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By Buizen M

An investigation into the mechanics of sub-surface deformation caused by caving of the extracted area behind retreating longwall faces has been completed by the Subsidence Engineering Section of the New South Wales (NSW) Department of Minerals and Energy. Changes in strata bulk permeability were also measured by standard packer tests undertaken before and after mining. The strata movement was measured by a multi-wire borehole instrumentation system consisting of mechanical anchors installed at different horizons in a borehole extending from the surface to the coal seam. The mechanical anchors were collected to suspended weights on the surface by stainless steel multi-strand wires. The movement of these weights was monitored as the longwall face approached and retreated past the borehole. The anchors did not move significantly until the face went past the borehole. For subcritical extraction geometry with the extraction width to mining depth ratio of 124, the caving zone extended to roughly 9 times the extracted seam thickness above the seam roof. Tensile strains within the overburden tended to be much more closely related to stratigraphy than to the proximity to the extracted seam roof. Larger tensile strains were associated with layers of sandstone, siltstone and conglomerate, whereas layers of mudstones, claystones and coal underwent much smaller strains indicating subsidence in blocks. A beller correlation was observed between pre-mining Rock Quality Designation and permeability than between rock type and permeability. This correlation was less evident in the post-mining core logs. There was an overall increase in bulk permeability after mining.

Jan 1, 1990

Every text book for blasting in Japan says that Hauser's law can be applied for practice. But recently it came true that there was no historical record about him and no actual datum of his own or other's to testify. According to his theory, the funnel ratio N = r/W in crater test is inversely proportional to the rock strength and proportional to the explosive amount: where r is the radius of crater and W is the burden. But experiment showed the opposite result, and revealed new information. Two kinds of experiment, crater test and boulder blasting of mortar, were carried out to investigate the effects of rock properties on blasting. The material used for test 1 and test 2 was a mortar block (60cm)3 cube, 4 vertical faces of which were used for crater test. The results from Test 1 and test 2 were summarized as follows. The funnel ratio ranges between 2.5 to 4.5 in proportion to rock strength and burden. The standard ratio of 1, reported by Hauser, was not observed in any instances. It was also noted that the funnel ratio is independent of the explosive amount. The material used for boulder blasting, test 3, was a mortar block (40cm)3 cube, in the middle of which was located a vertical borehole for the explosive charge. The results of test 3 were as follows. The necessary explosive amount for boulder blasting is in inverse proportion to the mortar strength. Fragmentation and throw are proportional to the mortar strength.

Jan 1, 1990

By J Bower

The JORC Code does not specify a definition for ælevel of confidenceÆ. The common approach in the mining industry is to use a certain drill spacing or number of data samples to classify resources by the confidence categories. Another approach includes application of the quantitative geostatistical criteria for non-subjective and consistent definition of the resource categories. This approach, which has become increasingly popular in the mining industry, provides a quantitative measure of the resource estimation uncertainty. In this study, uncertainties associated with the different drilling grids at the Weipa bauxite deposit (Queensland, Australia) have been modelled using conditional simulation methodology. Criteria used at Weipa for defining resource categories are as follows: mineralisation can be classified as a Measured Resource if tonnage and grade of its volume representing three months of production can be estimated with a precision error not exceeding ¦10 per cent (at 95 per cent probability, ie two standard deviations); and mineralisation can be classified as an Indicated Resource if grade and tonnage of its volume representing annual production can be estimated with a precision error not exceeding ¦10 per cent (at 95 per cent probability). Several different grids have been created by subsampling the drill hole database. The studied variables include Al2O3, SiO2, thickness of the bauxite seam and location of the footwall contact. The variables have been modelled by sequential Gaussian simulation. Based on this study the following drill spacings have been recommended: Measured Resources û 150 m by 150 m, Indicated Resources û 300 m by 300 m.

Jan 1, 2009

By Y Li, B Shen, S Zhang

Jointed rock mass is often encountered in rock engineering and its stability has always been a major concern in underground engineering. To analyze the stress characteristics and their variations in jointed rocks, in this study, a new concept of sub-instability stage before rock failure is defined, and a new experimental method is used to investigate interaction between defects and intact rock of the jointed rock mass during the subinstability stage., Firstly, external characteristics of stress and failure mode of the whole jointed rock are investigated systematically by conducting uniaxial compression tests on red sandstone samples with a set of preexisting open flaws of different sizes, and the interactive damage of intact parts and defects in the subinstability stage was further studied. Secondly, rock-like material samples made of bonded plaster blocks were tested and internal data from stress sensor between the strong and weak segments were collected. The transforming processes from independent activity of the individual segment to overall interactive movement of jointed rock before the unstable failure were analysed. The test results indicated that the subinstability stage marked the beginning of interactive failure between the intact rock and defects. In the early subinstability stage, the relatively intact parts bore most of the load in a jointed rock mass, and the defects were damaged firstly which caused high strain around it. The areas of high strain increase rapidly, extending and migrating, causing damage to the intact parts. In the later sub-instability stage, the interaction effect reached its maximum, and a large number of cracks appeared in the intact rock and they propagated and coalesced. Intact parts experienced rapid failure and then the jointed rock failed. The experimental method used in this paper to identify the sub-instability stage could be used to identify failure precursors of jointed rock masses and to develop technology for disaster prevention in rock engineering. CITATION:Zhang, S, Shen, B and Li, Y, 2018. Experimental studies on interactive failure characteristics of jointed rock, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 453–461 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By A Hughes, S G. Rosin

This paper presents the design and construction approach adopted for the widening and stabilisation of the existing decline tunnel forming part of the Scenic Railway Upgrade project at Katoomba in the Blue Mountains of New South Wales (NSW), Australia. The overall upgrade project included new trains and track, rebuilding of the top and bottom station and installation of a new winch and control system. All the works were undertaken over an eight-month period between August 2012 and April 2013 as part of a $30 M upgrade of the railway.The railway is the steepest cable-driven line in the world at a maximum of 52° extending over 350 m and descending from the escarpment into the Jamison Valley. The track was built in the 1880s for coal haulage and is recognised as a remarkable engineering achievement for its time. The tunnel section extends for about 120 m at the start of the decline and is about 3.5 m wide and 3.5 m high. The tunnel was excavated principally within medium to high strength Banks Wall sandstone and given that the widening only involved about 200 mm of trimming of the crown and sidewall this aspect of the work was not a critical support issue, except at the upslope portal. The tunnel crown however is entirely intersected by a major near vertical shear zone which presented significant challenges for the tunnel stabilisation works.Three-dimensional laser survey scanning was used for definition of the tunnel clearance envelope for the widening, and also to subdivide the tunnel into various geotechnical sections to assist in support design. Specifically oriented rock bolts extending beyond the shear zone into stable rock were used together with mesh, shotcrete and extensive strip drains and flushing points for drainage of the shear zone.Unique aspects of this project were included into the specifications and work methods. This included construction of a mobile working platform for tunnel works, the use of dry shotcrete application, difficult access for rock bolting and limiting vibration during the tunnel trimming works due to the risks associated with crown instability. The works also took into consideration particular safety constraints/work exclusion areas to address the risk of detachment of rock which could mobilise downslope to the track area below. This was required because other works were in progress such as micro-piling and bottom platform works which were being undertaken concurrently with the tunnel work.CITATION:Rosin, S G and Hughes, A, 2014. Scenic Railway Tunnel upgrade in the Blue Mountains, New South Wales – an approach to design and construction, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 607–618 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By A Jyoti, J R. Black, R R. Haese, E O. Ansah

Copper (Cu) is a critical metal in the transition to a low-carbon power supply. Presently, low-grade copper sulfide ores account for almost 80 per cent of the global reserves. Large amounts of water are required to process these low-grade copper ores. The mining industry utilises lixiviants from recycled water from different sources to conserve water, whilst enhancing Cu recovery. Some utilise intermediate to pregnant leach solutions, sea water, and processed water from electrowinning circuits with highly variable concentrations of ions. Previous studies have highlighted the formation of precipitates that passivate the surfaces of minerals in these low-grade copper ores and/or block flow paths for lixiviant during heap leaching. In this study, we utilised concepts of phase replacement to devise an innovative means of controlling precipitation and increasing copper recovery using industrial brine as opposed to freshwater. We propose the formation of Al-rich phases (such as AlSO4 + or alunite) to replace iron sulfate and iron hydroxysulfates (such as jarosite) during the chalcopyrite dissolution-precipitation mechanism. The rationale is to have available Fe3+ throughout the chalcopyrite leaching process. We tested this method by carrying out various batch experiments using CaCl2, AlCl3, and NaCl industrial brine types compared to freshwater and explored the capacity to leach Cu from chalcopyrite. There is higher Cu recovery during oxidative leaching of chalcopyrite in industrial brine with 91 per cent recovery using AlCl3-rich brine, 84 per cent with NaCl-rich brine, and 56 per cent with CaCl2-rich brine as compared to 35 per cent recovery using freshwater. In the absence of Al3+, various forms of iron sulfates, and jarosite are formed, reducing the availability of Fe3+ for chalcopyrite dissolution. The introduction of Al3+ leads to the formation of AlSO4 + species, thus lowering sulfate activity and the tendency for K-jarosite formation.

Aug 24, 2022

By Schaap W

A test on Taylor's rule of mine life using published data on open pit porphyry copper mines confirmed that mine life is, on average proportional to the fourth root of reserve tonnage. Deviations from this rule-of-thumb occur to a large extent as variations between regions that are qualitatively explained in terms of differences in grade, infrastructural needs or special taxation effects.

Jan 1, 1984

By J R BISHOP

Geophysical techniques are being increasingly used down exploration drill holes as deeper and more elusive targets are sought. This paper lists the various methods available and discusses the applications using a number of examples.

Jan 1, 1992

By J N. Farrell

Metallurgists frequently use a small number of large samples to characterise expected mill performance, with the a priori assumption that these few samples are representative of the entire deposit. Geometallurgical sampling is becoming more prevalent as a way to use many smaller samples to indicate the expected recovery as part of the Mineral Resource or Ore Reserve estimation.The evaluation of magnetite deposits involves specialised approaches to sample preparation, sample analysis and resource estimation. The sampling protocol for magnetite deposits will typically include the use of Davis Tube analysis. The Davis Tube is a mini-pilot plant that is used for determining the mass magnetic recovery from a small amount of sample ground to a specific size. The magnetic concentrate may then be analysed and together with the mass magnetic recovery, may be used to simulate the expected mill recovery. The magnetite sampling protocol is specific to each deposit, and is typically designed around a specific metallurgical flow sheet.During resource modelling, the mass magnetic recoveries and concentrate grades may be estimated directly or assigned to a block model using regressions with other chemical constituents. For estimation, the concentrate grades are weighted to account for the different mass magnetic recoveries of each sample and the impact of these differences on the concentrate estimates.

Sep 5, 2011

The Sishen iron-ore-mine produces 3 pro= ducts with size gradings of 25 to 8 mm, 11 to 5 mm and 5 to 0,2 mm and has a product capacity of 20 Mtpa. Ore is produced at an average Fe content of 66,2 % Fe for the two coarser pro= ducts and an average of 65,3 % Fe for the fine ore product. Three stage crushing is practised to re= duce the run-of-mine ore to -90 mm after which it is screened into five different size frac= tions of which four are heavy media beneficiated in static baths and cyclones and the fifth frac= tion discarded to slimes dams. A final three stage crushing and screening process is employed to produce the final three Products which are homogenized by means of blen=ding systems nrinr to despatch.

Jan 1, 1987

By D Baas, J Le, R Braun, R Chandramohan, K Hollis, G Lane

The Phu Kham Copper-Gold Operation (Phu Kham) is located in northern Laos, approximately 140 kilometres from the capital, Vientiane. The operation is a producing asset for Australian-based copper and gold producer, PanAust Limited (PanAust) and is operated by Lao-registered company, Phu Bia Mining Limited (Phu Bia Mining). PanAust holds a 90 % interest in Phu Bia Mining. The Government of Laos owns the remaining 10 %.The Phu Kham Operation has recently undergone a series of process improvements to treat the anticipated competent ores scheduled for 2017 and 2018. The operation’s comminution circuit, which comprises a semi-autogenous (SAG) mill and two ball mills, each with 13 megawatts (MW) of installed power, was expected to be SAG mill limited when treating competent basement rock. Ausenco Services Pty Ltd (Ausenco), was engaged to help optimise and enhance the productivity of the Phu Kham comminution circuit over an eight-month period. The work involved participating in and overseeing the redesign of the SAG mill liner systems and developing operational strategies for maximising throughput through to the end of mine life. Ausenco’s comminution optimisation tool, Ausgrind, was used to benchmark and analyse plant data with empirical models, predict circuit performance for varying ore characteristics and evaluate liner wear and predict the life for varying operating parameters. Variances between the actual and the predicted values were assessed in detail to identify missed opportunities, and guiding operating parameters were redefined to maximise throughput and productivity. In combination with the redesigned liner system, optimised process controls for varying ore competencies, and improved operational practices and troubleshooting strategies, increased Phu Kham overall production, exceeding the milling capacity when treating competent ores. CITATION:Chandramohan, R, Braun, R, Lane, G, Hollis, K, Le, J and Baas, D, 2018. SAG mill optimisation and increasing throughput at the Phu Kham Copper-Gold Operation – a success story, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 113–128 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By J Miedecke

A metalliferous mine has operated at Storys Creek from the 1890s to 1979. Storys Creek drains from a pristine catchment and National Park and remains as the most degraded stream from historic mining in north-eastern Tasmania. It has been the subject of public concern since the closure, particularly at times of high rainfall such as existed in 1985 and 1986. The mine is located on the banks of the creek, which flows into a major river, the South Esk River, which is one of TasmaniaÆs largest rivers and important for recreational fishing and water supplies. For much of the life of the of the operations tailings were directly discharged into the creek, and in latter years stockpiled or very close to it. Little rehabilitation was carried out at mine closure. The result was erosion and subsequent deposition on the banks of the creek downstream. Direct emissions of adit water and the consequential emission of contaminated ground water to the creek continue to affect water quality. Contaminant loads discharging from the mine and tailings comprise 70% of the metal load in the catchment and are by far the largest single source. Acidity data suggested that the introduction of systems to introduce alkalinity could be effective in ameliorating the residual acid drainage impacts in the Storys Creek catchment. After a period of investigations and trials which proved their effectiveness, treatments adopted have included the following: relocation of tailings to a constructed and clay capped disposal area and rehabilitation of tailings area; crushed limestone addition to stream flows; crushed limestone addition to creek banks and exposed tailings; sealing of a drainage Adit; and construction of an anoxic drain to generate alkalinity to surface waters draining to old mine workings. These innovative treatments have resulted in a marked improvement in water quality draining from the area. The anoxic drain is believed to be one of the few, if any, which has been constructed to have generated high levels of alkalinity from clean waters and offers a solution to the clogging problems experienced in such drains in the past. Similarly, the use of crushed limestone in an active stream has proved effective in buffering acid drainage and removing metals from solution.

Jan 1, 2003

By T Baumgartl, T Huynh, K Tungpalan, E Wightman, M Edraki, M Tayebi-Khorami, L Huang, S Palaniandy, E Manlapig

With the increasing rate of tailing production worldwide there is a growing concern about the hazards of tailings storage facilities (TSF). Past and current mining, processing and waste disposal strategies that focus on the extraction of the valuable minerals, and an economic assessment only, are no longer suitable. Social implications and environmental legacies must be included for effective evaluation. This is possible by using an integrated assessment framework to evaluate more alternatives, including the production of additional saleable and benign streams, alternative tailings treatment and disposal as well as options for reuse, recycling and preprocessing of existing tailings. Tailings are not viewed as a final waste product but as part of the resource. From the sustainability perspective the models developed in integrated research programs will contribute to more effective methods for assessing different scenarios and potential processes and lead to better environmental management, increased production of benign tailings and improved efficiency of water and energy use and thus more responsible resource stewardship of the ore resource.This paper presents preliminary results from a multiyear research program on integrated tailings management at the Sustainable Minerals Institute (SMI), The University of Queensland, called ‘Designer Tailings’. The project involves the gathering of experimental and observational information on tailings biogeochemical processes to design and modify the range of activities within mineral processing plants, upstream characterisation ore and gangue, and downstream tailings management for desired tailings properties and outcomes. This information will assist the development of new total integrated value chain CITATION:Edraki, M, Huynh, T, Baumgartl, T, Huang, L, Andrusiewicz, M, Tungpalan, K, Tayebi-Khorami, M, Wightman, E, Palaniandy, S, Manlapig, E, Evans, C, Farrokhpay, S, Bradshaw, D and Vink, S, 2014. Designer tailings – an integrated model for tailings management, in Proceedings Life-of-Mine 2014 , pp 599–608 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By M M. Hilden, M S. Powell, B Foggiatto

In an environment of decreasing ore grade, increasing costs and uncertainty with respect to commodity prices, the industry could benefit from evaluating alternative technologies and innovative circuit configurations. The flexible circuit approach suggests that the design of grinding circuits can be adapted to changes in feed properties and economic conditions. Advances in modelling and simulation are enabling metallurgists to predict the performance of more complex circuit configurations with increased confidence. Ore variability information and processing costs may be used as modelling inputs to determine the optimum processing conditions at a given time. A case study has been completed demonstrating the value of combining a flexible circuit with a model-based optimisation of the process. Ore properties and equipment performance data obtained in operating plants have been used to model and simulate flexible circuit configurations.This paper explores strategies to introduce flexibility to existing circuit configurations when processing ores with high variability. Multicomponent models incorporated in the model developers’ kit (MDK) allow the simulation of more complex and flexible circuits. This capability enables demonstration of the potential to enhance metal production through adapting processing routes according to the ore type being processed. The simulation of different flow sheet configurations allowed the definition of the best option for maintaining the metal production when treating lower grade ores, highlighting the advantages of flexible circuit configurations compared with a one-process-fits-all approach.CITATION:Foggiatto, B, Hilden, M M and Powell, M S, 2014. Advances in the simulation of flexible circuits, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 391–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By G B. Douglas

Lime-based neutralisation has long been the remediation treatment of choice for acidic mine pit waters. While suited to the attenuation of acidity, lime-based neutralisation may be difficult to implement efficiently due to variation in quality and the partial loss of neutralisation efficiency due to armouring. Large volumes of gypsum-bearing sludge may also require mechanical dewatering and transfer to final voids prior to resumption of in-pit mining or closure. Thus, operational costs may be substantially higher than primary neutralisation alone. Lime production also results in large greenhouse gas (CO2) emissions.Hydrotalcites (HT) are a class of Mg-Al layered double hydroxide minerals with the composition Mg6Al2(CO3 )(OH)16.4H2O. A range of other divalent and trivalent cations may also readily substitute for Mg (eg Cu, Ni, Pb, Zn), Al (eg Fe, La, Ce) and metalloids/oxyanions (SeO42-, AsO43 -/CrO42 -, MnO4-) for CO3 into the hydrotalcite structure. A common feature of acid mine pit waters, often overlooked in assessment of potential remediation options, is the frequent predominance of divalent and trivalent cations as a consequence of partial decomposition of both ore and gangue minerals during in-pit wall rock leaching. Thus, given the presence of substantial divalent and trivalent cations in acidic mine pit waters, an opportunity exists to exploit and in effect work harmoniously with the prevailing pit water composition to form a polymetallic hydrotalcite.The utility of hydrotalcites in the remediation of acidic mine pit waters lies in their ability to incorporate a wide range of contaminants; instantaneous formation, often in a single step; simple post-treatment solute composition; rapid settling; low sludge volume; and the potential to form ore-grade precipitates potentially amendable to reprocessing to (partially) recover remediation costs. Examples of hydrotalcite formation as a method to remediate contaminated acidic mine pit waters at laboratory-scale to full-scale will be presented.CITATION:Douglas, G B, 2015. Whither lime? In situ hydrotalcite precipitation as a method of remediation for acidic mine lakes, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 97–104 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By CorrOa de Araujo A, Salum MJG

The treatment of mining and metallurgical liquid effluents is becoming, everyday, a necessity felt by these industries. Physical-chemical and chemical methods for treating such effluents are generally necessary whenever heavy-metals and other toxic compounds such as cyanide are present. The present paper discusses the use of precipitate flotation as an alternative physical- chemical method that can be applied for the treatment of effluents containing heavy-metals (mainly zinc and cadmium) and cyanide. Examples of laboratorial scale applications on real effluents are given. In both cases precipitate flotation was able to reduce the concentration of toxic components of the effluents at a very high removal rate, generating a solid waste that can either be disposed, re-used or recycled. A cationic collector - dodecylamine hydrochloride - demonstrated to be the best choice of surfactant for the two systems investigated. Sodium sulphide and dithizone were selected for the precipitation of the zinc bearing effluent whereas a copper salt was preferentially used for precipitating cyanide in a form adequate for its recycling envisaging the use of an AVR (acidification - volatilisation - regeneration) technique.

Jan 1, 1993

By A V. Ozsever

The selectivity in flotation columns involving the separation of particles of varying degrees of floatability is based on differential flotation rates in the collection zone, reflux action between the froth and collection zones, and differential detachment rates in the froth zone. Using well known theoretical models describing the separation process and experimental data, froth zone and overall flotation recovery values were quantified for particles in an anthracite coal that have a wide range of floatability potential. For highly floatable particles, froth recovery had a very minimal impact on overall recovery while the recovery of weakly floatable material was decreased substantially by reductions in froth recovery values. In addition, under carrying-capacity limiting conditions, selectivity was enhanced by the preferential detachment of the weakly floatable material. Based on this concept, highly floatable material was added directly into the froth zone when treating the anthracite coal. The enriched froth phase reduced the product ash content of the anthracite product by five absolute percentage points while maintaining a constant recovery value.

Jan 1, 2005

Conditional simulation can be used to determine the probabilities of block iron-grades being above selected cut-offs. However, there are much faster alternatives that can produce acceptable results. In this paper blasthole data from a selected area of Joffre Member hosted ore of the Brockman Iron Formation at the Mt Whaleback orebody is used as the basis of a case study to assess alternatives to simulation. Iron grade, in per cent, is interpolated from a blasthole dataset into a block model using ordinary kriging. Samples are then removed from this blasthole dataset to produce data subsets. A complete distribution of iron grades for points or blocks is obtained utilising the data subsets and the following techniques: conditional simulation, median indicator kriging, the probability from conditional expectation and confidence intervals attached to the estimation of blocks in the framework of the discrete Gaussian model. The complete blasthole dataset is considered to represent the true iron grades at sample point support while the ordinary kriging estimate derived from these samples is considered to represent the true block grades. The distributions obtained from point estimates, block estimates and simulations are compared to each other and to the true estimates of iron grades using graphs and statistics. The conditional expectation technique reproduced the results obtained from conditional simulation extremely well and it is a viable alternative to simulation at point support. At block support the confidence intervals technique reproduced the results of the conditional simulation more closely than the median indicator kriging and in the data subsets tested the confidence intervals technique actually reproduced the true grade distribution more closely than the conditional simulation.

Jan 1, 2005

By S J Riley

The cover (cap) over the tailings pit at Nabarlek uranium mine must be structurally stable as it will act as a barrier to radon gas emission and have to contain other long-lived radionuclides. Structural stability is primarily an issue of erosional stability in the context of a design life of thousands of years. The primary agent of erosion is fluvial, dominated by rainwash, overland flow, filling and gullying in the local area. Other agents of erosion are of less concern although biogenic agents of erosion (eg termites and windthrow) may enhance fluvial activity. Several methods may be used to assess erosional stability. They fall into two main categories, namely erosion modelling and geomorphic modelling. The former is illustrated by the Universal Soil Loss Equation in which parameters describing aspects of the geotechnical and hydrological properties of the rehabilitated surface are used as input for the modelling of erosion rates. The latter is illustrated by estimates of gully and valley erosion using empirical models. Estimates of the erosion rates and stability of the Nabarlek cover are presented. The two main techniques are complementary and it is argued that rehabilitation design must make use of both approaches when estimating erosion and geomorphic stability. More recent developments in geomorphic modelling using numerical techniques incorporate both approaches.

Jan 1, 1994

By B J. Monaghan, R J. Longbottom, D J. Pinson, S J. Chew

Recycling steel plant by-products is a critical issue for achieving both environmental and economic sustainability of integrated steel plants. A key steel plant by-product stream is dust from basic oxygen steelmaking (BOS), which can be recycled back to the BOS vessel as iron units and to aid slag formation. The major limitations for its recycling are zinc and the uncertainty in zinc speciation of the dust. This uncertainty affects the amount of dust recycled and how it interacts with the slag during processing. BOS dust in stockpiles can undergo self-sintering reactions that oxidise the iron-bearing components. As this occurs, zinc (or oxide) may combine with iron oxides to form a zinc-iron spinel solid solution phase. Knowing which zinc-bearing species are present in the BOS dust is a key aspect in understanding and developing an efficient recycling process for the dust. To overcome difficulties associated with phase identification in the BOS dust (both fresh and selfsintered), particularly the magnetite-zinc ferrite spinel solid solution using X-ray diffraction (XRD) / scanning electron microscopy (SEM) / energy dispersive spectroscopy (EDS), high end characterisation tools, transmission electron microscopy (TEM) and Mössbauer spectroscopy, were also used. Such an approach allowed improved phase identification of key zinc- and iron-bearing phases that were not previously resolvable. The zinc in fresh BOS dust was mostly present as extremely fine separate particles of zinc oxide, attached to the iron particles. These extremely fine particles were <10 nm in size. Additionally, a small amount of zinc ferrite was also identified within the sample (most likely contained within a magnetite-zinc ferrite spinel solid solution). However, the zinc in the self-sintered BOS dust, was found to be present entirely in a magnetite-zinc ferrite spinel solid solution. While this spinel phase had been previously identified by XRD, it was not clear that it contained zinc. The Mössbauer results provided definitive evidence of zinc within the spinel phase.

Jun 19, 2024