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By Dip L. B

This paper describes the new legislative regime that will apply to the regulation of the minerals industry in New Zealand.The reform of New Zealand's minerals legislation was initiated in January 1988 when the Minister for the Environment, Rt Hon Geoffrey Palmer, announced the Government's intention to review all the major laws governing New Zealand's resources. The Resource Management Bill is scheduled for introduction to the House in December 1989 and its date of enactment is scheduled for June 1990.

Jan 1, 1990

By Denholm W. T, Rankin W. J

The reduction of zinc from lead blast furnace slags using hydrogen was studied at 1300¦C as part of a laboratory investigation of zinc fuming. To perform the experiments, 300 g "spent slag" was melted in a crucible. Hydrogen was then injected into the slag through a lance and fresh blast furnace slag was added regularly in small quantities over a period of 40 minutes. Zinc added in the fresh slag was reduced and the zinc level of the bulk slag attained a steady state value of between 1 and 9% after about 10 minutes, depending on the gas injection rate. Because of the high reactivity of hydrogen, bulk supply of hydrogen to the slag was the rate limiting step at the flow rates used and it is believed that the gas-slag reactions in the system were at equilibrium. A partially/stabilized zirconia cell with a Ni/NiO reference electrode was immersed in the slags during the experiments and the steady/state oxygen potentials of the slags were measured. By using the experimental oxygen potential values and calculated values of the steady state concentrations of zinc in the offgas, the activity of ZnO in the slags was calculated from the Gibbs's free energy change for the reaction:

Jan 1, 1989

By A L. Randriamanjatosoa, G Small, C Greet

In flotation simulation models, the effects of pulp chemistry other than pH are often ignored and reduced to particles hydrophobicity or contact angle, neither of which can be measured readily in real time in an operating plant. The flotation response of a given sulphide mineral is known to be influenced and can be improved by changing the chemical characteristics of the pulp during grinding and flotation. The on-line measurement of pulp pH, potential, dissolved oxygen, temperature and oxygen demand of a process stream was completed with the PCM® (Pulp Chemistry Monitor) developed by Magotteaux in this study. The data generated together with relevant plant operating parameters were used to construct an empirical model and simulate the metallurgical performance of the ore. The same approach was also applied to laboratory flotation tests data using various grinding media types. The flotation models better fit the actual data when the chemistry of the pulp is taken into account.CITATION:Randriamanjatosoa, A L, Greet, C and Small, G, 2018. Effects of pulp chemistry on plant and laboratory flotation modelling, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 423–432 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

South Crofty's ventilation network is large and complex. Of the total exhaust air quantity 40% enters the mine by leakage routes through old workings, this air carries high concentrations of radon gas and results in the mine becoming a classified work place under the Ionising Radiation Regulations 1985. Improvements in the control of the ventilating air and dilution by increased air quantity have reduced the average contamination to aelow-0.2 WL. The major part of the radon originates from ground water inflows and from concentrations of radium within the mine with direct emanation from rock surfaces being negligible. Of 600 kBgs-1 total radon leaving the mine 93% cannot be accounted for from known and accessible sources.

Jan 1, 1988

By J Czerwinski, M Kasper, M Wyser, N Heeb

The VERT project 1993 - 1998 laid the technical foundation for curtailing the emission of fine particles from diesel engines at Swiss underground workplaces. The targeted maximum was 100 ¦g/m3 EC. Extensive laboratory and field investigations demonstrated that this specification is only attainable with modern diesel particulate filter (DPF) systems that almost eliminate particles in the entire lung penetrating size range from 20 nm to 2.5 ¦m. In January 2000, Switzerland mandated compulsory particle filters in underground workplaces, particularly in tunnelling, irrespective of engine age, size and type. After the implementation, the particle concentration in the respiratory air was below 40 ¦g/m3 EC, compared to earlier values of up to 750 ¦g/m3 EC. Deployed DPFs have proven filtration rates of 99 per cent in the entire size range of alveoli intruding particles. The DPFs are as durable as the engine, suffer no ageing and require minimal maintenance. The failure rate is below three per cent annually. Of the 6000 retrofitted construction machines in Switzerland, about 400 are deployed underground. Prerequisites for this quality are a sophisticated certification procedure, electronic monitoring of DPF operation and meticulous periodic exhaust gas inspection of the engines.

Jan 1, 2005

Zinc sulphide concentrate from Mount lsa, Australia, was leached in acidic sulphate-chloride solutions using ferric ions as oxidants under atmospheric pressure. The parameters of temperature, particle size and concentrations of ferric and chloride ions were evaluated.The shrinking core model can be used to describe the leaching which is limited by the electrochemical processes in the initial leaching stage, and by both surface reaction and pore diffusion processes subsequently. The apparent activation energy measured in the initial leaching stage is 49 kJ/mole over the temperature range 60 to 90°C.About 99 per cent of the contained zinc in the -45+38 µm particle sample dissolved at 90°C in a 0.5 M H2SO4/0.1 M Fe2(SO4)3/0.8 M NaCI solution within two hours. Some nine per cent of sulphide sulphur was oxidised through to sulphate; the remainder was convened to elemental sulphur.The mixed sulphate-chloride system has advantages over separate chloride and sulphate systems due to the low reagent cost, high leaching rate and possible selective leaching of zinc sulphide concentrate with high lead contents.

Jan 1, 1994

By S T. Jarvis

Colliery spoil is the major constituent of colliery spoil ærockpasteÆ which has been used to infill abandoned limestone mines in the West Midlands of England since the early-1980s. The other constituents of rockpaste are pulverised fuel ash, lime and water. A key property of the rockpaste is its ability to flow within the mine workings over considerable distances before setting. This paper describes the work carried out to identify suitable sites as sources of colliery spoil for making rockpaste and goes onto consider the flow properties of the material and the monitoring methods used on-site. A full-scale trial comprising infilling a 6600 m3 section of an abandoned mine was conducted prior to the infilling of the Littleton Street Mine which had a volume of about 500 000 m3. As well as describing the methods used for monitoring the movement of rockpaste material, a description is also given of a dip-meter developed specifically for the purpose of measuring the level of paste in the mine. This paper shows how a colliery spoil based paste has been successfully used for infilling abandoned mine workings. The monitoring systems developed for use in the two case studies presented in this paper are now being used extensively for infilling other abandoned mine workings. To-date over 11 mines with a total volume exceeding two million cubic metres have been backfilled.

Jan 1, 1998

Tasker (1985) has detailed the accepted practices for constructing polygonal blocks of influerrce in the estimation of ore reserves. Further he suggests that users might fall into traps such as omission or overlap when determining the area of influence for each sample point.As an example of these types of errors Tasker (1985) describes under "Coverage ofthe Area" how 25 per cent of the exploration area will not be included in an equiangular triangular grid where hexagonal blocks of influence are used.The introductory suggestion of Tasker (1985) of "incorrect procedure" by Rudenno (1983) (and Armstrong (1983)) reiterated around the Figure 2a of Tasker (1985), is based on the brief description of the polygonal area of influence by Rudenno (1983). That description is not too different from that given by King, McMahon and Bujtor (1982).

Jan 1, 1985

By S Hapugoda, A Edenton, L Lu

The blast furnace cohesive zone has a profound impact on hot metal productivity and quality, fuel consumption, operational stability and the lining life of the blast furnace. The high temperature properties of ferrous burden materials determine the configuration and location of the cohesive zone and have therefore attracted particular attention. While numerous standard testing methods are in use to assess the quality of ferrous burden materials for the blast furnace, these simple tests are generally conducted under fixed conditions, which often represent the extreme situations encountered by the burden materials in the blast furnace. Furthermore, none of these simple tests provides information on the high temperature properties of the burden materials, such as their softening and melting properties. CSIRO is equipped with a fully computerised testing facility to characterise the high temperature properties of ferrous burden materials under realistic conditions similar to those encountered in the blast furnace. This paper will first review the CSIRO softening and melting test method and then discuss the softening and melting properties of a variety of blast furnace burden materials, including sinter, pellets and lump ore, and their implications for blast furnace operation.

Nov 8, 2021

Chlorination of organic matter by direct injection of chlorine gas or hypochlorite has been investigated metallurgically worldwide with little understanding of the basic chemistry of the passivation mechanisms in- volved. In this paper, chlorination of carbon is attributed to oxidation-reduc- tions, resulting in surface halogenation of graphitic or amorphous carbon. It is proposed that chlorine and carbon interact to form thin coatings of chioro-carbon complexes that block the adsorption of gold cyanide com- plexes, thus passivating the gold adsorption sites of carbonaceous matter. Analytical, spectrographic, microscopic and electron-optical methods have been applied to demonstrate the proposed mechanism of chlorine-carbon bonding, as well as to evaluate the advantages and limitations of chlorination in the pretreatment of refractory carbonaceous gold ores.

Jan 1, 1991

By Zamel G. I, Zenari L. P

Technological developments in modem Tunnel Boring Machines (TBMs) and associated back-up equipment are offering significant alternatives for mining operators to consider, in the selection of equipment for coal mine development drifts, roadways, longwall gate roads as well as metalliferous mining declines and development drives.Greater flexibility in handling variable ground conditions, muck disposal and radius of turn as well as advance rates, are just some of the areas where modem TBMs can accomplish the flexibility that mine operators require to achieve cost-effective developments.Compact TBMs are achieving this acceptance because of the fundamental design of a shielded machine containing electrics and hydraulics within the forward shell, ability to achieve tight radius of curvature and grades, and ability to provide highly flexible support systems to meet all possible ground conditions.However, a single TBM design will not suit all mine developments, as each development method - while having common goals with all mine developments - will also require certain unique criteria to be fulfilled.

Jan 1, 1993

By D J. Bradshaw, E M. Wightman, C L. Evans, B Triffett

During the commissioning phase of Prominent Hill, periods of reduced recovery were experienced with higher-grade ore blends. This was unexpected and as part of the process to identify the cause, surveys were conducted in May 2009, with two different ore blends (copper grades: 1.94 per cent Cu (blend 1) and 2.49 per cent Cu (blend 2)). Metallurgical performance was assessed in terms of rougher recovery and grade with consideration of both pulp and froth effects. In addition, hydrodynamic measurements (gas hold up, bubble size, superficial gas velocity) as well as measurements of bubble load and top-of-froth grade were taken during the surveys and full mineralogical assessment of selected streams completed to characterise the nature of the differences. The metallurgical results showed that the lower performance was obtained with blend 2 which contained the higher amount of chalcocite and was higher-grade. Analysis of the survey data showed that for both ore blends more than half of the copper loss occurred in the +38 ¦m size fractions. Almost 30 per cent of the copper in the +38 ¦m fractions that reported to the rougher tails during processing of blend 2 was liberated compared to less than five per cent for blend 1. Additionally almost 60 per cent of the copper in the +38 ¦m fraction of blend 2 was chalcocite compared with approximately 20 per cent in blend 1. This paper discusses the sensitivity of the chalcocite-to-surface chemistry effects causing marked reductions in recovery either through reduced pulp recovery or froth phase (detachment) effects. The reagent suite and operating conditions were subsequently changed and the recoveries increased substantially and the sensitivity to ore changes eliminated. It should be noted that subsequent optimisation work, which focused on recovery improvement, has led to copper recoveries of over 90 per cent being achieved.CITATION:Bradshaw, D J, Wightman, E M, Evans, C L and Triffett, B, 2012. Characterising the reasons for the difference in performance of two ore blends in early processing at OZ Minerals Prominent Hill Operation, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 273-278 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By R Sharpe, M D. Hannington, K Perrin, K Simpson, S Petersen, H Gibson, N Augustin, K Lackschewitz, T Monecke

Semi-massive to massive sulfides were drilled in a shallow-water (630 m) hydrothermal system in an island arc volcanic setting at the Palinuro volcanic complex in the Tyrrhenian Sea,Italy. Overall 12.7 m of sulfide minerlisation were drilled in a sediment-filled depression in a water depth of 630 - 650 m using the lander-type Rockdrill 1 drill rig of the British Geological Survey. The longest drill core recovered consists of 4.9 m of continues semi-massive to massive sulfides + sulfates with abundant late native sulfur overprint. Metal enrichment at the top of the deposit is evident in some cores with polymetallic (Zn, Pb, Sb, As, Ag) sulfides overlying more massive and dense pyritic ore. The massive sulfide mineralisation at the Palinuro volcanic complex contains a number of unusual minerals, including enargitefamatinite, tennantite-tetrahedrite, stibnite, bismuthinite and Ag-sulfosalts, that are not commonly encountered in mid-ocean ridge massive sulfides. In analogy to epithermal deposits forming on land, the occurrence of these minerals and the abundance of native sulfur suggest an intermediate to high sulfidation state for the hydrothermal fluids during deposition, implying that the mineralising fluids were acidic and oxidised rather than near-neutral and reduced as those forming typical base metal-rich massive sulfides along mid-ocean ridges. Oxidised conditions during sulfide deposition are likely related to the presence of magmatic volatiles in the mineralising fluids that were derived from a degassing magma chamber below Palinuro volcanic complex. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By P B. Hills, R J. Walton

Narrow vein tabular orebodies are prone to mining induced seismicity. The Tasmania Mine is a complex example of a seismically active tabular orebody, where the contrasting material properties of the host strata and of the orebody itself, serve to exacerbate the seismic response. Analysis of a continuous record of seismicity over a period of seven years has provided significant insight into the fundamental mechanics of the rock mass. Understanding seismicity to permit safe extraction of the orebody has been enhanced by instrumentation of rock mass behaviour in response to mining and mining induced seismicity. It is the purpose of this paper to explore that understanding in respect to the adoption of an alternative down-hole Avoca stoping method for use in particular circumstances.Intensive instrumentation of the Tasmania Mine over a period of four years has provided insight into the behaviour of the rock mass in response to extraction of the narrow vein orebody it encompasses. A range of instruments have been installed in clusters or single installations in order to measure changing stress conditions and the impact of those changes on the rock mass and the reinforcement system.Instruments are often installed in very close proximity to active production stoping. While it has been possible to observe the impact of the mining and mining induced seismicity at very close quarters, instruments installed in these locations are vulnerable to damage and consequently, the level of instrumentation is high. Instruments are continuously logged, typically on a six hourly basis coinciding with the end of regular blasting times. The response of the instrumentation to changed rock mass conditions is considered against the background of development and production blasting and against the seismic record to assess the viability of downhole Avoca stoping.CITATION:Hills, P B and Walton, R J, 2012. Continued observations of rock mass behaviour in response to stoping at the Tasmania mine, Beaconsfield, Tasmania, in Proceedings Narrow Vein Mining 2012 , pp 169-178 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022

By M E. Malmstr÷m

Quantification of site-specific sulfide oxidation rates is crucial to accuracy of prediction of, for example, the environmental impact of a mine site. Sulfide oxidation reactions are reportedly increased by bacterial mediation; determination of abiotic and biotic weathering rates thus requires the establishment of sterile control samples. However, sterilisation often involves exposure of samples to extreme conditions that may alter the physical, chemical, or mineralogical characteristics of the tailings and hence affect element release rates. The impact of various sterilisation techniques, common and novel, on the element release rates from tailings from the Kristineberg site, northern Sweden, has been investigated. Batch weathering experiments indicated that the different methods of sterilisation (autoclaving, heat treatment, ethanol/heat treatment, application of antibiotics, rinsing with distilled water, and γ-radiation) did not greatly affect long-term element release rates. Long-term experiments (>30 days) are thus to be recommended for establishment of weathering rates. Sterilised and untreated control samples showed similar element release rates after ~100 days of experiments; possible explanations include that microbial oxidation is not important under our experimental conditions (Po2 = 0.2 atm, pH ~2.3, 22¦C, 0.01 M HNO3, no additional nutrients).

Jan 1, 2003

By S Blackburn, T Veasey

The physical and mechanical properties of rock can be measured by a variety of standard tests, and studies have shown that there should be a fundamental connection between breakage in comminution and rock æstrengthÆ. The current study aims to develop the ring-loaded strength test, used as an industry standard for the characterisation of brittle ceramics, for determination of comminution behaviour from exploration borehole core samples. The test procedure is simple, reproducible and can yield 250 separate measurements from a one metre length of drill core. The effects of material grain size and fabric on the degree of scatter of results have been investigated with respect to the ring-loaded strength test. This study has also compared the ring loaded strength to the chevron bend test used to determine the Mode I fracture toughness. A wide range of rock materials have been studied and with further work it is conceivable that an operational work index could be obtained directly from exploration drill cores tested via the ring-loaded disc test.

Jan 1, 2000

By J M. Palin

Hydrothermal scheelite precipitated in fault-veins at Paradise, Bonnie Jean, Davidson's and Glenorchy mines display chemical variability involving REE patterns that are transitional between two end-member types. Type I is a MREE-enriched pattern with no or a small positive Eu anomaly. Type II is a flat to MREE-depleted pattern with a strong positive Eu anomaly. The chemical inhomogeneity of these scheelites can be explained by a model of fractional precipitation of REE, with preferential removal of MREE from the fluid during precipitation of scheelite. Irrespective of the mechanism responsible for scheelite precipitation, the source of dissolved constituents is different for scheelites from the Paradise Mine. Bonnie Jean, Davidson's and Glenorchy scheelites formed from LREE-enriched fluids whereas Paradise scheelites precipitated from fluids that were lower in LREE. These inferred fluid characteristics cannot be linked unambiguously to specific source rocks in the region, but could suggest that scheelite deposited in the Paradise fault-vein reflects a more mafic source of REE possibly greenschists, whereas the REE in scheelite from the other mines suggest a more felsic source.

Jan 1, 2003

By Henley R, Harris L

High resolution airborne magnetic and radiometric data have been shown to optimize exploration for epithermal gold deposits in the vicinity of Charters Towers, northeastern Queensland. The radiometric data allow extrapolation of poorly outcropping geology to provide a cost-effective mapping technique, even at exploration scales (eg. 1:25,000). At a regional scale (eg. 1:100,000) the magnetic data reflect the regional tectonics and divide the area into domains for the application of different genetic models. For example: 1. the Ravenswood Batholith is characterized by multiple intrusions dating from Ordovician to Permian age. The polarity of the magnetic anomalies implies an age for the intrusions and indicates a deposit style for exploration. 2. extensional and wrench tectonics along the northern margin of the Drummond Basin are interpreted from the magnetic data and indicate favourable blocks for detailed exploration. Genetic exploration models may be tested in favourable environments by the recognition of geophysical signatures. These signatures reflect structural, lithological and alteration patterns arising from controls on ore deposits and can be applied at regional or detailed scales.

Jan 1, 1989

The purpose of this work is to determine the equilibrium-state of the aqueous-solution which is produced by the leaching processes, including natural weathering of pyrite minerals. The latter can lead to acid-mine-drainage (AMD). The ferric iron species (Fe3+) resulting from bacteria-catalysed oxidation of ferrous iron (Fe2+), in the presence of water and air, is known to bring about steady-dissolution of minerals chalcopyrite (CuFeS2), sphalerite (ZnS), pyrite (FeS2), and so forth. Good-aeration, relatively high-porosity and sufficient bacterial activity tend to promote leaching in waste-rock-dumps. The composition of the aqueous-phase that accumulates in the pore-space (or in open-pits) is of practical interest as it would strongly influence the leaching of both sulfide and non-sulfide minerals. Since the reactions among the various ionic species occur relatively fast, the solution-phase may be regarded as approaching a state of virtual-equilibrium and it is possible to determine by computation the respective concentrations of the many dissolved species. For the Cu-Fe-H-O-S system, these species may include: H+, Fe2+, Fe3+, Cu2+, HSO4-, SO42-, OH-, CuSO4o, H2O, Fe(OH)+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, Fe(SO4)+, Fe(HSO4)+, Fe(HSO4)2+, and Fe(SO4)2-. The aqueous-system which may be constituted from appropriate mole-quantities of H2SO4, FeSO4, Fe2(SO4)3, and CuSO4 is in fact the result of various natural processes (reactions) and due respect must be accorded to the extents of these reactions. The present model computes the equilibrium molalities of the foregoing ionic and neutral aqueous species, using the iterative equilibrium constant method that ensures strict-adherence to charge-balance and elemental molar-balance constraints. The dissolving sulfide-minerals (FeS2, CuFeS2) consume Fe2(SO4)3, H2O, and O2 and yield FeSO4, H2SO4, and CuSO4 while the aqueous-phase tends to become progressively acidic (declining pH) reflecting the gradual increase in the extents of sulfide-dissolution reactions. The equilibrium-state of the solution-phase is computed for specific set of values for the extents of respective reactions. The temperature and pressure of the system are 25¦ C (298.15 K) and 101.325 kPa (1.0 atm), respectively. The mica-like minerals such as the biotite [H2K(Mg,Fe)3Al(SiO4)3] tend to consume much of the H2SO4(aq), with the extracted K+, Mg2+, Fe2+ and Al3+ ionic species accumulating in the solution. The precipitation of the jarosites (potassium, hydronium, or ammonium) contributes to the removal of ferric and ferrous species from the solution-phase. In the present work, the emphasis is on predicting the compositions of the aqueous- and condensed-phases with advancing time or increasing æextent of reactionÆ. The results of such calculations are compared to published data on raw AMD (acid-mine-drainage).

Jan 1, 2008