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By D E. Langberg, J S. J va, D R. Swinbourne

Specifications on the types and levels of impurities tolerable in metals are becoming increasingly stringent, and are pushing the limits achievable with conventional refining technologies. Particularly difficult is the removal of electrochemically noble elements with low volatilities, such as copper, from more active host metals such as lead, iron and aluminium. Electrochemical refining, utilising the ability of certain solid electrolytes to selectively transport copper or other impurity cations away from the molten host metal into a separate refining phase, may provide an answer to this problem. Numerous studies on solid electrolytes used in concentration sensors have been reported, as well as a limited number on metal refining. Oxygen anion conducting solid electrolytes have been applied to the deoxidation of copper and steel while cation conductors, eg ¯ -alumina and Nasicon materials, have been used to remove lithium and sodium from aluminium. However, solid electrolytes have yet to be applied to the removal of noble elements. The behaviour of solid electrolytes under the extreme conditions of molten metal refining is not well understood. This paper will examine the potential use of solid electrolytes to remove noble metals such as copper from active host metals such as iron. The suitability, and selection criteria of available solid electrolytes for implementation in the metal refining industry in the future will be discussed. In particular, the stability of Cusicon, a copper superionic conductor potentially suitable for use in metal refining, has been assessed and the results of the experiments are presented.

Jan 1, 2000

The interaction of man with the environment has a double character. From one side, mankind can not exist without co- nsuming the natural resources and, from the other side, we actively alter and exert influence upon nature. Analysis reveals that the ecological problem is, to a great extent, a geological one. The paper deals with the application of grouting techniques to construct impermeable barriers for the protection of ground water and soils from depletion and industrial wastes pollution. A number of case histories in the field of mine construction is given to illustrate the solution of geotechnical problems in concert with environ- mental protection measures.

Jan 1, 1988

By McCarthy P. L

With production at Olympic Dam scheduled to commence in June 1988, it has been necessary to install a complete underground ore handling system capable of removing two million tonnes of material annually from the mine. The system comprises mucking from stope drawpoints, truck haulage to underground storage, primary crushing, conveying and hoisting. On the surface, material is conveyed to stockpiles at the Metallurgical Plant. Mining of the numerous special excavations within the system was incorporated into the mine's ongoing development program prior to the underground construction phase. Utilisation of a decline from the surface enabled versatile construction equipment to operate at the underground sites as well as simplifying the transportation and delivery of construction Materials.

Jan 1, 1988

It has been thought in the past that New Zealand had ample coal reserves, able to provide fossil fuel supplies well into the future. Such is not the case and every effort must be made to achieve the highest possible extraction rate in all new coal mining ventures. While the relative cost and availability of completion or fuels has been largely responsible for the slow growth of coal production in the past, a world shortage of fuels has given coal a new importance and required better utilisation of coal reserves. New mining ventures in thick-seam coal deposits cannot be planned and designed without geotechnical investigations designed to provide information required by the mining engineer and analyst. Finite element analysis of mine workings may provide essential information on the optimisation of mining techniques and the design of underground support and roadway shapes.

Jan 1, 1976

By Hosking IA, Mirkov P

Among the solutions currently being considered for improving traffic flow in Sydney are the construction of major road tunnels, principally the Eastern Distributor Tunnels, leading from the end of the Cahill Expressway to Drivers Triangle and South of Taylor Square and the Sydney Harbour Tunnel, which incorporates sections of driven tunnel at the northern and southern sides of the harbour. The Eastern Distributor Tunnels, known as Stages 2 and 3 of the Eastern Distributor Scheme comprise: Stage 2 - A south bound two lane tunnel from north of William Street to Driver's Triangle. The southern end includes two Y junctions (locally 3 to 4 lane widths) with exits into South Dowling Street, Anzac Parade and Moore Park Road. Stage 3 - A north bound, two lane tunnel from Taylor Square to Palmer Street just north of William Street. Further details of the Eastern Distributor Tunnels are given in the paper by Baxter, Chappel and Fishburn (1986) which is included in this conference.

Jan 1, 1987

Magnetic methods have for a long time been used in the search for iron ore. In fact the first recorded geophysical prospecting was the use of a magnetic compass to locate iron ore in the Kuruna region in Sweden as early as 1640.The largest magnetic anomaly discovered, about 700,000 gamma-s, is in this region.The enormous deposits in Russia in the Kursk region, where the ore consists largely of magnetite, were discovered by magnetic methods. Heiland estimates the proved reserves at 290,000 million tons and the additional potential deposits at twice this amount.These magnetite ores Show extremely high magnetic anomalies and consequently very insensitive instruments could be used to survey them. The first aerial magnetic surveys were carried out in this area in 1928.Large areas of the iron ore producing regions in Norway, Sweden and the United States have been covered by magnetic surveys in the past 30 years, much of the work being started after the first World War.In every major iron ore producing country, except Australia, extensive magnetic surveys have been, or are, carried out with the purpose of extending the reserves of ore. Australia is indeed fortunate that the depletion of iron ore reserves and the location of new deposits has not become an urgent problem. Nevertheless, some minor reconnaissance work has already been carried out in Australia, and the Commonwealth Bureau of Mineral Resources, Geology and Geophysics is contemplating a more extended aerial magnetometer survey in the Middleback Ranges area. The work so far done in the Middleback Ranges country consists of a ground magnetic survey of a few small...

Jan 1, 1951

By Carthew SJ

The early period of South Australia's mining history was dominated by Cornishmen as large numbers of miners and their families migrated to escape closure of the Cornish copper mines. Records show that Carthew families migrated from Kent and Cornwall to South Australia. Those from Redruth, Cornwall, were miners and their family history provides an insight into the condi- tions under which early miners lived and worked. Carthews are one of the oldest surviving mining families in South Australia and their movement pattern has been typical of many other early Cor- nish mining families.

Jan 1, 1987

By Dr Subagyo

The energy consumption for producing metal from ore is strongly linked to the chemical stability of mineral being processed, availability and richness of the ore, and process route. Energy efficiencies are particularly linked to the process route. The energy efficiency of high temperature operations vary considerably but energy efficiencies greater than 70 per cent are achieved for large-scale metal production. Low temperature processing through grinding, leaching and subsequent electrowinning use large amounts of energy. In particular, grinding and electrowinning suffer from low overall energy efficiencies. The physical chemistry of a new proposed low temperature route, reactive ball milling, is unclear but preliminary evaluations indicate that it is likely to suffer from high energy consumption. In conclusion, low temperature processing routes for metals generally consume more energy that comparable high temperature processing routes.

Jan 1, 2002

Chile, which hosts around 30 per cent of the worldÆs copper resources, is now the largest producer and exporter of copper. Chilean copper output accounts for more than one-quarter of total worldwide production. An increase to around 40 per cent is forecast by the end of the century. In addition, Chile ranks eighth in silver production and 11th in gold output. In Chile, mining generates more than eight per cent of the countryÆs GDP and the total value of mineral exports is more than US $7.85 billion corresponding to more than 25 per cent of South AmericaÆs mineral production. The rate of growth of Chilean mineral production is indeed impressive. Table 1 shows that in the period 1969 - 1998, copper annual production increased 564 per cent from 667 000 t to 3 764 000 t. Gold production went up 27 times from 1827 to 49 770 kg. Silver output grew 1219 per cent from 95 650 kg produced in 1969 to 1 166 380 kg in 1998. Several facts explain this dramatic increase of production, but the most important was the success of exploration sustained over the same period. This resulted in the discovery of several world-class deposits which when developed into mines, account for much of the production increases. Therefore, this summary review shows the success of basic exploration carried out during the last 30 years in the Chilean territory. The review is based on data already published in different specialised mining books or magazines. It only includes those world-class discoveries not the lesser discoveries important at local scale. All figures were calculated using 1998 $US dollar and average estimated metal prices valid for 1999: copper $US 1653 per t ($US 0.75 per pound), gold $US 9452 per kg ($US 294 per ounce) and silver $US 177 per kg ($US 5.5 per ounce).

Jan 1, 1999

By Haslam C. O, Taylor S

Four historical periods of Australian lead-zinc-silver exploration and development are identified.In the first period, 1841-1900, Australia's deeply weathered surface yielded bonanza deposits. The outcrops of easily worked secondary ores, enriched in silver and lead, were discovered by prospectors with the incentive of production at times of high silver price. Districts discovered in this period still contributed, in 1982, 60 per cent of Australia's lead-zinc production, mainly from Broken Hill.The second period 1901-1944, was one of strong mine development but stagnant lead-zinc-silver exploration. Mount Isa was discovered and developed, but otherwise effort was devoted mainly to the mining of deposit extensions and to the metallurgical flotation of zinc. The deposit discovery rate was low but the discovery of Mount Isa was so significant that discoveries of this period contributed, in 1982, 30 per cent of Australia's lead-zinc production.The third period 1945-1972 was one of re-invigorated exploration.New geological and geophysical surveys, developing concepts of ore genesis, and worldwide comparisons of orebody settings improved target area selection. Evolving remote sensing methods, and rapid analytical techniques, assisted detection of lead-zinc deposits. Initiation of exploration led to discovery:1. in regions of previously unsuspected lead-zinc-silver potential (Sorby Hills, Mons Cupri, Golden Grove).2. of poorly exposed deposits in recognized mineral districts (Hilton, H.Y.C., Woodlawn, Elura, Que River).3. during active exploration for another commodity (Brown's, Woodcutters, Mary River, Beltana, Lady Loretla and Pegmont).The period saw a sustained growth in lead-zinc-silver production mainly from established operations. Mines discovered during the third period contributed, in 1982, 7 per cent of Australia's lead-zinc production.In the fourth period from 1973 to the present, exploration initiatives became fewer but resulted in continued discovery of poorly exposed deposits at Teutonic Bore, Thalanga, Benambra, Scuddles, Hellyer, and Jillawarra. Development initiatives strengthened in the period and production commenced at Woodlawn, Teutonic Bore, Que River and Elura; pre-feasibility work commenced at Scuddles, Hilton, Lady Loretta and Thalanga.

Jan 1, 1984

Bulk mining and handling technologies have been affected in two ways by the soaring costs of oil products in recent years. Firstly, the substition of oil by coal, oil sands and oil shale demands the development of high-capacity mining and handling equipment, and secondly the rising fuel costs favour a trend away from cost-intensive heavy truck transport. To cope with the growing volumes of material in mining and handling, larger equip- ment units have to be designed. This tendency becomes apparent from the examples of the Hambach open pit mine in Germany, and the Port Kembla handling plant in Australia. A combination of the flexibility of heavy truck transport and the cost advantages of belt conveyors is achieved by the system of semi-mobile crushing installations described in this paper.

Jan 1, 1981

Mineral deposits in New Zealand whose origin can be ascribed to primary magmatic segregations are associated with mafic-ultramafic complexes related to two orogenic episodes which took place during Palaeozoic and Mesozoic times. These mafic-ultramafic complexes are essentially of two types. One is ophiolitic and has podiform chromite mineralisation presumably formed below a spreading ridge. The other type occurs as intraplate layered intrusions in which Fe-Cu-Ni sulphides and Fe-Ti-V oxides have formed as a result of liquid immiscibility with the host magma, and have subsequently accumulated by gravity means. Generalised descriptions are given for some deposits in NW Nelson, Fiordland and Marlborough districts.

Jan 1, 1980

A brief descri;tioki is given of nuclear power reactors and their fuels. These fuels are made from a variety of uranium compounds such as uranium dioxide, and uranium carbide as well as uranium metal and its alloys. The various processes used to produce some of these compounds from yellow cake are outlined. Using the natural uranium, heavy water reactor by way of illustration, fabrication of fuel elements is dis- cussed and the characteristics of U02 powder required for this partic- ular fabrication are indicated. The flowsheets and equipment presently in use overseas for production of this type of U02 powder are described. Possible areas where improvements might be made to this conventional process are enumerated and some details are then given of the programme of work which has commenced at the A.A.E.C. Research Establishment to gain experience in the general field of nuclear grade UO20

Jan 1, 1968

By Wilson AF

Gold-silver mineralization at Cracow and Ukalunda in Queensland comprise quartz-filled veins, fissures and breccia zones hosted by propylitically altered volcanics and epizonal intrusions which are strongly fractured. The terrestrial volcanic facies, structural setting, type of alteration and complex mineralogy suggest these deposits are of the epithermal type.The 180 depleted character of the wall-rocks is consistent with the involvement of meteoric waters in convective hydrothermal cells associated with the vulcanism. The Cracow quartzes have remarkably low 6180 values from -2.0 to -3.4 per mil typical. of meteoric hydrothermal systems at high latitude, consistent with the inferred position of Australia during the Permian. 6180 values for the Ukalunda quartzes exhibit a wide range from 5.1 to 14.9 per mil which reflect the mixing of magmatic and meteoric waters, and a steep geothermal gradient.Further stable isotope and geochemical studies are in progress to establish the scale and morphology of the zones of anomalous 6180 and mineralogy in the wallrocks which constitute significant exploration targets.

Jan 1, 1984

The need to solve the problems associated with spontaneous combustion, system of ventil- ation and methane drainage in gassy coal mines has brought about the development of mining and degassing methods which has made possible up to 80% gas recovery in retreating longwalls. Beneficial results also were obtained mostly in the double or multiple-entry systems, but for single-entry systems and for a seam thickness exceeding 3 m, gas recovery rate is still very low. With some single-heading systems, such as those where a return roadway is not maintained in the goaf behind the face line, a new methane drainage technology is practiced. Attempts were made to extract methane from roof holes drilled from offsets in the ribside of the longwall block. The inclinations and lengths of the boreholes were planned and designed on the basis of the geological and mining condit- ions encountered at the time and every second hole was terminated precisely at the point where the previous hole intersected the immed- iate roof goaf area above the face. There are mathematical relations approp- riate to the design of the above drainage systems to give optimum methane recovery under the given conditions. Some examples of drainage have reached 87% recovery and have attained 94% CH4 purity.

Jan 1, 1982

The conventional approach to the disposal of fine coal mine tailings, which involves piping the tailings as an aqueous slurry to a storage where they remain in the form of a permanent wet deposit, is becoming unacceptable. This approach is a legacy of a "contain and forget" mentality, which has economic advantages only in the short term. In the longer term, wet tailings deposits occupy large areas of land and present extreme rehabilitation difficulties. Alternative tailings disposal systems, which are sustainable and which facilitate rehabilitation, are required. The possible alternatives include the mechanical dewatering of fine tailings prior to disposal in combination with coarse reject, tailings disposal into spoil pile valleys, and the combined pumping to disposal of tailings and coarse reject. The most appropriate choice of fine tailings disposal strategy will vary from mine site to mine site. The chosen strategy should be optimised to meet increasingly stringent environmental requirements, within the constraints imposed by each mine. The alternative approaches represent significant departures from past practices, and require considerable industry driven research and development before they can be adopted with confidence. All three alternatives involve mixing of the fine tailings and coarse waste streams, aimed at creating a mixture of reasonable engineering properties. Understanding the engineering behaviour of such mixtures is central to the success of these alternative disposal strategies.

Jan 1, 1991

Faced with rising costs and lower metal prices, several Ontario base metal sulphide mines have changed their method of mining to vertical crater retreat mining. This is a bulk mining method that utilises large diameter holes and mines successive cuts remotely by blasting and cratering the bottom of the drill holes. The orebody is mined from the bottom up. The method in turn has required a change in materials handling to cope with the greatly increased productivity.   This paper presents an overview of vertical crater retreat mining in the Sudbury area using examples from several producing mines. The paper reviews the history of vertical crater retreat mining, various methods of applying vertical crater retreat layouts, the development of in-the-hole drills capable of drilling the large diameter holes required, methods of explosives loading and blasting to achieve the required cratering effect, methods of ground support including backfill placement, and the ore loading equipment presently being utilised including remote control load-haul-dump units and continuous loaders.   The safety aspect of vertical crater retreat mining has been of concern, and was the focus of a provincial inquiry. The benefits in improved safety are demonstrated through an analysis of various records kept by the mines and provincial agencies.   Future trends can now be envisaged, particularly in relation to deep mining. Some experimental work which could have practical applications, is described.

Jan 1, 1989

By Yang RL, Bailey ML

During overburden blasting operations in dragline pits, coal edge losses along the lowwall edge of the new pit are often experienced. In tonnage terms, losses can be significant. With the thick seams at Callide Mine, 20,000 tonnes of coal can be lost along a 600 metre pit. In addition to the immediate dollar value of the coal, replacement of this coal (from which overburden has been removed) will be from higher ratio and higher cost pits in the future. Unit costs of production for the remainder of the coal uncovered in the current pit increase. Experiments involving variation of blasthole inclination and/or amount of standoff on the front row of blastholes have given no significant improvement in the coal edge loss control.

Jan 1, 1988

The refractory industry in New Zealand is small, consisting of two main manufacturers - one at Huntly and the other at Kamo. Together these would have an annual refractory production of about 30 000 tonnes. The industries which use refractories include two steelworks, NewZealand Steel Limited and Pacific Steel Limited, the former is involved in continuous casting from sponge, iron and scrap steel and the latter is involved in ingot teaming from scrap steel and steel billets; One aluminium smelter, cement works, dairy companies, small foundries producing engineering requirements and many other small users. The New Zealand manufacturers produce refractories in thefire brick range, that is up to 50 per cent alumina content (ignited basis), based on indigenous raw materials and in the high alumina range up to 85 per cent alumina content (ignited basis) based on imported bauxites. All of the basic refractories high purity silica and high alumina low alkali refractories and many of the higher grade acid resisting refractories are imported.

Jan 1, 1976

In Australia, current production of rare earth element (REE) minerals, monazite and xenotime, occurs as by-product from titanium-enriched placers and beach sands. Undeveloped REE resources are associated with carbonatites, alkaline igneous rocks, pegmatites, phosphorites, cemented fluvial sandstones, and uranium mineralisations. The REE are held within a range of minerals including silicates, phosphates, a1uminophosphates, carbonates, and oxides. The development of these REE resources may require new processing and extraction methods. The distribution of REE in the currently mined ore minerals, monazite and bastnaesite, does not match that requested by the market. Exploration for new REE resources should be focused on ores with more marketable REE distributions, particularly with heavy REE, neodymium, samarium, europium and yttrium enrichments. Such ores occur within alkaline igneous rocks, in laterites overlying carbonatites and alkaline igneous rocks, and in placers derived from low-grade regional and contact metamorphic sediments. Lateritic REE deposits may be easily and economically mined by shovel in open pits and are unlikely to require extensive crushing and milling. In addition, lateritic REE clay deposits may be processed by simple hydrometallurgicaltreatment mehtods.

Jan 1, 1991