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By A Nigam, K Biswas, R Sarkar

Because of the problems with 1st and 2nd generations of Advanced High-Strength Steels (AHSS), a 3rd generation of AHSS steels has become prominent and these steels have properties in between the 1st and 2nd generations of AHSS. However, although the 3rd generation of AHSS is a promising candidate as a replacement for its predecessors, there remain some challenges in processing these steels which are essentially medium Mn (Mn content ~ 5–7 wt per cent) and high Al (Al content ~ 1– 3 wt per cent) steels. The use of conventional casting powders based on the CaO-SiO2 system is unsuitable for high and medium Mn/Al steels. This work investigates the development of CaO-Al2O3- based mold fluxes for casting third-generation AHSS steel. Mold fluxes, with otherwise similar compositions but different C/A ratios, are tested and their crystallisation behaviour is examined using differential scanning calorimetry (DSC). A calcium aluminate phase having a composition Ca12Al14O33 was found to be the main crystalline phase in the mold fluxes. A decrease in crystallisation temperature was observed as the CaO/Al2O3 ratio increased from 1.00 to 1.33. The effective crystallisation rate constant exhibited an increase with decreasing crystallisation temperature, indicating a potential influence of nucleation rate on the overall crystallisation rate and suggesting an anti-Arrhenius behaviour in the crystallisation process of these mold fluxes.

Aug 21, 2024

By Christie A. B, Swain A, Brathwaite R. L

This study provides quantitative data on vein distributions within seven selected epithermal systems, four deposits hosted predominantly in rhyolitic rocks: Ohui, Wharekirauponga, Neavesville and Komata, and three major deposits mainly hosted in andesite: Martha Hill, Golden Cross and Karangahake. The technique of fractal analysis was used to help quantify vein distribution patterns. The fractal dimensions (D) obtained are related to the number of veins per metre, the degree of vein clustering, and vein thickness. An increase in any of these tends to increase the fractal dimension. It is the relative relationship of these parameters that is important for the characterisation of vein distributions, and the comparison of different deposits. Within the same systems, the rhyolites are characterised by lower vein thickness and vein density, but have a higher degree of vein clustering compared to the andesites. Sections that are deeper and more centrally located within the epithermal system and/or close to major structures, tend to have a greater degree of vein clustering, higher average vein thickness and density, and higher thickness to density ratios. This depth control is most pronounced in epithermal gold-silver systems because they have formed at shallow crustal levels where physico-chemical conditions change drastically both vertically and laterally. In addition to lithological and structural control at vein scale, deposit scale structure is of great importance in the deposition of economic mineralisation. Large open vein structures capable of sustaining high fluxes of hydrothermal fluid, favourable for the formation of large, high-grade gold deposits, are best developed in andesite sequences.

Jan 1, 1995

By J Hall, A Gallardo, M Strizek

Mineralogy and coproponents Sino Iron, International Minerals and Austeel are in the process of developing four world class magnetite iron ore mines with multiple open pits along a 25 km strike length of Brockman Iron Formation to the south of Cape Preston on the West Pilbara coast. The close proximity of the proposed pits raises some challenging project approvals and environmental management issues relating to the impacts of dewatering at individual projects and the cumulative impacts of progressive development on local and regional groundwater resources, which includes a large fresh water aquifer system in the Fortescue River alluvium.This paper presents an outline of the hydro-environmental impact assessment process adopted and the key result that the cumulative impacts of dewatering at all four projects on the local brackish groundwater system in the basement rocks is only marginally more than the impact of any one project on its own, and that the impact on the Fortescue River alluvium aquifer is negligible. The paper also presents an outline of the proposed integrated water management approach that will involve coordinated monitoring, ongoing impact assessment and management, and reporting programs for all projects.

Jan 1, 2009

Effect of pH and Chain Length on the Flotation Separation of Fluorite from its Synthetic Mixtures with Calcite and Dolomite with Imino-Bis-Methylene Phosphonic Acid

Sep 13, 2010

I offer some comments which might complement the valuable recent paper by De Angelis et al (1987), on the newly discovered nickel-copper deposit at Radio Hill.The authors have accepted subdivisions and correlations by Hickman (1977, 1983) although they are disputed (Fitton, Horwitz and Sylvester, 1975; Horwitz, 1979; Horwitz and Guj, 1986).Also, in my opinion, more plausible correlations of the Sholl Belt with Whim Creek Belt have been shown, but not discussed, in Hudson and Horwitz (1986, Figure 1). Our suggested correlations and subdivisions have appeared in publications and reports which are not readily available, but it is gratifying to note that many of the observations and conclusions of De Angelis et al are consistent with our conclusions of the Whim Creek Belt.The units of the Sholl Belt (of Hickman, 1983), between the Sholl Fault (Shear Zone) and the overlying Mt Bruce Supergroup to the south, equate well with units of the Whim Creek Belt. A basalt, characterised by an abundance of vesicles and similar in many ways to the Wararnbi Basalt of Fitton, Horwitz and Sylvester (I975), is well developed at the base of the succession, particularly in the southern part of the area (Figure 1). It is overlain by acid tuffs (locally metamorphosed, such as at Whundoo Mine) and associated acid and mafic lavas, similar to those of the Mons Cupri area. The mafics in the succession are marked by the absence of the numerous cherty sedimentary intercalations, such as the Marble Bar Chert, which occur in the Warrawoona Group; and they also lack the intense chertification that is prevalent in all parts of the proven areas of Warrawoona Group rocks.The Whim Creek Group is overlain, locally unconformably (two to three km east of Mount Negri), by the Negri Volcanics which include here the Louden Volcanics (unit Abu of Hickman, 1977), (Horwitz, 1979). The negri volcanics are an alternating sequence of variolitic and quench textured lavas not dissimilar to the highest units of the Sholl Belt (Figure 1). They range from high-Mg basalt to tholeitic andesites (Glikson et al, 1986, pp 79 and 84). The whole succession of the Sholl Belt is estimated to be of the order of four km in thickness, more consistent with the two km thick (Horwitz, 1979, Figure 1) Whim Creek area sequence than with the much thicker Warrawoona Group sequences. The Whim Creek Group (including the Negri Volcanics) is considered to be a widespread grouping (Fitton, Horwitz and Sylvester, 1976; Horwitz, 1979; Horwitz and Guj, 1986) which is prevalent in the northern part of the Pilbara Craton. It is considered by these authors to include the Mallina Formation turbidites of the trough area of Ryan (1965). One component, the Mons Cupri Volcanic, is about 2.95 Ga (Richards and Blockley, 1984). Between the Sholl Fault and Egina, the Whim Creek Group is intruded by large ultrarnafic to granophyric ills of the Millindinna Complex (Fitton, Horwitz and Sylvester, 1975), dated at 2.860 ± 002 Ga by Gulson and Korsh (1983) near the Sherlock River (south side of Caines Well Granite area). The Millindinna Complex has been equated to the same magmatic episode as the layered complexes of the Sholl Belt by Fitton, Horwitz and Sylvester (1975, p 20).

Jan 1, 1988

By F Clark, J T. Carswell

Ore definition for final stope planning is often a challenging prospect in underground (UG) gold mines which exhibit high geological and grade variability. Unlike the grade control (GC) scenario in an open pit (OP), the ability for the mining geologist to plan a sampling campaign which effectively characterises the underlying mineralisation is fraught with difficulty. UG sampling patterns are strongly clustered and typically not dense enough to characterise the spatial and statistical properties. Very commonly, sample volumes are not large enough to provide a reliable grade estimate of the surrounding rock. These factors critically affect our ability to accurately map out ore positions and estimate metal quantities.At Sunrise Dam, traditional UG sampling and modelling techniques have proven to be an unreliable strategy for successful stope planning and extraction. The problem was first observed during the final cut-back in the open pit for which the mineral resource model was constructed from UG diamond drilling. Open Pit grade control reconciliations were strongly positive for both tonnage and grade compared to the resource model. Underground workings missed significant quantities of ore which was laterally defined by open pit reverse circulation (RC) GC drilling. Upon examination it was realised that the cause of the problem was one of inadequate sample density and sample support, the implications of which potentially affected the entire UG mine.As part of a broader study into underground grade control procedures, detailed reconciliation of initial stope production from the GQ domain also pointed to inadequate sampling as a major constraint to effective grade control and reserve conversion.To overcome this deficiency, dense 115 mm wet RC grade control drilling and conditional simulation modelling has been successfully implemented with the intent to replicate the grade control process in the open pit. The increase in sample density and sample volume has proven to be a very effective tool for mapping out highly complex mineralisation. A marked improvement in stope definition, reserve conversion and Mine to Mill reconciliations has been demonstrated on the back of an innovative approach to UG grade control.CITATION:Clark, F and Carswell, J T, 2014. Using reverse circulation drilling to improve sampling in a complex underground gold operation – an innovative approach to underground grade control at the Sunrise Dam Mine, Western Australia, in Proceedings Ninth International Mining Geology Conference 2014 , pp 143–152 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

Mr Kapp's paper helps considerably to clarify the subsidence/mine geometry relationships in New South Wales. It is in the best tradition of the presentation of field investigations such as has built up internationalknowledge over the years.The Author has plotted in Fig. 10, the maximum subsidence developed over each of a number of panels of different width/depth ratios and concludes that the maximum possible subsidence over a super critical extractionarea is around 0.65 of the mining height and that this is reached with the critical width/depth ratio of extraction of around 1.5.Although, as Mr. Kapp says, the maximum possible subsidence in the UK can reach 90% of the seam thickness extracted the more usual figure for the first seam is up to 80%. It has also been found in the UK that with shallow workings such as those at Kemiro Coliery the critical width of extraction is 2.0 or more times the depth.

Jan 1, 1981

By B Ilich, M Brad, R Brandli, E MarT

The Wirtgen surface miner was investigated for application to the Cloud Break iron ore deposit since it can selectively mine thin seams and there is no requirement for drilling and blasting or primary crushing as the surface miner cuts and breaks the rock to secondary cone crusher feed size. A physical metallurgical study of the surface miner run-of-mine (ROM) from Cloud Break was conducted to better understand the product size distribution, amount of -31.5 +6.3 mm lump produced, lump stability and physical metallurgical quality compared to conventional drill and blast techniques. Since the Cloud Break mine was not in production, the lump product from crushing and screening of surface miner ROM was compared with product simulations using traditional premining physical metallurgical processing techniques including drop testing of PQ diamond core. Drop test conditioning is widely used in the iron ore industry to simulate blasting, crushing and screening at the mine and subsequent product degradation during handling from mine to port to predict both the amount of lump product on ship and the size distribution of the fines and lump. The size distributions of surface miner ROM for hard, medium and friable ore types show very tight size distributions with very little above 100 - 150 mm, about 60 per cent of the distribution between 75 and 6.3 mm, with less below 1 mm compared to conventional drill and blast ROM. Crushing, screening and drop test conditioning of the surface miner ROM produced more lump in equivalent ore types compared to drill and blast techniques or their breakage simulation using PQ diamond core. The higher lump yield from the surface miner was also confirmed by pilot scale crushing of some 7400 t of surface miner ROM from the Cloud Break trial pit. The lump produced from surface miner ROM was quite stable and showed similar low degradation characteristics to lump simulated from drill and blasting techniques. Product size distribution simulations using conditioned crushed lump from 1 m diameter Bauer hole samples were found to compare well with processed PQ core samples and surface miner product from trial mining at Cloud Break. The Bauer sample method is therefore considered to be a very useful close simulation to actual lump production, although the lump yield is lower.

Jan 1, 2007

By T Isaksson, J Anderson

The procurement process for underground construction contracts, in particular those contacts involving tunnel boring machines (TBMs), is subject to many complex and inter-related variables, including national and local politics, public policy, community involvement and media attention û as well as strict environmental and legal requirements. Other restrictions include the time available to adequately investigate geotechnical conditions and viable technical options to determine the best construction methodologies û including selection of tunnel boring machine characteristics and, those construction means and methods suitable for the specific geotechnical and environmental conditions. The latter are, most often, quite imperfectly understood. æGetting it rightÆ implies that an optimal configuration û of machine type, characteristics and associated methodologies û can be found and successfully implemented for a particular project. æFrom the beginningÆ implies that the lack of time issue can be successfully resolved. Within an international context this paper highlights a number of issues of concern which relate to tunnel procurement systems and the ways in which certain key processes are managed during planning, design and construction. The authors argue that there is considerable room for improvement in the way tunnelling projects are undertaken and an approach is discussed which has the potential for substantial gains in cost and schedule and reduction of risk. Savings, however, may only be fully realised if the new methods can be fully implemented by all parties involved. This, we believe, will require the rejection of ætraditionalÆ forms of management and procurement with associated changes in the roles and responsibilities of owner, engineer and contractor. Additionally, risk identification, assessment and mitigation are essential cost and schedule control process which have, to this point, been underutilised by the underground construction industry.

Jan 1, 1999

The relationships between Aboriginal Traditional Owners and mining companies have often been mired in dispute, particularly since the High Court Mabo decision and the Native Title Act of 1993. In the Pilbara region, Rio Tinto Iron Ore (RTIO) impacts the traditional country of 12 Aboriginal Traditional Owner/language groups. Over the past 12 years the company and the Traditional Owners have negotiated and settled several significant land use agreements including the Yandi Land Use Agreement over the Yandicoogina mine in 1997, between Hamersley Iron (now Rio Tinto Iron Ore) and three language groups û the Bunjima, Nyapaili and Innawonga people and the Eastern Guruma Indigenous Land Use Agreement (ILUA) of 2006. These substantive agreements are now being followed by a new generation of region wide ILUAs which are close to conclusion. Arising from these regional agreements is a new framework for engagement which has been informed by the implementation of the previous agreements in the Pilbara and across the Rio Tinto group of companies. They are driven by both a company desire to have a consistent approach to engaging with Traditional Owners and the Traditional Owners wanting to have a similarly transparent and consistent standard of performance by the company in implementing the agreements which can deliver improved employment, cultural heritage engagement and direct and indirect benefits for the life of mining by the company. During the past three years the growth in the Pilbara, Western Australia brought new opportunities with people flocking to the region for employment flowing from the mining boom. Housing was at a premium and FIFO (fly-in, fly-out employment arrangements) was developed as a method to manage the general growth and demand for skills. Despite the recent down turn in the world economy since September 2008, which has reduced demand for minerals, the Pilbara continues to enjoy high levels of employment and as a result there is still significant pressure on housing and services provision. Although there has been vast economic growth in the Pilbara not only by mining companies but also oil and gas companies, the 2006 census data indicated that the direct benefits of improved employment, business development and engagement in the mainstream economy continued to exclude Aboriginal people. Indigenous people constitute a significant proportion of the population in the Pilbara region, some 6000 people û currently 14 per cent of the population rising to 18 per cent by 2015 û yet they remain at the bottom of the socioeconomic scale. More than 40 years of mining has returned relatively little to this group of people who are the permanent residents of the region and are connected through their traditional culture to this country (Taylor and Scambary, 2005). Ensuring local Aboriginal participation in the mainstream economy has been a challenge for resource companies, Traditional Owners and local residents in the Pilbara. The case study explores the relationship between a mining company û Rio Tinto Iron Ore and the Traditional Owners of the Pilbara. It examines two projects that have been developed to engage Indigenous people in the development of their region and through regional representation and business development to build a sustainable future for themselves and their future generations and at the same time ensure social cohesion to support social licence to operate. The case study also examines the process that was followed by Rio Tinto Iron Ore and its operations in undertaking a regional agreement for land access, participation and the integration of local Indigenous people into their business and the local economy.

Jan 1, 2009

By E Amini, N Beaton

Application of ore pre-treatment technologies such as Grade Engineering and in-pit ore treatment require comprehensive analysis to show proven value is being generated by switching away from the current practices. Considering most mining operations last several decades; the pre-treatment technologies must be investigated over life of mine (LOM) to truly show value was generated or lost. Therefore, a value chain flowsheet model has been usually developed to run those analysis/simulations over LOM using a set of defined ore characteristics and the operating equipment capacities. The Integrated Extraction Simulator (IES) has been used for this type of LOM simulations as it has the necessary flexibility to accommodate the whole mining value chain flowsheet in one platform and provide essential computation power to run mass simulations for the given scenarios using the resource block model. This allows to forecast the value chain response over the LOM for all given scenarios in a feasible amount of time. The traditionally developed flowsheets for the analysis/simulations are usually limited to the mineral processing plant and were developed based on a single audit conducted on the plant in a very short time, e.g. several hours. The process plant is being operated with a certain ore at a certain condition during the short audits which would not reveal the true capacity of the operation equipment when ore characteristics changes. Therefore, it would be impossible to define the true capacity of the equipment and identify the constraints along the value chain. In this study, a methodology was developed to identify the constraints along the value chain and implement those in the IES flowsheet using process information. Also, the equipment models were fine-tuned to represent the true capacity of the equipment in the flowsheet using the same data set. The methodology was tested over five process plant in two operations and showed the performance forecast was significantly improved over the traditional methods being used so far. Then those high-fidelity flowsheets were used to evaluate the ore pre-treatment technologies proposed by the relevant resource company experts.

Nov 10, 2020

By D Matthews

With the increasing demand for quality-specific ores, coupled to the reality of even more complex minable iron ore reserves, there is a growing need for real-time online material analysis of plant feed and product. For a full system mass balance, the combination of conveyor weight scales, flow and density transmitters are required. This alone does not guarantee product grade. For optimal process control and material blending, real-time online elemental scans in combination with the mass weighting is becoming more than a ‘nice to have’. These elemental scans located at key positions, enable the mining and plant operators to make informed decisions timeously, therefore ensuring product outcomes and optimising operations where material grade and the control thereof are important. Typically, these units follow the mining and primary crushing circuit as well as on the product conveyors, low-grade conveyors and tailings lines. Deployed after the primary crushing circuit, an analyser acts twofold:1. guaranteeing mining production, and2. processing facility feed blends.The analysers on the product conveyors guarantee saleable product. The analysers on the low-grade conveyor and tailings line complete the elemental balance and identify the potential of the low-grade and tailings for future processing. The system losses (accumulation) are calculated to determine the amount of material ‘lost’ during the processing stage which does not report to any of the aforementioned and can be used as a measure of the efficiency of the plant. A further advantage of the real-time online analysis of material is that immediate intervention can be taken in the event that the product is not of saleable product grade requirements. In the Khumani Iron Ore mine, Northern Cape, South Africa, run-of-mine (ROM), product and control analysers were included. Run-of-mine and product stockpiles are certifi ed, low-grade material is not currently directly measured, but calculated from the internal control loops. Iron units are reconciled between product and feed material.

Jul 11, 2011

By A Audétat, W T. Li

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Middle and Lower Yangtze River metallogenic belt is one of the most important polymetallic resource areas in China. Iron oxide-apatite deposits, mainly distributed in Ningwu and Luzong volcanic basins, are a distinct type of iron deposits in this region. These deposits have a close temporal and spatial relationship with Mesozoic dioritic porphyries and are characterised by magnetite-apatite-pyroxene/actinolite ± anhydrite assemblage and large-scale sodic-calcic alteration.Widespread multiphase inclusions in pre- to main-mineralisation stage pyroxene and garnet in Meishan (in the Ningwu basin), Luohe and Nihe (both in the Luzong basin) iron deposits were trapped at ~780°C in extremely saline brines (~90 wt per cent NaCl equivalent), consisting of Na (13–24 wt per cent), K (7–11 wt per cent), Ca (~7 wt per cent), Fe (~2 wt per cent), Cl (19–47 wt per cent) and SO4 (3–39 wt per cent), based on petrologic, microthermometric, Raman spectroscopic studies and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of natural fluid inclusions and synthetic analogues. The high Cl/Br, Na/B and S/B ratios in brine inclusions and the heavy sulfur isotopic values of anhydrite and pyrite (d34SAnh = +15.2 to +16.9‰, d34SPy = +4.6 to +12.1‰) suggest a significant contribution from both halite- and anhydrite-bearing sedimentary rocks. The involvement of evaporites caused the production of large amounts of high-salinity brines with apparently enhanced capacity to extract iron from the dioritic intrusions.According to their geologic features and the above characteristics, these iron oxide-apatite deposits are considered to be a special type of iron oxide copper gold (IOCG) deposits characterised by high contents of Na, Ca, Cl and SO4 in the ore-forming fluids. Moreover, we believe that evaporite-bearing sedimentary basins are more prospective than evaporite-free ones for these kinds of deposits.CITATION:Li, W T, Audétat, A and Zhang, J, 2015. The connection between evaporites and iron oxide-apatite deposits, Yangtze River, China – laser ablation inductively coupled plasma mass spectrometry analysis of Na, S, Cl and Br in fluid inclusions, in Proceedings PACRIM 2015 Congress, pp 623–630 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By W A. Peppin, D N. Riley, N W. Schulenburg

In June 2008, a joint airborne collection using hyperpspectral systems was tested on a single Twin Otter aircraft. This experiment was designed to incorporate two airborne hyperspectral sensors for geological and environmental projects. Mineral exploration and environmental impact statements are two areas where full spectrum hyperspectral data can document the mineralogy at the surface prior to mining operations. Many previous hyperspectral remote sensing collections were collected on a single aircraft with a single sensor. Mineral mapping using hyperspectral sensors that measure in complimentary regions of the electromagnetic spectrum is cost effective as it allows for the mapping of clays, sulfates, carbonates, feldspars, quartz, garnets and many other minerals. This report describes the experiment using the following two hyperspectral sensors: ProspecTIR, a visible near and shortwave infrared (VNIR-SWIR) sensor with 356 channels and spectral range of 0.4 to 2.5 ¦m, along with a spatially enhanced broadband array spectrograph system (SEBASS), a midwave and longwave infrared (MWIR-LWIR) sensor with 128 channels from 2.5 to 5.3 ¦m and 128 channels from 7.6 to 13.5 ¦m. SpecTIRÆs ProspecTIR system and The Aerospace CorporationÆs Spatially Enhanced Broadband Array Spectrograph System (SEBASS) are pushbroom sensors, have high signal to noise ratios, have similar swath widths and instantaneous fields of view. Examples of data collection experiment will be shown with a focus on mineral/lithologic identification and mapping along with environmental assessment in the western United States. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By E P. Leite, L A. Magalhpes

The Amazon Craton is one of the largest cratonic areas and comprises one of the est-endowed metallogenic provinces in the world. It hosts a number of different ore deposit types for which a variety of mineral exploration data are presently available at various scales and formats. These data, however, are not properly organised nor integrated by means of advanced spatial analysis tools. In this view, here we present a suite of neural network methods that were applied to these data, providing unprecedented mineral potential scenarios for several precious and base metals in the region. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By B Crossley

Self-cleaning fluidised bed heat exchangers have demonstrated unparalleled performance internationally for the implementation of indirect heat transfer in severely fouling fluid environments. Recent advances in equipment design have increased the scope of application to include indirect heat transfer in slurry environments, including fouling, scaling and viscous slurries. The ingenious configuration of recirculated cleaning particles through the tubes of vertical shell and tube heat exchangers provides the ability to solve heat transfer problems that arise as a consequence of tube-side fouling during indirect heat transfer to process fluids or slurries. In most cases, the cleaning particles consist of chopped metal wire, however other process-specific materials may be used.

Jan 1, 2004

By E Jak, G Khartcyzov, M Shevchenko

The increasing complexity of ore resources and recycled materials in the feed of pyrometallurgical processes present a technical challenge to the metallurgical engineers working on maximising the recovery of the valuable elements and minimising the environmental impact of the processes. To address this challenge, the availability of computational tools that can predict the mass and energy balance in complex systems is required. Then the accurate description of phase equilibria in the complex multicomponent systems describing the chemistry of the pyrometallurgical processes becomes critical for the correct implementation of the indicated tools and facing the outlined industrial challenges. In the present study the distribution of selected elements (Pb, Zn, Fe, As, Sn, Sb, Bi and Ni) between oxide liquid and metal in the ‘CuO0.5’-CaO-AlO1.5 system in equilibrium with Cu metal at 1400°C (liquidus of CaAl2O4) was experimentally studied using the equilibration and quenching technique followed by the electron probe X-ray microanalysis of the resulted samples. The study covered a wide range of effective p(O2) over the system from 10-11 to 10-3.5 (corresponding to formation of immiscible CuO0.5-rich slag). To avoid loss of volatile elements (Pb, Zn, As, Sn, Sb and Bi), a correlation between ‘CuO0.5’ in oxide liquid and p(O2) in open system was obtained first, followed by studying the volatile elements distribution in closed conditions (Al2O3 crucible sealed in SiO2 ampoule), where ‘CuO0.5’ concentration was used as a marker to evaluate the effective p(O2) over the system. The experimental results were then used for the optimisation of the thermodynamic model parameters of the system as part of the integrated experimental and self-consisting thermodynamic modelling research program of phase equilibria in the Cu-Pb-Zn-Fe-Ca-Si-Al-Mg-O-S-(As, Sn, Sb, Bi, Ag, Au, Ni, Cr, Co and Na) gas/oxide liquid/matte/speiss/metal/solids system.

Jun 19, 2024

By T Mizuta, T Nakano, D Ishiyama

The Tamagawa Hot Spring, from which Ra-Pb-Sr-bearing barite precipitates, is a representative hot spring in a volcanic gas-bearing hydrothermal system associated with Quaternary andesitic to dacitic magmatic activity beneath the Yakeyama Volcano. Thermal water in the Tamagawa Hot Spring is divided into three types: Cl-SO4-type (Ohbuki hot spring: pH 1.2); SO4-type (pH 1.8 to 2.9); and neutral-type (pH 6.1). The concentrations of dissolved components in the Ohbuki Cl-SO4-type thermal water are about ten times higher than in the SO4-type thermal water. The 87Sr/86Sr isotopic signatures of the Ohbuki Cl-SO4-type thermal waters (0.703992 ¦ 0.000004 to 0.704032 ¦ 0.000006) are different from those of SO4-type thermal waters (0.704245 ¦ 0.000003) formed by the interaction of andesitic volcanic rocks (0.704065 ¦ 0.000007 to 0.704093 ¦ 0.000009) and groundwater derived from river water (0.704314 ¦ 0.000012 to 0.704519 ¦ 0.000013) in a shallower part of the hot spring area. The possible origins of Sr in the Ohbuki Cl-SO4-type thermal water and in the SO4-type thermal water are different. The Sr isotopic ratios (0.704130 ¦ 0.000012 to 0.707556 ¦ 0.000014) of Aniai Formation andPreYakeyama Lake deposits occurring below the hot spring area are distinctly higher than those of the Cl-SO4-type thermal water. However, it is expected that a solidifying andesitic or dacitic magma which has similar Sr isotopic ratios of the Ohbuki Cl-SO4-type thermal water, occur in the deep portion of the Tamagawa Hot Spring. The Cl-SO4-type thermal waters having low Sr isotopic ratios do not acquire their Sr isotopic signatures by interaction with strata below the hot spring area, but they are likely to reflect water interaction with a solidifying magma with low Sr isotopic ratios. Components including rare metals in Cl-SO4 type thermal water could be transported from a deeper part. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By C J. Berry, P H. Briggs

Assessment of metal mobility, acid rock drainage production, and toxic effects from weathering of mineralised materials (ie mine-waste piles and outcropping alteration/ore zones) is key in evaluating and mitigating metal mining sites. Many metal- and acid-generating materials at these sites are sulfur minerals (sulfides to sulfates) with differing reactivities, weathering characteristics and metal contents. Our working hypothesis predicts that data on the types and quantities of sulfur minerals, coupled with comparison of their sulfur isotopic compositions to that of aqueous sulfate in the surrounding environment, can be used to evaluate primary pathways of weathering reactions at mining sites. We developed a sequential extraction scheme to separate the phases of sulfur in mineralised materials. Operationally defined phases, including monosulfides, disulfides, elemental sulfur, water-soluble sulfo-salts, acid-soluble sulfates, and resistant sulfate phases such as barite, are quantified gravimetrically and/or instrumentally. Several sets of experiments were designed to test the effectiveness of this extraction scheme. First, a variety of ore sulfides diluted in an inert matrix was analysed with the scheme. Results showed that molybdenite and arsenic-bearing sulfides do not behave as predicted from just their sulfur oxidation states, indicating that samples containing these minerals need special treatment for complete phase recovery. Second, a natural mine-waste composite standard was analysed by the scheme. The sum of the phases was equal to the total sulfur concentration analysed independently. Each phase had a similar, but distinct sulfur isotopic composition. The results were verified with a laboratory prepared æproxyÆ having the same mineralogical composition as the standard, but with each phase having a very different sulfur isotopic composition. The sulfur isotopic compositions of the recovered phases from the æproxyÆ showed that the scheme effectively separated the sulfur with only minor cross contamination of phases. The speciation and isotopic analyses were applied to both mine-waste piles and naturally occurring alteration zones at nine mine sites. A case study from one site comparing the sulfur isotopic composition of minerals in an alteration zone and dissolved sulfate in proximal streams is presented. This case study shows the application of our data to differentiating sources of sulfate in the surrounding environment.

Jan 1, 2003

By A McCallum, J Abols, G Patrick, G Johansen

The authors challenge the traditional thinking that whole ore cyanidation followed by Carbon in Pulp (CIP) or Carbon in Leach (CIL) should be applied as a standard process in the majority of gold processing flow sheets. The concept of whole ore leaching by using cyanide can result in unnecessary environmental and capital risk. Alternative, currently available technologies can be used to provide the desired level of gold recovery at a much lower installed cost and less impact on the environment. Gravity concentration, alone or in conjunction with flotation, can produce a gold bearing concentrate that can then be fed directly to a batch or continuous intensive cyanidation unit. The In-line Leach Reactor (ILR) is an intensive cyanidation unit developed by Gekko Systems of Australia. Advantages of this technology include significantly reduced capital outlays for greenfield plants or plant upgrades and increased investor returns. Reduction of onsite cyanide and carbon inventories improves plant safety, materials handling and site security. By using direct electrowinning to treat the gold bearing solutions produced by the ILR, the need for a conventional carbon stripping circuit is removed. Potential also exists to increase grind size û saving energy, further reducing capital and operating costs and decreasing the environmental impact of a mill. Detoxification of cyanide before the release of solution to the tailings dam can minimise tailings disposal and containment requirements. When used in the right application the proposed process will have little or no impact on gold recovery and may actually increase recovery for complex ores. Areas applicable to this type of treatment include: plants in environmentally sensitive regions, lower tonnage higher grade deposits, coarse gold deposits, and preg robbing ores û some of which may not currently be economically feasible using standard processes and flow sheets. We have provided two examples of such projects, where an alternative to whole ore leach and CIP or CIL has the potential to deliver these benefits.

Jan 1, 2004