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Valuable Components Recovery from Lead-Zinc Metallurgical Slag

Sep 13, 2010

By Clarke DS

The igneous intrusions in SE Papua New Guinea are part of a sub-volcanic to plutonic, high-K calc-alkaline to shoshonitic suite. High-K andesitic to dacitic intrusives on Misima and Woodlark Islands, and shoshonitic intrusives in Milne Bay and the eastern Owen Stanley Ranges are related to late Cenozoic andesitic volcanism. Both suites are associated with epithermal Au-Ag deposits and weak porphyry Cu-Au mineralisation. All significant alluvial and lode gold occurrences in the region are spatially related to intrusions. Intrusions in the D'Entrecasteaux Islands and near Mt Suckling are core plutons related to basement doming, and appear to have no association with either volcanism or hydrothermal mineralisation. The core plutons are not petrochemi:ally distinct from the volcano-re:-ed Intrusions.

Jan 1, 1991

As a result of the world depression and the consequent heavy fall in the price of tin, Malaya joined with other great tin producing: countries of the world in a restriction scheme that heavily restricted production from its individual mines. This condition, together with the knowledge that it was becoming more and more difficult in, Malaya to acquire further areas and so prolong the existence of a specific company's activities, induced Mr. H. G. Scott, managing director for the Siamese Tin Syndicate Ltd., to consider other possible sources of production. Mainly because of the conditions that obtained in Tasmania, he turned his attention to that country, where, not only could mining be carried on without restriction as to output, but where the incidence of the exchange position created favourable conditions for operation. The district selected for examination was that of St. Helens, on the East Coast of Tasmania, which district had behind it a long record of successful tin mining operations.PRELIMINARY OPERATIONS OF SIAMESE TIN SYNDICATE LTD. AT ST. HELENS.First of all the district was examined, and there was no lack of evidence to show that tin existed, although it was impossible to get down to quantities and values without an extensive prospecting campaign. For one thing, the physical features of the country seemed to be all wrong. There were no extensive alluvial flats such as a mining engineer...

Jan 1, 1934

By D Barclay, S Mercer, S Wright

Mine water management is often an afterthought in mine planning processes and can introduce significant risks to projects when studied as a stand alone component at a later stage in the mine design. Incorporation of a mine dewatering and pore pressure dissipation strategy in the early stages of mine planning is imperative in order to minimise constraints on the production schedule, to match designed pit slopes and maximise project value for an open cut mine option such as Olympic Dam. A risk-based mine planning approach was adopted during the project selection phase study whereby water management was introduced into mine planning, scheduling and the development of an operational strategy. Hydrological and hydrogeological studies and outputs were successfully integrated into the various iterations of the mine planning cycle during early selection phase to manage the potential water management risks associated with pit slope depressurisation and access to dry working conditions during rapid advancement of mining phases.An extensive network of vibrating wire piezometer sets and long-term depressurisation testing characterised aquifer conditions and demonstrated that hydraulic connectivity exists within the geological profile due to the presence of structures and resource drill holes which enhance vertical connectivity. This connectivity, along with underdrainage from mining activities contributes up to 100 m of depressurisation in low permeability units.A pit dewatering strategy incorporates the mine planning schedules and accounts for operational constraints as to the location and development of the dewatering wells, storages and pipelines. Numerical modelling generated a range of likely pit inflows and dewatering requirements with the average initial dewatering discharge likely to be 150 L/s and reduce quickly to 50 L/s after five years, depending on the premine schedule.Coupled hydrogeological and geotechnical assessments were also carried out as part of the mine planning cycle and indicate that successful dewatering will go a long way to reduce the pore pressures within key geotechnical units during the rapid mining phase where around 300 m of cover sequence is stripped in five years. However, the residual storage in the primary aquifer and the residual pore pressure in underlying low permeability units will need to be dissipated (in-pit horizontal holes) as the pit floor advances. Pit slope design angles are sensitive to depressurisation and dewatering and up to 70 per cent depressurisation of key geotechnical rock units are required. Whilst an accelerated program of aquifer dewatering supported by lithostatic unloading should drive rapid depressurisation in the lower permeability units, intervention is anticipated in key geotechnical units such as the Tregolana Shale and volcaniclastics. The extent of induced drainage will ultimately depend in part upon the mining rate and geotechnical stability requirements. Practical operability testing addressed the potential for operational constraints to mine depressurisation activities such as congestion and mining schedule development within the pit and identified that depressurisation drilling can be achieved even with reduced access availability. Mine operations and planning groups established design criteria and considered the likely inoperable periods following rainfall events of seven to 14 days to manage the base surge and minimise impact on production. In-pit surface water management options to minimise operational disruptions during and after significant rainfall events were estimated used a stochastic approach.

Jan 1, 2009

By B W. Riddol1s

The 1983 Energy Plan calls for an increase in North Island coal production from both underground and opencast sources from the 1982/1983 production of 843 000 tpa to approximately 3.4 Mtpa within the ten year period to March 1993. This increased production is scheduled to come from the following sources: Huntly West No 1 underground mine reaching full production of 1.26 Mtpa. Huntly East underground mine increasing production to 750 000 tpa. The proposed new Huntly West No 2 mine producing 100 000 tpa in its first year of operation û 1992. The proposed Ohinewai opencast producing 920 000 tpa for supply to the steelmaking plant at Glenbrook, replacing Weavers opencast which will be worked out in 1990. Rotowaro opencast producing at 220 000 tpa (currently being achieved). Two additional sources of supply which are not scheduled to begin production for at least ten years, and both of which have been designated for coal fired thermal power generation, are the Maramarua and Mokau coalfields. It was originally envisaged that development of both coalfields would be a combination of underground and opencast mines. The form of development is yet to be confirmed by detailed feasibility studies. The location of the Maramarua, Ohinewai (Waikare Coalfield) and Mokau deposits is shown on Figure 1. Worley Consultants Limited, in conjunction with their partners Rheinbraun Consulting GmbH (Germany) and Longworth McKenzie Pty Limited (Australia) have been involved with investigations and mining assessments for the Maramarua, Mokau and Ohinewai prospects. The Maramarua and Mokau studies form part of the New Zealand Coal Resources Survey programme of updating information to the Pre-Feasibility Mining Assessment level before proceeding to detailed feasibility studies. The Ohinewai study was commissioned directly by Mines Division to investigate the feasibility of mining coal by 1989 before reserves at Weavers opencast are depleted. This paper describes typical studies which are now being commissioned by Mines Division to investigate large-scale mining development and the effect geotechnical-conditions may have on coal recovery. The magnitude of these projects is reflected in the proposed outputs û up to2 Mtpa from individual mines û and the introduction of new continuous mining systems for both underground and opencast mines on a scale which has not previously been contemplated.

Jan 1, 1984

By A B. Christie

Space-based synthetic aperture radar (SAR) data is becoming available over much of the world, includingNew Zealand. Radar imagery has a number of very advantageous features, including all-weather capability; it also has artifacts, such as layover, which require processing before these data may be used to best effect.   This paper gives an outline of SAR, details the image processing required, and discusses the use of the first New Zealand Japan Earth Resources-1 SAR data to aid geological mapping on the Coromandel Peninsula.

Jan 1, 1994

By R O. Laidlaw, J L. Mauk

The Coeur d'Alene mining district in northern Idaho, USA is the second largest producer of silver in the world. Mesothermal silver-lead-zinc veins occur in the metasedimentary rocks of the Belt Supergroup with five main types of associated hydrothermal alteration: 1) feldspar destruction, 2) hydrothermal bleaching, 3) carbonatisation, 4) sulfidation, and 5) silicification. Hydrothermal bleaching is characterised by hematite destruction with associated siderite and quartz veins and veinlets, coarse euhedral pyrite and magnetite. Bleached zones envelop both mineralised and barren veins and extend for metres to tens of metres into the wall rocks. Carbonatisation consists of addition of siderite, which occurs as veins, veinlets, stockwork, irregular blebs or spots, and coarsely disseminated grains, depending on the relative distance from the main vein structure. Siderite envelops nearly all mineralised veins, relates to all other alteration types and extends from several metres to tens of metres into the wall rocks. Pyrite and galena alteration dominate sulfidation and are associated with some mineralised veins. Pyrite alteration strongly correlates with siderite alteration and exists in three main forms: a) very fine-grained pyrite flooding, which can extend for metres to tens of metres into wall rocks; b) coarse-grained, euhedral pyrite, which is sporadic and associated with the redox boundary in hydrothermally bleached zones; and c) small isolated zones (6 - 15 cm) of medium-grained, subhedral to euhedral pyrite associated with pervasive siderite alteration. Where present, disseminated galena extends for metres to tens of metres into the wall rocks. Silicification is characterised by veins, veinlets, stringers, irregular patches and variable hardness in siltites and commonly appears in association with hydrothermal bleaching and siderite alteration. Although related to mineralisation, silicification is sporadic and in most places a clear envelope around mineralised veins cannot be identified.

Jan 1, 2001

The granulites and related "dry" igneous rocks tend to be passed over during exploration for metals. Preliminary data show that high trace concentrations of Cu, Ni and other metals of economic interest are common in orthopyroxene and some of the other granulite minerals. During retrograde metamorphism of granulites, pyroxenes are converted to amphiboles or phyllosilicates, and significant quantities of metals are released and become available for incorporat- ion into new mineral phases, or may be transported elsewhere. S--rich scapolite is the normal scapolite of granulites. Its retrogression to secondary plagioclase provides much S which scavenges Cu, Ni, etc., from pyroxenes undergoing retrogression, thus producing ore-fluids. A full analysis of a scapolite with 5.10 per cent S03 is given. Beryl is unstable in granulites but the rare Be mineral taaffeite (Al4Pf (Be,Fe)O3) with 5,50 per cent BeO occurs in central Australia as a pale green Tabular mineral easily confused for chloritoid in hand-specimen. Metamorphic differentiation and mobilization of primary ore concentrations are major factors controlling their post-granulite attitude and grade.

Jan 1, 1969

By Wyborn L. A I, Idnurm M, Hinman M. C

Comparison of the Proterozoic Apparent Polar Wander Path (APWP) for Australia with the corresponding geology of northern Australia suggests that a number of discrete interplate tectonic events, manifested on the APWP as bends or inflections, may have controlled sedimentary basin evolution, ore fluid production and the timing of mineralisation. Similar features in the Phanerozoic APWP for the North American plate appear to correlate with major orogenic events, basin deformation, movement and 'entrapment' of hydrocarbons and minerals. Interplate tectonic events cause intraplate deformation which in turn controls the subsidence/uplift and sedimentation histories of the basins. Interplate events are thus responsible for creating, deforming and destroying sedimentary basins and the associated petroleum and mineral systems. The basins of northern Australia show remarkable similarities in the successions of volcanic and sedimentary deposits. Unconforrnities of regional or sometimes only local extent have been mapped between the major sedimentary sequences and it is predicted that interplate tectonic events corresponding to bends or inflections on the APWP directly reflect the processes that have produced these widespread unconformities. These processes are also likely to have controlled the geometry and character of the fluid migration pathways and hence the mineralising events. Palaeomagnetic studies of Proterozoic rocks in sedimentary basins provide a tool for predicting the timing of regional mineralisation events, particularly for low-temperature mineral systems. The techniques, when coupled with systematic regional basin analysis, using petroleum exploration techniques, may identify a number of new mineral 'plays' in northern Australia. Prominent inflections in the APWP occur at approximately 1700, 1670, 1650, 1600, 1540, and 1480 Ma. Each of these may be related to a regional compressional deformation, important mineralising event, or significant change in style and type of sedimentation. Most appear to be associated with magnetic overprints. Some of the inflections between 1400 and 540 Ma may also mark significant events in the evolution of Meso- and Neoproterozoic basins. Further work is required to correlate inflections in the APWP with alteration events in order to understand their regional significance.

Jan 1, 1994

By P Dean, M Elmouttie

Radar monitors are now widely used in surface mining for monitoring slope deformations and predicting failure events. Their introduction has facilitated better management of risk associated with slope failure during mining and therefore protection of personnel and equipment. However, a wellrecognised problem is that radar monitors only measure deformation directed towards the detector (line-of-sight bias). This bias can lead to misinterpretation of deformation size, rate and failure mechanism, and therefore miscalculation of failure volume, which can significantly impact safety and productivity. This paper presents recently completed research and field trials into the feasibility of using low cost vision systems to mitigate this issue. It has been demonstrated that by integrating a computer vision system with an existing slope monitor, high precision tracking of features in the field of view can be performed. Combined with assumptions on the deformation characteristics, the true 3D deformation vector can be estimated. The applicability of using this technique for monitoring iron ore mine slopes is discussed.

Nov 8, 2021

Iron production in one year exceeds that of all other metals combined in ten years. It is a huge industry that started from a modest furnace producing one - two kilograms metal per day to a gigantic reactor producing 10 000 tons per day. The major milestones of these developments are reviewed.

Jan 1, 1999

By T. Baker

The Eloise Cu-Au deposit is 60 km SE of Cloncurry in NW Queensland and has a current indicated reserve of 3.2 Mt @ 5.8 per cent Cu, 1.5gA Au and I9g/t Ag. It is hosted by metasediments and metabasic rocks that underwent amphibolite facies metamorphism at 550-600¦C and less than 3.5 kb. Peak metamorphism coincided with the regional D2 event which produced an S2 foliation with north-south strike and variable sub-vertical to steep east or west dip. The deposit is associated with several major shear zones parallel to the S2 foliation. The lodes form part of a large alteration system that is localised by the retrograde shear zones. Homblende-biotite-quartz with minor sulphides occur early in the alteration paragenesis which is overprinted by chlorite-muscovite-pyrrhotite-chalcopyrite ¦calcite+¦nagnetite. The later assemblage replaces the earlier Fe-K alteration as well as Fe-rich metamorphic assemblages such as homblende, biotite and staurolite indicating a post peak metamorphism timing for ore formation. Although replacive textures are the most common, the alteration can display open space infill and brecciation as well as durchbewegung and mylonite textures indicating that mineralisation occurred during ongoing ductile deformation. All these features are crosscut by a later brittle phase of calcite-chlorite-quartz¦pyrite alteration.

Jan 1, 1994

By Lyon R. J P

The quartz-cassiterite-wolfram veins at the Aberfoyle Tin Mine, north-eastern Tasmania, form a sheeted zone about 200 ft. wide and 1,600 ft. long in slightly contact metamorphosed shales, slates and greywackes, and are associated with a cupola of aplitic granite whose top is about 1,050 ft. below the present surface. Economic mineralization persists from the surface down to a vertical depth of 1,050 ft. to 1,100 ft., dying away in the vicinity of the cupola. Down to the 9-level there is a progressive increase in wolfram content of the veins, and a decline in cassiterite content, with increasing depth.The veins are banded or zoned, with a seivedge of muscovite on the wall. Cassiterite, wolfram and sphalerite occur inside the selvedges, projecting into a core of quartz of varying width. Other sulphides form the central part of some narrow veins, or occur as clots in the quartz. The general sequence of deposition of the ore minerals was: (1) cassiterite, wolfram; (2) arsenopyrite, pyrite, molybdenite; (3) pyrrhotite (in part); (4) blende-group minerals-chalcopyrite, sphalerite, stannite, pyrrhotite (in part)-as solid solutions; (5) galena, tetrahedrite, matildite, native bismuth, scheelite; (6) marcasite and secondary pyrite, magnetite and hematite. The sequence of deposition of the gangue minerals was: (1) fluorine-bearing minerals-muscovite topaz, apatite, triplite, fluorite-more or less contemporaneous with the cassiterite and wolfram;' (2) quartz-contemporaneous with the earlier sulphides; (3) carbonates--contemporaneous with the later sulphides. The stages overlapped somewhat.The composition of the sphalerite and heat treatment experiments with the solid solutions indicate that the blende-group sulphides were deposited at about 6000 C., and cooled rapidly, so that unmixing of the solid solutions was arrested. This accords with the likelihood that the country rock temperature was not above 2000 C. Annealing experiments at between 3500 C. and 6000 C. led to further precipitation from solid solution at the lower temperatures, and to significant segregation by solid diffusion within, a week, indicating that both deposition and cooling of the ore were rapid processes-completed in a matter of days. Since the mineralizing solutions must have lost some heat during...

Jan 1, 1957

A wide-ranging base of jig data was collected from various types of commercial jigs in 9 coal preparation plants in China, and a complete data analysis was made. It was found that the sharpness ofseparation was very variable, which demonstrates the complex interplay of the many factors which influence jig performance. Tests showed that there exist optimum frequency ranges in each compartment of a jig. Stepwise regression analysis indicated that the sharpness of separation is most sensitive to the intake fraction ofthe air cycle, the frequency, and the feed rate. By means of non-linear curve fitting techniques and statistical analysis, several mathematical models were developed to describe both partition curve and the jig performance, for simulation purposes.

Jan 1, 1986

Mineralogical analysis of a nickeliferous laterite from the Rockhampton region shows that the nickel is largely associated with the manganese wad and opaline silica. The laterite also contains an appreciable chromite content (about 12 per cent Cr2O,) although this tends to be poorly liberated.Leaching with hydrochloric or sulphuric acid, at atmospheric pressure at the boiling point is non-selective with respect to iron dissolution.The degree of dissolution increases as the acid concentration and retention time are increased; cobalt dissolution requires less aggressive conditions than does the dissolution of an equivalent amount of nickel.Leaching with sulphuric acid at elevated temperatures and pressures leads to a minimum amount of iron dissolution, is rapid, and requires a reduced acid addition rate. Nickel and cobalt recovery from the clarified leachate would be simplified because of the leach selectivity.Pressure leaching appears to be the most practical route for treating the Rockhampton laterite. The economics of processing would be made more attractive by the recovery of a chromium concentrate from the leach residue. This would typically contain about 45 per cent Cr2O, and could be used as a source of chromium chemicals.

Jan 1, 1986

By Crook KAW

New sedimentological and biostratigraphic data indicate that the Leron Formation in the Markham Suture Zone, Papua New Guinea (PNG) represented Pleist- ocene alluvial fan-delta deposition in shallow marine to lacustrine environments. The distribution of sedimentary regimes in the Leron Formation indicates that during collision zone evolution, various tectono-sedimentary regimes do not always track the movement of the triple-junction systematically as idealized by Crook's (1989a) model. The migration of various tectono-sedimentary regimes are also controlled and influenced by the effects of second-order geometric features of the convergent margins. Leron Formation in the Markham Valley represents late to post-collisional marine to fluvial molasse. Foraminifera indicate that the collision and concomitant suturing of the Markham valley occurred after 1.32Ma.

Jan 1, 1991

By Lamont G

The significance of blasthole stemming in determining blasting efficiency has been extensively studied for small diameter holes using gelignite explosives. Recent developments in blasting technology with the use of large diameter holes and low cost blasting agents have not included studies of the effectiveness of different types of stemming materials. A review of previous measurement techniques and the relevance of these earlier results to present stemming practice is presented in this paper. A survey of operating mines in Australia provided information for this analysis. The value of stemming in reducing blast noise and improving blasting efficiency is generally accepted but the use of bulk-loaded explosives in underground operations has resulted in the practice of eliminating the use of stemming material.In surface operations drill cuttings are used for stemming on the basis of availability rather than efficiency in providing resistance to movement. The development of laboratory testing techniques, based on noise level and borehole pressure measurements, to evaluate the relative efficiency of different types of stemming materials is described. The results of an extensive series of tests with ANFO explosive showed similar trends tothose obtained from earlier published results with gelignite type explosives. Conclusive quantitative results on the relative effectiveness of different stemming materials will require minor modifications to the existingequipment. Observations and the results of pressure measurements indicated the presence of shock wave effects which caused the ejection of the top section of the stemming column when using coarsely fragmented material.

Jan 1, 1979

By C A. Fleming

Gold extraction is largely driven by mineralogical factors, which often cause gold losses to various tailings. Mineralogical factors affecting gold recovery include grain size and shape, surface coating or rimming on gold particles, the presence of cyanide or oxygen-consuming minerals or preg-robbers, the presence of slow-dissolving gold minerals and the refractory nature of submicroscopic gold. Among these factors, locking of fine gold particles in sulfide, silicate and other minerals, either as visible, fine-grained gold inclusions and/or as invisible submicroscopic gold, is by far the most common factor leading to poor gold recovery in gold ore processing. This paper discusses the mineralogical characterisation of gold lost in tailings and its metallurgical implications. The techniques used in characterising the un-recovered gold are also briefly introduced.

Jan 1, 2007

By D J. Fray

In this work, a fused salt electrochemical process was investigated experimentally for production of metals and alloys directly from respective solid oxides by electro-deoxidation. Direct electrochemical reduction of the oxides was carried out in molten CaCl2-based chlorides in an electrolytic cell, incorporating an oxygen-evolving inert anode, over the temperature range of 850 - 950¦C. The technical viability of the process was demonstrated by the electro-deoxidation of pure oxides and oxide mixtures including NiO, Nb2O5, Nb2O5/TiO2 and Nb2O5/SnO2 to produce nickel metal, niobium metal, NbTi alloys and the intermetallic compound, Nb3Sn. Compared to the conventional metallurgical processes for producing these metals and alloys, this new electrochemical process appears to be much less energy intensive, with lower costs and no direct greenhouse gas emissions from the electrolytic reduction process. The present electrolytic reduction process has the potential to be scaled up for the green extraction of a number of non-ferrous base metals and processing of many advanced alloys.

Jan 1, 2006

By Koch D. F A

An electrochemical study of the dissolution of gold in aerated cyanide solution shows that the dissolution rate is determined by the nature of the surface. A passive film (probably a basic cyanide) formed at -0·6 V vs a saturated calomel electrode inhibits both the anodic dissolution of gold and the cathodic reduction of oxygen. Thallium has an "activating" effect on these reaction mechanisms.INTRODUCTIONIn general the dissolution rate of a solid in a liquid is studied by weight loss measurements or analysis of the solution at known time intervals. However, if the solid is a metallic conductor, on which a redox reaction can occur at the metal-solution interface, it can be studied by electrochemical techniques. Electrochemical measurements have the advantage that the overall reaction can be separated into its components, in some cases by electrical measurements alone, and in others by a combination of these with analytical determinations.The overall equation for the dissolution of gold in aerated cyanide solution may be written4Au + 02+ 8CN- + 2H20 = 4Au (CN)2- + 40H- ..... (1)which can be separated into the two electrochemical componentsrepresenting the oxidation of gold and the reductionof ogygen respectively.4Au + 8CN-,= 4Au(CN)2- + 4eand O2+ 2H20 + 4e = 40H- These two reactions occur at the gold-electrolyte interface and it is the purpose of this paper to discuss the mechanism...

Jan 1, 1964