not to absorb the phosphorus vapour readily. When the slag was reduced in a graphite crucible in contact with a tin bath, the phosphorus reduced from the slag was carried away in CO explosively generated by the reduc- tion of iron oxide. When graphite powder was used as the reductant instead, 78% of the phosphorus was removed from slag, only 3% of which was absorb- ed into the tin bath. The rest left the system as gas. Gaseous dephosphorization depends on the area of contact between slag and reductant as cll n.u the amount of the latter. the reduction behaviour was directly observed, using an X ray transmission technique, to conlirm the reaction mechanism.

Jan 1, 1980