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By Blattner P

The Late Miocene gold-silver bearing epithermal system at Waihi has some close similarities in its paleo-thermal and -geochemical structure with modern, volcanic-hosted geothermal systems such as Ohaaki-Broadlands. At Waihi an extensive braided quartz vein system is enveloped by hydrothermally altered andesites with minor tuff breccias and tuffs. A main stage of vein filling consists of multiple phases of chalcedonic quartz and fine to medium grained quartz, which are accompanied by pyrite, sphalerite, galena, chalcopyrite and acanthite below the base of oxidation. Platy calcite is present locally. Fluid inclusion studies indicate that the main stage quartz was deposited at temperatures of 189¦-273¦C from dilute (T¦ of -0.1 to -1.0¦C) fluids that were locally boiling. Homogenisation temperature Th versus T. data points lie within the field enveloped by dilution and boiling/gas loss paths determined for the Ohaaki geothermal field, and indicates that the parent hydrothermal fluid for the Waihi epithermal system had a similar composition to that at Ohaaki, ie 0.2 wt% equiv NaCI and 3.3 wt% equiv CO2. The hydrothermal alteration mineralogy and the isotopic composition of vein calcite indicate that the hydrothermal fluid contained relatively high concentrations of CO 2' as at Ohaaki. Oxygen isotope analyses of main stage quartz range from 6.1 to 11.6 %o and of vein calcite from 2.29 to 9.4% . Calculated d8Ow.½ values for the hydrothermal fluid that deposited the main stage quartz range from - 2.0 to -5.7%c , with a trend to less negative values with depth. They are similar to those in the deep chloride fluid in active geothermal systems with a substantial fluid throughput. A high fluid throughput at Waihi system is also evident from the extensive high intensity hydrothermal alteration and large volume of quartz deposited in the vein system.

Jan 1, 1995

By Lacy JC

Human habitation of the Pacific Rim began when mankind began migrations out of its place of origin in the Rift Valley of Central Africa c. 4million years ago. This migration was erratic and largely controlled by advances and retreat of the various Ice Ages which, while limiting advances in areas of intense cold, at the same time aided migration thro-ugh the creation of land bridges as ocean levels declined during periods of glacial advance (Fig.l).Mankind began its trek to the Pacific from Africa across India then north into southern China and south into Indonesia (Fig.2). In part, these migrations stimulated early technological develop-ments to fulfill needs and adapt to environmental conditions; thus, these nomads developed stone and bone tools, animal skin clothing and the use of caves and other simple shelters. The earliest evid-ence of mankind's use of fire can be found at Zhou-koudaian near Beijing, c.400,000 BP.From China, the completion of the Pacific Rim's population can be attributed to the last Ice Age that dropped the ocean level by more than 300 feet and created land bridges about 40,000 BP allowing migration across the Bering Strait into Alaska and to Australia from Indonesia. The American migration reached Mexico about 30,000 BP, and by 6000 BP the occupancy of the Pacific Rim was complete when the first human settlers reached the southern tip of Chile.

Jan 1, 1990

By A S. Venkatesh, A Das

The Precambrian iron ore of Singhbhum-North Orissa region of eastern India occurs as part of the horseshoe-shaped broad synclinorium known as the Iron Ore Group (IOG) of rocks, which hosts the most important iron ore deposits in India. The Jilling-Langalota iron ore deposits are part of the IOG. Detailed mineralogical characterisation of different ore types has been carried out using transmitted and reflected light microscopy. Scanning electron microscope-energy dispersive spectroscopy (SEM- EDS), X-ray diffraction (XRD) and X-ray fluorescence (XRF) have also been used with a view to test the amenability of these ore types for beneficiation requirements. It has been observed that haematite, martite and goethite are the main iron-bearing minerals. Kaolinite and quartz are the major gangue mineral phases. Considerable mineralogical, textural and compositional variations have been observed among the different ore types. Characterisation data reveals that the massive and hard-laminated ores are of higher grade with very few interlocking textures having haematite and martite as major mineral constitutents. The soft-laminated lateritic and friable ores are relatively low-grade varieties containing various proportions of impurities with complex interlocking textures. The soft-laminated and lateritic ores are porous in nature and contain friable oxide and hydroxides of iron along with kaolinite, gibbsite and quartz. The occurrence of kaolinite, gibbsite and hydrated oxides along the cavities and weaker mineral planes of haematite and martite has been observed. The friable nature and high alumina content of these ores are attributed to these secondary phases. The nature of these ores is responsible for producing large amounts of alumina-rich slime during mining and handling operations. Suitable beneficiation schemes have been recommended for each type based on detailed characterisation investigations on these ores.

Jan 1, 2007

The earliest suggestions that some metallic ore deposits might have resulted from seafloor volcanic exhalation seem to have been those of Elie de Beaumont in 1847 and Henry de la Beche in 1851. In 1885 Tinoco, and Bouglise and Cumenge, independently investigating-.the manto copper deposits of the Boleo district of Baja California, proposed that these had formed on the seafloor by precipitation from "hydrothermal submarine emanations". Some twenty years later the Japanese geologists Kukuchi and Tsujimoto (1904) put forward the idea that the Kuroko ore- bodies were seafloor volcanic sinter deposits and in 1919 this was re-affirmed by Ohashi. In 1909 the English geologists Thomas and MacAllister postulated a similar origin for some of the gold deposits of Mount Morgan in Queensland. Between the wars the great European economic geologists Niggli and Schneiderhohn both clearly recognized a class of seafloor hydrothermal deposits. The idea rose again immediately after the Second World War in a very clear statement by Hegeman in 1948, which was followed by contributions by Ehrenberg and Kraume and their co-workers on the submarine volcanic origin of the Meggen and Rammelsberg orebodies in 1954 and 1955 respectively. In 1955 the present writer, quite unaware of early or contemporary work on volcanic exhalative ore deposits, proposed a volcanic sedimentary/diagenetic origin for the stratiform base metal ores of SE Australia. In doing so the writer emphasized the probable importance of island arc volcanism, suggested that some "metallogenetic regions" of ancient terrains were in fact old island arc systems, that the composition of the ores might be related to the composition of the associated volcanic rocks and that such ores would be tied to volcanic stratigraphy. Ideas on relations between volcanism and stratiform ore genesis have thus been evolving over.a period of some 140 years and, beginning with the observations on Baja California in 1882, work round the rim of the Pacific has made an important contribution over a period of more than 100 years.

Jan 1, 1987

By Kazis JV

The beneficiation of fine coal has been the major problem facing the coal preparation engineer in recent years. The influence of clay slime, particle size and reagent type are but a few of the many factors that affect the recovery of fine coal. Laboratory test work has indicated that substantial increases in recovery could be achieved by improvements in technology in all these areas. Unfortunately, in most cases this technology has not carried through to the operating plants.

Jan 1, 1984

INDEX OF CONTENTSBlast Furnace SlagsForehearth AccretionsConverter SlagsConclusionsIllustrationsCOMPOSITION OF SOME COPPER SLAGS FROM PORT KEMBLASamples of copper slags from the Port Kembla Smelter of the Electrolytic Refining and Smelting Co. of Australia, Pty. Ltd., have been submitted for mineragraphic examination, with reference to the mode of occurrence of copper in them. The samples included (I) blast furnace slags, (H) a forehearth accretion, and (IH) converter slags. 1. BLAST FURNACE SLAGS Four series of samples of blast furnace slag have been submitted. The. chemical compositions of the several slags are shown in Table 1. Analyses Nos. 1 and 2 are of samples of slowly or normally cooled slag, taken from the slag dump, Analyses Nos. 3 and 4 are of samples comprising slowly or normally cooled slag, together with granulated slag from the same melt.

Jan 1, 1949

By D Craw, P Lindsay, B Peake

The geochemical properties of Kaiata Mudstone and Brunner Coal Measures are evaluated in order to determine their suitability for placement at the proposed Cypress and existing Stockton mines. Correct scheduling of this waste material is needed in order to prevent sulfide oxidation and the generation of acid rock drainage. The Kaiata Mudstone has both acid generating and acid neutralizing properties. Results from this study and previous research from Kingett Mitchell Ltd (2003), indicate that within the Kaiata Mudstone sulphur content decreases with distance away from the Brunner Coal Measure/Kaiata Mudstone contact, while calcium carbonate content increases; sulphur values range from 0.33 to 4.23 wt %; and the acid neutralizing capacity ranges from 0 to 10.4 wt %. The Brunner Coal Measures have a low capacity to neutralize acid and sulphur content is variable ranging from 0.25 to 3.5 wt %. Appropriate control measures are therefore needed for the Brunner Coal Measures and any Kaiata Mudstone within close proximity to its contact. Tests have been undertaken to develop a rapid field or laboratory procedure to define the potentially acid-forming from the non-acid-forming Kaiata material. Results indicate that paste pH, Net Acid Generation (NAG) and Carbonate Bomb tests are suitable. Results from the Carbonate Bomb Test show a strong relationship with the Acid Neutralizing Capacity (ANC) and the Net Acid Production Potential (NAPP), indicating that this method may efficiently determine non-acid forming material in the field within fifteen minutes. Ongoing research includes kinetic column and shake extraction tests. These tests will quantify what trace elements could be leached from the waste rock and provide information on the usefulness of alkaline producing products such as Bauxsol, Limestone and Cement Kiln Dust.

Jan 1, 2004

By Dixon D. R, Sparrow G. J

Pressure leach liquors from the pressure oxidation of a bulk flotation concentrate prepared from a complex Cu-Pb-Zn sulphide ore were treated to remove iron, either by pressure oxidation (the Hematite process) or with particles of magnetite (the Magnetite process), followed by cementation of various metals with zinc dust to obtain a purified solution from which zinc was electrowon. Satisfactory iron removal was achieved by both processes after neutralisation to pH 4.5 or 5.5. Pressure oxidation of the liquor at 200¦C and 690 kPa oxygen overpressure, conditions similar to those of the Hematite process used in the zinc industry, resulted in the precipitation of the iron as hematite. With the Magnetite process, an iron hydroxide was precipitated onto magnetite at atmospheric pressure and ambient temperature and removed by a magnetic separation step. The performances of both these processes for the removal of iron are compared. It is concluded that the Magnetite process offers considerable cost savings. Other impurities, in particular arsenic, were also removed with the iron in both processes. Cementation at pH 5.2 and 85-90 ¦C with 3.5 g/L zinc dust reduced the levels of copper, cadmium, and nickel to a satisfactory level and subsequent electrolysis in a laboratory cell gave an acceptable deposit of zinc.

Jan 1, 1989

By Guo-Zheng J

This paper describes the risk management strategies adopted to control unstable slopes in the east open pit of the Daye iron ore mine. Extensive experience has been developed over the last 35 years in the management of pit wall instability resulting in the successful excavation and reinforcement of pit slopes over 350 m in height.

Jan 1, 1994

By Madgwick J. C

A novel, microaerobic, heterotrophic microbial leaching system for manganese dioxide is described. Mixed natural microflora were enriched by addition of sugars and crude plant nutrItIOnal supplements. Between 84 and 104 mg MnH was solubilized per gram sugar at I per cent (w/v) concentrations for fructose and galactose in the presence of 0.03 per cent w/v dried microalgae (a Chlamydomonas species). Some 42 per cent soluble manganese was dissolved by microbial action on MnO, (3 per cent (w/v) pulp density) using a 10 per cent (w/v) molasses growth substrate.

Jan 1, 1983

Backfil ling of excavated Sub Level Open Stopes has been underway since March 1989 and as at December 1992 some 1 100 000 cubic metres of Cemented Aggregate Fill have been placed. During these three years significant developments in fill quantities, types and cost have taken place.Operational improvements have reduced the quantity of Cement Aggregate Fill by 40 per cent. These results have been achieved by:ò rescheduling stopes,ò designing smaller primary stope, and ò use of uncemented rockfill.Unit cost for Cement Aggregate Fill have fallen in the order of 50 per cent through:improving fill hole reli ability,simplified barricade construction procedures, reducing the cement content,ò substituting dune sand for deslimed mill tailings, ò improved maintenance at the Backfill plant, and ò renegotiated site freight agreement.This paper will review the historical developments of backfill use at Olympic Dam.

Jan 1, 1993

By Lavers G

Factors governing the dissolution of nickel and iron in pentlandite and pyrrhotite concentrates from Mt. Windarra were studied for aqueous solutions at normal temperatures and pressures. The effects of dissolved dioxygen, carbon dioxide, hydrogen ions, and chloride ions are described. The direct reaction of aerated water wiili pyrrhotite is much faster than with pentlandite, and reaction rates are proportional to the dissolved dioxygen concentration. In both cases divalent metal sulphates are produced initially. The subsequent oxidation of iron(II) to iron(III) and its oxolation produces acid solutions which rapidly attack both minerals. The presence of carbon dioxide or chloride ion has little effect on these rates.

Jan 1, 1976

Utah's Blackwater mine began operations in 1967. The four CQCA mines controlled by Utah followed over the period 1971 to 1979. Project feasibility studies for all these were based on open cut mining to overburden depths of 60 metres, with typical project lives of 12 to 16 years, depending on reserves Further studies, initiated after the mines had started, showed that continuation of open cut mining beyond the 60 metre highwall was viable. In 1973, the Deep Stripping Project (DSP) was launched to define the scope for stripping deeper, to determine what the additional equipment needs might be, and to pu forward proposals for a full scale trial system. The project commenced at grass roots with a literature survey, proceeded through a sequence of equipment evaluation, specification, design and manufacture to the commissioning of the Goonyella BWE system. Studies are continuing to assess the future deep stripping requirements for all Utah's Bowen Basin mines.

Jan 1, 1983

By Bourne R. W, Smith T

This paper presents initial findings of a project examining novel processes for the treatment of refractory sulphidic gold concentrates. Non-oxidative roasting of such concentrates for 12 hours at 750¦C resulted in the finely disseminated gold agglomerating to form discrete grains. The pyrite and arsenopyrite decomposed to form pyrrhotite, whilst the labile sulphur and arsenic driven off was collected on a condenser as a mixture of elemental sulphur, metallic arsenic and various arseneous sulphide compounds. As a result, the cyanide solubility of the gold contained in sulphidic refractory gold concentrate from the Emperor mine in Fiji improved from 54.5 per cent to 98.4 per cent; from the Fimiston mine in WA (65.2 per cent to 96.6 per cent), from the Windarra mine in WA (69.6 per cent to 91.3 per cent), from the Harbor Lights mine in WA (20.4 per cent to 60.7 per cent), and from the Wiluna mine in WA (12.6 per cent to 28.0 per cent). The non-oxidative roasting conditions have not been optimised for each of these minerals. Subjecting the non-oxidatively roasted minerals to mild oxidative acidic iron sulphate pressure leaching (with typical temperature of 100¦C and typical oxygen overpressure of 500 kPa) to remove iron and so further liberate finely disseminated gold, resulted in the cyanide solubility of the gold exceeding 96 per cent for each of these five concentrate types (including those from Harbor Lights and Wiluna). Thiourea leaching of the sulphur-rich residues under acidic conditions resulted in remarkably high gold extractions being achieved. These novel processing options need to be optimised, and their economic viability established.

Jan 1, 1991

By Woodcock J. T

A sulphide ion selective electrode (ISE) is suitable for control of sodium sulphide additions in flotation because it has a rapid response to changeS in S2- concentrations, can indicate -low concentrations at differentpH values, suffers from few interferences, and is robust enou'gh to use in a pulp. Three sulphidization techniques were studied using the lSE electrode for measurement and/or control of S2- levels. Metallurgy was assessedfrom concentrate grades and copper recovery.With slug additions of sodium sulphide, sulphidizing conditions were poorly defined and reproducibility tended to be poor. Although acceptable metallurgy could be achieved by multiple additions, sodium sulphide consumption was high.Controlled potential sulphidization readily gave good metallurgy. The optimum potential of the lSE for sulphidizing was about -500 mV versus SCE, but depended on sulphidization and flotation times; suitable times were3 and 5 min respectively for three to five stages. Application of this technique to previously untested ores gave good metallurgy in a first test in spite of variation by a factor of three in the sodium sulphide requirements ofthe ores.Simultaneous sulphidization and flotation was satisfactory when conducted at an lSE potential of -450 mV versus SCE. Mixed cha!copyrite-oxide copper ores responded satisfactorily.Besides optimizing sulphidization conditions it is also necessary to optimize xanthate additions (e.g. by measuring xanthate residuals).

Jan 1, 1978

Tumbling mills have been used in the minerals indusu) for occr WO years, with the design changing little, but the size of the individual pieces of equipment increasing significantly with the lowering of head grades, and the push for greater

Jan 1, 1997

A rotating disc geometry was used to provide a uniformly accessible surface for a kinetic study of copper cementation with zinc in sulphate solution. For copper concentrations of the order of 10 p.p.m., a porous, adherent deposit is formed on the zinc surface and this has a significant influence on the reaction rate. When the specific mass of deposit is less than about O· 35 mg/cm2 the surface may be considered as smooth and the rate is described by simple convective counter diffusion of zinc and copper ions through a laminar diffusion boundary layer to the deposit-solution interface. In the presence of additional deposit, the diffusional mass transfer rate is increased by increased surface roughness.The rate under these conditions is first order, with the degree of enhancement independent of further increases in the specific deposit mass. The enhancement in rateis, however, directly related to the initial mass flux and the species involved in the reaction.Preliminary work showed the same mechanism to apply to cementation from chloride solution, solutions of high zinc concentration, and cementation of copper with iron..

Jan 1, 1970

New Zealand's obligations under Kyoto protocol New Zealand's economic and emissions profile Use of energy and electricity generation in New Zealand World energy supply Coal's rule in the world today Coal and New Zealand Future energy needs in New Zealand Clean coal technologies

Jan 1, 2002

Single particle breakage tests have been used by a number of researchers to investigate some salient features of the complex comminution process. The characteristics of the common single particle breakage tests such as single impact, double impact and slow compression tests are examined and the results from these tests are compared. A comparison of the results from single particle breakage tests with grindability and ball mill tests is given. Application of the results from single particle breakage tests to modelling industrial comminution processes is described. The necessity for further research into single particle breakage tests to develop a simple but comprehensive technique for estimating the breakage characteristics of ores is discussed.

Jan 1, 1986

By R Barrette, V Lawson

Over the last year at Clarabelle Mill, three circuit reconfigurations were implemented. One circuit reconfiguration, æA CleaningÆ, was initiated due to a furnace failure at the smelter complex, and two of the circuit reconfigurations, æincreased copper (Cu) separationÆ and the æInterim IsaMillÖ circuitÆ, were seen as opportunities to increase cash flow through the mill. A Cleaning and the Interim IsaMillÖ circuit took advantage of engineering design already completed for a major capital project. The engineering for each was modified, as needed, and construction of the required portions of the capital project was fast tracked. The increased Cu separation circuit change used existing test and plant equipment to increase the plant Cu concentrate production. Implementation of the projects required teams that included operations, maintenance, technical support, project management and capital project resources. This paper discusses the business reasons driving the changes and the forethought or synergies with other work, which made them a success, and what was learned through each project. CITATION:Taylor, A, Lawson, V and Barrette, R, 2012. Responding to the challenge - Necessity driving circuit change, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 247-254 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012