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Removal of Arsenic in Enargite from Copper Ores by Flotation and Leaching in NaHS Media

Sep 13, 2010

Wet mining of auriferous gravels at L & MÆs Waikaka operation in Southland creates spoil dumps derived from stripping of a clay rich overburden, tailings from past dredging and the processing of auriferous sands and gravels. Over recent times, spoil dumps have slumped on six occasions, threatening the viability of the wet mining operation. Close examination of slump morphology, coupled with the sequence of material placement and rate of dumping suggested a mechanism associated with undrained failure of a 2 m layer of silt and sand tails forming the base of dumps.Commencing with some information on the geotechnical properties of source overburden, back analysis of failure morphology and sequence and development of undrained loading conditions from first principals, the most likely failure mechanism and factors controlling failure were defined. Based on analysis results, a scheme to stabilise the lowwall dumps was developed and implemented, augmented by continuous monitoring of pore pressures in the basal wet tails, and laboratory testing for confirmation of computed material properties.Lowwall spoil stability has improved since implementation involving changes to the method of spoil loading, and modification of wet tails composition to improve permeability and drainage of the basal wet tails under load. The method and approach to prediction and verification of failure mechanism provide a sound basis for continued mining of deeper auriferous gravels.

Jan 1, 2002

Flue dust from the sintering of base metal sulphides was leached to remove cadmium and arsenic. Leach liquor contained cadmium, zinc and small amounts of other base metals as chlorides. Results are reported of the use of a cation exchange resin Zeocarb 225 to separate the base metals from the arsenic. The resin was eluted with sodium chloride or sulphate to give a solution of relatively concentrated cadmium suitable for recovery by zinc cementation. The limited solubility of sodium sulphate presented some practical problems which were investigated. Another problem was the precipitation of lead sulphate in the resin during elution.INTRODUCTIONWhen lead-zinc sulphides are sintered prior to smelting, the gases passing to the flue are mainly uncondensable but contain a certain proportion of sublimates and dust particles which deposit in the flue or are carried, after condensation in the gas stream, to some form of dust extraction equipment.The recovered dust is a complex mixture of base metal sulphates, sulphites, sulphides, chlorides and oxides, the composition depending on the original concentrates. A large proportion of the cadmium and some of the arsenic originally in the concentrates finds its way to this flue dust, the treatment of which can be a convenient means of removing these elements and controlling their concentrations in the main lead-zinc smelter circuit. However, disposing of this material represents an appreciable waste of base metals as well as a serious toxicity hazard.Sulphide Corporation Pty. Ltd. was faced with this problem in planning the flow sheet of the new lead-zinc smelter at Cockle Creek, N.S.W. From a test run carried out on a pilot plant at Avonmouth, U.K., using a mixture of lead and zinc concentrates, a sample of dust was obtained for...

Jan 1, 1960

By A H. Clemens, T A. Moore

This paper discusses a number of technical issues related to marketing coal. It outlines how the results of research undertaken in New Zealand and overseas can help producers address a range of technical factors that impact on production costs and marketability. The paper also discusses trends in coal utilisation for power generation and how new technologies may require coal with different characteristics. Research and development into options for CO2 sequestration are discussed including carbon storage in forests, and removal of CO2 from flue or fuel gas in power stations, and its disposal.

Jan 1, 1997

By J Samosir, L Snyman

Northparkes was the first mine in Australia to use block cave mining method which relies on gravity and natural rock stresses to fragment and recover the ore. It was also the first hard rock mine to use hydraulic fracturing, in conjunction with CSIRO, to promote caving of E26 Lift 1. The technique was later used on E26 Lift 2 wedge and E48 prior to undercutting.Northparkes production is currently sourced from the E48 Lift 1 block cave mine and E26SLC. The E48 block cave contains economic ore to the north and south of the current cave footprint. To recover this ore the footprint has been extended on the north and south with two extraction drives and one extraction drive, respectively. Modelling of cavability above the additional drives indicated that the cave would not readily propagate to a sufficient height of draw to mobilise the ore and tended to arch over into the existing cave. To address the modelling results and to reduce the risk of the project, rock mass preconditioning was adopted.This fracturing campaign was performed from surface drill holes adjacent the subsidence zone angled to intersect the higher grade and higher elevation ore zones.Optical televiewer surveys, run prior to fracturing, picked intervals and fault zones to be avoided. Holes were resurveyed post-fracturing to detect newly created fractures and as a measure of success of the program.During fracturing operations water and gel fractures were run at varying depths and pumping pressure was logged for each fracture. The mine seismic system monitored significant events and dye in the fluids utilised for tracking water inflow locations during underground inspections.Towards the end of the project, guar fibres from gel were detected within the mill circuit and required treatment to resume optimum processing.CITATION:Webster, S, Snyman, L and Samosir, J, 2016. Preconditioning E48 cave extension adjacent to an active cave, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 471–478 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

Mining is still a significant economic activity within the Hauraki District. The Martha project is particularly significant. Estimates are that in the order of 850 direct and indirect jobs are derived as a consequence of the Martha project within the Waikato Region. The Resource Management Act 1991 (RMA) is New Zealand's primary piece of environmental legislation. It sets out to provide the framework for the control of the use, development and protection of almost all physical and natural resources. Minerals are excluded from the sustainability requirements of the legislation but as mining invariably involves the use of land, all the other elements of RMA apply. The Council's role in dealing with mining changed with the introduction of RMA. It became responsible for administration of those matters that fell within the functions set out in section 31 of the RMA in respect to existing authorisations. Mineral development needed to be considered in the development of the District Plan that the Council is required to prepare. Implementation of the Act has been a challenge for not only local government but for many industries and resource users since it came into force in 1991. There have been, and are, differing views on both the way it is administered and its intent. The Hauraki District Council has been at the forefront of some of the challenges that are a consequence of the Act. Its reactions to these challenges have been consistent. It treats mining in the same why it treats any other industry. At times this approach has not been understood and without challenge from sections of the community.

Jan 1, 2000

By W. M. LONIE

Address by the President of the Institute (Mr W M Lonie) in making the presentation of the Certificate of Honorary Membership to Sir Ian McLellan, K.C.G.M, K.B.E. Address by Sir Ian McLellan after accepting the award.

Jan 1, 1979

By E Christodoulou, L Zoumpoulakis

The kinetics of the thermal decomposition of MgCO3 was investigated using isothermal experiments performed in a thermogravimetric analyzer under a nitrogen atmosphere at 380¦, 400¦, 450¦ and 480¦C. The weight loss data as a function of time were modified to give the fraction that reacted (ß) and the rate of reaction (dß/dt) vs. time (t). Kinetic analysis of the experimental results, using three different methods, showed that diffusion predominates the MgCO3 decomposition over the investigated temperature range, with the data being best fitted by JanderÆs equation ([1−(1−ß)1/3]2=kt). The activation energy was estimated by Arrhenius plots using both the initial reaction rates and rate constants from fitting the above equation. The values estimated were 27.1 and 171.4 kJ/mol respectively.

Jan 1, 2001

The Bayswater seam of the Singleton Coal Measures is discussed in relation to its field occurrence and related li~hotype profiles. The seam is correlated throughout widely separated areas of the Hunter Valley with the Farrells Creek seam at Howick, Broke seam at Broke, and Saddlers Creek seam at Mt. Arthur. The unusual features of composition of the seam in relation to adjacent seams is dealt with in terms of the seam environment, particular attention being given to the sandstone at the base of .the seam. Petrographic and other data are used to support the arguments submitted.

Jan 1, 1973

Management of Mining Wastes in European Union and Developments in Turkey

Sep 13, 2010

By H Sofatzis, J Kinal, J Siliezar, B Kirkwood

Ernest Henry Mining (EHM) is a copper, gold and magnetite mining and processing operation located 38 kilometres north east of Cloncurry in the Mount Isa - Cloncurry mineral district of north west Queensland, Australia. The EHM ore body is an iron oxide copper gold deposit with an average grade of 1.1 percent copper, 0.5 g/tonne gold and 22 percent magnetite.At the end of 2009, after a series of promising laboratory test work, EHM converted the ball mill media charge from forged steel to high chrome media. Laboratory test work also indicated that with the use of high chrome media, the pH was able to be reduced with no negative impact on plant performance. At high pH values (above 10.5), the forged media is passivated, so as the pH of the system drops the media corrosion rate increases and floods the system with corrosion products, affecting flotation. As the high chrome media is much more inert, pH has less of an effect on copper flotation response.This paper provides an overview of the effects of reducing the pH in the EHM copper rougher flotation circuit. The pH in the roughers was dropped from 10.6 to 9.6 to determine the impact on the rougher performance and the subsequent performance of the whole copper flotation circuit. It was found that there was a slightly increased improvement in copper recovery and no statistical change in either the rougher or final copper concentrate grades for copper and gold.With the reduction in pH, there was a noticeable reduction in lime usage from 0.85 kg of lime per tonne of ore processed to 0.55 kg/t. This reduction in lime is equivalent to approximately $700,000 per annum at current production rates.CITATION:Kirkwood, B, Kinal, J, Siliezar, J and Sofatzis, H, 2013. Low pH trial in the Ernest Henry Mining copper rougher flotation circuit, in Proceedings MetPlant 2013 , pp 371-377 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

By C M. Hall

We report 40Ar/39Ar ages for adularia and illite from veins and wall rocks at the Waihi and Favona deposits, in the Waihi district. One sample of vein adularia from the Favona deposit yielded a plateau age of 6.04 ¦ 0.06 (la) Ma, and two samples of vein adularia from the Waihi deposit yielded plateau ages of 6.17 ¦ 0.03 and 6.17 ¦ 0.09 Ma. Two samples of wall rock adularia from the Waihi deposit yielded plateau ages of 6.07 ¦ 0.06 and 6.08 ¦ 0.03 Ma. Adularia ages overlap at the 2s level, and we do not consider them to be significantly different. Two samples of illite from wall rocks at Favona have total gas ages of 5.66 ¦ 0.04 and 5.65 ¦ 0.04 Ma, and retention ages of 6.57 ¦ 0.04 and 6.61 ¦ 0.04 Ma, whereas one sample of vein illite yielded a total gas age of 5.29 ¦ 0.17 Ma, and a retention age of 6.26 ¦ 0.19 Ma. The total gas ages of illite are minimum ages that are equivalent to conventional K/Ar analyses, whereas retention ages of illite are maximum ages. Although interpretation of the illite data is complicated, the adularia results strongly suggest that the Waihi and Favona deposits formed contemporaneously in the same fossil geothermal system at 6.0 to 6.1 Ma.

Jan 1, 2003

In the estimation of reserves the known values of the variables of interest from surrounding drill holes are used to compute or estimate the unknown value of the orebody over a given region or at a given point of interest. The classical means of doing this are: 1. The Polygonal Method û where the region is divided into polygons centred on bore holes, each variable is then assumed to have constant value over each polygon. 2. Inverse distance methods, where the variable is assumed to vary linearly with the distance between the known values of the drill holes. 3. Inverse distance squared method û a quadratic variation is assumed for the variables between the bore holes.

Jan 1, 1983

By D Sert, A Jayasekara, P Gardin, B J Monaghan, S J. Chew, P Zulli, D Pinson, X F. Dong, R Ferreira

In an ironmaking blast furnace (BF), molten slag and hot metal form in the softening-melting (cohesive) zone and then trickle through the coke packed bed before being discharged from the taphole. During their downward flow, there are significant interactions occurring between liquids and other phases, such as gas and packing particles. Overall, the formation, dripping and discharging of these liquid phases, particularly molten slag, have a significant impact on BF operations in terms of furnace permeability, fuel consumption, process stability, product quality and ultimately, productivity. Hence, understanding the liquid flow behaviour in the BF lower zone is critical for designing optimal operations. In the current investigation, the flow behaviour of slag droplets was investigated at a mesoscopic level using a combined numerical and physical modelling approach. The interaction between slag and carbonaceous materials was studied using sessile drop wetting experiments, slag flow through a funnel and a high temperature packed bed and the Volume of Fluid (VOF) modelling technique. Molten slag flow and counter-current gas-slag flow in the packed bed was investigated in terms of superficial gas velocity, slag properties and packing structure. The gas-slag flow behaviour at a mesoscopic level was numerically visualised, with gas velocity gradually increased up to the flooding point. The strong interaction between gas and slag was uniquely identified, which can cause localised slag flooding as well as gas channelling. Detailed information concerning the effect on slag holdup distribution, residence time and flow patterns of wettability, slag properties and bed structure were obtained. The current investigation highlights the significant role of research at a mesoscopic level in understanding macroscopic slag flow behaviour. Gas channelling, which is a critical phenomenon in a packed bed with counter-current gas-slag flow, is predicted. It can be speculated that significant gas channelling in the BF can inevitably occur prior to operational limits being reached. In the BF process, the formation of permanent gas channelling and large slag rivulets should be avoided to maintain appropriate contact between phases and hence, furnace permeability.

Jun 19, 2024

By J H. Heo, J H. Park, M J. Lee

In this paper, the challenging points regarding the high temperature physical chemistry of slags to achieve the improved and stable electric arc furnace (EAF) or electric smelting furnace (ESF) technology on the way to green steel will be reviewed, and the recent experimental and modelling research will be discussed. For example, the initial melting phenomena of hot briquetted iron (HBI) and the slag formation behaviour was observed using a high-frequency induction furnace. Main component of gangue oxides in HBI was SiO2, Al2O3, and CaO in conjunction with unreduced iron oxide. To increase the dephosphorisation efficiency, the distribution ratio of phosphorus between metal and slag was calculated using FactSage™ software, version 8.2 (CRCT ThermFact, Inc., Montreal, Canada) and was compared to the measured results. The optimisation of slag chemistry is required not only for maximum dephosphorisation efficiency with good slag foamability but also for minimum slag volume with less refractory corrosion in EAF process. The slag chemistry is also one of key parameters affecting the operation efficiency in ESF in view of FeO reduction behaviour, viscosity, sulfide capacity, etc.

Jun 19, 2024

Behaviour of Bubble Clusters in a Turbulent Flow

Sep 13, 2010

Autocompression and virgin rock tempera ture have a marked influence on the ventilation of the lower levels at North Broken Hill Limited N.S.W. To maintain comfortable working temp- eratures without penalty to working hours, increase in airflow or the cooling of the work area is necessary. The use of refrigerated air cooling is discussed. Ventilation of underground mining opera tions at North Broken Hill Limited is accomplished by downcasting air through No.3 shaft, the main operating shaft, 1581 m deep, with additional air through No.1 shaft (542 m) 2 and No.2 shaft (978 m), both no longer opera- tional shafts. Air is upcasted through No.3 ventilation shaft which is 4.9 m diameter and concrete lined, from the No.28 level (1140 m) to the surface. On the surface level of this shaft is a horizontally mounted Richardson 4800 mm diameter single stage axial flow fan with adjustable pitch rotor blades.

Jan 1, 1977

The main aim of the conference is to work towards improved useage of steelplant slags which have largely been considered waste mater- ials, This paper summarised investigations carried out on the suitability of air cooled blast furnace slag, blast furnace granulated slag and basic oxygen steelmaking slag as road base materials. All slag samples were obtained from the PortòKembla Works of Australian-Iron and Steel Pty Ltd. Since road making materials are increas- ingly being characterised by use of resilient moduli, the compressive strengths and resilient moduli were determined for road base of the following slags. 1 Air cooled crushed blast furnace slag 2 mixes of air cooled blast furnace slag, granulated slag, and lime 3 mixes of air cooled blast furnace slag,-granulated slag and basic oxygen steelmaking slag. Evaluation of a local dacite (dense medium grained igneous rock, classification rhyolite), generally considered an excellent road base course material, was carried out for use as a reference material.

Jan 1, 1979

Casing or lining pipe is used in boreholes for the following reasons:1. To preserve the hole while drilling and after it is finished.2. To shut water out of the hole or to isolate any particular water, gas, or oil-bearing stratum.Deep holes can seldom be drilled without casing, and only when in firm strata. If caving from the walls is at all likely while drilling, casing is necessary in order to prevent the tools horn being buried...

Jan 1, 1924

By Tumilty JA, Schmidt CG

Sulphide ion is a powerful poison in gold cyanidation, however, the detrimental effect is less severe in plant practice. This is thought to be due to the presence of depassivating elements in the ore, mainly lead. Trace amounts of lead can counteract the poisonous effect of considerable amounts of sulphide. The reaction is instantaneous and is likely to be a direct involvement in the electrochemical surface reaction. Lead addition cannot be regarded as an all-round cure when experiencing poor leach efficiencies. A possible beneficial effect depends on the mineralogy of the ore and has to be determined individually for every material.

Jan 1, 1989