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A Study of Extracting Vanadium from Stone Coal Using Cyclic Oxidation

Sep 13, 2010

By T Mahlangu

The leaching of gold in alkaline aqueous cyanide solutions may be reduced significantly by the passivation of the gold by a surface layer of polymeric aurocyanide. This passivation of the gold is typically countered by the presence of Pb(+2) species in solution, which may be present as an impurity in the solution, or specifically added for this purpose. The speciation and availability of Pb(+2) in typical cyanide leach solutions is illustrated as a function of pH, and the presence of S(-2), S(+6), Cu(+1) and Ag(+1) species. The probable role of the Pb(+2) species in efficient gold leaching is discussed.

Jan 1, 2007

Downhole survey uncertainties observed at various De Beers operations prompted an investigation into their possible effect on deposit shape and volume. An accurately surveyed artificial æboreholeÆ was constructed and different downhole survey instruments tested. In this way an empirically determined error range of 0.1 per cent to ten per cent was derived for downhole survey data. These survey errors were applied to an orebody model at an existing mine. Visualising the sphere of uncertainty associated with a borehole trace using a general mining package (GMP) gives an indication of possible volume variance. The resulting orebody maximum and minimum volume scenarios for three different depths (200 m, 500 m and 800 m) are presented. For certain instruments and borehole angles, the 3D positional error can be as high as 100 m at 1000 m down the hole. At depths below 200 m the resulting volume deviations can become significant for borehole survey errors exceeding 0.35 per cent. At 800 m depth the volume difference can approach 25 per cent. These figures assume that the error is compounded. The impact of these downhole survey errors is greatest for pipe-like orebodies such as porphyries and kimberlite pipes. Subhorizontal sill-like orebodies (and coal seams) will not be significantly affected by these errors. The impact of this type of survey error needs to be stated (and quantified) and is significant in JORC classification.

Jan 1, 2009

All minerals contain radioactive elements, from the uranium ores of the Gabon, which contained sufficient uranium to initiate a natural nuclear reactor, to the very low levels of some recent evaporites. The commonly occurring heavy minerals such as ilmenite, rutile and zircon are no exception to this and contain varying qualities of radionuclides, depending on the source. With recent changes in legislation many natural minerals may become officially classed as radioactive. Such moves can inhibit the sales and exploration of many minerals in the heavy minerals suite. The many negative perceptions associated with the word radioactivity can produce an over cautious reaction from regulators and users. This paper presents a method of managing the radioactivity issues associated with minerals such that the safety aspects of workers and public are not compromised, whilst allowing the commercial use of such minerals to continue in a sensible manner. The paper focuses mainly on the mineral zircon and its uses. However the legislation changes particularly in Europe and the USA have the potential to affect all minerals imported into or produced in those countries. The model developed for addressing the issues of zircon radioactivity may be readily applied to other minerals since legislation governing such matters is not mineral specific. There is a strong need for education of both regulators and users of minerals. Regulators are usually not aware of the specific properties or uses of individual minerals. Similarly mineral users are not aware of the radioactive nature of their materials or how to manage this property. The paper concludes by recommending strong cooperative action by both producers and users of minerals to protect the future of their industry.

Jan 1, 2001

Adsorption Effect on Multi-Heavy Metal Ions in Wastewater by Water-Washing Waste Saccharomyces cerevisiae

Sep 13, 2010

An Evaluation of Froth Recovery Measurement Techniques

Sep 13, 2010

Selection of the mining method and most appropriate mine layout for deep open cut coal mines is discussed, giving particular attention to the types of mines expected to be developed in the future in Australia. Because of the more complex nature of these operations a large number of alternatives for mine design are available, and the constraints associated with these designs are discussed. Potential problems to be overcome are identified to allow setting of realistic targets for maximum output and build-up production rates.

Jan 1, 1981

By Buisman C. J N, Koch R. O

Soil and groundwater beneath the Budelco zinc production plant at Budel-Dorplein (The Netherlands) are contaminated with metals and sulphate. To avoid contamination of nearby drinking water aquifers in the very distant future, a geohydrological containment system (GCS) and a microbial treatment plant for extracted contaminated groundwater have been developed. As a first step in the design of the system groundwater data from over 150 wells and geological profiles were used to model geohydrological conditions beneath the site. Several configurations of water-extraction wells were deduced from the model. Data gathered during additional fieldwork were then used to improve the model. Finally results that were calculated for the various configurations were used to select an optimal groundwater containment system. Currently some 5000 m3/day groundwater are extracted from a combination of 12 shallow and deep wells. Heavy metals and sulphate have to be removed from the extracted water before it can be discharged into the river system or used as process water. Several water treatment methods have been studied and pilot-tested at the site. The preferred and selected process is based on the activity of sulphate reducing bacteria (SRB) and combines sulphate removal and heavy metal removal in one single step. The anaerobic bacteria reduce the sulphate to sulphide resulting in the precipitation of metal sulphides. A pilot plant gave promising results and a commercial-scale plant has been designed. The proposed design has been tested in a demonstration plant which included all main process units. Test results for all process units are presented. The collected information was then used to optimise the design of the commercial-scale plant. Special attention was paid to automation and safety items. Construction of the plant was finished in May 1992. Start-up, commissioning and operational experience are reported. The concentrations of metals and sulphate in the effluent of the SRB water treatment plant are well within the limits set by the authorities for discharge to public waters.

Jan 1, 1993

By Smith Z, Huppert P, Charbucinski J

The paper describes a spectrometric method and apparatus developed for lithology logging in brown coal formations. The nuclear spectromet- ric technique developed is able to delineate coal/sand/clay seams. One requirement was to log inside drilling rods, as well as cased or open holes. The method described is based on combined natural gamma and gamma- gamma techniques using a spectrometric system for signal acquisition and subsequent computer based on-line data analysis and interpretation.

Jan 1, 1989

Gravity concentration of tin at Renison Limited uses tables and spirals to treat the various coarser fractions produced from sulphide flotation tailing. An acceptable final tailing cannot be made from one pass over the tables and spirals and therefore the tailing from these separators is reground and combined with the sulphide flotation tailing as the feed to the classification section. The gravity section became increasingly overloaded in the years preceding 1976 due to efforts to maximize tin recovery to the gravity concentrate. In April, 1976, two 2DSV Reichert cone concentrators in series were installed to treat the table and spiral tail- ing stream, prior to regrind, to scavenge a small tonnage of hard, coarse low tin grade material for rejection to final tailing. Gravity section loadings were decreased markedly, allowing operator attention to be directed more to table performance than to spillage collection. An increase in mill throughput of approximately 15% was possible following the commissioning of the Reichert cones. The cones are currently operated to make the minimum tonnage of tailing consistent with reasonable- gravity section loadings.

Jan 1, 1978

Jan 1, 2004

A novel problem-solving exercise for undergraduates is described which is directly relevant to production supervision. It is based on the fictitious Metwin Plant which produces refined metal from sulphide concentrates via a hydrometallurgical route with six unit operat- ions. Students are given details of the chemistry, process engineering and normal operating conditions. They are also given min- imum data for the Plant when it is operating with a fault. By requesting further data, for which they are 'charged', the students must diagnose the fault. The responses of students to the exercise are described. The data were produced by computer simul- ation of steady state operation under normal and various faulty conditions. The development of this program was an educational experience for the author and it stimulated new interest in metallurgical process engineering.

Jan 1, 1984

The application of new and currently practised mining techniques in new areas and at greater depths necessitates considerable and immediate research effort. This effort is aimed at identifying the factors which make a particular method suitable and economically viable in a given geological, structural and operational environment. These factors, together with greatly enhanced knowledge of a deposit at the exploration and planning stage, allow selection of the most appropriate and efficient mining method in a new area such that coal resource recovery is maximised in a cost effective manner. Current research and future requirements for research into mining methods and associated equipment and mine services are reviewed.

Jan 1, 1981

Pasminco is actively addressing the optimal utilisation of the known orebody at the Broken Hill mine, in addition to actively exploring for economic mineralisation in the region. As part of the policy of better utilising the known mineralisation a major upgrade of geological systems at the mine was initiated. The software chosen for this change was Maptek's Vulcan, mainly because of the ease of use of this package. Rather than having numerous data sources in varying software packages the mine aimed to limit interfaces and packages. The decision to upgrade the mine's software was not taken lightly, especially in view of the inature stage of Broken Hill mining operations. However, the current mine life of Pasminco Broken Hill mine is I I years, which is longer than many new mines setting up in Australia today. Also, a more sophisticated system brings with it a better understanding of the economic mineralisation, possibly extending the mine life further. The process of moving the Broken Hill databases into Vulcan was a huge task which included, database transfer, digitising, wire framing, modelling and eventually ore resource calculation. To ensure the validity of the new ore resource accounting system, the existing system was run as a duplicate for the introductory year, providing a comparison and if necessary a safety net. The benefits of such a change, however, became apparent almost immediately. Area geologists realised the opportunity to revise geological interpretations in their areas of responsibility, enabling them to obtain a better understanding of orebody morphology. Three- diniensional analysis provides an excellent method by which review of ore targets both in the underground and mine lease exploration areas can he made. As each new find of mineralisation enters the system and hopefully extends the mine life, the opportunities for further mineral exploration in Broken Hill area by Pasminco are enhanced.

Jan 1, 1997

By L M. Foster, J R. Kellett, G A. McMah

The Great Artesian Basin (GAB) contains one of the largest reserves of fresh water in the world. The volume in storage is enormous, being estimated at nearly 65 000 million megalitres (ML). Development of this resource, dominantly for the pastoral industry, began in the late-1800s and quickly accelerated. With exploitation of the resource, artesian pressures declined almost as rapidly. This loss of head is a result of the total discharge from the basin and much of this discharge is waste of water. The waste through uncontrolled bores and inefficient distribution systems still amounts to about 75 per cent of all discharge. However, the volume in storage has hardly been depleted. The major concern is the effect of withdrawal on artesian pressures. Due to the size of the Basin, the relatively flat gradients and low permeability, the movement of water through the aquifers is extremely slow and independent of recharge. Hence, the normal concepts of sustainable yield (ie discharge should equal recharge) cannot be applied to the Basin as a whole as travel times do not allow for the effect of recharge to be seen away from the outcrop areas within management timeframes. The large volume in storage, though, can provide an extensive buffer to the impacts of temporary water needs. This effect should be considered when assessing the acceptability of fixed life projects such as mines and the extracted volumes from their operations. Identifying a sustainable yield involves balancing the acceptability of the economic, environmental and social costs with the associated discharge and fall in head, to arrive at an acceptable balance.

Jan 1, 2003

Recycling of Process Water in Sulfides Processing and Flotation Selectivity

Sep 13, 2010

By T Hayward, G Lane, M Phillips

In December 2004 Phu Bia Mining Ltd commissioned Ausenco International Limited to conduct a feasibility study for its Phu Kham copper-gold project located in Laos. The feasibility study for a mining and processing operation treating 12 Mtpa of ore averaging 0.56 per cent copper and 0.25 g/t gold to produce an anticipated annual average 200 000 t of concentrate containing 25 per cent copper was completed in early 2006. The plant design incorporates a single processing line and includes a gyratory crusher, overland conveyor, coarse ore stockpile, SAG and ball mill grinding circuit, flotation circuit including regrind and three stages of cleaning, concentrate dewatering and concentrate load-out facilities. The Phu Kham copper-gold mineralisation comprises two principal styles: stockwork-disseminated and banded-massive sulfide within skarn limits. Primary copper in both mineralisation styles occurs as chalcopyrite and secondary copper sulfide minerals. Skarn includes the copper and gold mineralisation contained in pyrite, silicate, magnetite and haematite skarns, and in quartz-pyrite altered sediments. Both the stockwork-disseminated and banded-massive sulfide ores contain relatively high proportions of pyrite relative to the copper and gold mineralisation. Thus, the flotation metallurgy of the Phu Kham orebody is characterised by the need to reject a high proportion of the pyrite during differential flotation to yield a concentrate grade of approximately 25 per cent copper. The rejection of pyrite is accompanied by the rejection of some copper and gold and can result in modest metallurgical recovery. Consequently, the greater the pyrite content, the lower the expected copper and gold recoveries. The relative pyrite content is expressed on the basis of sulfur:copper ratio. For Phu Kham ores, the sulfur:copper ratios are in the range eight to 14 on a blended annual basis, but can be greater than 20 in the skarn components. Higher grades of copper and gold are also present in the skarn mineralisation. The design concepts for the concentrator were influenced by the need to provide a low capital cost approach for the project due to the relatively low grade of the ore and the modest metallurgical recovery. The concepts used to minimise capital cost whilst retaining operating and maintenance flexibility are discussed, together with the metallurgical challenges imposed by the high pyrite mineralisation.

Jan 1, 2007

Parallel lenticular orebodies occurring at the C.S.A. mine of Cobar Mines Pty. Ltd. are mined by mechanized cut and fill stoping over the full strike length. Access is provided for each stope lift from an inclined drive adjacent to the orebody. Mobile drill jumbos mounting hydraulically-operated booms are used for drilling upholes which are subsequently charged with ANFO explosive.Close control of drilling has been found essential for good back conditions and to ensure optimum fragmentation.Broken ore is transported from the face to the main ore pass by rubber-tyred, diesel-powered, load-haul-dump units. Initially, the units trammed ore to the main pass via the incline drive. As the stopes advanced and the lead distances increased, stope passes were developed in the wall rock and raised concurrently with each stoping lift. The passes terminate in drawpoints and production loaders are used to transport ore from the drawpoints to the main ore pass system.Two parallel ore pass systems have been developed to cater for both copper and copper-zinc ores. These systems terminate above a 48 in. by 60 in. jaw crusher. The crushed ore is conveyed to a traversing rock box and thence to one of two crushed ore bins adjacent to the main hoisting shaft. A loading station conveyor is interlocked with the winder to provide automatic ore hoisting.All phases of ore handling have been mechanized as completely as possible. Results to date indicate this policy has been vindicated but highlight the need for tight operating control and close liaison between operating and maintenance personnel.

Jan 1, 1969

Investigation on Multicomponent Semi-Autogenous Grinding

Sep 13, 2010

The purpose of any feasibility study is to determine whether a particular investment or management program will enhance shareholder wealth by, for example, producing an economic return in excess of the cost of equity capital.The threshold rate of return conventionally used in gold feasibility studies is higher than the cost of equity capital, meaning that some viable projects are wrongly described as being sub-economic with their development deferred.Is the industry failing to fully realise its potential? Aside from important technical considerations that determine the cost of exploiting inground inventories, feasibility studies need to incorporate expectations about future gold prices, exchange rates, interest rates and tax rates.Rather than revert to speculation, insights from capital markets give a rigorous framework in which these parameters can be determined for feasibility purposes. Separate questions sometimes, and then inadequately, addressed by feasibility studies include: ò Is it optimum? Many projects are expanded soon after project commissioning - what does this say about the quality of the initial feasibility study? Moreover, does the rate of extraction really matter? ò What is it worth? Although feasibility studies are designed to address viability rather than valuation, such studies are never- theless used by the industry as further evidence that the equity markets have got it wrong again! More likely the problem is with the financial slide rule being used. ò Can it be debt financed? The bankable feasibility study has entered the vocabulary of the gold mining industry but what does it mean? Does it matter anyway how the project is to be Financed?

Jan 1, 1991