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By P Ritchie, E H. Briese, N A. Currey

Kidston Gold Mines, located in semi-arid North Queensland, Australia is currently in its closure phase. Highly innovative and comprehensive rehabilitation strategies were employed at the site, including the direct revegetation of the surface of the tailings storage; the construction of a tailings sediment entrapment pond; the construction of a spillway to drain large rainfall events from the surface of the tailings; the construction of store/release covers over the tops of the waste rock dumps; the sheeting with oxide waste rock of the waste rock dump slopes; the partial back-filling of the initial Wises Hill Pit with waste rock and thickened tailings produced from the subsequent Eldridge Pit; the partial flooding of Eldridge Pit following the end of mining; and the construction of wetland systems to treat contaminated tailings and waste rock dump seepage. These closure strategies involved the careful consideration of water management. Specific water management issues included understanding the water balance of the tailings dam; the operation of the tailings dam sediment entrapment pond and spillway; understanding the water balance of the store/release waste rock dump covers; the importance and sustainability of vegetation on the tailings, store/release waste rock dump covers, and on the sheeted waste rock dump slopes; the level and quality of water in the partially flooded Eldridge Pit; and the treatment of contaminated seepage in the constructed wetlands. The seasonal and highly variable rainfall experienced in this semi-arid climate posed a number of challenges for the management of water on the site post-closure. The paper details these challenges and highlights how they were resolved over the period leading up to and following the end of mining.

Jan 1, 2003

By Palmer C. G, Rowe P. G

Ore handling improvements at Mount Isa Mines Limited were necessary to keep abreast of technological advances in all phases of sublevel stoping practice.In the early 1930s an efficient ore handling system was in operation.However in 1936 excessive water encountered in deepening the hoisting shaft necessitated the sinking of a second hoisting shaft. Financial difficulties prevented abandoning the original shaft and surface ore handling and crushing facilities, so ore was transferred underground and underground crushing deferred. It was not until 1951 Jhat multilevel crushing permitted increased efficiency in the handling of ore from stopes. Ore was then hoisted in one shaft and transferred on the surface by conveyor belt to a new crushing plant.In 1956 a planned production increase from 5,000 to 11,000 tons per mining day made possible further improvements in ore handling. Larger equipment was installed and existing equipment modified to capacitate the handling of larger sized ore at increased daily tonnages.INTRODUCTIONThe intensive exploratory programme commenced in 1954 disclosed large reserves of both lead and copper ores and in 1956 an expansion programme was initiated to increase production from 5,000 to 11,000 tons per mining day. The increased tonnage would result in decreased costs per ton and further cost reductions would result from increased mechanisation underground. The combined effect would permit larger tonnages of lower grade ores to be included in ore reserves. To achieve both cost reduction and the scheduled production increase, improvement in ore handling was of vital importance.For efficient and low cost sublevel stoping it is necessary to maintain an economic balance between...

Jan 1, 1961

By C E. Loayza, R M. Pinto, J G. G=mez

The Yanacocha District is located 20 km north of the city of Cajamarca, in the Northern Andean Orogenic belt of northern Peru.Gold production may have occurred as early as Incan times (Paverd, 2000), but modern exploration that began in the 1960s targeted only copper and silver. Newmont Mining Corporation, BRGM and Compa±fa de Minas Buenaventura began exploring for gold in 1983, with Newmont as operator.Initial drilling took place in 1985. By 1992 a reserve of 1.28 million ounces was reported (Teal et al, 2002).Production began at the Carachugo deposit in 1993.Current reserves are 31.7 million ounces at $US 325 per ounce at a grade of 1.03 ppm (Newmont Annual Report, 2003).The operating company, Mineral Yanacocha SRL (Newmont 51 per cent, Buenaventura 44 per cent and International Finance Corporation five per cent) produced 2.85 million ounces in 2003, making Yanacocha one of the largest gold mining operations in the world. The district is made up of a series of epithermal, high sulfidation style gold deposits and one gold-rich gravel deposit (La Quinua), aligned in a NE trend.La Quinua is not discussed in detail in this paper. The bedrock deposits are hosted in a Miocene volcanic package, the Yanacocha Volcanic Complex that also trends NE.Re gional NW striking Andean faults intersect the NE striking Trans-Andean Chicama-Yanacocha structural corridor (Turner, 1997), localising the district mineralisation. These two structural orientations dominate the district, controlling breccia and intrusion locations, and gold mineralisation. Discontinuous EW oriented fracture zones are interpreted as extensional and locally are important in controlling gold mineralisation.

Jan 1, 2004

By C Zhang, I Canbulat, S Saydam, H Yu, H Chen

Natural rocks are frequently exposed to groundwater and complex geological conditions. Environments with water presence are more susceptible to chemical corrosion, which notably affects rock’s micro properties. Generally, the pH of acid mine drainage in hard rock mines can be low to 5, and the pH of quarrying waste deposits can be below 3. With the expanding scope of mining engineering in aquifers and salty areas, chemical corrosion can also caused by different types and concentrations of anions. The anions can significantly affect rock’s mechanical properties. Therefore, it is critical to emphasise the impact of anion and acid on the mechanical and micro characteristics of rock. This paper commences with an introduction to representative corrosive environments. Then the UCS tests are conducted on granite samples corroded by chloride ions and sulfate ions. Anion has negative effects on the strength of granite. The reason is that certain minerals can react and be dissolved by anions and hydrogen ions, such as Al2O3. Furthermore, the scanning electron microscope (SEM) shows that the roughness of the fracture surface increases with the anion concentration. The effect of acid is notably more pronounced than anion on the micro properties of granite. The initiated fissures and pores also increase with the concentration of SO42- and Cl- ions, which is the micro explanation for the impact of anion on rock strength and stability. Subsequently, the permeability of the granite specimens is tested. The reason that granite performs insensitivity to acid and anion is attributed to its low permeability and high content of inactive oxides, such as quartz. To summarise, anionic and acidic conditions can slightly deteriorate the mechanical and micro properties of granite. While SO42- demonstrates a higher level of corrosiveness on granite than Cl-.

Sep 1, 2024

By J J. Jiang, B G. Bow

Atlas Iron Limited’s (Atlas) Abydos Mine has developed its Scarborough open pit proximal to a rock shelter that has been assessed as a significant Aboriginal heritage site by the Traditional Owners of the land. The rock shelter, named Yurlu Kankala, is located to the north-west of the pit with a stand-off distance of 35 m. Within Atlas’ Native Title Agreement with the Traditional Owners, and approvals from the Western Australian Department of Aboriginal Affairs, commitments have been made to conduct mining in a way that avoids or at least minimises disturbance and damage to the rock shelter. This complies with the Aboriginal Heritage Act 1972 (WA) and respects the heritage and culture of the Traditional Owners.CITATION:Bow, B G and Jiang, J J, 2018. Iron ore mining in proximity to a significant Aboriginal heritage rock shelter, Pilbara Region, Western Australia, in Proceedings Life-of-Mine 2018, pp 2–5 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By T R. Gibbons, I Grayand

Geotechnically massive strata may lead to a host of problems during longwall mining. These include windblast on initial goaf fall, sudden loadings on powered supports, periodic weightings, fractures that may propagate to surface, and extreme subsidence problems. It is essential to identify these problems prior to mining and to appropriately deal with them. The problem is essentially that the rock mass does not breakup evenly and when it does so it tends to produce large blocks which may suddenly move. The rock types that produce these problems tend to be massive sandstones, massive siltstones and sometimes igneous sills. The fundamental problem with these is that they do not breakup readily. This is because the ratio of stress they are subject to compared to their strength is low. Thus, the shallower mines with lower stresses are more subject to this problem than deep highly stressed ones with similar strength rock.

Nov 29, 2022

By W Zhu, J H. Zhao, H Ma

The permeability coefficient is an essential parameter for the study of seepage flow in fractured rock mass. This paper discusses the feasibility and application value of using readily available RQD (rock quality index) data to estimate mine water inflow and grouting quantity. Firstly, the influence of different fracture frequencies on permeability in a unit area was explored by combining numerical simulation and experiment, and the relationship between fracture frequencies and pressure and flow velocity at the monitoring point in fractured rock mass was obtained. Then, the stochastic function generation program was used to establish the flow analysis model in fractured rock mass to explore the relationship between flow velocity, pressure and analyse the universal law between fracture frequency and permeability. The concepts of fracture width and connectivity are introduced to modify the permeability calculation formula and grouting formula. Finally, based on the on-site grouting water control case study, the rock mass quality index is used to estimate the mine water inflow and the grouting quantity. The results show that it is feasible to estimate the fracture frequency and then calculate the permeability coefficient by RQD. The relationship between fracture frequency and RQD and the relationship between structure surface frequency and permeability follow an exponential function. The calculation results are in good agreement with the field monitoring results, which verifies the rationality of the calculation method. The relationship between the rock mass RQD index and the rock mass permeability established in this paper can be used to invert the mechanical parameters of the rock mass or to evaluate the permeability and safety of the rock mass, which is of great significance to the prediction of mine water inflow and the safety evaluation of water inrush disaster management.

Nov 29, 2022

By Y H. Zhu, X X. Tang, Y C. Yin, M L. Xing

Based on the stiffness theory, the stiffness difference and energy supply of surrounding rocks are important inducing factors for strain burst. However, due to the lack of multi-level low stiffness testing machine, there are few experimental studies on rock failure mechanisms under the influence of loading stiffness. This paper introduced a self-developed rock testing system with changeable stiffness. The main testing machine of this system is a combined structure of inner and outer frame. The change in the loading stiffness is achieved by using a stiffness servo control system to control the energy accumulation in the inner frame. The tests of the sandstone specimens under three different loading stiffnesses in the testing system showed that the loading stiffness did not significantly affect either the uniaxial compressive strength or the Young’s modulus of the rock. However, the post-peak stress-strain curve of the rock became smoother and steeper when the loading stiffness was decreased, and the stress drop rate increased. It is shown that the stress drop rate had a power function correlation with the loading stiffness. After the peak load, the inner frame of the testing system rebounded several times at high speeds. The magnitude of the instantaneous rebound speed and the rebound duration increased with the decrease of loading stiffness. Both the mean rebound velocity and the total rebound deformation had power function correlations with the loading stiffness. The loading stiffness has limited effect on the energy storage and energy dissipation characteristics of the specimen, while the released energy of the testing machine increases as the loading stiffness decreases, which is the key factor affecting the failure mode of the specimen. According to the test results, a rock burst mechanical model considering the stiffness is established, and the energy supply mechanism of rock burst is quantitatively explained.

Nov 29, 2022

The Osborne copper-gold deposit (within the Trough Tank project area) is located in the Cloncurry Shire about 195 kilometres south-east of Mount Isa. It is hosted by Proterozoic metasediments of the Eastern succession of the Mount Isa Inlier. The deposit is overlain by 25-40 metres of Mesozoic cover, so it represents a true "blind target". Placer Exploration has 100% outright ownership of the property, having purchased the remaining 10% interest in the property from Shell in early 1993.Intensive exploration, both surface and via drilling at Osborne, has taken place since 1985, when CSR Limited Mineral Exploration and Development Group (acquired by Placer in 1988) entered into a joint venture with Billiton Minerals. Exploration effort from 1985 to June 1988 outlined a 20 kilometre strike length of magnetic horizons, in what was termed the North-East, Central and Southern anomalies, which were drilled with weak indications of copper-gold mineralization in the North-East anomaly. During the later half of 1989, four core holes were drilled into the shallower northern partofthe North-East anomalywhere previous drilling had outlined economic intersections of mineralization. These holes encountered high-grade copper-gold mineralization confirming the potential for an economic deposit to be hosted within the ironstone sequence. Further drilling involving over 400 holes (100 kilometres of drilling) has brought the deposit up to its present resource status.The current resource inventory is 36 million tonnes grading 2.0% copper and 1.0 grams pertonne gold and includes a high-grade zone of 13 million tonnes grading 3.6% copper and 1.5 grams per tonne gold. The discovery of this potential economic mineralization resulted from a persistent exploration effort based on indications that a large mineralizing system existed within a sequence of ironstones.

Jan 1, 1993

The æProfit Driver ModelÆ is a tool which builds costs from first principles and integrates revenue, costs and physical mining parameters and, hence, can quantify the impact and leverage on profit. In this paper an æexample mineÆ has been created to represent a typical Australian Open Cut Coal Mine. This has then been input into the Profit Driver Model to allow different variables to be tested. A series of variables were tested to determine which ones had the highest impact on profit and results are useful to management as a guide to the areas in which they can focus effort to achieve better profitability. Whilst the highest profit drivers are those external to the control of management and include selling price and exchange rate, the next most sensitive are those variables related to the geology of the mine and the mining method. These included coal quality, yield and strip ratio. Site management has some control of these. For example, the ability to vary the sequence of mining or improve the yield by a more efficient coal washing process. The efficiency of the workforce and management has similar impact to the mining variables. Finally, there are the supply variables, such as fuel, labour and explosives which are the least sensitive although, cumulatively, still significant. Each mine is different and the results of the example mine will not apply to all mines. However, the approach taken is universal and the tool illustrates a simple method to quantify the profit impact when changing variables. The benefit of the approach is the short time taken to get a set of results. This allows the more detailed and time consuming work to be more focused. The results illustrate that management has a significant influence on profitability.

Jan 1, 2000

A significant resource of uranium has been discovered within a buried palaeochannel located in the south western corner of the Officer Basin of Western Australia by PNC Exploration (Australia) Pty. Ltd. The mineral- isation is redox controlled and is hosted by Eocene organic rich paludal sediments. Prob- able insitu reserves are 13,000 t of contained uranium with an average ore grade of 0.12% at a cutoff grade of 0.03% U. The Mulga Rock palaeochannel has been traced for at least 100 km beneath the Quaternary surficial cover. The main channel is horseshoe shaped with the channel arms vary- ing from 5 to 15 km in width. The western arm connects to the Lake Raeside-Ponton Creek drainage system, whilst the eastern arm'is open to the south. The headwaters of the palaeo- channel are thought to have been the Lake Minigwal drainage system, prior to its capture by the Lake Rason system. Differential.erosion of the basement rocks during the Late Cretac- eous to Early Tertiary strongly influenced channel shape and resulted in the main channel being confined to a Permian,mudstone filled valley. Upwards of 100 m of fluviatile sediments accumulated within the palaeovalley during a period of subsidence in the Early Tertiary. Three broad stratigraphic units have been re- cognised within the channel: 1. An upper unit of fluviatile sands with interbedded lacustrine sediments, which have subsequently been wholly oxidised and variably silicified and ferruginised. 2. A middle unit of lacustrine to paludal sediments, which host the main mineral- isation. 3. A basal unit of fluviatile gravels and sand. The presence of excellently preserved Nothofagidites in organic rich paludal sediments from the middle unit, suggest that unit was laid down in a non-marine, fluviatile, humid environ- ment during the Middle Eocene.

Jan 1, 1988

It is generally known that Charters Towers was discovered by Mosman, Clarke and Fraser in 1871. However, the time was ripe, and these three were barely in front of others. There is one account that prospectors from Ravenswood visited the area months before but decided it was too far from water, and that one of them had told Mosman and party of the find. There is another account that Joe Larkins found the discoverers before they had registered any ground - this may explain Mosman's quick departure for Ravenswood.When the news spread, the rush was rapid, and there was soon a sizeable population: probably too many, as within twelve months the infant settlement was under considerable stress. First, the presiding Gold Commissioners had adopted "unusual and arbitary" interpretations of the Regulations, and many of the miners were aggrieved; Charters, the senior Commissioner, was accused of favouring moneyed interests, and of retiring ill whenever a brawl or confrontation occured. As a result, the law of the field soon became "the survival of the strong". Second, the settlers were, divided on where the main town should be: Millchester, near the water, or Charters Towers near the mines. Third, the discovery of gold at the Millchester Deep Lead in August, 1872 was followed by highly exaggerated accoants in_' the southern papers, apparently fabricated by local business speculators. The resulting rush resulted in hundreds of unlucky prospectors having to return or seek other fields. In that period two men were killed in squabbles over ground. To make matters worse, by October 1872 a drought had set in, water cost three pence a bucket, fodder was scarce, cartage expensive, and the price of crushing ore rose to thirty shillings per ton.

Jan 1, 1986

By J J. Cilliers, E Ventura-Medina

Mineral froth flotation is used to separate particles of valuable mineral from its associated gangue. It involves the selective separation of the hydrophobic particles from the slurry into the froth. As air is blown into the slurry, the hydrophobic particles attach to the air bubbles, while the waste particles remain in suspension. While the froth rises up, bubbles start to coalesce and burst, allowing the entrained liquid surrounding the bubbles to drain and return part of the gangue to the pulp. Mineral separation is therefore a function of the amount of valuable material loaded on the bubble shells, as well as the amount of gangue material entrained in the liquid channels separating the bubbles (Plateau borders). As a result, the separation performance of the process is affected by mineral attachment and drainage or bursting in the froth. This study aims to establish the relationship between solids loading, froth stability and separation performance. For this purpose, a series of industrial experiments were carried out to measure mineral attachment as well as bubble bursting by combining direct sampling of the bubble films and video image analysis of the froth surface. This work suggests that the solids loading on bubbles strongly affects the separation performance. The results generally showed that solids loading and concentrate grade are closely related, while froth bursting rate can be linked to the drainage of gangue from the Plateau borders and also to the overall recovery of valuable mineral. It was shown in particular that higher loadings, usually associated with higher froth bursting rates, are indicative of more selectivity in attachment and therefore a higher mineral grade in the concentrate. Additionally, this work suggests that bubble solids loading and froth stability are essential parameters to include in froth flotation models as they allow control and optimisation of the flotation performance.

Jan 1, 2005

New South Wales mining legislation reinforces a systematic approach to safety management. It is now a requirement of all mines in the coal, metalliferous and quarrying sectors in NSW to prepare a Mine Safety Management Plan. The paper briefly outlines work currently being undertaken by the Safety Operations Branch of the NSW Department of Mineral Resources (DMR). The DMR is working proactively with NSW mines in the preparation and implementation of effective Mine Safety Management Plans. There is a growing realisation that a systematic approach to safety management, underpinned by the process of hazard identification, has real potential to improve safety in the workplace. The paper briefly describes the framework used in a current æmines education programÆ and its æduty of careÆ foundation. Particular attention is paid to the role of mining operators in the implementation of Mine Safety Management Plans and their expected behaviour in demonstrating compliance. One challenge is convincing some mining operators that they must adopt new ways of working. Safety Operations officers are often reminded of the need to translate Mine Safety Management Plans into practical safety systems during audits and inspections of mines and through investigations into accidents and incidents. To have a real effect on the mineÆs safety performance, using these systems must be a normal way of going about a dayÆs work for all persons who work at the mine: not a safety manual collecting dust on the mine managerÆs bookshelf. Mine Safety Management Plans are important to mining operators. Not only will positive involvement in the development and use of safety systems ensure they meet their obligations under mining legislation, but it will also help prevent themselves or their workmates being injured or killed.

Jan 1, 2002

The paper deals with the taking of soundings in connection with coal mining operations under part of the Pacific Ocean adjoining John Darling Colliery.INTRODUCTIONIn the early days of mining in the Newcastle District there did not appear to be any definite law specifying the limits to which mine workings, other than certain borings, could extend under tidal waters.As time went on, a figure of 120 ft. was fixed as the minimum thickness of strata between the roof of the seam and the sea bottom; beyond this mining operations are disallowed. The laws relating to working coal under tidal waters are as follow:-The minimum width of pillars to be left shall be eight (8) yards and the maximum width of bords or other excavations shall be six (6) yards, but the lessee may at his discretion increase the minimum width of the pillars or decrease the maximum width of the bordsor other excavations so as to increase the general safety.The eight (8) yard pillars shall be left unwrought.In on-road of every pair of Winning-off or leading headings, a bore shall be kept going ten (10) feet in advance for the purpose of foretelling the presence of any fissure, wash-out, open joint, fault, dyke, or otherwise, and all winning-off headings shall be driven atleast one hundred (100) yards in advance of the working bords.The most accurate and trustworthy information shall be obtained by the lessee not only' of the depth and character of the ocean bed, river, lake, or estuary deposit, but also of the strata overlying the coal seam.When working under the ocean, strata shall be bored through and proved a minimum thickness of thirty (30) feet at the face of the leading headings or levels immediately such headings or levels are under the ocean, and...

Jan 1, 1947

By H Aral, L Malishev

The carbothermic chlorination of titaniferous materials such as rutile, synthetic rutile (SR), upgraded slag and ilmenite in a fluidised bed is an established commercial process. In this work, ilmenite sourced from the Murray Basin area of South Eastern Australia was chlorinated and an assessment of the chlorination characteristics of the ilmenite, in terms of pre-treatment, type of reductant and reaction time was made. Selective chlorination of Murray Basin ilmenite to remove Fe and Mn was achieved in this work. A synthetic rutile sample containing around 93 per cent TiO2, one per cent Fe2O3 and 0.5 per cent MgO was produced at a chlorination temperature of 1000¦C with around 25 per cent loss of Ti as TiCl4. Raising the reductant to ilmenite ratio in the chlorination reactions increased the amount of Ti chlorinated. However, complete chlorination of Murray Basin ilmenite to produce FeCl3 and TiCl4, was not achieved under the conditions used in this work. Pre-oxidation of Murray Basin ilmenite before chlorination had little affect on its reactivity, compared with æas receivedÆ ilmenite. In contrast weathered West Coast ilmenite chlorinated appreciably better than West Coast primary ilmenite, in terms of bed residues remaining and amounts of elements removed. The presence of large amounts of Mg and chrome spinel grains in the Murray Basin ilmenite used in this study are likely to make it difficult to chlorinate directly in a commercial chlorinator. However, this is not to say these ilmenites will be unsuitable for chlorination applications. Further work is needed in the separation of Mg and chrome spinel grains from Murray Basin ilmenites and the products resulting from these tests could then be assessed in terms of chlorination performance, so that further processing options can be explored.

Jan 1, 2000

Existing production facilities are constantly looking at ways to increase capacity. Many recent solutions have focused on the implementation of capital and infrastructure projects. It is accepted that capital expansions are frequently necessary for production gains; however, in many cases existing assets have the potential to deliver substantially better throughput than they are currently achieving. By focusing on automation of production control systems, production reporting and business processes substantial gains can be achieved utilising existing assets. This potential can be realised quickly and has been proven across several sites and industries. In the Pilbara region of Western Australia throughput gains of between two per cent and 25 per cent (translating to millions of tonnes per annum) have been achieved from existing assets using the methodologies discussed. The improvement process involves evaluating the entire production chain from the time the ore arrives at the plant to the time it is dispatched. A technical evaluation of the performance of the control system and plant automation interfaces to upstream and downstream processes is conducted. The relationship of these processes to the business systems and the human interface to the systems is reviewed to ensure a complete picture of the system is understood. Technical evaluation targets include: individual equipment operation, the engineering level of control systems, feed controls, etc; managing recirculating loads, surge capacities, dynamic inventories as well as management of in-feed systems and integration into yard and out-feed systems; and communication flow between control and other systems, data alignment between rail and shipping schedules, yard systems, sales systems and maintenance systems including such fundamentals as truck dispatch links to plant control. In parallel with the technical evaluation, business system evaluation takes place, including analysis of the operational systems, methods and personnel.

Jan 1, 2007

Mispah form (FAO: Lithosol) soil contaminated with >380 000 mg kg-1 creosote was co-composted with sewage sludge and poultry manure for a period of 19 months. The soil was mixed in a ratio of 1:1 (v/v) with wood chips to improve aeration. The soil-wood chips mixture was then mixed in a ratio of four soil-wood chips mixture: one compost material (sewage sludge or poultry manure). Compost heaps were set up in triplicate on wood palettes overlaid with double layers of nylon straw bags. Control experiments, which contained the contaminated soil-wood chips mixture without sewage sludge or poultry manure were set up in triplicate. Moisture, temperature, pH, ash content, C:N ratio of the compost and the creosote concentration of the soil was monitored monthly. The concentration of selected creosote components in the soil was also determined at the end of the incubation period. Temperature was observed to rise to about 60¦C in the poultry manure and about 58¦C in the sewage sludge within two months of incubation, while temperature in the control fluctuated between 15¦C and 35¦C throughout the incubation period. Creosote concentration in the control was reduced by 17 per cent at the end of the incubation period while concentration of creosote in the sewage sludge and poultry manure compost was reduced by about 99 per cent. The percentage rate of creosote reduction in the poultry manure compost was initially lower than observed in the sewage sludge compost. However, the reduction rate became similar towards the end of the treatment period. The concentrations of selected creosote components were reduced by about 100 per cent within the same period. Respiration of compost microorganisms and counts of microbial populations showed that microbial activity correlated with reduction in creosote concentration.

Jan 1, 2004

Basicity(aO2−) has been known to affect the physicochemical properties of molten slags in the metallurgical processes. However, because of the impossibility of direct measurement of single-ion activity, various indirect measures such as capacity, redox equilibrium of transition metal ions, activity of basic oxides, and (theoretical) optical basicity have been proposed; but these basicity measures have been restricted within slag systems and the interaction between measuring elements and slag components has affected the quantitative estimation of slag basicity. Recently, since it was reported that solubility of noble metals in molten slags could be an indirect measure of basicity, the influence of slag basicity on the solubility of platinum and silver has been reported. The reaction mechanism of platinum dissolution into basic slags has been reported, whilst that in acidic slags has not (Nakamura and Sano, 1997; Sano and Nakamura, 1997; Nakamura et al, 1998). Richardson reported that the solubility of metals such as cupper, gold, silver, and lead in the CaO-SiO2-Al2O3 slag was presumably dependent on the atomic radius and the accommodation ability of the silicate network (Richardson, 1974). Swinbourne and You measured silver solubility in the Na2O-SiO2 slag over a wide range of oxygen partial pressure and suggested that silver would be present as both Ago and Ag0.5 in the slags (Swinbourne and You, 1999). For brevity, these previous works discussed the dissolution mechanism of silver into the slags based on the existence of silver as a neutral or molecular species. However, because the almost chemical reactions occurring in the slag are affected by the basicity, the reaction formula with O2- ion is required based on the ionic characteristics of the slag such as desulphurisation and dephosphorisation reactions as given in Equations 1 and 2, respectively.

Jan 1, 2000

High-sulphidation (HS) gold, silver and/or copper deposits are generated in both the epithermal and the upper parts of the underlying porphyry environments over vertical intervals of up to 2 km. The HS deposits are generated in advanced argillic lithocaps, which are products of the absorption of acidic magmatic volatiles by voluminous groundwater systems. Mineralisation styles in HS systems reflect depth of formation as well as the interplay between structural, lithological and hydrothermal parameters. The deep parts of HS systems, at depths of >1000 m, are typified by disseminated copper¦gold mineralisation comprising digenite, chalcocite and covellite in pervasive advanced argillic as well as underlying sericitic alteration. In highly telescoped systems, suchmineralisation may overprint porphyry stocks and associatedquartz-veinlet stockworks. Intermediate levels of HS systems commonlycontain fault-controlled copper-gold mineralisation, typically as enargite in bodies of vuggy residual quartz, silicification and/or massive pyritic sulphide. The shallow parts of HS systems, at depths of The exploration focus is on four principal HS mineralisation styles: 1. copper (eg Chuquicamata, Monywa) or copper-gold (Wafi) in thedeep porphyry-hosted parts of systems preferably, in the case of thelatter, where supergene oxidation is limited and, hence, flotationmay be used for metal recovery,2. copper¦gold-bearing replacement mantos and pipes hosted bycarbonate wallrocks in the deep parts of systems (eg Bisbee),3. high-grade gold in late-stage veins or hydrothermal breccias thatoverprint the intermediate to shallow levels of systems (eg El Indio,Goldfield), and4. large, bulk-mineable gold deposits in the shallow parts of systemsthat were subjected to supergene oxidation, thereby permittingheap-leach treatment (eg Yanacocha, Pierina).To these preferred HS styles may be added the low-sulphidation veinor disseminated gold¦silver mineralisation that is commonplacealongside many HS systems (eg Victoria at Lepanto). * Originally published in the Proceedings of PACRIM æ99,published by The AusIMM.

Jan 1, 2000