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By Chander S

Properties of surface films on chalcopyrite and pyrite differ due to variations in the mechanism of oxidation of the two minerals. In the case of chalcopyrite the first step in the oxidation is the release of iron as ferric ions, which hydrolyse depending upon conditions prevalent in solution. The iron oxide/hydroxide layer formed by hydrolysis of ferric ions is quite porous and easily detachable from the surface of chalcopyrite. When the surface oxide layer is detached a sulphur-rich layer is exposed making chalcopyrite hydrophobic. The thickness and properties of the sulphur-rich layer determine its flotation response, both in the absence and presence of collectors. In the case of pyrite, on the other hand, iron is released as ferrous ions which require much higher pHs to hydrolyse. These ions remain adsorbed on the surface of pyrite making the surface hydrophilic. When the iron species are complexed with chelating agents such as ethylene diamine tetra acetic acid, pyrite was hydrophobic. Siderite forms in the presence of carbonate ions, which might be present in several flotation systems. Siderite nucleated on isolated sites at the surface. The presence of such a precipitate is likely to influence the interaction of pyrite with various reagents thereby altering its flotation behavior. To determine the mechanism of oxidation, kinetics of oxidation of chalcopyrite and pyrite was studied using several electrochemical techniques, namely, cyclic voltammetry, polarisation and impedance spectroscopy. Floatability of the minerals was investigated by measurement of contact angles on mineral electrodes and by Halimond tube flotation. Impedance spectroscopy was especially useful for estimating various properties of surface film for both the minerals. Properties such as charge transfer resistance, porosity, and capacitances of the surface films on the two minerals are compared under several conditions of oxidation. These properties were found to be a strong function of the rate and the extent of oxidation.

Jan 1, 1993

Subsidence issues associated with historic mine workings have highlighted the need for enhanced geotechnical management of the Martha pit over the remaining life. In conjunction with a detailed analysis of pit slope issues a comprehensive geotechnical management plan has been developed at Martha and is being used as the basis for development of similar plans in other Newmont operations.   This paper covers the geotechnical issues facing the Martha operation and the development and application of the management plan.

Jan 1, 2004

By H A. Linn, K Winn, C W. Lee

The Q-slope method for rock slope engineering was developed to enable engineering geologists and rock engineers to rapidly assess the stability of excavated rock slopes in the field and make optimal adjustments to slope angles as rock mass conditions become apparent during construction of road cuts or benches. An empirical relationship between Q-slope and long-term stable slope angle is now supported through over 500 cases studies from Asia, Australia, the Americas and Europe. This paper presents about the stability analysis by first-ever applying Q-slope method on abandoned quarry wall in Singapore. The 30 m high rock slope which is composed of monzogranite rock was severely damaged by blasting operation. As the rock slope is intended for public view the objective was to retain the natural outlook and without any artificial support application thus manual scaling was carried out to clear the loosed rock blocks. In the end stable slope angle of clean rock face is determined once again by Q-slope method.

Nov 29, 2022

In presenting the paper, Mr. Davey quoted subsequent work which yielded k, at miscibility gap composition, of about 50.We can confirm the authors' findings for k j 300 for nearly pure tin to k 2 about 50 (average 47) from our own experience and from repeat experiments on materials described by the authors, at 1150°C.During laboratory-scale trials we also found confirmation of the authors' view that it is more difficult to reach equilibrium from the high-iron (in slag) side than from the low-iron (high-tin) side. Working from the high-iron side tends to yield results that point to a high k, leading to optimistic values of iron/tin ratio in final slags. In practice the smelting of a tin concentrate, unless it is exceptionally low in tin and high in iron, must yield initially a tin-rich slag and therefore equilibrium can only be reached from the "tinny" side.

Jan 1, 1967

By Kikuta K

ISP (Imperial Smelting Process) produces zinc and lead simultaneously from zinc and lead sulphide concentrates and recovers copper and precious metals into a lead bullion. The strength of sinter is important to keep permeability in the shaft of the Imperial Smleting Furnace. The residual sulphur content of the sinter is also important as it causes metal losses into slag. The paper describes an investigation into the sintering operations to improve sulphur elimination and sinter strength. The micro structure of the sinter and the effect of the blast rate, sintering temperature etc have been studied.

Jan 1, 1993

The objectives of this paper are to introduce the International Code of Practice for Risk Management of Tunnel Works and to illustrate to the participants of the 13th Australian Tunnelling Conference 2008 how the insurance industry would like to see the future of tunnelling insurance. Tunnel construction projects have suffered large losses over the years as can be shown from various loss examples and a list of major losses over the last ten to 15 years. Since the consequences of insufficient risk control had to be borne by insurers, these losses have heightened the need for improved and adequate risk management measures so that insurance cover can also in future be provided for this hazardous industry sector. Observations are made as regards to the prevailing trends in the tunnelling industry, which contribute to the increase in risk and have adverse consequences for the insurance industry. To find a solution to this dilemma various options are examined with the suggestion of a Joint Code of Practice for Tunnel Works being agreed by all stakeholders, which would become essential to secure future insurance protection for such project work. The British Tunnelling Society has, in cooperation with the Association of British Insurers, developed such a code, which the International Tunnelling Insurance Group has now adopted for global application in international markets. The content and concept of this code is explained to establish a framework of understanding and applied risk management principles for tunnel works. This initiative also has the support of the International Tunnelling Association and the International Association of Engineering Insurers. The international application of this new code is demonstrated with a few examples, which also includes Australian projects. It is the aim that this code forms in future part of the insurance coverage for tunnelling works in order to put this risk segment on a more sustainable basis. For that reason the insurance industry is seeking the support of all stakeholders of tunnelling construction projects.

Jan 1, 2008

By Valenti M

A by-product of the lead smelting operations at BHAS is a copper-lead matte typically containing 35% copper, 38% lead and 12% sulphur. A hydrometallurgical treatment process has been developed for the treatment of this matte to recover copper as cathode and results in a lead-sulphur residue which is recycled to the lead smelter. A commercial plant with a nominal capacity of 4000 tpa utilising this process was commissioned during 1984. This plant has been shown to be capable of producing copper cathode at rates approaching 4000 tpa over short periods of time.

Jan 1, 1989

In Australia we usually define "resource" in purely material terms, and rarely relate it to intellect and human capacity. We look at the sheer abundance of our natural resources and are satisfied with the feeling that we don't really need-to rely on using our brains. Certainly our country is fortunate to have the mineral resources it does, but in many ways Australia's worst enemy is its "lucky country" syndrome because we tend to underutilise the great resource we have in the capacities of our people. Raw material exports will undoubtedly continue to contribute a major share of our export revenue, but to harness the riches our country has to offer most effectively we need the vision and planning necessary to bring together our material and human resources. There is a need not only to find, exploit and process our minerals economically, but to turn as much of our mineral wealth as possible into high value products before it leaves the country. In particular we must use our brainpower if we want to maximise economic benefit from and political influence over the strategic minerals which leave our shores. In the past we have been successful in finding and exploiting minerals because our mining industry has been in the forefront of private sector research and development. But if Australia is to have an advantage over other mineral rich countries in insulating itself from the effects of cyclical swings in commodity prices, then the future of the industry must lie even more in technological sophistication rather than depending. on such considerations as size and location of mineral deposits. To survive, our mineral industry must have the foresight and resourcefulness to make its own luck. There are two keys to increased efficiency in exploration and production and in further processing methods: enhancement of the skills of the workforce and continual improvement of R&D.

Jan 1, 1986

It is a great privilege to be invited to give this address at this centenary conference. A centenary is a time for recollection, for celebration and for looking ahead. The AusIMM has much to celebrate and many things to recall. I hope in this address to make some useful comments about Australia's future (and mindful of but not forgetting New Zealand), looking ahead for 25 years or so, and the mining industry's role in that future.

Jan 1, 1993

By Klenowski G, Gilmour G. A

The Metropolitan Water Supply, Sewerage and Drainage Board, Perth, has recently con- structed two major sewerage tunnels in the metropolitan area and a further one is under construction. These tunnels were constructed in sand, sandstone and limestone. The Tamala Limestone is a Pleistocene calcareous dune sand which now varies in com position from loose sand to cemented rock. Investigation techniques included surface mapping, auger and diamond core drilling, seismic refraction geophysics and mechanical testing. The variable nature of the ground caused difficulties in all aspects of the investigation, particularly in core recovery and seismic work. The Beenyup Tunnel, 2.25m in diameter and 3440m long was excavated with a Dosco TBM 1800 machine and shield with precast concrete Charcon Universal bolted segment lining. The Burns Beach Sewer Tunnel, 1.27m in diameter and 860m long was hand excavated with precast reinforced concrete lining pipes jacked continuously behind an excavation

Jan 1, 1981

By Mutton B. K

A systematic approach to the collection, presentation and application of structural geology data is employed in the extraction of narrow en echelon Ag-Pb-Zn orebodies by rut and fill stoping at Mount Isa. The aim is to locate, document and predict areas of adverse ground thereby enabling adequate ground support to be installed in advance of production mining. The important structural features are identified and their relevance illustrated by case histories of previous failures. The methods of collection, documentation and application of data are discussed.

Jan 1, 1977

By Lightfoot BW, Bultitude-Paull J

The Sirosmelt top submerged lancing system has many applications in the smelting of base metal and complex materials. It has particular advantages for smaller scale smelting and the treatment of recycle materials in smelters where its low capital and operating costs and its operational flexibility are of immediate benefit. The system can be fueled by oil, gas or coal, as well as by mixtures of fuels. For many applications, the use of coal as a fuel has operating cost advantages over oil and gas, but conventional pulverised coal feeding systems entail very large capital expenditure and this militates against the use of coal. The methods available for improving on conventional technology for coal firing of Sirosmelt systems are discussed and operating experience with alternative systems are outlined. The use of coal as a reductant in the Sirosmelt system is also discussed.

Jan 1, 1987

By Pollard D, Meadows N

The presence of impurities which are electropositive to zinc in acid zinc electrolyte causes changes to deposit morphology and reduced current efficiency. Glue may be added to control some impurity effects, but assaying for animal glue concentration is difficult and seldom done. Measurement of the activation overpotential for zinc deposition by cyclic voltammetry is used in some plants to monitor electrolyte quality and control glue additions.The deposit morphology and current efficiency of zinc deposition from commercial electrolyte were investigated for various glue additions in the presence of increased levels of antimony. Cyclic voltammetry was investigated as a method of optimising glue additions in the presence of antimony.Scanning electron rnicroscopy showed deposits characteristic of the impurity element present and the glue addition rate. Cyclic voltarnmetry measurements showed some correlation between current efficiency and activation polarisation potential. The importance of using tankhouse electrolytes where results are to be related to tankhouse operation was noted.

Jan 1, 1988

The effects of changes in sintering bed height, coke fuel, suction and basicity on sinter productivity, physical strength and mineralogy were determined. It was found that, for a given iron ore, there is a narrow -coke range which maximises sinter strength, irrespective of bed height (in the range 300 to 500 mm) or basicity (in the range 1.2 to 2.2). Increases in bed height, at a constant coke level, improved the physical strength of the sinter. Productivity increases were obtained by increasing the sintering suction but, at coke levels other than the optimum, these *ere somewhat offset by the decrease in sinter physical strength. At basicities higher than 1.2 (i.e. 1.6, 1.8 and 2.2) there was a narrowing of'the size range of product sinter, with a decrease in the percentage of top size material, and a decrease in the amount of fines produced. Changes in coke, bed height and basicity exert major effects on sinter mineralogy, while the Nagoya index was mainly influenced by cote and bed height Changes.

Jan 1, 1975

By L M. Lobato, J C. S Seoane, F J. Baars

The Carajßs Province presents several volcano-sedimentary sequences that comprise the Itacai·nas Supergroup. The rocks represent bimodal volcanism, and clastic and chemical sedimentation in relatively unstable basins subject to recurrent structural events with subsidence and volcanism. The Grpo Parß Group represents one of these sequences with mafic volcanic rocks that enclose discontinuous jaspilite lenses, with development of large high-grade orebodies (Fe >65 per cent). This unit is named the Carajßs Formation and presents peculiar characteristics compared to other iron districts in the world, thereby departing from the classic Lake Superior or Algoma iron formation types. Owing to the dense vegetation, lack of outcrops and harsh landscape, the structural analysis of the district can only be accomplished by combination of regional field work, detailed structural work on the open pits, and remotely sensed image interpretation, in this case Landsat ETM7, JERS-1 images and the SRTM digital terrane model. The regional trend of the several sequences of the area is approximately N-S and the structure is dominated by a flattened flexural fold system with axes moderately dipping WNW, intersected by several strike-slip faults subparallel to their axial plane. The Serra dos Carajßs represents an s-shaped synform-antiform pair, herein named the Carajßs Fold. This regional structure is partially disrupted by the Carajßs Shear Zone that divides it in the northern (Serra Norte) and the southern (Serra Sul) Ranges and also probably prepared the terrane with the development of pathways for mineralising hydrothermal fluids forming large high-grade massive iron bodies. Syntectonic granitic bodies played an important role in the structural evolution of the area as well. They caused localised ductile flattening deformation and thermal contact metamorphism in surrounding terranes. The Estrela pluton, for instance, was responsible for the discontinuity of the regional trend between the Serras do Rabo and Leste. The Carajßs Province is regionally the upper crustal product of a very shallowly eroded dome-and-keel geometry of Neo-Archaean volcano- sedimentary units intruded by syntectonic calc-alkaline intrusives and overlying pre-existing infracrustal rocks. The lithostructural data suggest continental-margin back-arc basin development and closure in an oblique collision belt, with N-S shallow crustal shortening, parallel to the inferred pre-existing strike of the stratigraphy.

Jan 1, 2005

By Sorentino C

Mineral valuation may appear to be a special field of financial valuation when in fact it is a subset of general investment decision theory. The only significant difference in mineral valuation is that in the case of valuing an on-going mineral asset, ie a mine, often there is no initial capital outlay involved. One is required to determine what the mineral asset as it stands is worth. But this is the same problem as determining the maximum one could pay today and not incur a loss over the life of the asset. In other words one needs to determine the Net Present Value (NPV) of the asset. The two most widely used discounted cash flow methods, NPV and Internal Rate of Return (IRR) came of age with the rapid adoption of the personal computer and spreadsheet programs. The two methods are directly related as the IRR is a special case of NPV. NPV measures the absolute increase in real wealth that can be expected from a certain investment, which makes it particularly suitable for mineral asset valuation, but ignores the efficiency of the investment. In contrast, IRR gives the expected efficiency of the investment but ignores the increase in wealth aspect. IRR has two serious theoretical weaknesses; multiple IRR's and a very rigid assumption about the rate of return of reinvested proceeds, plus if no initial equity expenditure is involved there is no IRR. The choice of the ""hurdle"" rate can also be a problem and in certain circumstances one can obtain different rankings of mutually exclusive projects using IRR and NPV. Although NPV and IRR supposedly measure financial risk, in fact they only address a very narrow area of risk, namely the time value of money given the real discount rate. They side step the issue of what the real discount rate should be and varying degrees of risk. The classical way to establish the real discount rate is to use the weighted average cost of capital.

Jan 1, 1994

By Hill KC, Foster DA

Methods for ore reserve estimation are classified. The amount of information needed to asses ore reserves is analysed. Reference is made to gold sampling. Consideration is given to nugget effects and ore reserve estimation procedures where they are significant. Computer methods are discussed

Jan 1, 1997

By Shinnosuke U, Zhang HE

In this paper, it is shown that the higher the pre-activation concentration of copper ions in pulp, the larger the adsorption amounts of copper ions and xanthate on arsenopyrite surface, and the better the arsenopyrite flotability in strong alkaline medium. On arsenopyrite pre-activated with cupric ions, the xanthate adsorption density in strong alkaline medium is approximately equivalent to that of cupric ions. It is therefore concluded that an amount of copper ions adsorb on arsenopyrite surface first, and then an amount of xanthate can (and only can) adsorb dependently on the surface active sites produced by these adsorbed copper ions on the mineral, so that arsenopyrite is kept rather flotable and is hardly separated from pyrite even in very strong alkaline medium. Selectively wiping out the surface copper active sites on arsenopyrite is the key point of successful separation of pyrite from arsenopyrite. According to this theory, a new 'SZLI' (know-how) method was recommended to satisfactorily deal with the difficult separation.

Jan 1, 1993

Dartbrook (Hunter Valley and South Bulli (Southern Coalfield) Collieries provide contrasting settings for gas sorption studies. Gas compositions at Dartbrook are dominated by carbon dioxide, with minor methane, while those at South Bulli are dominated by methane with minor carbon dioxide. Total gas contents at Dartbrook are also significantly greater than those at South Bulli. The two collieries are also contrasted in terms of coal composition and mining environment. Dartbrook Colliery mines a relatively small sectionb(4m) of very thick seam (up to mapproximately25m); the coal is vitrinite-rich, high volatile bituminous. South Bulli mines most of the seam thickness, with coal being an intertinite-rich, medium volatile bituminous coal.Coal samples have been collected from in-seam gas drainage holes for evaluation of relative gas desorption rate (methane versus carbon dioxide). Following adsorption isotherms, petrography, chemistry (proximate and ultimate analysis) and pore structure analysis (carbon dioxide surface area, mercury porosimetry). Bomb desorption studies indicate different behaviours for methane desorption at these two collieries desorbed gas compositions at South Bulli show a small enrichment in methane content. The opposite is observed at Dartbrook. Both collieries show enrichment in CO2 in the residual content. Adsorption studies show marked variation in adsorbed gas contents for methane and carbon dioxide at each colliery and between collieries. These variations are related to differences in coal pore structure, chemistry and Petrology.

Jan 1, 1998

By S Fidler

Underground coal gasification (UCG) is a process by which coal is converted in situ to a combustible gas that can be used as a fuel or chemical feedstock. The process has been used in commercial-size projects in the former Soviet Union for more than 40 years, while significant national research programs have been undertaken in the United States and Western Europe. The Chinchilla UCG project is located at a site southeast of Chinchilla in Queensland. The UCG operation commenced in December 1999. A controlled shutdown of the process was initiated in January 2002 and successfully completed in April 2003. The process is currently under conservation and ready for restoration of gas production for commercial use in the near future. Groundwater plays an important role in the gas formation process during UCG. Most of the process water required for chemical reactions is usually derived from the coal seam itself and from surrounding aquifers. If insufficient water is available for chemical reactions the UCG gas will contain reduced concentrations of combustible components, and conversely, excessive water influx into the process area would cool down the reactor and thus limit the energy available for gas production reactions. Because of the importance of groundwater in the gasification reactions, and the potential to contaminate groundwater if the process is not correctly controlled, it is essential to predict and to control the groundwater influx into underground gasifiers during and after underground gasification. Control of groundwater requires a thorough understanding of hydrogeological conditions in the vicinity of the gasifier in order to be able to predict inflow rates, and constant monitoring throughout the process of water production rates and groundwater pressure in the coal seam and adjacent aquifers. Hydrogeological testing and groundwater monitoring in the vicinity of the UCG operation commenced six months in advance of its initiation. Monitoring of groundwater pressures in the vicinity of the gasifier have also been undertaken using vibrating wire piezometers installed in the coal seam at varying distances from the gasifier. This paper presents the results of the hydrogeological testing and groundwater quality monitoring carried out at the site, which show that it is possible to operate a UCG process without uncontrolled impacts on groundwater.

Jan 1, 2003