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By A Marta

Geomembrane (GMB) liners are being used more frequently for the storage or capping of mine waste due to stricter regulatory requirements relating to environmental protection. The longevity of any liner system will be a function of environmental conditions, design (including materials selection), construction and condition monitoring during operations or closure. Based on experience and case studies, this paper presents a review, from design to handover, of some of the smaller and often overlooked details that can have significant impacts on the performance of the GMB and the project overall.The topics covered will include approaches to selecting and testing GMBs to ensure they are suitable. Design considerations to aid installation and quality assurance during construction. Understanding action leakage rates and the consequences of leakage when it creates whales. Construction quality control and assurance procedures, including a brief discussion on non-destructive liner integrity testing. CITATION:Marta, A, 2018. Geomembranes – from design to handover and some of the lessons learnt, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 190–207 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Noller B. N, McGill R. A

The Alligator Rivers Region has been the scene of one of Australia's most intensive environmental monitoring efforts since the current generation of uranium mining was mooted in the 1970s. Prior to mining, the local environment and the nature of potential impacts were not well known. The initial monitoring programs therefore included large baseline characterisation and research components. After some 15 years, water, soil and sediment monitoring programs have been reduced to a fraction of their early size, as the mining and natural systems became better known and characterised, and the actual nature of the environmental impacts were established. Modem techniques allow much more rapid and thorough identification of chemical species and elements of concern, allowing much more focused monitoring programs to be designed. In the 1980s data collection was emphasised at the expense of interpretation, and monitoring programs were maintained at much higher levels than were in fact required. It is now clear that investigations are important and should be distinguished from monitoring programs, and that the timely interpretation of investigations and implementation of recommendations can greatly reduce the effort and expense that can be involved in a monitoring program. Monitoring programs based on a sound understanding of potential environmental impact may then be efficient and cost-effective, yet provide sufficient information to assess the environmental impact of mining, guide further environmental protection measures when problems are detected, and demonstrate compliance with regulatory requirements.

Jan 1, 1994

By H Han, d S. Hapugoda, L Lu

With the recent rapid development of Chinese steel industry, the world iron ore resources of good quality are depleting rapidly. As a result, iron ore deposits of lower quality have been or are being developed to meet the market demand and are becoming increasingly important to iron and steel companies. As concentrates have advantages of high Fe grade and less harmful impurities, they are ideal sweeteners to maintain sinter grade and quality when high proportions of low-grade ores are used in the sinter blends. However, due to their fine nature, addition of concentrates will inevitably increase the proportion of adhering fines and reduced the proportion of nucleus particles of the sinter blends, which can adversely affect the green bed permeability and sintering productivity. In the present study, lab scale sintering tests were carried out under the conditions similar to the sintering process to examine the effect of concentrates on the high temperature sintering characteristics of sinter blends and the structure and strength of the resultant sinter analogues.

Sep 18, 2023

By M Pernechele, U König

Most of the operating steelmaking capacity currently relies on conventional, coal-based steelmaking processes. Currently, direct reduced iron (DRI) is only produced in regions where energy is available at low cost. To align with net-zero emissions goals, steelmaking capacity must transition to loweremissions steelmaking technology. Direct reduction of iron ore will get one of the preferred methods in the future due to its high technology readiness. New reduction technologies include hydrogenbased direct reduction processes. To ensure optimal efficiency during DRI production and to cope with newly developed technologies, processes need to be monitored more frequently and accurate. Traditionally quality control of raw materials and DRI has relied on time consuming physical testing, wet chemistry or the analysis of the elemental composition. The mineralogy of DRI that defines its properties is not frequently monitored. Process monitoring and quality control of DRI is possible by using modern X-ray diffraction (XRD) methods. In addition to the metallic iron content (Femet), metallisation (Metn) and the total carbon content (Ctot), XRD analysis also identifies the overall mineralogical phase composition. This allows additional information about the reduction process and enables fast counteractions on changing raw material mixtures. The benefits of the quantitative determination of the phase composition and the calculation of process critical parameters to produce DRI will be demonstrated with a case study

Sep 18, 2023

By R Schiller, E Chait

"Quebrada Blanca is a porphyry copper deposit located in the Eocene-Oligocene belt of Chilean Andes. Operation started in 1994 and original reserves for supergene mineralisation gave a life-of-mine (LOM) of 20 years; however, further exploration extended the LOM until 2020.In order to optimise the remaining five years of supergene resource, geometallurgical variables were added to the geological model including copper recovery and acid consumption. LOM plan encompasses finishing the phase number eight and the future development of phases 11 and 13.LOM lithologies include diorites, quartz monzonites, porphyries, igneous and tourmaline breccias. Main alterations are: potassic, phyllic and argillic. Litho-alterations or geometallurgical units were formed by combining five types of rocks with three types of alteration. According to statistical information, the deposit can be represented with 12 litho-alteration units, which cover 98 per cent of the LOM volume.For copper recovery information, there were 40 mini-columns tests made in order to obtain kinetics curves and copper recovery values after comparing the difference between head and tails grades. Acid consumption was obtained using an automatic neutraliser device-based test.Historical data said that copper recovery in pads after 450 days of irrigation is around 75 per cent of recoverable copper while acid consumption is around 5.5 kg/t.According to this study, lower recoveries are related with potassic-altered diorites and argillic-altered quartz monzonites with values around 60 per cent. On the other hand, best recoveries could be found in potassic-altered quartz monzonites and argillic-altered diorites with values closer to 80 per cent.It was also revealed that the most reactive rock is the potassic-altered diorite with 12 kg/t of acid consumption. This rock covers approximately 40 per cent from phases 11 and 13.The final geomet model was calculated using a program that relates each geometallurgical unit with a specific copper recovery and acid consumption value. Results found after comparing model-obtained information with historical leached pads data were used to validate the model.CITATION:Chait, E and Schiller, R, 2016. Adding Copper Recovery and Acid Consumption Variables to the Geological Model of Quebrada Blanca, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 257–266 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By J Wen, P Hou, W Yu, M Hu, Z Jiang, C Bai

Vanadium titano-magnetite (VTM) is one of the important iron ore resources in the world. High viscosity and low fluidity are the basic characteristics of hot metal containing vanadium and titanium during the ironmaking process. Clarifying the influencing mechanism of the melt viscosity would be a significant issue for the high efficiency smelting of VTM. In this paper, a self-developed melt viscometer based on the principle of torsional vibration theory was employed to measure the viscosity of hot metal accurately. Simultaneously, the thermodynamic calculations and some modern detection methods were also used to investigate the precipitation behaviour of high-melting-point phases in hot metal containing vanadium and titanium. The measuring results show that the viscosity of molten iron gradually increases with the increase of titanium content when the mass fraction of titanium is between 0.09 wt per cent – 0.50 wt per cent. Meanwhile, the viscosity of the hot metal was affected significantly by the vanadium content. When the vanadium mass fraction was higher than 0.30 wt per cent, the viscosity of hot metal increased sharply, which will have a serious impact on the fluidity of the hot metal. Furthermore, it was revealed by thermodynamic calculations that an increase in titanium and vanadium content would result in the precipitation of high melting point phases such as TiC, TiN, VC, and VN in the molten iron, ultimately resulting in a decrease in its fluidity. Meanwhile, it was confirmed by Scanning Electron Microscope (SEM) observation that the precipitates in the hot metal were compounds consisting of V, Ti, C, and N elements, which agrees well with the thermodynamic analysis results.

Aug 21, 2024

By J. K. A. McLEOD

Address by the President of the Institute (Mr J K A McLeod) in presenting the Institute Medal to Howard Knox Warner, C.B.E. Address by Howard Knox Warner after accepting the award.

Jan 1, 1978

By N N. Viswanathan, D Kumar, S Kumar

In secondary steelmaking, calcium treatment is practised to modify the solid alumina or spinel inclusions into liquid or partially liquid calcium aluminates. It has been seen that the dissolved calcium reacts with sulfur or oxygen present in the steel to form CaS or CaO type of transient inclusions. Post-calcium treatment these transient inclusions further react with pre-existing alumina or spinel inclusions and modify them. In addition, direct modification of pre-existing inclusions is also reported in the literature. In the present study, laboratory-scale induction furnace-based experiments are carried out to melt electrolytic iron in an alumina crucible followed by deoxidation with aluminium. The CaS-based composite material, prepared in-house, is added after the aluminium deoxidation to study the stability of CaS at the steelmaking temperature. Multiple steel samples were also taken to track the dissociation of CaS by means of sulfur pick-up in steel. Additionally, inclusion analysis of these steel samples was also performed to track changes in the chemical composition of inclusions in response to CaS addition. It has been seen that the CaS dissociates leading to a gradual pick-up of sulfur in steel. The scanning electron microscope – energy dispersive X-ray spectroscopy (SEM-EDS) analysis reveals that the alumina crucible and floated alumina inclusions are modified into calcium aluminates and the extent of modification depends on the contact time of CaS with the two sources of alumina mentioned earlier. However, the modification of alumina inclusions in the bulk steel did not occur during these experiments.

Jun 19, 2024

By R Atmuri, W Liang, R Prasad, Y Liu, E Wingate

Yellow phosphorus (YP) has been commercially produced since the 1920s. First in the USA by the Tennessee Valley Authority (TVA), next in Russian (Kazakhstan) in the 1950s, and finally in China in the late 1970s and early 1980s. There are operations in Vietnam and Sarawak on a smaller scale. YP has become very in vogue due to its use in the production of lithium iron phosphate battery cathode precursor materials by the Chinese and other western battery manufacturers. The YP is also used to produce purified phosphoric acid and higher grades of acid using a thermal oxidation process after smelting. This paper will look at the basics of the smelting including slag chemistry, alloy chemistry and offgas chemistry. The paper will look at the design of the furnaces used in the YP production process as well as the downstream recovery of phosphorus from the smelter off-gas stream to YP. The next part of the discussion will focus on the operations of a YP smelter with regards to control of the furnace to optimise phosphorus recovery to YP. Will discuss tapping cycles for alloy and slag with a view to optimal phosphorus recovery. The discussion will close out with a review of operational challenges in the smelter and a brief description of the downstream conversion of YP to high purity phosphoric acid.

Aug 21, 2024

The Estonia Mine, operated by Eesti Energia Kaevandused AS (EEK), the mining division of the Estonian Government's energy company, Eesti Energia AS, is a large room and pillar mine located in Eastern Estonia. It supplied approximately 4.9 Mt/a of oil shale in financial year ending 2010, which is used for electricity and shale oil generation. Due to the Estonian climate and the power station's need for a dry product, Estonia Mine has developed a planning system where short-term demands of the power stations dictate the schedule. Such an arrangement requires maximising flexibility and consequently the mine only operated for 199 days in 2010.The footprint plays a key role in achieving mass mining rates as the 12 km + 12 km lease area allows the mine to split into mining districts that act independently of each other and maximise the number of work areas available. Coupled with this, the geology of the mine is relatively homogenous over the mining lease, simplifying the mine design and production methods.During the last five years, EEK has commissioned a comprehensive conveyor network. Consequently, material handling only requires loaders to dump oil shale direct from the production face onto a chain conveyor that feeds the conveyor network that ultimately supplies the enrichment plant. Dewatering is also of critical importance, with 90 Mm3 of water discharged annually. EEK uses large trenches up to 3.5 m deep and 1.2 m wide to channel groundwater. Track mounted mechanical saws are used to cut slots in the floor, to control overbreak in blasting these trenches.EEK has introduced Salzgitter Machinenbau GB 280S auger drills that drill three 280 mm diameter holes simultaneously. This has improved void hole drilling times and reduced the drilling required for each face, reducing the overall production cycle time. Blasting activities have also been decoupled from other mining activities negating the need for firing times through the use of small independent firings, required to control vibrations.

Dec 6, 2010

By R Cooksey

The Globe-Progress Mine is an open pit gold mine that is part of the larger Reefton Goldfields deposit located on the West Coast of New Zealand. The regional geology comprises a series of north to south oriented fold structures that have undergone post-deformation mineralisation. The structural geology within the mine itself is more complex, with major shears hosting numerous high-grade mineralised quartz shoots and splays that have been historically mined.The selective mining of ore within the pit is challenging due to the orientations of the hanging wall and footwall areas of the main Globe shear zone, the lithologies of these areas which range from highly brecciated and sheared material to competent mineralised host rock, and in the hazards presented by the numerous old historic underground workings. The coordination of drilling, modelling and excavation of the ore requires careful planning to maximise recovery whilst operating with the pit design boundaries.Grade control packages are custom designed to reflect the orientation of the footwall and hanging wall mineralisation. The shear material in the footwall zone dips between 60° and 70° and requires angled drilling whereas the footwall mineralisation is contained in shallow dipping quartz veins sub parallel to bedding and can be vertically drilled to best intercept the mineralisation. Ore excavation is directed so that the contact between the footwall and hanging wall is mined in the correct direction so that any non-visual ore contacts can be safely mined and that the ore-waste dilution is reduced.The ongoing grade control and selective mining of the Globe Progress deposit continues to deliver high grade ore for processing by ensuring that waste and dilution of ore is reduced and that recovery is maximised.

Aug 22, 2011

By V Gumba, S Narendranathan, C Barker, R D. H Thomas, G P. Bungard

This paper presents the positive outcomes on an EPCM project, which was undertaken in a challenging environment, whereby the design team had to generate a design with a number of stringent serviceability criteria, any deviation from which would have had significant implications to the proposed design performance. The success of the design implementation within the tight time frame hinged upon the precise installation by a skilled contractor. The overall objective was achieved as a result of close collaboration between the designer and contractor ensuring all stringent quality assurance/quality control (QA/QC) aspects were met and opportunities to optimise design without compromising on performance were identified and implemented, resulting in a cost saving of over A$13 M.CITATION:Narendranathan, S, Thomas, R D H, Bungard, G P, Gumba, V and Barker, C, 2012. The importance of collaboration between designers and contractors in implementing a design in challenging conditions, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 97-102 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By Lawson E, Purkiss S. A R, Van Ashwegen p C

It is only in the past decade or so that industrial exploitation of biological resources and techniques has become regarded as a distinct discipline. Commonly referred to as Biotechnology, it embraces biochemistry, microbiology and the engineering sciences and is mainly aimed at the biological conversion of suitable raw materials into desired end products. The catalytic agents are more often than not bacteria although other micro-organisms such as fungi are used. The range of micro-organisms used is wide and the choice depends upon the desired end product, which in turn depends upon the metabolic attributes, genetically engineered or otherwise, of the cells. The metabolic diversity of micro-organisms has been applied to processes such as antibiotic production, food processing, brewing and chemical production, and of course extraction of metals from ores. Metabolic diversity is, to a certain extent, based on nutrition, which, in its simplest form, can be divided into energy source, carbon requirements and nature of the electron donor producing reducing power to the cells. The source of energy may be light, in which case the organisms are phototrophic (eg green plants, algae). The carbon requirements and reducing power may come from organic sources. These organisms are then called heterotrophic (eg man and most bacteria, including the well known Escherichia colt). However, there is a group of bacteria whose energy metabolism depends upon chemical redox reactions, use inorganic carbon (CO2) and obtain their reducing power from reduced chemicals such as metal sulphides. These are known as chemolithotrophs. They play an important role in mineral recycling in nature and are also ideal for extraction of metals from ores. This is because they are extremeophiles being acidophilic (grow at very low pH) and sometimes also thermophilic (grow at very high temperatures). These bacteria operate in such hostile environments that competition, or contamination, by other organisms does not occur. Extraction of metals from ores by chemolithotrophic bacteria is commonly referred to as biohydrometallurgy. Other related areas are bioadsorption of metals from dilute solution,- microbial treatment of metal contaminated wastes and removal of toxic chemicals produced or used during mineral processing. This paper basically reviews the work that Gencor has undertaken in the field of biohydrometallurgy and the advancements it has made in commercialising the technology, but also touches on certain long-term areas of research that are currently under investigation.

Jan 1, 1995

By Bigu J, Grenier M. G, Knight G

Particulate control is a major concern in underground mining and the subject of continuing research world wide. In Canada the federal government's Mining Research Laboratory at EIIiot Lake, Ontario, has been using two aerosol counters to aid its investigations. Specific studies with the units include: a) evaluating total and elemental size efficiencies of dust filtration units: b) characterizing the dust particulate cloud from different mining operations: and c) determining dust transportation characteristics.

Jan 1, 1988

By B Hou

The Eucla Basin in southern Australia is emerging as an important global source of zircon from heavy mineral sands. Understanding the geological evolution of the basin and movement of heavy minerals down peripheral paleovalleys and along paleocoastlines is essential to effectively refine exploration strategies for heavy minerals in the basin. Integration of geoscientific datasets in a Geographic Information System (GIS) environment has proved to be effective in reconstructing depositional environments along the Cenozoic basin margin and in tracing the buried paleorivers that once drained broad areas of the Archean-Paleoproterozoic Yilgarn and Gawler cratons, the dominantly Mesoproterozoic Musgrave and Albany-Fraser Provinces, and the Neoproterozoic-Early Paleozoic Officer Basin. Sea level highstands during the late Middle Eocene (39 - 36 Ma) are associated with formation of the Ooldea coastal barrier complex and the zircon-rich heavy mineral deposits at Jacinth, Ambrosia and Tripitaka. More extensive transgression during the Late Eocene (36 - 34 Ma) built the complex Barton shorelines that host the Cyclone deposit and the extensive ilmenite-dominated occurrences of the Barton West prospect. Multi-generation reworking of the source sands is indicated by the high proportion of deposits that are zircon-rich relative to titanium minerals. The age distribution of zircon grains in heavy mineral concentrates from the Ooldea and Barton barrier systems points to the Musgrave Province as the predominant ultimate zircon source. Paleorivers discharging along the northern basin margin presumably carried a sediment load that was then redistributed by easterly longshore drift to build the extensive coastal sand deposits along the northern and eastern basin margin. The south-eastern extension of these deposits was reworked during Miocene-Pliocene (15 - 2 Ma) times into a series of regressive strandlines that show angular discordance with the Eocene coastlines. This discordance is consistent with evidence for long-wavelength tilting of the Australian continent from Middle Miocene times, as the continent drifted toward a dynamic topographic low induced by convective mantle processes associated with the South East Asia subduction systems. The Dromedary and Gulliver’s deposits probably formed at this time. Ongoing research is focused on the geological features of the basin that influence heavy mineral transport, concentration and preservation, and the processes leading to deposits with high zircon content.

Oct 5, 2011

By M I. Pownceby, S Hapugoda, H Han, V Nunna, L Lu

Charcoal produced from Syzygium Zeylanicum (local name: Yakada Maran = iron killer) trees were widely used in ancient Sri Lankan iron smelting practices. In this study, relict charcoal from Syzygium Zeylanicum tree trunks, branches and leaves were analysed for the first time. Unusually high concentrations of calcium oxalate (CaC2O4.H2O – CaOX) crystals were identified preserved in plant cell structures by optical mineralogy and SEM analysis. Thermogravimetric Analysis (TGA) of CaOX showed that it displayed three decomposition stages, releasing H2O at 177°C, CO at 493°C and CO2 at 750°C. Following the identification of CaOX in Sri Lankan charcoal, a series of reduction tests on a low-grade, high-P iron ore fine sample (high SiO2: 5 wt. per cent; Al2O3 4 wt. per cent; P: 0.135 wt. per cent) doped with CaOX were carried out at various temperatures. Samples were analysed by XRF, SEM and EPMA to determine the degree of reduction and the effect of reduction on the deportment of impurities, in particular P. Reduction tests at 800°C and 900°C with 5 wt. per cent CaOX showed that the reducibility increased to over 65 per cent. At temperatures above 900°C, P was located mainly within a fine, interstitial glass matrix suggesting that the CaOX flux enhanced removal of P from iron-rich pre-cursor phases to form glass. Preliminary magnetic separation tests to remove the P-rich interstitial glass were unsuccessful due to the fine grain size. Further complete reduction tests at temperatures above 1200°C with addition of coke to convert the iron oxides into Fem were conducted with samples doped with 10 wt. per cent CaOX, 10 wt. per cent CaCO3 and equivalent undoped samples. Results confirmed the preferential P-incorporation into a glassy matrix in the CaOX samples although some rare P incorporation into the metallic phase was noted. Experimental results, including comparisons with the CaCO3 fluxed and undoped samples, are discussed in view of the potential for CaOX flux for removing P (and potentially other impurities) from P-rich iron ores.

Nov 8, 2021

By Y Öztas, S McKinley, T Baker

The Kisladag Mine, Turkey, is a large porphyry gold deposit which is mined by open pit methods. In operation for over ten years, Kisladag provides an excellent example of how attention to a geologic feature, namely hydrothermal alteration, became a very effective predictive geological tool for planning and operation. The alteration domains were initially used as a geological tool to assist with establishment of resource model domains and to guide delineation drilling, but they were soon recognised to be correlative to geotechnical characteristics (affecting pit slope angles) and metallurgical performance (heap leach recoveries). Recent developments in spectral processing allow the systematic quantification of complex overlapping alteration phases and have greatly improved the ability to rapidly define internally consistent alteration domains for geotechnical and geometallurgical purposes.Alteration at Kisladag comprises a central core potassic (K-feldspar-biotite) zone, a tourmaline-white mica enveloping zone, an advanced argillic lithocap on the deposit’s eastern side and an overprinting pervasive argillic zone. These alteration zones and their distribution were based initially on strictly qualitative, visual mineralogical logging of diamond drill core. With the need for more accurate and consistent identification of the alteration mineral suites, particularly the phyllosilicate phases, logging was augmented by systematic measurement of spectral data using a Terraspec instrument.Recently the Kisladag spectral database (over 85 000 readings) was reprocessed by the newly developed methodology (aiSIRIS™) that allows relative quantification of the spectrally-responsive minerals. Visualising this transformed spectral mineralogy at various mineral concentration thresholds using implicit modelling software (Leapfrog®) led to the creation of consistent mineralogical and alteration domains that are used for the definition of geotechnical and geometallurgical parameters. An implicit modelling workflow enables these domains to be easily updated as new data is collected while maintaining geological integrity of the model.CITATION:McKinley, S, Baker, T and Öztas, Y, 2017. Alteration at Kisladag gold mine, Turkey – a progressive study in geology, geotechnics and geometallurgy, in Proceedings Tenth International Mining Geology Conference 2017, pp 51–62 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By D J. Williams

Tailings management is typically constrained by many factors that are taken as given. These include the tailings production rate that must be accommodated, the desire to deliver the tailings cheaply and easily as a slurry using centrifugal pumps, and a tailings footprint limited by the desire to minimise capital costs leading to a rapid tailings rate of rise and a low settled density. Other constraints include wall raises being delayed due to limited capital, inadequate tailings water and rainfall run-off management, and the net present value (NPV) approach to capital expenditure that puts off expenditure at the expense of performance. All of these constraints result in the tailings occupying much more volume than is necessary, being difficult to rehabilitate, and not being capable of supporting a beneficial post-mining land use or function. Ultimately, such constrained tailings storage facilities will assume very large dimensions, but each will typically be developed as a series of smaller storages that are filled rapidly and added to progressively. The optimal stage to efficiently recover process water is in the process plant, but this is limited by the desire to use centrifugal pumps rather than the more costly positive displacement pumps, which also require greater management of tailings deposition. Process water can also be recovered from the tailings storage facility (TSF) decant. Tailings water that is not recovered from the plant or the decant will be lost to entrainment within the tailings, seepage to the foundation or through the wall, or evaporation. However, tailings water is not always suitable for reuse in the plant, particularly when it becomes contaminated by the processing, and it may simply be stored on the TSF. This will exacerbate the seepage of contaminated water to the environment, and will limit the densification of the tailings that would otherwise occur due to desiccation of the tailings on exposure. If a larger tailings footprint were developed early, cycling of tailings deposition in thin lifts between a number of cells could occur, maintaining the dormant cells dry to enhance desiccation and densification, and ultimate rehabilitation. The end result would be a much reduced stored volume of tailings, the potential for upstream raising, and ease of rehabilitation to a high level. The higher initial capital cost would be overtaken by reduced ongoing capital, operating and closure costs.CITATION:Williams, D J, ?2014. An alternative whole-of-life approach to tailings management, in Proceedings Life-of-Mine 2014 , pp 285–298 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By N Voller, A Ishmurzin, G Hackl, M Wu, A Kharicha, M Chintinne, C M. G Rodrigues, A Ludwig

Slag fuming (SF) is a critical process for recycling zinc-containing slags, but the corrosive nature of molten slag poses challenges to the reactor durability. The freeze-lining (FL) technique offers a solution by forming a protective layer on the reactor wall. It requires intensive cooling using watercooled jackets, which can stabilise the FL while compromising the energy efficiency of the process. This study presents a computational fluid dynamic (CFD)-based model to optimise the SF process by considering FL formation and its impact on heat transfer and reactor wall temperature. A volumeof- fluid (VOF) model is coupled with a mixture continuum (MC) solidification model to capture the intricate multiphase flow dynamics within the SF furnace. Two FL types are considered: FL solidifying on the reactor wall in the slag bath region; and FL solidifying on the reactor wall in the freeboard region. The FL of the first type forms when the slag temperature drops below liquidus temperature. The FL of the second type only forms when a splash-induced slag droplet collides with the freeboard wall and solidifies. A series of splashing events are necessary to coat the freeboard wall. The simulation was run until a global energy balance was reached. This means that the heat losses from the water-cooled jacket, bottom wall, outlet and fuming balance the heat gains from the hot gas injected through the submerged plasma torches. The increase in FL thickness, due to its low thermal conductivity, reduces the heat losses through the reactor walls. The calculated FL thickness and heat fluxes were in good agreement with industrial data, validating the model’s credibility. The simulation results provided valuable insights into the fuming process, including slag bath temperature evolution, slag splashing dynamics, FL formation patterns, local heat fluxes through the reactor wall and overall energy balance. These findings can inform process optimisation strategies to enhance the energy efficiency and sustainability of SF operations. The authors have built a prior version of the model framework and applied it to simulate FL formation in an electric smelting furnace (ESF). The results from both the ESF and the current SF highlight the applicability of such model framework to a range of industrial processes involving FL formation. This model framework can ultimately contribute to more energy-efficient and sustainable industrial operations.

Aug 21, 2024

The history of the discovery and development of the Kambalda nickel orebody. is reviewed and the decision to process the Kambalda concentrates by the Sherritt-Gordon process at Kwinana is discussed. The Kwinana Nickel Refinery is described and the problems encountered in the first year of operation are Outlined.

Jan 1, 1971