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IN this paper it is proposed to present certain features of operating practice at the Port Pirie works of The Broken Hill Associated Smelters Proprietary Limited, in the smelting in a blast furnace of lead ores carrying a high concentration of zinc.The subject matter selected for presentation is:(i) The effect of zinc on lead blast-furnace operations, together with an outline of the methods adopted in actual practice in dealing with the zinc problem.(2) Development of the height of tuyere above the bottom of the jacket, and the extension of the tapping interval and the combined effect of both factors upon the lead content of blast furnace slag.It will later be seen that one phase of the investigation carried out in connection with the effect of zinc on blast-furnace operations was largely responsible for the decision to increase to a marked degree the height of the tuyere above the bottom of the jacket.Due to this interdependence, it has been considered advisable to deal with the two features above mentioned.The high concentration of zinc in the lead-bearing materials smelted at Port Pirie has brought with it those troubles which are associated with zinc in the smelting operation.In the early stages of the history of The Broken Hill Associated Smelters Pty. Ltd. the trend towards increasing cost for labour, fuel, and stores, etc., rendered it necessary to increase the lead content of the charge, and reduce to a minimum the quantity of barren flux used.

Jan 1, 1931

Broken Hill is situated at an elevation of approximately 1000 ft. above sea-level, on the Barrier Ranges, in the State of New South Wales, Australia. It is approximately 700, 280 and 330 miles from the ports of Sydney, Pirie, and Adelaide, respectively.The summers are usually hot and dusty, with a recorded maximum shade temperature of 114° F. The rainfall averages approximately 9 in. per annum.

Jan 1, 1932

By M I. Jeffrey, J A. Rumbal, D M. Hewitt

Ion chromatography utilising an anion exchange column and UV detection has facilitated an improved understanding of sulfide mineral leaching in cyanide solutions. By analysing for sulfide, sulfite, thiocyanate, thiosulfate and metal cyanides it is possible to show that chalcocite dissolution is a non-oxidative process in which copper cyanide and sulfide ions are formed in solution. Further, the homogeneous oxidation of the sulfide ions by dissolved oxygen is slow, but catalysed by a surface of lead sulfide or pyrite. Polysulfides may also be formed as an intermediate oxidation product and these undergo further reaction to produce thiocyanate, thiosulfate and sulfite. The leaching of copper from a pyrite concentrate sample is shown to be rapid, and accompanied by significant iron dissolution; however, the iron is not believed to be from pyrite, pyrrhotite or chalcopyrite. The rate of iron leaching and cyanide consumption is reduced by maintaining low cyanide and high oxygen concentrations. Preoxidation or the addition of lead(II) ions does not reduce the iron dissolution from this pyrite concentrate.

Jan 1, 2007

This paper presents the descriptions of a final year geological engineering project at the Royal Melbourne Institute of Technology involving the correlation of borehole and mapped ground conditions and their statistical Analysis.

Jan 1, 1994

By Walker G. S

A study of the crystalline materials on or near the surface of freshly made or "green" superphosphate granules and mature, "set" superphosphate granules was undertaken using X-ray diffraction, X-ray mapping, scanning electron microscopy and electron probe micro analysis techniques. Calcium sulphate (CaSO4), calcium sulphate hemihydrate (CaSO4 1/2H20), and mono calcium phosphate monohydrate (Ca(H2PO4)2H2O), were the only crystalline species present in the "green" superphosphate.In the set superphosphate however, additional compounds were present, namely complex iron and aluminium phosphates Ca(Fe,AI) H(HPO4hF2)2H2O, (Fe)3(H3O)H8 (PO4)6H2O and calcium sulphate dihydrate (CaSO4.2H2O).The complex phosphates tied up the major part of the Fe and Al in the system and were concentrated on or near the surface of the granule. An intimate mixture of CaSO4.2H2O, and CaSO4, along with the above mentioned complex Fe-AI compounds, crystallize close to the surface of the granule and cause the setting of superphosphate that takes place during storage.

Jan 1, 1980

This Department handles all ores prior to blast-furnacing, the object of the operations being to mix the lead-bearing material with fiuxes, eliminate sulphur from the mixture, and produce a homogeneous sintered product which is chemically and physically suitable for treatment in the blast furnaces.During the financial year ended the 30th June, 1937, the tonnage of charge treated was 458,960 tons, containing some 183,470 tons of lead and 8,504,000 oz. of silver.The quantities of the principal components of the charge treated were as follow:-

Jan 1, 1937

Creating Value and Improving Environmental Performance by the Recovery of Valuable Products from Tailings from the Athabasca Oil Sands in Alberta, Canada

Sep 13, 2010

The following paper on the development of processes for the treatment of crude ore, accumulated dumps of tailing and slime at Broken Hill, has been prepared by a committee of the Broken Hill Branch of the Australasian Institute of Mining and Metallurgy, with the object of recording, in chronological order, the developments of the various processes which have led up to the metallurgical practice of the present day.

Jan 1, 1930

By A Murphy, I Samsonova, N Eastwood, D Whittle

Part XI of the United Nations Convention on the Law of the Sea (UNCLOS or the Convention) (United Nations (UN) Division for Ocean Affairs and the Law of the Sea, 1982) establishes a comprehensive regulatory framework for the conduct of deep seabed mining (DSM) activities of mineral resources in the Area (defined in Article 1(1) of UNCLOS as ‘the seabed and ocean floor and subsoil thereof, beyond the limits of national jurisdiction’). Under that framework, DSM activities can only take place in the Area pursuant to an approved Plan of Work in the form of a contract with the International Seabed Authority (ISA) (the Authority), a 168-member international body created under UNCLOS to administer the Area. Private contractors can undertake DSM activities if they are sponsored by Member States of UNCLOS, providing a dual system of international and domestic regulatory control and oversight for activities in the Area.

Sep 1, 2024

THIS excellent volumetric method commends itself as a means of estimating the fineness of silver firstly, owing to the large number of possible impurities which do not affect its accuracy (these impurities include Cu-up to 70 % Au, Ph, Zn, Bi, Cd, Fe, Mn, Sb, and As); secondly, the method combines accuracy with speed. The above impurities are the only ones likely to be present in the B. H. A. S. Pty. Ltd. refined silver, and, with the exception of Cu and Au, the others, if present at all, would be well under 0.1 parts per 1000.Briefly stated, the method consists in the solution of the refined silver in HN03 , addition of ferric alum (indicator), and titration with an alkaline (either ammonium or potassium) thiocyanate solution until the brown ferric thiocyanate is formed, and gives a definite tint to the solution. The method is used at the Port Pirie smelters, and the outstanding feature in the method as there applied is the type of burette employed. This burette enables the operator to read 0.01 of a cc. with ease, whereas, with the ordinary burette fitted with a float, 0.05 of a cc., when a number of readings have to be taken, becomes very straining to the eyes. Moreover, waiting for the float to rise, and dislodging air bubbles from it, hinders rapid working.A description of the burette and fittings is appended with fig. 2. DETAILS OF THE METHODSolutions required are:a) Stock Solutions:(1) Ammonium thiocyanate, 40 grm. per litre of water; 30 litres are prepared and placed in a carboy with glass syphon attached.(2) Ferric alum, 250 grnl. per litre; two litres are prepared.

Jan 1, 1922

The mining industry, both here and internationally, is continually developing increasingly sophisticated software to compute mineral resource estimates, but these processes cannot compensate for a flawed geological interpretation of the geology of the economic commodity(s) concentrations. Quality assurance and quality control (QA/QC) is becoming increasingly common in association with the sampling and assaying practices within the industry. However, it is rare in the case of a geological interpretation associated with mineral resource estimation. Why? In the context of this paper, QA/QC relates to the use of statistical and graphical tools to show that the geological economic commodity concentrations have been appropriately domained. Domaining is essential to improve the chance of getting a mineral resource estimate right. Commodity value and acceptable concentration variation within a mineral resource can be ingredients that make mineral resource estimation difficult to get right. But it is possible to get it right a very high proportion of the time. It is more likely to occur when inappropriate data consolidation is minimised. In any case, inappropriate data consolidation is significantly reduced when the geological interpretation is strongly consistent with the data and it is demonstrable. To achieve quality global estimates of geological domain concentrations, it is essential that the geology of the prospect is understood sufficiently that the deposit is appropriately domained. Appropriate domaining occurs when sample populations are separated in such a way that only data in harmony with each other within the population contributes to the domainÆs concentration estimate. The paper will use four brief case studies to illustrate how QA/QC can be used to display data and validate the underpinning geological interpretation through its associated domaining to get it right when it comes to a mineral resource estimation.

Jan 1, 2007

By S Das

Deposit-10/11A is situated in the iron rich Bailadila region of India comprising haematite ore of average grade 65 per cent Fe. The deposit production line was commissioned in the year 2002 having a capacity of 5 Mt/a. The plant has the state of the art mineral processing equipments.The ore is transported from mines to crushing plant by means of dumpers. The ore is comminuted in two stages to get 150 mm top size product and this product is transported through conveyor system and is stored in silos as feed stock for beneficiation plant. In the beneficiation plant this crushed product is wet screened in two stages to produce a product of lump (-150 + 10 mm) and fines (-10 + 3.15 mm). The product of -3.15 mm top size is fed to primary classifier for a size separation at 150 µm. The resultant product (-3.15 mm + 150 µm) is dewatered and transported to fi ne ore product stock yard through conveyor system. The minus 150 µm material from classifier overflow is fed to cyclones (508 mm cyclone battery with an apex of 65 mm) for desliming at 45 µm and to recover ultrafi nes (-150 + 45 µm). The cyclone overfl ow slimes (-45 µm) along with water is treated in lamella thickeners to recover process water. The thickener underflow material is transported to tailing pond (discharge rate is 300 m3/h at a specific gravity of 1.4) by pumping through HDPE (high density poly ethylene) pipeline and the over flow water is being recirculated. The water requirement for beneficiation is approx 1.5 m3 per ton of ore.This paper aims at identifying and quantifying the factors that affect the overall plant performance (grade and recovery) during the different seasonal variations especially in the rainy season (mid-June to end October). The effect of seasonal variations on unit operations such as milling, classification, thickening and filtration are discussed. Specific cases are presented as examples and recommendations are formulated.

Jul 11, 2011

By W Dodson

Major ions, d18O and d2H and Carbon-13 concentrations in groundwater from 30 bores near an open pit iron ore mine were used to better understand the chemical evolution of groundwater in the aquifer. The relatively depleted d18O and d2H isotopes of groundwater from various depths suggest that groundwater is recharged from intense rainfall events, with little evaporative effect. The 300 to 500 mg/L increase of major ions relative to that of rainfall is due to evapotranspiration of rainfall during recharge. Geochemical mass balance modelling suggests that the evapotranspiration of rainfall during infiltration through the unsaturated zone varies over six fold from 20 to 130. This coupled with the dissolution of CO2 from the unsaturated zone and partial dissolution of carbonates and gypsum from Tertiary sediments and carbonates from the Wittenoom Formation accounts for the current major ion, d18O and d2H distribution in groundwater. Despite the relatively dissected morphology and steep hydraulic gradient the results of this study highlight the dominance of vertical flow relative to horizontal flow. The study also shows the dominance of rapid recharge by significant rainfall events as an important component of the water budget for east Pilbara aquifers.

Jan 1, 2009

By K Myers

Since the mid-1990s, the Chino Mine Facility (Chino) located near Silver City, New Mexico has been developing a closure plan with financial assurance to protect water quality, as required by State regulations. In February 2002, Chino and the New Mexico Environment Department (NMED) reached agreement on a closure plan; a closure cost amount of approximately $US 394 million ($A 591 million) was finalised in April 2003. Both the New Mexico Water Quality Act Regulations (1977) and the New Mexico Mining Act Regulations (1993) guided development of the closure plan and financial assurance amount. The process incorporated many years of correspondence, studies, negotiations and administrative hearings. The major technical issues focused on regrading slopes of the leach ore stockpiles and waste rock piles; cover systems; water treatment systems; and abatement of ground water contamination. The proposed financial assurance amount covers all closure costs and provides for perpetual water treatment.

Jan 1, 2003

By H Q. Zhang, M C Chai, W Fu, H Y Chen, L M. Wei, Q J. Yang

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Fozichong deposit – located in the south-western segment of the giant Qinhang metallogenic belt, South China – is a large-sized lead-zinc polymetallic deposit. This deposit contains two main ore districts, termed as the Guyi ore district in the north and the Hesan ore district in the south respectively. We present an integrated data set on sulfide minerals, fluid inclusions and stable isotope (H-O-S-Pb) geochemistry to better understand the features and genesis of the Fozichong deposit.Field and paragenetic relationships indicate three mineralisation stages forming the early (Po+Sp+Gn+Ccp+Py+Di+Ep+Qtz), middle (Sp+Gn+Ccp+Py+Ep+Chl+Qtz) and late (Gn+Sp+Py+Qtz+Cal) sulfide assemblages respectively. Mineral chemistry – particularly S/Fe and Co/Ni ratios in pyrite, Zn/Fe, Zn/Mn and Zn/Cd ratios in sphalerite and Pb/Ag ratios in galena – indicates a magmatic association for the sulfide minerals.Quartz and calcite coexisting with the sulfide minerals of various stages host abundant fluid inclusions. Quartz in the early stage contains two- or three-phase CO2-H2O and liquid-rich aqueous inclusions, which have homogenisation temperatures of 162~365°C and salinities of 2.9~17.8 wt per cent NaClequiv, whereas quartz and calcite from the middle and late stages are dominated by two-phase, liquid-rich aqueous inclusions that have slightly lower homogenisation temperatures (153°C~320°C) and much lower salinities (1.0~6.0 wt per cent NaClequiv). Hydrogen isotopes (dD = -59‰~-41‰), analysed using fluid inclusion waters from quartz and calculated oxygen isotopes (d18OH2O = -5.47‰~4.00‰) for the equilibrated ore fluids, indicate that the ore-forming fluids may have been sourced from magma and mixed with groundwater in the late stages. Sulfide minerals have d34S values of 2.3‰~4.3‰, consistent with a magmatic-derived source for sulfur. Lead isotopes (206Pb/204Pb = 18.592~18.794, 207Pb/204Pb = 15.648~15.864, 208Pb/204Pb = 38.909~39.580) confirm that lead and, by inference, zinc were mainly derived from magmatic rocks, with subordinate contributions from sedimentary rocks.Various lines of evidence support that the formation of the Fozichong deposit has close genetic association with the granite porphyry intruded in the late Yanshanian period (106 Ma), and it can be classified as a magmatic hydrothermal type lead-zinc deposit. We propose that the Hesan and Guyi ore districts may represent the proximal and distal products of a magmatic – hydrothermal system respectively.CITATION:Fu, W, Zhang, H Q, Chai, M C, Yang, Q J, Chen, H Y and Wei, L M, 2015. Genesis of the large-sized Fozichong lead-zinc polymetallic deposit, Guangxi, south China – constraints from the sulfide mineralogy, fluid inclusions and isotope geochemistry , in Proceedings PACRIM 2015 Congress, pp 609–614 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

The Matakan Unit of New Ireland, Papua New Guinea is a highly fossiliferous lagoonal deposit containing numerous coal pods and lenses. The unit is strati graphically part of the massive reefal Lelet Limestone of Miocence age. These organic-rich sediments have a high hydrocarbon potential as evident from microscopical observations as well as Rock- Eval pyrolysis data. The coal is varied in regard to dominant macerals, vitrinite being predominant in some parts and pollen and spores present in sufficient proportions to constitute a cannel coal elsewhere. The highly fossiliferous carbo as Rock-Eval pyrolysis data. The coal is varied in regard to dominant macerals, vitrinite being predominant in some parts and pollen and spores present in sufficient proportions to constitute a cannel coal elsewhere. The highly fossiliferous carbonaceous sedimentary rocks associated with the coal are rich in pyrite expressed in the sulphur content (19.7 - 22.8%). A high primary productivity and anoxic sediment pore waters or just above sediment - water interface have given rise to sufficient organic matter accumulations to yield a potential hydrocarbon source rock. Atomic H/C ratios of the coals are between kerogen type III and type II mainly, expressing the mixed nature of the coal and that of the associated sediments is type II. Early generated hydrocarbons (exsudatinite) have formed from pollen exines filling the pollen cavities and in places filling micro- fissures in the surrounding vitrinite.

Jan 1, 1987

By B Menzel, M Wlasenko, J Phillips

Yandicoogina (Yandi) open pit mine is located in the eastern part of the Pilbara region of Western Australia. It hosts pisolitic iron-oxide mineralisation distributed within a meandering paleoriver channel. The deposit is characterised by clays occurring as lenses, accretions, desiccation joint infill and voids in the pisolite ore. The irregular shapes and highly erratic distribution of these clay pods represent a serious challenge for grade control at this mine.The current grade control approach used at the Yandi mine is based on sampling of production blastholes on a 6 m X 6 m spacing. Their good spatial coverage, tight spacing and low cost make blastholes a very convenient media for grade control and ore-waste definition. However the potential downside of this grade control approach is poor sample representivity. An alternative grade control approach is to drill and sample using reverse circulation (RC) holes distributed on a 25 m X 25 m grid. This approach has been tested in Yandi mine and compared with the blasthole sampling approach for sample representivity. The impact of increased drill spacing on mining block predictions has been studied using a conditional simulation technique. Blasthole and RC samples proved to be similarly biased, underestimating Al2O3 and SiO2 grades and overestimating Fe grades, when compared to full cone assays. These results show that using RC drilling for grade control at the Yandi open pit will not necessarily improve the representivity of the grade control samples. However, increasing the grade control spacing to 25 m X 25 m will lead to more than 12 per cent of the selective mining unit (SMU) sized blocks being misclassified. This is approximately a two-fold increase in the number of misclassified SMU blocks in comparison with 5 m X 5 m spacing.

Jan 1, 2007

By G E. Smith, G N. Lye

Wall control blasting practices are necessary to reduce the impact of blasting on mine faces but can also have a significant negative impact on mine productivity and operating costs. The conventional practice in deep open pit mines is to use so-called trim blasts adjacent to pit walls. To provide burden relief these trim blasts have fewer rows than full production blasts and are fired to a cleared free-face; hence they are termed æunchokedÆ. This practice leads to scheduling constraints on the pit operations and can cause ore dilution due to excessive muckpile movement. The use of such trim blasts stems from the perception that increased wall damage results from æchokedÆ blasts. These concerns are based on the unproven assumptions that blast vibration levels and explosive gas penetration increase with increased blast burden and face confinement. This paper describes work undertaken as part of a major investigation into wall control blasting at the KCGM Fimiston Mine, Kalgoorlie, Western Australia. It details a study to assess damage effects due to blast burden. Borehole air pressure measurements and borehole video camera inspections were done behind a series of single blastholes drilled with varying burden distances, as well as behind a dedicated trim blast and a full production blast. It was found that the measured damage effects, including visible rock cracking, dilation, and the limited extent of gas penetration behind the blastholes, did not vary significantly with burden or blast type for the cases tested. This result was in complete agreement with detailed vibration measurements conducted by Blair and Armstrong (2001) during the study, which found that vibration was independent of blast burden. As a result of these investigations, changes to the blasting practices at the mine were implemented. Dedicated trim blasts and free-face blasting have been replaced by modified production blasts and the practice of æchokingÆ blasts has been introduced. This has resulted in a significant improvement in productivity and cost savings without compromising pit wall integrity.

Jan 1, 2001

By Sans H

The geostatistical Discrete Gaussian (DG) model is demonstrated to be capable of providing an effective means of implementing change of support for Enterprise-style mineralisation and thus providing reliable global recoverable resource estimates. At Enterprise, sample grade distribution proves to be highly positively skewed, therefore significant deskewing of the histogram and reduction of variance occurs when going from sample to block support. The DG model was experimentally tested in'the Southern Primary Zone (SPZ) at Enterprise, where high anisotropy ratios and pronounced short range structures are observed in variograms. The experimental test was run for a change of support for which the variance reduction was. approximately 60 per cent. This reduction is similar to that predicted by Krige's Relationship ('the volume-variance relationship') for the practical situation of a change of support from 5 m vertical blasthole samples to 3 m x 8 m x 5 m selective mining unit (SMU) blocks. The DG model was found to correctly predict the grade tonnage relationships for a wide range of cut off grades. The experimental test indicated that, given a representative histogram and variogram, the DG change of support provides a computationally efficient and practical means of reliably assessing global mineable resources at the early stages of a mining project. Further, it allows a range of selectivity strategies to be meaningfully and comparatively considered prior to mining.

Jan 1, 1995

By C. P. BATES

In November 1969, New Zealand Steel Ltd pioneered the commercial use of the SL/RN solid fuel direct reduction process to make sponge iron as a feed material for electric arc furnaces. Serious process problems with the use of green balls and coal injection were progressively overcome. The process was developed by New Zealand Steel along a radical route, of feeding the fine grained raw ironsand concentrate and coal directly to the kiln. Contemporaneously with this development of direct reduction, steelmaking process innovations were made that enabled the arc furnaces to operate successfully with the high volumes of acid slag.

Jan 1, 1980