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By C R. Stanley, D Lawie

The measurement of error in assays collected as part of a mineral exploration program or mining operation, including errors introduced during sampling, sample preparation, or geochemical analysis, historically has been undertaken in a variety of ways. Different parameters have been used to describe the magnitude of relative error and each of these parameters is related to the standard measure of relative error, the coefficient of variation. Calculation of the coefficient of variation can be undertaken in a variety of ways; however, only one produces unbiased estimates of measurement error: the root mean square coefficient of variation calculated from the individual coefficients of variation. CITATION:Lawie, D and Stanley, C R, 2012. Average relative error in geochemical determinations - Clarification, calculation and a plea for consistency, in Proceedings Sampling 2012 , pp 181-184 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 21, 2012

Twenty years of effort in developing the use of computers in the design and control of mineral treatment circuits has resulted in a sound base for future widespread application of the techniques.. The intent of this paper is to speculate to some extent about future applications of computer related techniques in the mineral extraction industries. The use of simulation methods for the analysis and design of circuits is discussed. In the area of process control, computers have been largely devoted to process monitoring and reporting tasks. The application of computers for the total control and optimization of complete plants is considered. Finally, the role of computer based modelling studies for definitions of optimum treatment flowsheets is suggested.

Jan 1, 1985

A simple and rapid method for delennining gold and silver in carbon samples is described. The method involves dissolution of carbon ash in a strong oxidising medium of aqua regia and hydrofluoric acid. Gold and silver are determined in the resultant solution using atomic absorption speetrometry (AAS). The method is efficient and reproducible. Gold results are comparable to the standard fire assay results, with agreement of results within ± 5 per cent. The co-efficients of variation for gold and silver are 0.37 and 0.39 per cent respectively for six replicate analyses. The analysis of gold and silver in a batch of ten carbon samples can be completed in approximately four hours.

Jan 1, 1992

Hindustan Zinc Limited has successfully installed an In-Stream Analysis and Process Control System in the flotation section of the Balaria Lead-Zinc concentrator at Zawar Mines. The system comprises In-Stream Analysis to continuously monitor lead and zinc levels in feed, concentrates and tailings streams, field instrumentation for reagent distribution and flotation cell level control linked to a central Distributed Control System for supervisory control functions. An intensive training scheme was conducted by the system supplier for concentrator metallurgical and instrumentation engineers. Since commissioning of the system in April 1989, Hindustan Zinc has enjoyed the benefits of improved lead, zinc and silver recoveries, improved concentrate grade control and reduced reagent costs.

Jan 1, 1991

By W Pytel

A special model of vertically loaded pillar behaviour is introduced to the general, multi-plate based, floor-pillar-roof system interaction analogue. This permitted analysing room-and-pillar mine systems in any geological conditions, including the effect of pillar elastic-plastic behaviour with strain softening. In the model, pillar instability is one of the important phenomenon, which may be expected to occur, and which the operator has to be prepared for. Thus the entire systemÆs safety is determined mainly by strong roof strata behaviour and therefore they have to be examined in actual stress-strain conditions utilising the appropriate strength theories. It was assumed that the so-called safety margin, representing the relation between load intensity and material strength, might serve as the basic indicator of possible roof instability development. Therefore, the safety margin may be estimated by comparing the actually computed components of stress-strain tensor with ultimate values characteristic for a given material determined in laboratory. In order to illustrate the effect of technological pillar size on roof strata stability, two different mining systems (methods of mining) in one of the æPolkowice-SieroszowiceÆ Mine districts was modelled using the finite element method formulated in three dimensions, assuming different materials within different rock mass strata, as well as a number of horizontal planes of discontinuity within the model.

Jan 1, 2003

Microorganisms have been used throughout history for the benefit of mankind with some of the earliest applications being in the production of fermented foods and beverages. Reactions involving inorganic substances such as metals, sulphur and sulphide compounds were hardly ever used until the early 1900s when it was discovered that Thiobacillus ferrooxidans was capable of promoting the oxidation of metal sulphides in ores. Today, it is widely recognised that biotechnology has great potential in the minerals industries, particularly in such areas as the leaching of low-grade ores of metals such as copper, gold and uranium; removal of heavy metal ions from process streams and from liquid process wastes; and in the desulphurisation of high-sulphur fuels. Although widespread commercialisation of mineral biotechnology has not yet been achieved, it is estimated that by the Year 2000 mineral biotechnology will have a significant impact on the minerals and metal industry and will probably account for tens of billions of dollars worth of annual production world-wide. This paper examines the actual and possible future applications of biotechnology in the minerals, metal refining and fossil-fuel processing industries. Firstly, the important chemical (and biochemical) principles involved in bio-dissolution of metals from ores and solid wastes, and in bio-accumulation of metals from process and waste solutions are reviewed, including leaching practices - past, present and future. Microbial desulphurisation of coal, and microbially-enhanced oil recovery are also discussed. The practical aspects of genetics and genetic engineering, the types and characteristics of those microorganisms important to mineral biotechnology, and the current research trends are reviewed as well. KEYWORDS: Biotechnology, microbial leaching, bioaccumulation, biosorption, bioleaching, biohydrometallurgy.

Jan 1, 1993

By R R. Lovel

In this paper, life cycle assessment methodology has been used to assess the variations in water use associated with different metal production and processing routes and provide insights into the value derived from water usage in the minerals sector. Using water consumption data derived from the literature it has been shown that the æcradle-to-gateÆ water consumption (or embodied water) for production of the various metals considered in the study ranged from 2.9 m3/t for steel up to 252 087 m3/t for gold. The results largely reflect the grade of the initial ore used to produce each metal, and can be approximated by the following equation: W = 167.7 G - 0.9039 where: W = embodied water (m3/t refined metal) G = grade of ore used to produce metal (per cent metal) The study showed that indirect water consumption in the metal production life cycle, in particular that due to electricity generation, can make a significant contribution to the embodied water value, eg aluminium production. When expressed in terms of m3/t ore, the results for all metals considered indicated that the embodied water is roughly, on average, three times the water consumption of the mining and concentration stage. It was also shown that the economic value per m3 of water consumed for the minerals industry exceeds that for the agricultural and industrial sectors, supporting the view that allocating water resources to the minerals industry has a strong underlying economic basis. Water reforms currently taking place in Australia aim to address issues such as competition for water access, reduced security of supply and increase in cost. Consequently the minerals industry, along with others, can be expected to come under increasing pressure to reduce fresh or raw water use and to integrate water use across sectors. While water recycling is an obvious candidate to help reduce water consumption in the minerals industry, issues such as water quality, among others, will influence the extent to which this can be achieved. In addition, wastewater volumes can be minimised using techniques such as pinch analysis to establish and use the minimum water requirement for the process. The use of dry or near-dry processing technologies, for which the demand for water is small or zero, may be a more radical solution to the water consumption problem; however, it is possible that the introduction of dry processing would bring with it a new set of problems, including dust.

Jan 1, 2006

By D J Rawlings

The Palaeo- to Mesoproterozoic McArthur Basin contains a thick (-10 km) intracratonic platform cover sequence of unmetamorphosed and relatively undeformed sedimentary and volcanic rocks (Pietsch et al, 1991). It covers an area exceeding 180 000 km2 of the North Australian Craton (Figure 1), overlying segments of the older deformed basement and transitional igneous units. Volcanism in the basin (including transitional domain) followed a four-phase pattern. These phases are geologically distinct and widely distributed, and are also recognised beyond the McArthur Basin in many similar-aged tectonic provinces in northern Australia. The four phases are described briefly below. Regional and structural nomenclature used refers to Figure 1. A stratigraphic correlation diagram is presented in Figure 2.

Jan 1, 1994

By C E. Loo

The cohesive zone has a significant influence on blast furnace operation and performance. The high-temperature behaviour of the reducing ferrous burden determines the properties of the cohesive zone and is studied in a laboratory using a softening and melting test. This paper summarises recent work aimed at better understanding the physico-chemical changes in a ferrous bed during softening and melting. Using a combination of standard, non-standard and quenched tests supported by optical image analysis, this work has highlighted some important differences in behaviour between lump, pellets and sinter as well as between the two lump ores and two acid pellets. As with the two lump ores, one pellet is denser than the other and the denser ore/pellet is also higher in silica.Within the cohesive zone, densification of the ferrous layer leads to reduced permeability and greater pressure drop. From the work presented in this paper, two key mechanisms of ferrous layer densification were identified. Firstly, the formation of fayalite, which melts at low temperatures, can act as a lubricant between particles and lead to densification of the ferrous layer under load. Secondly, reduction to metallic iron is topochemical and fayalite in the outer shell of the particle restricts gas flow to the centre and results in the formation of a wustite core. As temperatures rise, the wustite melts and eventually exudes out of the shell, occupying void spaces between particles and further reducing layer voidage and permeability.This work has shown that density and silica content are two key factors that result in increased densification of the ferrous layer. For porous Australian lump ore, the higher porosity and lower silica reduces the formation of fayalite and limits the formation of the wustite core, ultimately leading to a more permeable bed. The difference between the porous and dense ores was more pronounced with the introduction of prereduction to better simulate blast furnace conditions. This suggests that a porous ore gives significantly better cohesive zone permeability and blast furnace operations than a dense ore.The behaviour of fluxed sinter particles is different in that the silica reacts with lime to form dicalcium silicate. Minimal wustite core forms because relict hematite particles in sinter are only small and reduction occurs uniformly throughout the particle. Even with significant loss of material through prereduction, beds formed from sinter remained comparatively rigid. Studies using a typical blast furnace burden mix of 80 per cent fluxed sinter and 20 per cent porous ore showed that the structures of these beds at softening and melting temperatures are very similar to the sinter-only test. Measurements of bed contraction and pressure drop also confirmed that the introduction of 20 per cent porous ore into a sinter bed did not alter its properties. This is an indication that 20 per cent ore can be easily accommodated by blast furnace burdens.CITATION:Loo, C E, 2015. Important acid ferrous burden properties in the cohesive zone of a blast furnace, in Proceedings Iron Ore 2015, pp 367–376 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Hang G, Hongtian X

In this paper, it is briefly introduced that China's Ordovician limestone confined-water menaces coal mining and Ordovician water is prevented and cured to secure the safety of coal mining. The theory of "Down-Three-Zones" is presented on the basis of research and practice in recent ten years. The concept of "Down-Three-Zones" of floor water-eruption is described clearly. Finally, the principle and method of applying the theory of "Down-Three-Zones" are discussed. 1. An Introduction of Damage: China is rich in coal resources. The conditions of coal field geology are quite complicated. There is an area of two million square kilometre of Karst limestone in nine million six thousand square kilometres of territory. The resources of underground water are rather plentiful, but this menaces coal exploration. Sixty percent of coal mines in China are damaged by limestone confined-water in different scales, particularly coal mines located the Carboniferous-Permian coal fields of the Ordovician limestone distribution area of Northern China. Because there is the 500-800 metre thickness of Ordovocian limestone and the well developed Karst containsl plentiful water, Karst water can have more than 100 Kg/cm pressure. Limestone aquifers have only distances of several metres or several decade metres to coal seam, Karst water can enter the aquituge and even the coal seam, large eruptions often occur. For example, a mine of 3 million ton production capacity had an eruption of 2053 cubic metres per minute. This is the largest confined-water eruption which has brought enormous economic damage and threatened the safe production of coal mining. Therefore, the prevention and cure of Ordovician water has immense advantage to the development of the coal industry. There are several decades experience in the prevention of Ordovician water-eruption in China. The prevention of Ordovician water-eruption has two kinds of plans. 1) dewatering and depression: it refers to dewatering of aquifers as roofs of seam and depression of aquifers as floors of seam in mining areas. 2) comprehensive prevention under the condition of having water pressure in aquiters. Due to enormous water, electricity, equipment and lots of other factors, the former isn't used extensively, the latter tits to China's actual conditions and is used widely. So-called comprehensive prevention under the condition of

Jan 1, 1988

By P Ireland, S Mitra, G Evans, A Wang, M M. Hoque

This work presents an experimental study of flow dynamics in a bubble column system (crosssection: 100 mm × 100 mm) using a non-intrusive optical technique with targeted application in a novel REFLUX™ Flotation Cell. The study had two aims – measurement of the bubble size distribution (BSD) and local energy dissipation rate in the system due to bubble motions over a low range of gas flux varied from 0.02 to 0.08 cm/s without impairing the visibility of the system. A central bubble plume was generated by injecting compressed air through a sintered glass distributor in quiescent liquid. Highspeed shadowgraphy imaging was performed to determine the BSD in the presence of surfactant (Sodium Dodecyl Sulfate (SDS) concentration ~ 10 ppm). The BSD exhibited a unimodal shape at different locations of the column for all gas flux cases. A non-intrusive particle image velocimetry (PIV) technique was used to quantify the flow field generated by the bubble motions, which was used to estimate the local energy dissipation rate. The local energy dissipation rate exhibited an increasing power-law dependency on the gas flux.

Aug 24, 2022

By Chander S

Properties of surface films on chalcopyrite and pyrite differ due to variations in the mechanism of oxidation of the two minerals. In the case of chalcopyrite the first step in the oxidation is the release of iron as ferric ions, which hydrolyse depending upon conditions prevalent in solution. The iron oxide/hydroxide layer formed by hydrolysis of ferric ions is quite porous and easily detachable from the surface of chalcopyrite. When the surface oxide layer is detached a sulphur-rich layer is exposed making chalcopyrite hydrophobic. The thickness and properties of the sulphur-rich layer determine its flotation response, both in the absence and presence of collectors. In the case of pyrite, on the other hand, iron is released as ferrous ions which require much higher pHs to hydrolyse. These ions remain adsorbed on the surface of pyrite making the surface hydrophilic. When the iron species are complexed with chelating agents such as ethylene diamine tetra acetic acid, pyrite was hydrophobic. Siderite forms in the presence of carbonate ions, which might be present in several flotation systems. Siderite nucleated on isolated sites at the surface. The presence of such a precipitate is likely to influence the interaction of pyrite with various reagents thereby altering its flotation behavior. To determine the mechanism of oxidation, kinetics of oxidation of chalcopyrite and pyrite was studied using several electrochemical techniques, namely, cyclic voltammetry, polarisation and impedance spectroscopy. Floatability of the minerals was investigated by measurement of contact angles on mineral electrodes and by Halimond tube flotation. Impedance spectroscopy was especially useful for estimating various properties of surface film for both the minerals. Properties such as charge transfer resistance, porosity, and capacitances of the surface films on the two minerals are compared under several conditions of oxidation. These properties were found to be a strong function of the rate and the extent of oxidation.

Jan 1, 1993

By G L. Simmons, K M. LeVier, R Kappes

The low potential hydrophobic state of pyrite in amyl xanthate (PAX) flotation with nitrogen is of particular interest with regard to the N2TEC flotation technology currently being used for the recovery of auriferous pyrite at NewmontÆs Lone Tree Plant in Nevada. Initially, the N2TEC system had been found to operate satisfactorily, but cyanide in the flotation mill water appeared to be responsible for a loss in pyrite recovery. This supposition was confirmed with laboratory experiments, and a program was initiated to study flotation chemistry variables by electrochemically controlled contact angle measurements. Experimental results show that activation of pyrite in such cyanide solutions can be achieved more effectively with lead than with copper. Subsequently, based on these fundamental studies, significant improvement at the Lone Tree Plant was achieved by lead activation, in which case the recovery increased to expected levels. The effect of activator is particularly significant not only with respect to pyrite depression by residual cyanide, but also with respect to collector (PAX) consumption and the initial state of the pyrite surface. Experimental results show the importance of the pyrite surface state and the rather interesting features of the activation process.

Jan 1, 2005

Material sampling theory is well established in mineral process monitoring, improvement and control. It has been much enhanced by fundamental contributions due to Gy. When GyÆs sampling theory is applied to sampling inspection and monitoring, it provides estimates of average quality or extent of contamination. It also provides estimates of uncertainty, but these often ignore uncertainty in estimated variograms or other measures of variability. Risk assessment is often an implied task in sampling inspection and quality monitoring. A valid technique of risk assessment needs to take into account the uncertainty in the variational measures themselves. Standard statistical tolerance limit calculations which do take such uncertainty into account can be adapted to develop a technique for handling uncertainty in variational measures such as the variogram. Data from a published example is used to illustrate the technique.

Jan 1, 2005

By D P. Telionis, P P. Vlachos, R-H Yoon

Industrial processes involving multi-phase flows such as flotation require understanding of the relationships between bubbles, solid particles and the flow. Modern experimental tools are employed in this effort to measure with great accuracy the basic features of the motion of all three phases in turbulent flow. We employed a unique digital particle image velocimeter (DPIV) that can record with great accuracy and kHz temporal resolution, velocity vectors of all three phases, namely the fluid, the solid particles and the air bubbles. The interaction of these three phases was studied in homogeneous isotropic turbulence generated by cylindrical grids. Particles and bubbles were released into the turbulence and the motions of the three phases were monitored. The experimental results obtained in the present work were compared with the predictions of the models published in the literature.

Jan 1, 2005

By Dalmijn WL, Valk HJLvd

At the Faculty of Mining and Petroleum Engineering, the Department of Raw Materials Technology, a mathematical model has been developed to predict the porosity distribution in an uniform jig bed. If the porosity distribution in an uniform jig bed is known, it is possible to correlate this to the settling velocity of particles with a density different from the density of the bed grains and thus model the stratification in a jig. For measuring the porosity distribution in the jig bed a method has been developed based on light absorption techniques.

Jan 1, 1993

By Loughnan FC

There are some thirteen laboratories in Australia in which coal petrological work is carried out on a consistent and routine basis. Applied coal petrological research is conducted by several institutions in different disciplines which can be grouped into four main categories:

Jan 1, 1989

By B Lance, D O’Brien

The Hidden Secret ore body is located within the Mt Charlotte underground mining system in Kalgoorlie, Western Australia. Mineralisation of the Hidden Secret ore body is lode style and therefore differs from the typical economical mineralisation mined at Mt Charlotte and consequently demanded a novel approach to the mining methodology. The ore body is lens like in shape, extending 200m along strike, 210m vertically, and dipping at 55 degrees. The lode width varies from 1.5m at the extremities to over 22m in the central zone of the ore body. Average grade is 3.4 Au grams per tonne. The initial mining methodology was Modified Avoca utilising Longhole Open Stoping with pillars, in a bottom up stoping sequence. However, as Hidden Secret became better defined and wider than initially modelled, it was identified that a high portion of gold would remain in the pillars and other mining concerns emerged such as remote backfilling large open voids and potentially unsafe vertical standoff distances between levels and wide open stopes. A re-evaluation of this method was undertaken and a new approach adapting a variation of Avoca methodology was identified to remove the rib pillars and replace them with a sill pillar separating the 4 levels into 2 distinct blocks. This new approach provided an immediate advantage by removing the bogger backfilling activity from the same level of the active stope front, enabling stope drilling and prepping to occur during the backfilling cycle. Bogging productivity has also improved as the fired ore is funnelled to the draw point by the backfill rill, significantly reducing the requirement for remote bogging thus improving bogging productivity. This mining method is currently in progress in the first of the two mining blocks and is on track to realise the targeted recovery of 7,700 ounces from the rib pillars.

Mar 15, 2021

By Hermulheim W

In the Federal Republic of Germany hard coal is mined underground only. The coal mines reach down to 1 500 m deep, recently having an average depth of 900 m. The commonly used winning system is long- wall mining with face lengths up to 250 in. The gate roads, which separate the seam into single panels, have an average length of one kilometre with a cross- section up to 20 m2. These single entries are usually supported by yielding steel arches. The installation of steel arches can hardly be mechanized. The choice of heavier support, caused by increasing depth and roadway cross-section, results in high cost for labour and material in gate roads. Furthermore, the heavy steel arch is acci- dent-prone, not only during installation but also during transportation and ship- ment. Rock bolts combined with a suitable lagging offer a way of mechanizing support work in headings. The aim is to decrease cost and to increase mine safety and pro- ductivity. Over the last ten years, 50 km of gate roads have been reinforced by a combination of rock bolts and weld mesh. Nevertheless, there are still differing opinions on the feasibility of rock bolting in gate roads. In Germany a long tradition and experience with steel arch support exists, whereas the function of an anchorage is a closed book to miners, preventing this new technique from spreading more quickly. Advantages and shortcomings of both steel arch support and rock bolting are compared. The experience with rock bolting up to now is reported. Possible improve- monts arm discussed.

Jan 1, 1986

By H Zhang, S Li, J Song, Z Lv

In this paper, a method for extracting and refining metallic molybdenum using low-temperature ZnCl2- NaCl-KCl molten salt was proposed. The electrochemical behaviour of molybdenum ions in ZnCl2- NaCl-KCl molten salt was investigated in detail, and pure metallic molybdenum was collected on the cathode. The reduction and diffusion processes of Mo(V) ions in ZnCl2-NaCl-KCl molten salt were determined through a series of electrochemical methods. The diffusion coefficients and nucleation modes of Mo(V) ions were also studied, and electrolysis was conducted for a prolonged period at a constant current density. The results indicated that the electrode reduction of Mo(V) ions in ZnCl2- NaCl-KCl molten salt proceeds through a three-step reaction: Mo(V) → Mo(IV) → Mo(III) → Mo at 250°C. The Mo(V) → Mo(IV) reaction was reversible and diffusion-controlled, with a Mo(V) diffusion coefficient of 6.02 × 10-6 cm2 s-1. Additionally, the nucleation mode of Mo(V) ions was instantaneous nucleation. The products electro-deposited were confirmed of metallic molybdenum with a particle size of less than 1 μm.

Aug 21, 2024