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The following is based on two examples of emission control with coal fired power stations as practised in Germany at Heilbronn Block 7 power station and the Rheinbraun coal combined power station with integrated high-temperature Winkler system (HTW). Heilbronn Block 7 demonstrates the successful emission control of sulphur and nitrogen oxides and the (HTW) system the reduction of the specific carbon dioxide emission. Both were sparked off by legislation which demanded certain emission control standards. Since the early eighties environment protection has been a matter of heated public debate in the European Community. A recent survey in Germany showed unemployment as being the only subject matter more frequently in the minds of people than environment protection. A new kind of forest devastation in areas away from industry has caused investigations by several government departments and private enterprise. Because of lack of conclusive evidence so far, the principle of PRECAUTION has replaced the CONCLUSIVE evidence as a base for new legislation concerning the environment. The new legislative standards for nitrogen oxide emissions in Germany for example have reduced NOx emissions of power stations from 1000 mg NOx per cubic metre of flue gas in the beginning of 1983 to 200 mg NOx per cubic metre of flue gas in April 1984. These new standards were enshrined in legislation when research provided some evidence linking nitrogen oxide emissions through photo-chemical reactions with forest devastation. Thirty European countries signed a treaty in 1983 expressing their concern about air pollution and their willingness to co-operate with each other in controlling large scale emissions.

Jan 1, 1991

A short overview of the research program of SveBeFo, Swedish Rock Engineering Research, which was founded in 1993 is first given. Then four recent and ongoing projects in rock blasting and explosives engineering are presented in greater detail: 1. Burn Equations for Commercial Explosives. 2. Blast Damage in Contour Blasting. 3. The Role of Gas Pressure in Pit Wall Damage. 4. Fragmentation of Aggregate Rock. The goal of the bum equation project is to be able to control the energy release from explosive charges to the desired part of the expansion curve of the reaction products under various rock conditions. SveBeFo's work has reached the stage where a burn equation for a lab emulsion has been established which can model the influence of charge diameter on the VOD and detonation front curvature in a cylindrical charge quite well. This work now continues with other emulsion recipes. In the blast damage project the goal is to develop techniques and recommendations on how to minimise the blast damage in construction blasting. The project has gained extensive practical knowledge from the blasting of more than 200 holes in a granite quarry under controlled conditions. The cracks in the rock surrounding the contour holes have been cut open and measured. The influence of factors like charge concentration, decoupling ratio, hole and charge size, VOD and time delay in initiation have been investigated. A simultaneous initiation of a group of contour holes with EDD detonators is quite superior to single hole blasts, even when they are timed as closely as 1 ms.

Jan 1, 1995

By Murphy A. S, Budod A

The Philex concentrator represents the first time Jameson Cells have been used in a cleaner scavenger application or in large scale flotation in roughing and scavenging. This necessitated a major change in Jameson cell design as well as a chan

Jan 1, 1997

By D Reid

Many of the relevant engineering behaviours of tailings are controlled to a large degree by the density of the material. For example, loose tailings are prone to brittle strength loss, while dense tailings are dilative (i.e. gain strength) at large shear strains. The critical state framework has been successfully developed over the past few decades to assess whether in situ conditions are contractive or dilative, and estimate relevant engineering parameters on that basis. Tailings comprising primarily silt-sized particles, when subaqueously deposited, often form a particularly loose state compared to subaerially deposited material of similar index properties. Such subaqueous deposition occurs in the decant pond area, where the tailings typically pluviate in quiescent conditions within a pond of standing water. Silt tailings deposited in such a manner have been observed to be extremely loose in a number of TSF investigations. Of particular concern, the deposited material in such cases appear to be significantly looser than can be reproduced in the laboratory - even using moist tamping, the sample preparation method which can usually produce the loosest samples possible in laboratory conditions. While the loose density of subaqueously deposited silt tailings is clear, in a well-managed upstream-raised TSF the decant pond is usually small and far from the perimeter embankments, however there are a number of examples where the engineering performance of such materials becomes relevant – for example, when historical deposition practices were poor, resulting in subaqueous deposition near the perimeter embankment. This paper outlines the geotechnical characterisation of a number of such subaqueously-deposited zones, compares the in situ state to that achievable in the laboratory, and discusses options for assessing the expected engineering performance of such materials when comparable laboratory tests are unavailable.

Jul 1, 2021

By T Takayama, M Matsumura, Y Konno

The steel industry accounts for 14 per cent of domestic CO2 emission in Japan, and iron ore sintering process occupies approximately three per cent. While Fe content in iron ore is gradually decreasing. So, the amount of concentrated iron ore will increase in the future. We have focused on magnetite concentrate as sinter materials, because magnetite can be easily magnetically beneficiated. However, it is experienced that blending magnetite ore resulted in increasing Fe2+ component in the iron ore sinter, which results in lower reducibility. Therefore, promoting the oxidation reaction from magnetite to hematite in the sintering process is countermeasure for reducibility. In addition, this promotion causes increase of oxidation heat, which results in high sinter strength and reduction of coke. It is assumed that the oxidation of magnetite tends to proceed in the cooling stage, where the oxygen partial pressure increases after the combustion of fine coke, but there are few studies on the effect of heat profile, especially cooling path. The purpose of this study is to design the effective sintering heat profile to promote oxidation of magnetite ore, especially, to investigate the effect of cooling path on sintered ore microstructure. In this study, magnetite ore and magnetite reagent were respectively mixed with calcium carbonate reagent. Then the mixed samples were pressed and formed into cylindrical tablets for simulating the adhesive layer of a pseudo particle. Through examining influence of maximum temperature and cooking rate on oxidation reaction of magnetite, we confirmed that the oxidation reaction of magnetite is suppressed at above 1350°C for maximum temperature, compared to 1300°C. Sintering at lower temperature is desirable because hematite is stable below 1350°C in the Fe2O3-CaO phase diagram.

Nov 8, 2021

ALTHOUGH discovered as long ago as 1817, by Strohmeyer, the use of cadmium did not become in anyway general for nearly a century. Its properties, although well known, did not recommend it to users of metals generally, and it was, on the whole, regarded more in the light of a nuisance to zinc producers than anything else. Its real value was not appreciated until both the United States of America and Germany, who are entirely dependent on outside sources for their supplies of tin, were faced with the unpleasant fact that their tin stocks were being rapidly depleted, with practically no prospect of having them replenished. This resulted in serious efforts being made in the UnIted States of America to conserve what tin was available, and, as a consequence, several metals were tried in the hope that they would prove satisfactory substitutes for tin. Among these was cadmium, and it was found that cadmium could replace tin in a manner sufficiently satisfactory to permit of its use in many directions where tin had been used before.It is on this ability of cadmium to replace tin that its use became in any way general at first; but since then new avenues of development have been opened up in which its physical and chemical properties are proving their value. It is highly probable that its use will extend very considerably as time goes on. OCCURRENCE OF CADMIUM.There are several cadmium minerals known, but none of them occur in profitable quantities as ores. The cadmium of commerce is derived almost entirely from zinc minerals and ores in which it is almost invariably present in proportions which are usually very small. Cadmium behaves metallurgically almost the same as zinc, and hence constitutes a fraction of 1% of almost all spelter.

Jan 1, 1923

By S Brochot

In cases where coarse gold is present in a deposit, it is usual to use the screen fire assay (SFA) method to analyse the samples. There is no doubt that this method is more accurate than the standard fire assay (FA) and reduces the risk to have a systematic bias. Nevertheless, the difference between the analytical errors of both methods can be glossed over when the overall sampling error is added to obtain the measurement error. In that case, the advantage of the SFA cannot justify its higher cost.The current paper attempts to address this question in the case of a gold ore deposit with visible coarse gold in various sampling situations (drill core sampling in exploration, blasthole or chip sampling in mining exploitation). The overall measurement error is estimated taking into account the analytical error and all the sampling error components following the Pierre GyÆs theory of sampling.Firstly, only the last sampling stage is considered when the pulverised sample is processed either to obtain one analysis sample for a FA or to be screened and subsampled for a SFA. The calculated measurement error clearly shows the advantage of the SFA specifically in presence of coarse gold. Secondly, the half core sampling is studied to explain the observed discrepancies when controlling the second half core. Finally, the blasthole sampling is treated using in situ heterogeneity models to show that the relative advantage of the SFA is hidden by the large overall sampling error.In conclusion, the choice of the assaying method is discussed at the light of the overall measurement error and in accordance to the analysis objective.CITATION:Brochot, S, 2012. Standard fire assay or screen fire assay? Application of the overall measurement error approach to choose the most appropriate method, in Proceedings Sampling 2012 , pp 135-142 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 21, 2012

By Misk A

Several logging methods are presently available to the oil industry for the evaluation of formation porosity: the Sonic and Neutron logs are already widely used, the Gamma-Ganmia log is being progressively introduced. The readings of these instruments are primarily a function of the rack-porosity, hence the general term of "porosity tools". Apart from porosity, however, other variables such as type of fluid in the pores, nature of matrix and degree of shaliness have an important influence.The response of each device is a different function of such parameters: therefore, a cci bination of porosity tools can lead to information on these variables in addition to the evaluation of effective porosity.For example, the presence of gas; rather than water or oil, in a formation which is not deeply invaded, will tend to give Neutron derived porosity values which are too 'low; on the other hand, the Sonic derived porosity: value will be too high in such- a case. For the same porosity, the Sonic gives a longer transit time in sandstone than limestone, whereas in the low porosity range, the Neutron will read more counts per second in a sandstone than in a limestone of the same porosity. The presence of shale also affects the readings of the various porosity tools in different ways so that the combination of two or more methods may lead, in some cases; to an evaluation of both the-effective porosity and the shale, content.In conclusion, it may be said that the various porosity tools pre-sently available, are, to a large extent, complementary, and that in many problems the use of two porosity tools, instead of one, is very likely to bring valuable additional information.

Jan 1, 1962

By D Craw

Quaternary warping and uplift of antiformal schist ranges in Central Otago, New Zealand, has resulted in recycling of alluvial gold from widespread, generally weakly auriferous, Miocene fluvial gravels that unconformably overlie the schist, into aprons of fan sediments along the range margins. Basement erosion during uplift has been limited and so gold input from sparse gold-bearing quartz veins in the schist has been relatively minor. In an eluvial cycle on the slopes of the ranges, chemical remobilization of gold occurs during oxidation and erosion of the Miocene sediments. The typically fine-grained (300 - 400 ¦m) gold undergoes chemical modification and grain size enhancement of up to two orders of magnitude, and much of it is redeposited in a large number of relatively small alluvial fans along the range margins. Groundwater mobility within the fans results in minor additional gold mobility and grain size enhancement. During range uplift, a small number of relatively large axial streams and rivers have developed in structural lows between growing antiformal folds. Axial streams 'gather' their flow from consequent streams draining the folds, and flow parallel to a range axis for some distance before cutting across it in an antecedent gorge. The axial streams rework alluvial fan sediments along the range margins, and transport mainly fine-grained gold from the fans along the ranges. This gold is redeposited where the axial streams emerge from a range in the neighbouring structural basin. Axial streams drain relatively large areas of range surface, and thus reconcentrate significant quantities of gold in a small number of relatively large fans and fluvial deposits. The processes of gold collection and re-deposition by axial streams are essentially the same, regardless of stream size. Coarse-grained gold produced by chemical remobilization, is more difficult to transport in fluvial systems, and thus remains in close proximity to eluvial environment where it was formed.

Jan 1, 1995

By M Olsen

"Segregation of conveyor roadways is a ventilation practice that is being increasingly applied in Australia. It is largely driven by the legislated requirements in Queensland pertaining to separation of escapeways from the mine. This legal requirement was based on a recommendation from the Moura No. 2 WardenÆs Inquiry (Windridge, 1996) into the mine disaster that claimed 11 lives. The report recommended: ... the introduction of a requirement for all underground mines to have one intake airway that is completely segregated from other parallel intake airways so as to provide two separate means of egress from the mine via an intake airway.This recommendation seeks to assist mine workers in escape from a mine after a fire by providing them with an airway that is free from smoke or contaminants.The concept of an airway being æcompletely segregatedÆ is an ideal that is challenging to implement in practice when considering the effect of leakage. The practice of belt segregation is concerned with the potential for fires in the belt roadway although there are numerous other potential fire sources in underground coal mines. A review of segregation practices has been conducted applying ventilation engineering principles. Four different scenarios have been analysed with regard to the effectiveness of the segregation stoppings in preventing potential fire contaminants migrating to other parts of the mine. The results show that in some cases the benefits of segregation to a person evacuating a mine in the event of a fire range from beneficial to detrimental. This is influenced by many factors including the location of that individual in that particular mine. There is room for improvement in the design and implementation of escapeways in underground coal mines. Escapeways need to be planned and designated with regard to the potential sources of fire, pressure differentials between escapeways and the operational practicalities of maintaining the pressure differential between them.CITATION:Olsen, M, 2013. Belt road segregation and escapeways - Compliance or risk management?, in Proceedings The Australian Mine Ventilation Conference, pp 311-318 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 1, 2013

In Australia we usually define "resource" in purely material terms, and rarely relate it to intellect and human capacity. We look at the sheer abundance of our natural resources and are satisfied with the feeling that we don't really need-to rely on using our brains. Certainly our country is fortunate to have the mineral resources it does, but in many ways Australia's worst enemy is its "lucky country" syndrome because we tend to underutilise the great resource we have in the capacities of our people. Raw material exports will undoubtedly continue to contribute a major share of our export revenue, but to harness the riches our country has to offer most effectively we need the vision and planning necessary to bring together our material and human resources. There is a need not only to find, exploit and process our minerals economically, but to turn as much of our mineral wealth as possible into high value products before it leaves the country. In particular we must use our brainpower if we want to maximise economic benefit from and political influence over the strategic minerals which leave our shores. In the past we have been successful in finding and exploiting minerals because our mining industry has been in the forefront of private sector research and development. But if Australia is to have an advantage over other mineral rich countries in insulating itself from the effects of cyclical swings in commodity prices, then the future of the industry must lie even more in technological sophistication rather than depending. on such considerations as size and location of mineral deposits. To survive, our mineral industry must have the foresight and resourcefulness to make its own luck. There are two keys to increased efficiency in exploration and production and in further processing methods: enhancement of the skills of the workforce and continual improvement of R&D.

Jan 1, 1986

Mid-ocean ridges host approximately 65 per cent of about 100 known sites of high-temperature venting and polymetallic sulfide deposits; most of them are located at the East Pacific Rise (EPR), while more diverse mineralisation styles occur at the Mid-Atlantic Rise (MAR). Seafloor hydrothermal activity at the EPR are related to MORB while different substrates, including MORB and ultramafic intrusive rocks, are associated with æblack smokersÆ at the MAR. Depth of hydrothermal activity ranges from 0.7 to 4.3 km. High-temperature vents precipitating Cu-Fe sulfides (chalcopyrite and isocubanite, rare bornite), pyrrhotite, pyrite (¦ marcasite), and sphalerite, and low-temperature edifices precipitating marcasite (with pyrite), sphalerite, barite, andsubordinate chalcopyrite (pyrrhotite and isocubanite are absent) occur in both environments. There are considerable differences in Fe, Zn, Cu, Ag, Au and trace element contents in ores and in theFeS contents in Zn-sulfides in these deposits. Acomparison with anhydrite and sulfide minerals precipitating from modern black smoker fluids sulfide reveals many similarities but also some important differences. Fluids with salinity values above and below that of seawater at 400¦C down to 130 - 170¦C deposited sulfide minerals. Mantle-derived He prevails in fluids trapped by sulfides in EPR 9¦N and 21¦N hydrothermal systems. Hydrothermal fluids in MAR and back-arc systems are richer in radiogenic 4He. The sulfur isotope composition varies in the different hydrothermal fields and within zones of a chimney. EPR sulfides display narrower range of d34S values, while MAR and back-arc sulfides can bedepleted and enriched in the heavier d34S isotope. The most important finding is that fluid temperature, salinity, R/Ra ratios and d34S values ranged more significantly in the polymetallic sulfide deposits than when measured directly on venting fluids. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

Australian wheat belt agriculture is causing a decline of its natural resource base. The major problem, salinity, arises from a small reduction in water consumption by agricultural crops compared to what prevailed under the prior native vegetation. This causes groundwater accumulation which, in the low relief landscapes of the wheat belt, is leading to extensive surface saturation in low landscape positions and dramatic, destructive change in the hydrological behaviour and habitat of streams and rivers. The ability of agriculture to invest in salinity control is severely limited by its long-term decline in its terms of trade. Extensive planting of perennial vegetation has the potential to increase water use and arrest the salinisation process. If these perennials were also commercially attractive, the cost of salinity treatment could be minimised. Given the difficult commercial position of food commodities, it is logical to develop ænon-foodÆ perennial crops, in particular woody crops suitable for industrial products. This paper looks at the example of Sweden, where there has been a generation of investment in developing forest harvest residue recovery, and short cycle woody crops for bioenergy, but with only limited success. In contrast, secondary residues (processing wastes) from forestry industry are readily saleable for low value uses like bioenergy. This suggests that the model woody crop must have a higher value fraction to facilitate delivery and commercial use of its lower value fractions. This model is being emulated in the development of native mallee eucalypts as short cycle woody crops in Western Australia. Some $50 million has been expended on mallee development in the past decade and this has culminated in an engineering demonstration of integrated processing. The putative high value products are activated carbon and eucalyptus oil and the residue (plus waste heat) will be converted to electricity. The potential scale on which crops of this type would be required to achieve salinity control means that many more high value and residue products will have to be developed. Metallurgical charcoal appears to be a promising product option.

Jan 1, 2006

Structural geological modelling is a process which results in a 3D computer model that represents the essence of the geological and structural understanding of an area and is presented in a way that is directly useable, typically by internal customer groups. BHP Iron Ore operates a number of open cut iron ore mines in the Pilbara Region of Western Australia. The largest mine is the Mt Whaleback Mine located at Newman close to the southern margin of the Pilbara Craton. The structurally complex Mt Whaleback Mine is the largest metalliferous single pit open cut mine in Australia with over 1.6 billion tonnes of original iron ore resource. Additional to the Mt Whaleback Mine, a number of satellite open cut iron ore mines are operated by BHP Iron Ore (BHPIO) in the Newman area. BHPIO also operates the Yarrie mine approximately 400 km north of Newman at the northern edge of the Pilbara Craton Most of the BHPIO mines are located in the Archean- Proterozoic Hamersley Province that overlies the Archean granite-greenstone terrain of the Pilbara Craton. The orebodies are considered to be the result of supergene enrichment of the approximately 2.5 Ga Brockman Iron Formation and the slightly older Marra Mamba Iron Formation. Folding represents the most prevalent and penetrative structural element in the Newman area. Four folding phases have been identified regionally (Fj, F2, F3, F5), while a more local folding deformation (F4) developed mainly in the Mt Whaleback and Orebody 29 mine area. A northeast trending, southeast dipping, 45 km long, high angle, normal fault zone, the Whaleback Fault Zone, cuts through the Mt Whaleback mine resulting in an approximately 1400 in gap in stratigraphy. Additionally, two large, low angle, normal faults, the East Footwall Fault and the Central Fault, are present at the Mt Whaleback Mine. During the formation of supergene orebodies, up to 40 - 45 per cent volume loss occurred resulting in local non-tectonic deformation in the orebodies.

Jan 1, 1997

The earliest suggestions that some metallic ore deposits might have resulted from seafloor volcanic exhalation seem to have been those of Elie de Beaumont in 1847 and Henry de la Beche in 1851. In 1885 Tinoco, and Bouglise and Cumenge, independently investigating-.the manto copper deposits of the Boleo district of Baja California, proposed that these had formed on the seafloor by precipitation from "hydrothermal submarine emanations". Some twenty years later the Japanese geologists Kukuchi and Tsujimoto (1904) put forward the idea that the Kuroko ore- bodies were seafloor volcanic sinter deposits and in 1919 this was re-affirmed by Ohashi. In 1909 the English geologists Thomas and MacAllister postulated a similar origin for some of the gold deposits of Mount Morgan in Queensland. Between the wars the great European economic geologists Niggli and Schneiderhohn both clearly recognized a class of seafloor hydrothermal deposits. The idea rose again immediately after the Second World War in a very clear statement by Hegeman in 1948, which was followed by contributions by Ehrenberg and Kraume and their co-workers on the submarine volcanic origin of the Meggen and Rammelsberg orebodies in 1954 and 1955 respectively. In 1955 the present writer, quite unaware of early or contemporary work on volcanic exhalative ore deposits, proposed a volcanic sedimentary/diagenetic origin for the stratiform base metal ores of SE Australia. In doing so the writer emphasized the probable importance of island arc volcanism, suggested that some "metallogenetic regions" of ancient terrains were in fact old island arc systems, that the composition of the ores might be related to the composition of the associated volcanic rocks and that such ores would be tied to volcanic stratigraphy. Ideas on relations between volcanism and stratiform ore genesis have thus been evolving over.a period of some 140 years and, beginning with the observations on Baja California in 1882, work round the rim of the Pacific has made an important contribution over a period of more than 100 years.

Jan 1, 1987

By P R. G Milne

A risk-based approach to optimising pit wall slope angles was trialled in the design of a 60m deep open pit in extremely weathered and distinctly weathered materials in the Kalgoorlie area. The pit used for this approach was Stage 1 of a three-stage open pit project. The Stage 3 pit will require long term stability, as it will contain the portal for a long life underground project. Information from failures induced by steeper wall angles used in the Stage 1 pit would be valuable in predicting and preventing long-term stability issues in Stage 3. In this approach, the pit wall slopes are based not on the normal factors of safety, but on the assessment of the probability of failure and the direct and indirect costs of dealing with the failure when it occurs. In this example, the benefits and risks of adopting steeper wall angles were compared in a series of graphs. These charted the increasing probability of failure and simultaneous decreasing factors of safety with increasing pit wall slope, and the range in the possible volumes of circular failures for increasing wall angles. These were brought together in a graph showing the potential excavation savings (in BCM) and the probable cost of a failure (probability of failure times the probable volume of the failure). The resulting pit design was based on the project Mining EngineerÆs semi-quantitative assessment of where and when a higher risk of failure was acceptable and where it was not acceptable as it may have unduly affected the integrity of haul roads or production. The design incorporated wider than normal berm widths to accommodate anticipated failures and to enable modification of the wall configuration if required. Several re-designs were required during the life of the project in response to aggressively induced failures. It is considered that this risk-based approach provides a practical route to optimal pit design and operation but it requires an experienced, dedicated and efficient mining team for it to be implemented with benefit.

Jan 1, 2003

By D Thornton

Geologists use large data sets and spend many hours and much computing time modelling the distribution of minerals throughout a rock mass. Significant investments in drilling, assaying and quality assurance and quality control (QA/QC) are made before sophisticated geostatistical techniques are applied to the collected data. A large amount of research has been done in this field such that the ore control model is a reasonably accurate reflection of the mineral that is actually in the ground. However, after all this effort, the mining engineers then work just as diligently to blast the in situ rock mass to a particle size that can be efficiently handled and further reduced by downstream comminution processes. In open cut mines, this invariably requires large amounts of explosive energy that displaces the ore boundaries from where the geologists originally defined them. Failure to accurately account for blast movement will result in misclassification, whether that is ore to waste; low grade to high grade; sulfide to oxide; or other contaminates û collectively referred to as ore loss and dilution. The financial consequence of getting this wrong is substantial and not well quantified. This diminishes all of the good geological QA/QC done in defining the ore. This paper discusses various technologies used to physically measure blast-induced orebody movement and the difficulties in modelling this with a purely theoretical approach. Rock mass structure, blast energy, design and timing contours all have significant and interrelated effects on blast movement vectors. Measured blast movement has a large variance due to the uncertainly of many of the controlling parameters û arguably dominated by the heterogeneous nature of the rock mass. Although there have been significant advances in blast movement modelling capability in recent years, this unpredictable blast movement limits their use in the context of production ore control. Certainly, without physical field measurements, accurate predictions of movement are near impossible.Limitations of traditional surface markers in determining three-dimensional (3D) blast movement within the orebody are also reviewed, and advancements in accurately measuring these vectors within blasted ore discussed

Sep 26, 2011

By S-C Shim, H-R Lee, Y Kang, H Shin

Since iron oxide and silicon oxide are major gangue components in various types of ore, FeO-SiO2 base slag, ie fayalite slag, has been often encountered in pyrometallurgical processes of non-ferrous metals. During most matte production processes such as the smelting of Cu, Pb, and Ni, the FeOSiO2 based slag is inevitably formed and plays an important role in refining crude metal as well as engineering aspects. Recently, similar pyrometallurgical approaches have been attempted in the recovery of valuable metals (Ni, Co, Cr) from wasted secondary batteries. Thus, the viscosity of the FeO-SiO2 based slag has great significance in properly controlling smelting processes. However, when molten metal or matte does not coexist with the slag during the measurement, there has been a serious difficulty in maintaining Fe valance and consequently, the slag composition. In the present research, the viscosity of molten FeO-SiO2 slag was measured in 1573~1673 K using a rotational viscometer. In order to keep the state of iron oxides, the oxygen partial pressure was controlled using CO/CO2 gas mixture. The optimised ratio of CO/CO2 could be calculated using Fe/Fe2+ and Fe2+/Fe3+ equilibria at each temperature. The composition of the slag, particularly Fe valance, after the measurement was analysed with the aid of an inductively coupled plasma – optical emission spectroscopy (ICP-OES) and an automatic potentiometric titrator. The measurement showed that the FeO-SiO2 slag has considerably low viscosity values in the molten state, and it sharply increases as the temperature decreases. In spite of the careful oxygen partial pressure control, a part of Fe2+ was found to be oxidised to Fe3+, with a maximal case reaching about 20 per cent. The increase in viscosity of FeO-SiO2 at low temperatures can be attributed to the composition change due to an unavoidable Fe2+ oxidation. In addition, the relationship between the change in the viscosity and the liquidus temperature of FeO-SiO2 based slag was discussed to understand the composition dependence of viscosity.

Jun 19, 2024

An extensive railway construction prog- ram in the People's Republic of China has required the excavation of many tunnels in difficult ground, particularly in mountainous regions. Conclusions drawn from case histories permit guidelines to be formulated as to the optimum location of tunnel alignments in faulted and folded terrains, and also in karst regions. Geological factors adversely affecting durability of tunnel linings can be minimised by adoption of appropriate construc- tion practices.

Jan 1, 1987

By Wasserman A. D

Methodological approaches and in- vestigation results are considered in the paper of heatmass transfer processes when harmful impurities are scattered and remo- ved from chamber-like workings, of the air distribution in complicated ventilation sys- tems and of chemical conversion of exha- ust gases in mine atmosphere when diesel equipment is operating. The results presented in the paper are the base for creation of the automatic design, control and regulation of the venti- lation processes.

Jan 1, 1988