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ABSTRACTFor the binary system copper-lead two relationsEquation 1andEquation 2have been derived for the activities of copper and lead at compositions and absolute temperatures within the liquid region of the phase diagram.These relations give, with greater accuracy than is given by previously published relations, the activity-composition temperature variations for all regions of the phase diagram of interest to metallurgists.These relations are essentially simple forms of the Margules equations but with linear temperature dependence applied to their coefficients. This has been done in such a manner that a phase diagram obtained from these relations agrees well with the data available for this system. The methods of obtaining the relations and constructing a phase diagram from them are both given in detail. The enthalpies and entropies of mixing are compared with those derived by other methods.

Jan 1, 1971

By A Purchase, C Stacey

The procedure for operation of deluge systems installed in road tunnels is still a subject of debate. The work undertaken in this paper assists in the understanding of the effects of deluge in road tunnels, and thus aims to help inform the development of operational policy. Analysis was undertaken using computational fluid dynamics (CFD) simulations to help explore the deluge interaction with the tunnel ventilation (including smoke exhaust) and combustion products. It was found, for the scenarios considered, that: Deluge activation can decrease the required critical velocity for smoke backlayering, and this in turn can improve the effectiveness of a smoke exhaust system.The dominant parameter for deluge effectiveness is the vehicle configuration, with shielded scenarios (such as a fire in the passenger compartment) showing almost no water reaching the fire. The water delivery rate (5 mm/min versus 10 mm/min) has only a minor effect on the smoke duct damper inlet temperatures and downstream smoke temperatures for small fires (5 MW). For large fires (50 MW) the higher water delivery rate gives slightly improved performance (lower damper inlet temperatures and lower downstream smoke temperatures). A one-dimensional transient tunnel model incorporating different operational and deluge response policies (ie deluge activation times) was developed. It was used to examine the influence of different operational parameters on life safety risk and tunnel damage risk. It was found, for the scenarios considered, that: The life safety risk for different scenarios has a sensitivity to deluge activation policy with the case of delaying the deluge activation for a long time giving the worst outcomes. However, the most critical parameters for life safety risk are operator response time (for all response activities, not just deluge) and the type of fire (configuration, size and growth rate).There is a reduction in risk of tunnel damage when the deluge is activated earlier, although the fire configuration (ie whether or not the seat of the fire can be reached) has the greatest influence on the outcome. It is concluded that the deluge activation policy should be case-dependent. It will depend on the tunnel, the safety systems provided, and most particularly the vehicles involved. The current policy in Australian tunnels is for manual activation of the deluge by the tunnel operator as soon as practical after the fire is confirmed (see also PIARC, 2007). This is a good policy. However, future work may be helpful to improve the skills of operators to make the best judgement as to when deluge should be activated, balancing all risks. This work could include research to further the understanding of deluge and fire in road tunnels, training programs and consideration of historical fire events.

Jan 1, 2008

Upon cessation of mining activity open-cast mine pits typically fill with water, forming a æpit-lakeÆ. The water in these lakes, in some instances, contains high concentrations of ædeleteriousÆ material. Containment and/or dilution typically requires an understanding of how stratification in the pit-lake will develop over a long timescale (say 100 years). Vastly different transport rates can develop due to differing hydrogeochemistry, basin morphology and climate. Numerical (computer) modelling is the most likely approach for successful prediction over long times. While lake modelling tools are available, useful numerical modelling requires improved understanding of transport in such systems because they are different to natural lakes in a number of ways. Notwithstanding the effort required to improve our understanding, the modelling provide a means of testing approaches to active management of pit-lakes.

Jan 1, 2002

By Felice J. J

The assessment of the face velocity of blasts is important in the analysis and subsequent improvement of blast performance. POWERWAVE RADAR is a new tool which will make the collection of this data easier for blast researchers. The data collection technique ensures that a large amount of face velocity data is collected from a blast, and describes the velocity characteristics of the face at a new level of detail. This results in a greater understanding of the effect of drilling and blasting parameters on blast performance. Several case studies are presented which illustrate the collection technique, the type of data generated and how the data is used.

Jan 1, 1992

By Torrance AC

A joint research programme conducted by BHP Central Research Laboratories and Du Pont Wesfarmers Pty Ltd examined the effect of the size of cast primers on the run up and steady state detonation veloci- ties of ammonium nitrate based explosives as a function of blasthole diameter. Both continuous and point to point velocity of detonation meas- urement techniques were used. The field trials examined a number of the Du Pont HDP series of primers in conjunction with ANFO, emulsion and watergel explosives. Results indicate that the run up velocity of 187mm diameter ANFO charges is negligible using cast primers as small as 150g. owever, emulsion and watergel explosives did exhibit run up in both 187 and 311mm diameter blastholes, independent of the size of primer. This could last from 7 to 10 blasthole diameters.

Jan 1, 1988

Synthetic hollow microspheres have demonstrated reliable sensitization and detonation characteristics in industrial explosives for almost two decades. During that time, water gel formulations and use conditions have changed. The introduction of emulsion explosives has also dictated technical improvements in microsphere sensitizers. In contrast to microspheres, gassing or other sensitizing techniques often cannot satisfy the manufacturing and blasting characteristics required of today's explosives. This paper discusses the sensitizing properties of microspheres, formulating guidelines and quality considerations. Packaging, sampling, transfer, metering, mixing and pumping information is also provided.

Jan 1, 1990

By Bastias J

The Ranger uranium mine has operated in the Kakadu region of the Northern Territory since 1979. The mine's water management system was designed to cater for the wet-dry monsoonal climate and to satisfy the recommendations of the Ranger Uranium Environmental Inquiry - Second Report, 1977 (The Fox Report) with respect to environment protection. The Fox Report advised that the aquatic ecosystem of the region must be protected and that the mine should collect all runoff from disturbed areas. Furthermore, the mine was to operate as a no-release system until release standards, based on the experience of several years of operation and on the results obtained from monitoring and scientific investigations, could be established. Monitoring and research data have now been collected for a decade. it is evident that lower-than-expected concentrations of chemical constituents are present in the runoff waters which are retained on site. Standards have been established for the release of these waters to the streams when in flood during the wet season. Mine water quality data and release standards are presented. It can be confidently concluded that controlled release will not cause detriment to the aquatic ecosystems of the Kakadu region. The Ranger operation has demonstrated that environmentally responsible management of mine waters is feasible for future mining ventures in the Kakadu region.

Jan 1, 1988

By Kavanagh M. E, Henley R. W

The Meekatharra mining district lies in the northern pan of the Murchison Province of the Archaean Ynlgam block of Western Australia. Since dis- covery of the Paddy's Flat belt in the district in 1897 total gold production has been 67 tonnes and a further 33 tonnes in resources have been defined by drilling. The Paddy's Flat gold deposits occur within the Gabanintha Formation, a basal formation of the Murchison greenstone sequence containing komatiitic basalts, ultramafics and minor banded iron formations. The regional control on the distribution of deposits is an anastomosing shear belt which extends over 350 km and incorporates the Mt Magnet, Reedys and Meekatharra deposits. The following gold deposit styles may be recognized based on lithological association and alteration: Albite porphyry hosted, Carbonate-fuchsite- quartz alteration hosted deposits, Banded Iron Formation hosted sulphide replacement gold deposits and quartz vein deposits. With the exception of the banded iron formation hosted deposits, the Paddy's Flat alteration zone shows strong similarities to the alteration styles at Kerr-Addison (Ontario).

Jan 1, 1991

The overwhelming weight of scientific opinion indicates that human activity is having a discernible and negative influence on the earthÆs climate system. The Australian Government, together with about 100 other nations, has accepted the findings of the Intergovernmental Panel on Climate Change third assessment report, released in 2001. This report was prepared by several hundred eminent scientists from all over the world, from various scientific disciplines and with differing opinions on global warming. The IPCC third assessment report contains a series of relevant, significant conclusions; for example, it finds that there is an increasing body of observations that gives a collective picture of a warming world and other changes in the climate system. Global average surface temperature increased over the past 100 years by about 0.6¦C. This may not seem much, but in the 900 years beforehand, the EarthÆs temperature remained relatively stable. The 20th century was the warmest of the past 1000 years in the northern hemisphere (there is much better information available from the northern hemisphere than the southern hemisphere). The 1990s were the warmest decade of the millennium in the northern hemisphere and 1998 was the warmest year. Although many factors influenced the EarthÆs climate, scientists are confident that greenhouse gas increases were the main factor contributing to global warming in the last 50 years of the 20th century. Increases in carbon dioxide, methane, troposhperic (lower atmosphere) ozone, halocarbons and nitrous oxide have all contributed to global warming. Combating climate change cannot be done without the cooperation of industry and the community at large. It is important that Government and industry work together to achieve greenhouse gas abatement while ensuring continued economic growth. The cause of the problem û the generation of greenhouse gas emissions û lies at the heart of the structure and size of modern economic activity. Greenhouse gas emissions are embedded in our way of life from our energy consumption patterns to the basic production of food. Moreover, the costs of the impacts of climate change to the earth will be potentially revolutionary, not merely evolutionary. It is in this light, acknowledging both the seriousness and nature of the problem before us that I want to reflect on the key drivers in the international climate change negotiations. A consideration of the past, present and future from what I see as the mid-way point in the process. In 1997, Parties agreed to adopt the Kyoto Protocol, which sets out mandatory targets for greenhouse gas emissions for developed countries.

Jan 1, 2002

By I M. Platten, Y Xie

Complex gold deposits are generally characterised by variable geometries, strong structural controls on grade distribution and a high-nugget effect. The use of diamond drilling and fire assays in this environment often results in an understatement of grade. Bulk samples are likely to be the closest estimators of true grade, and may be required to evaluate geological/grade risk during resource estimation/feasibility studies. Any bulk sampling program requires appropriate planning and implementation. The planning stage should attempt to delimit the extent and nature of mineralisation; characterise mineralogy and metallurgical properties of the ore; and define bulk sample size and how it will be sampled/processed. The approach to sample processing will be governed by the results of metallurgical testing and geological knowledge. Careful design of sampling protocols must be undertaken through material characterisation, understanding of gold particle sizing and the application of GyÆs Sampling Theory.

Jan 1, 2008

By Bell LC

Overburden removal, mining and reclamation are now accepted as the basic operational steps involved in the winning of coal by open cut methods. To attain the lowest operational cost, the recontouring and revegetation of spoilpiles must be planned concurrently with the planning of overburden removal and mining. The earthworks associated with reclamation work on spoilpiles often account for 75 - 90 per cent of total reclamation costs. Experience at Callide Mine has shown that the way that spoilpiles are contoured does influence water retention and can reduce erosion from rainfall run-off. However, provided the recontoured slopes meet'Mines Department specifications, the quality of reclamation work is judged not by the quality of the earthworks but by the plant regrowth on the reshaped surface. Thus it is the quality of the revegetation which is of prime importance. For vegetation to be successful, time must be spent on planned research into methods of overcoming plant nutrient deficiencies and selection of suitable grass and tree species. The research programme undertaken at Callide Mine consists of three stages :- laboratory studies glasshouse trials field trials

Jan 1, 1978

This paper contains an account of some creep tests on electrolytic lead and some of its alloys. The stresses used in determining creep were 500, 350, and 200 lb. per sq.' in. The alloys contained silver, bismuth, tellurium, antimony and zinc respectively. All were castin vacuo, and tested "as rolled." Tests were done also on electrolytic lead which had been cast in air.The electrolytic lead contained 0.0005% total impurities.The preparation and vacuum casting of this lead have been described in a previous paper in this series. The preparation of the alloys, and the air casting of the electrolytic lead, are described in the next section.EXPERIMENTAL PROCEDURE.Every effort was made to keep the vacuum-cast specimens from contact with the atmosphere throughout their history.The ingots were stored eIther in a vacuum desiccator or immersed in heavy oil. The creep specimens were coated with vaseline except during rolling, etching and photography, which involved exposure to the atmosphere for about 45 minutes all told.It is not claimed that vaseline is a perfect shield against the intrusion of atmospheric gases. Possibly during the months that some tests were in progress the gases diffused through the vaseline and gained a limited access to the lead.Nevertheless, the use of vaseline gave protection that brought the tests nearer the ideal at which the author aimed, *Research Fellow, Dept. of Metallurgy, University of Melbourne.

Jan 1, 1936

Much of the coal and gold mining industry of New Zealand is small scale. Funding is tight and mechanisation limited. The country has many well documented small coalfields (some with significant outcropping) and alluvial gold deposits. These are generally remote, difficult to access (physically and otherwise) and of submarginal value (largely a consequence of size when viewed for extraction by traditional techniques). The industry is also burdened by environmental and bureaucratic constraints. The above over simplified setting suggests to the Author, a newcomer to New Zealand, the opportunity to consider some novel concepts based on technology and techniques developed overseas or borrowed from other industry sectors. The objective being to make viable in economic and environmental terms projects that might otherwise be stillborn if considered for exploitation by conventional means. The paper mainly discusses 2 concepts focusing on the application of augers for exposed high wall or outcrop coal and micro-tunnelling augers for alluvial gold extraction. These may be considered high mobility 'container' (as in shipping container) packaged, or 'non invasive' mining systems. It is stressed that these are but concepts and have yet to be subjected to rigorous financial or engineering scrutiny. This could only follow their acceptance by, and input from, New Zealand miners. There will also be brief mention of a new modular conveyor system which might have application within the concepts or existing small scale mineral extraction operations and mention of a project currently in progress to apply tangible 'sustainability' to underground coal mining.

Jan 1, 1996

The Khanong supergene-enriched copper resource, (~23 Mt at 3.0 per cent Cu), is one of several resources recently discovered in the intrusive-centred, sediment-hosted Au-Cu Sepon mineral field located in southern Lao PDR. The unusual style of hypogene mineralisation and unique set of conditions have resulted in the development and preservation of a supergene-enriched profile in this subtropical climate. Hypogene sulphide-rich mineralisation replaced calcareous cataclastite (fault rock) developed in the flat-lying, extensional, Khanong Fault. Spatially, the hypogene mineralisation was immediately out board of the skarn û hornfels Cu-Bi front and in board of sediment hosted Au-(As-Sb) mineralisation in a zoned intrusive-centred hydrothermal system. In situ supergene enrichment of the sulphide protore has resulted in a high-grade chalcocite-clay zone (~10.3 Mt at 4.6 per cent Cu) overlain by leached limonite-clay. A very high-grade in situ to exotic limonite-clay Cu-oxide-mineral zone is locally developed above impermeable dolomite at the base of chalcocite-clay zone. Exotic Cu-Mn-wad mineralisation developed for up to 1 km down the hydraulic gradient from the chalcocite-clay zone. Unique supergene enrichment conditions have resulted in the high-grade Khanong Cu resource in a subtropical weathering environment. The base of the currently active supergene profile coincides with the base of a flat-lying, pyrite-rich fault rock, dipping parallel to the hill slope, maximising Cu enrichment. Meteoric water has been channelled along subvertical faults and narrow horizontal subsurface zones. Low permeability of the fault host rock and footwall rocks has controlled the low volume and slow movement of groundwater required for supergene enrichment. Erosion has been slowed by the resistive ironstone and limonite-clay layer at surface, which assists in preserving the gentle slope over the chalcocite-clay zone.

Jan 1, 1999

The geographical region of South East Asia is variously defined, but generally agreed to include the Asean group - Philippines, Malaysia, Thailand, Singapore and Indonesia. Other regional countries, such as Vietnam, Laos, Burma, Kampuchea etc. are of course geographically part of the region, however in economic terms, they play a minor role. It is the Asean group that dominates present economic activity and provides the overwhelming opportunity for commercial development. My experience in South East Asia has been gleaned over 15 years of regular travel in the region. More recently, we have established company offices in Malaysia, Singapore and Indonesia to extend and deepen contacts with major customers. This progressive development is an integral part of a planned growth pattern and will be discussed in more detail shortly. South East Asia is a rapidly developing economic growth centre, a fact which is clearly recognised and accepted by most commentators. An important question is then to be asked: Why has the region been relatively neglected by Australian, U.S. and European industrial supply companies? I will attempt to address this question in the context of industrial minerals and propose some ideas as to how effective sales programs could be developed. Firstly, let's consider the market potential provided by countries within the region. It is reasonable to suggest that industrial growth in S.E. Asia over the past 20 years has been generally steady and in some cases, explosive. Until recently, this growth has predominantly been driven by development of internal (regional) demand. Population growth and rising living standards have ensured that basic industries have enjoyed a solid uptrend in sales and production. The industries which most benefitted from regional economic development over this period were, interestingly, those which we understand to be major users of industrial minerals - glass, ceramics, paper, surface coatings, cement, refractories, rubber and plastics. Each of these industrial sectors has been influenced by different growth stimulii over a 20 year period. Nevertheless, they also enjoy a common feature which ensured an above average performance. All sectors are fundamental to an environment enjoying rising living standards and rapid growth in general prosperity. More recently, internal growth factors have been overtaken by a recognition that manufactured products from the region are competitive in export markets. This comparatively recent development provides the most interesting possibilities for higher value industrial mineral raw materials. Let me explain: For 20 years, industrial growth in South Asia has essentially been focused on satisfying domestic demand. Finished quality of manufactured items was orientated to a developing market more interested in cost than aesthetics or long life. This was reflected in raw material specifications, which often did not exist and at the best were undemanding.

Jan 1, 1989

The relationship between the permeability of coal to a mixture of methane and carbon dioxide, and the permeability to methane and carbon dioxide separately is described in this paper, along with the analysis of the differences in permeabilities of coal to methane and carbon dioxide.

Jan 1, 1989

The Upper Waimangaroa mining permit is part of the Buller Coalfield and lies on the eastern side of the Stockton-Denniston Plateau. The mining permit area is estimated to contain a total in-ground coal resource of 58 million tonnes, contained within 13 separate coal resource .blocks. The coal is Bituminous High Volatile B rank with export potential as semi soft coking or thermal coal. The Northern Opencast mine is the first mine proposed for Upper Waimangaroa and consists of the three resource blocks at the northern end of the permit area. The highwall of the mine will cut into the Mt William Range resulting in overburden cover of up to 150 metres in some areas. The ability to rehabilitate the area after mining was a major consideration in the design of the mine. The Northern Opencast area has been geologically mapped, extensively drilled and effectively modelled using Vulcan software. Three distinct coal seams are present and the mineable in situ resource is estimated at 8.7 million tonnes of which approximately 7.1 million tonnes is likely to be recoverable. It is proposed that this resource will be mined using opencast methods and the void will be backfilled with overburden. The life of the mine is at this stage estimated at 19 years based on an annual production of 500,000 tonnes at 1.8% sulphur and the Upper Waimangaroacoal will be blended with low sulphur coal from the Greymouth Coalfield to meet export specifications. The Northern Opencast area contains a range of native flora and fauna and physical features which make it an environmentally significant area. Mining will totally modify the area, thus an effective rehabilitation scheme is an integral part of the mine plan. Various rehabilitation methods will be used, and wherever possible, the backfilled areas will be rehabilitated so as to resemble the original area as closely as possible.

Jan 1, 1998

Operations of the new copper smelter at Mount Isa commenced on the 6th February, 1953. Prior to this date a paper by R. V. Anderson (1953) outlined the smelter layout, proposed operation and expected performance.Nominally a 50-ton per day plant, output is currently at the rate of 85 long tons per day. In the first 3t years, of operation to 30th June, 1956, '71,339 tons of blister copper were produced. Operation has been stabilized' and a number of modifications to plant and operation have been made. This paper reviews the progress made to date.GENERAL LAYOUT AND EQUIPMENTThe general layout and equipment follows well-established practice as study of Figs. 1 to 4, and Appendix II will show. This diagrammatic representation of layout (Fig. 1) and flow sheet (Fig. 2) is intended for the purpose of brevity to take the place of a detailed plant description.Choice of site for the smelter was limited by the necessity for close proximity of the waste heat boilers to the powerhouse.Much excavation was necessary before foundation work commenced, but the plant is compact and further expansion is possible.CHARGE MAKE-UPRoaster charge initially comprised concentrates, purchased ores, revert materials, mine sulphide ore and barren sand. As purchased ore receipts increased and as domestic black rock oxidized ore became available, the latter two fluxes were eliminated from the charge. Fluxes at minus i-in. sizing are trucked from crushing plant or stockpile by motor lorries. Filtered mill concentrates are dropped from an overhead conveyor on to the storage patio floor adj acent to the two concentrate bins.

Jan 1, 1957

By Shrivastava P

The iron orebodies of the Pilbara region are formed by supergene enrichment of banded iron formation and rarely do such processes produce orebodies with uniform grade distrib- utions. The orebodies being mined or developed have to be worked to grade/quality constraints imposed by contractual agreement rather than natural characteristics. Hence it is imperative to use a non-biased ore reserve calculation method. The geostatistical study of a typical iron orebody is presented. Emphasised are the geological characteristics of the orebody manifested as a variable grade distribution of iron and impurities; the determination of variogram model; subsequent uses of the model for computation of ore reserves and kriged lock estimates; computation of dispersion variance and conditional simulation of orebody.

Jan 1, 1977

By Baird G. R, Jurak R. N

In this study Dynamic Finite Element Modelling is used to investigate the distribution of peak particle accelerations (PPA) induced in a rock mass by a vertical decked column of explosives. The rock mass is assumed to be viscoelastic. The influence of the delay time between decking charges, the viscosity attenuation (quality factor Q), the decking configuration, and the velocity of detonation (VOD) on PPAs is examined. The results of this paper are relevant to fragmentation since the nature of the fragmentation is related to the stress magnitude and hence the PPAs. It was found that increasing the VOD, and increasing Q increases the PPAs in the neighbourhood of the blasthole. However, the VOD and rock quality factor Q have little influence upon the distribution of PPA. It was also found that an even distribution of PPAs, at a fixed distance from the blasthole, could only be obtained by increasing the ratio of charge length to stemming length. The study showed that the amplitudes and distribution of PPA surrounding the blasthole was approximately independent of the delay time between the decked charges. The modelling also shows that the particle accelerations at locations below the bottom of the charge are relatively small and so the model predicts no substantial damage below the bottom of the charge after blasting.

Jan 1, 1995