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By Sandenbergh RF

The debate on the mechanism of adsorption of gold and silver di-cyanide onto activated carbon could be divided into two schools of thought. On the one hand, it has been proposed that the combined effects of electrostatic and chemical interaction between the activated carbon surface and adsorbing gold di-cyanide anion results in the adsorption of the latter. On the other hand the `ion-pair' adsorption reaction mechanism has been vigorously advocated as the dominant mechanism responsible for the adsorption of gold di-cyanide onto activated carbon. It is maintained that gold is adsorbed onto the carbon surface as the neutral ion-pair [M"+][Au(CN)z ]". Adsorption is viewed as the result of mainly the chemical interaction while electrostatic interactions are neglected. The validity of the `ion-pair' adsorption mechanism may be challenged on a number of counts. However, the alternative mechanism (based on aqueous surface chemistry principles) has not gained general acceptance yet, because it has not been applied widely enough to explain the different adsorption phenomena associated with gold di-cyanide on activated carbon. In the present study the case in favour of an adsorption mechanism based on general aqueous surface chemistry principles is presented. A model framework is developed for the adsorption reaction mechanism of gold di-cyanide onto activated carbon which incorporates the effects of chemical and electrostatic interactions between the dissolved species, the aqueous solution and the carbon surface. This model is then employed to explain a wide variety of reported adsorption phenomena for gold di-cyanide on activated carbon, such as the effects of pH, the adsorption of different metal cyano complexes, ionic strength, and type and concentration of cations in solution. In addition the effects of cyanide and dissolved oxygen concentration were investigated. No ready explanation, in terms of aqueous surface chemistry principles, is yet available for the switch in adsorption behaviour that agrees with ion exchange to ion-pair adsorption with increasing ionic strength.

Jan 1, 1997

The Prospero orebody is a part of the Helene mine at Cosmos and was scheduled to begin production in March 2008 after the exhaustion of the Tapinos orebody in the same mine. Treatment of the Tapinos orebody was challenging and it was envisaged that Prospero would have similar properties given that it was also anomalous in deleterious elements and would be of a similar mineral hosting. It was deemed necessary to undertake a metallurgical test work program to identify any potential processing issues, complex mineralogy or significant metallurgical domains. The paper discusses the processes which were employed to undertake the metallurgical test work program and describes the aspects that can be employed by other developers to quickly and effectively assess potential future orebodies. It will demonstrate that the work was successful at determining expected metallurgical behaviour, providing direction for mining operations and highlighting areas for more extensive research.

Jan 1, 2009

By O Ignatenko, A van Schaik

Environmental legislation for the process and manufacturing industries is frequently formulated without considering the fundamental limits of physics, chemistry and thermodynamics within process technology. Recycling of end-of-life goods is used in this paper to show how the limits can be evaluated on the basis of the theory of minerals processing and metallurgical engineering. This theory has been applied on European Union level to re-examine the legislation for automobile recycling in a recent stakeholder discussion involving the automotive industry (http://www.assurre.org). This theory and our models are finding their way into the computer aided design (CAD) tools of the automotive industry, developments that form part of a project to design the super light car of the future (http://www.superlightcar.com). Only such fundamental approaches will in future be able to provide the basis to argue and define realistic and sensible environmental legislation.

Jan 1, 2006

By Lo YC, Pate WT

In recent years there has been a great deal of interest in ways to optimise the performance of mineral processing plants. This paper describes a methodology developed for optimisation of autogenous and semiautogenous mills. The methodology involves plant sampling, batch testing, modelling, computer simulation, control strategy evaluation and implementation. The models have been tested in plant operations to verify the research findings and predictions. Two example applications of this approach to plant optimisation are presented. Benefits reported in these two examples are in the range of four - eight per cent increase in size reduction efficiency.

Jan 1, 1993

By J Chßvez, J Rosa del Castillo, J Rui

Environmental Impact Assessment (EIA) and Feasibility Studies (FS) were carried out to evaluate the potential use of treated acid mine drainage (AMD) occurring at the Kingsmill Tunnel in the Central Andes of Peru. The 11 km long tunnel drains the underground works of the Morococha Mining District and discharges about 1.25 m3/sec of AMD directly into the Yauli River in the Amazon Basin. The communities living downstream cannot use the Yauli River water due to its low pH and elevated concentrations of metals (eg Cu, Zn, Fe, Mn, As, Cd) and sulfate. Studies carried out for this project included technical feasibility, EIA, economic viability and social impact assessment phases. During the æTechnical FeasibilityÆ phase, the treated AMD was produced by simulating a high density sludge (HDS) lime neutralisation/ precipitation process and was evaluated for various potential uses. Mining companies located in Morococha, in particular Centromin Peru SA, and the Water Works Company of the City of Lima (Sedapal) collaborated with Golder Associates during the studies. The Canadian International Development Agency (CIDA) provided the financial assistance. The results of the physical, chemical, biological and toxicological analyses demonstrated that the AMD could be sufficiently treated to be potentially used to supplement the drinking water supply of Lima, and for agricultural (eg irrigation and livestock) and recreational purposes. Process design and scale-up parameters were also determined for implementation of the full-scale treatment facility at the site. The use of the treated AMD as a drinking water supplement would be economically feasible.

Jan 1, 2003

By Crosby N. R

The design of mine openings and the assessment of their reserve are processes ihicl, require the routine manipulation of considerable amounts of data. A number of computer programs have been assembled to operate in a mini computer in order to provide some mechanical assistance for these processes. The system responds to plain language commands. which allows mining engineers to compute the reserves for a number of possible mining outlines, on an interactive basis. Methods of numerical analysis were used in preference to statistical or qeostatistical techniques.

Jan 1, 1977

The large, low grade, Kidston Gold Mine in North Queensland has achieved outstanding economies of scale and profitability. The total mineable ore reserve including mined to-date (as at December 1993) was 70.75 million tonnes at 1.54 grams gold per tonne. After nine years of mining, grade control mine production routinely reconciles against mill production and ore reserves to within five per cent of contained gold. The grade control system developed at Kidston is examined in detail, with emphasis on the geological thinking behind the strategies, as well as the development and application of a computerised, graphical production control and reporting system. Reconciliation procedures and results are explained, illustrating the success of geostatistical methods, as a risk management tool, in both ore reserves and production grade control.

Jan 1, 1994

By Mostyn G. R

An important problem in rock engineering is to control the properties of artificial rock. A compaction technique for casting artificial rock specimens with controlled properties is described, i.e. using a compression-testing machine to compress the mixture. Uniform density is necessary to achieve uniformity of properties of the specimens, and uniform density can be obtained by using the specific pressing method presented. Rebound and borax content are important to the technique and have been studied as well.

Jan 1, 1992

By Jacobsen L. K, Gross K. B

This paper, describing milling practice at Mount Isa Mines, is one of a series covering milling methods and costs that is being published by the Bureau of Mines, United States Department of the Interior.The Mount Isa concentrator began operations in May 1931, by treating a mixture of oxidized and sulphide ores. Since March, 1935, only sulphide ores have been milled; this change involved major alterations to the flow sheet. The maximum capacity on mixed oxide and sulphide ores was 2,650 tons per day; the present capacity is approximately 1,880 tons of sulphide ore per day. The installation of additional Grushing, grinding, and flotation equipment when completed early in 1939 will increase the maximum capacity of the concentrator to 2;240 tons of sulphide ore daily.All tonnages in this paper are expressed in tons of 2,000 pounds, gallon measurements in terms of Imperial gallons of 277·41 cubic inches, and costs in dollars at the rate of $4 United States currency to the Australian pound.

Jan 1, 1939

By Stevens LG, Mok JK

With the long lead time requirement for engineering and construction of mineral pro- cessing facilities and the costly financing arrangements necessary, effective project management is essential to the successful and timely start up of these major production units. An added complexity is the frequently remote location of such projects and the demands this imposes on efficient project staffing, scheduling, logistics and cost control. Parsons recent experience with major projects such as Greenvale in Queensland and La Caridad in the desert of Northern Mexico and at remote locations like Sar Cheshmeh in Iran are described. The applications being developed for improving project controls through the use of computer techniques such as MSCS-COPES, and readily accessible and versatile transportation means are reviewed.

Jan 1, 1981

Traditional methods for monitoring, and hence controlling, pyrometallurgical processes rely heavily upon the skill and experience of operators. A skilled operator will usually achieve consistent, though often conservative, results, whilst an un-skilled operator will require considerable time and training to achieve the same results. Semtech Metallurgy AB have demonstrated that continuous and precise control of pyrometallurgical processes can be achieved through on-line analysis of pyrometallurgical flame off-gas using optical spectroscopy. The feasibility of the technology has been demonstrated on a large number of full-scale tests at production plants and by several commercial installations. Evidence suggests that installation of this technology, called Semtech Optical Production Control (OPC), has resulted in considerable economic benefits to the plant efficiency and asset life. These economic benefits are believed to be a direct result of improved objective on-line control. Technically the following benefits have been demonstrated: improved metal grade control, reduced metal losses, reduced processing time, and improved personnel safety. SemtechÆs OPC is a non-intrusive technology which relies on the fact that the composition of the vapour phase above a high temperature melt is closely related to the instantaneous status of the melt. This enables on-line real-time analysis of the furnace melt to accurately determine melt status and in particular reaction endpoints. Originally developed for on-line monitoring of copper converting in a Pierce-Smith vessel the field of applications for the technology is steadily growing. This paper introduces the Semtech OPC technology; discusses various applications and outlines the demonstrated benefits.

Jan 1, 2002

An understanding of the way that solutes are transported in mining or natural environments is essential to the development of sound strategies for managing waste disposal. Research on miscible pollutant movement in unsaturated porous media is carried out both experimentally and numerically. Results of numerical modelling are obtained by solving the groundwater flow equation and the solute transport equation. The finite element method is employed and comparisons between simulation results and experimental data are found in remarkable agreement.

Jan 1, 1995

By P Hayes, B Zhao

A range of materials are treated in zinc fuming processes to recover metal values and produce benign slag waste products. The selection of the optimum process conditions in these various technologies can be greatly assisted by the use of a chemical thermodynamic model of the system. In this paper the effects of slag chemistry on the liquidus temperatures, subliquidus phase equilibria and thermodynamic properties are described by a FACT model of the ZnO-PbO-FeO-Fe2O3-CaO-SiO2 system. In addition new experimental data on the effect of Al2O3 on the liquidus are presented. The implications of these findings for plant practice are discussed.

Jan 1, 2000

By B Siddall, A Gunstone

The use of a partial secondary crushing circuit provides a flexible way to optimise existing SAG comminution circuits limited by rock competency or enables optimal processing of an ore through second hand equipment not specifically selected for that ore. This paper details the process involved in designing a partial secondary crushing circuit using the recent installation at Mt Rawdon Gold Mine in Queensland as an example.

Jan 1, 2004

By Rosengren KJ

Geotechnical conditions often have a critical influence on the design of new open pit and underground mines, but they are often considered of secondary importance in relation to other factors, such as detailed geology, orebody geometry and grade distribution. As a result, geotechnical studies may not be carried out during early project investigations or, at best, may be given only superficial attention, often to the overall detriment of the project. Technically and economically, it is logical that geotechnical studies should be integrated with geological investigations as soon as it becomes evident that the particular deposit may prove to be economic. The paper discusses the use of geotechnical information in the selection of mining methods and mine design for underground mines and for wall design and assessment of excavation characteristics in open pit mines. It then considers methods of obtaining the relevant data, with particular reference to exploration boreholes. Selected case studies on the application of geotechnical data to mine design are Included.

Jan 1, 1986

By Muir D. M

Highly saline process water has a number of implications for the CIP process during the leaching, adsorption and recovery of gold. The reduced oxygen solubility in saline water can seriously reduce the rate of gold leaching, while dissolved oxygen meters do not necessarily reveal actual oxygen concentrations in saline water. High levels of magnesium in the ground water necessitate operation at lower pH (-9), with the potential for greater cyanide loss via HCN stripping. In addition increasing salinity renders viscosity modifiers largely ineffective.The adsorption capacity of aurocyanide onto activated carbon is improved with increasing salinity, but misleading results can be obtained in assessment of gold loading kinetics of plant carbon samples already loaded, or partially loaded, in saline water if subsequently tested in fresh water. Elevated chloride levels in the Zadra elution process can cause severe anode corrosion in the elecuowinning cell. The Anglo elution process is tolerant to only slight increases in water salinity, but elution times can be reduced by ethanol addition. Care is required in carbon regeneration, as salts can catalyse carbon decomposition as well as increase kiln corrosion.

Jan 1, 1994

By Shoobridge PH, Firkin GR

The Imperial Smelting Process blast furnace (ISF) of the Sulphide Corporation Pty Limited zinc/lead smelter at Cockle Creek, New South wales, has in recent years greatly increased its consumption of low grade feed materials, and as a consequence has experienced periods of unstable furnace operation. Routine examination of production sinter, including softening characteristics and micro- examination, showed that the problems had been caused by an increasing silica content in sinter. The silica entered a low melting point glass phase containing calcium and lead oxides. The relative volume of this phase increased until it formed a continuous matrix in the sinter structure and this made the sinter more likely to soften at lower temperatures. Premature softening caused loss of operating stability in both the shaft and hearth of the ISr. The required sinter structure for ISF smelting was found to consist of a network of intermeshing, refractory crystals which provided skeletal strength for sinter lumps even after the glass phases had begun to soften and melt. With an understanding of the importance of microstructure and softening temperature of zinc/lead sinter and the progressive identification of those factors in sinter production which affect the microstructure, a significant improvement in stability of operations has been possible.

Jan 1, 1980

By Bassett N

The Eneabba deposit, located 280 km north of Perth, Western Australia, and 30 km inland (Fig. 1) is one of the most recently developed deposits of mineral sands in the world. The area has been in production since 1974, while the Associated Minerals Consolidated Limited (AMA) operation commenced production in 1976. Total ore reserves of close to 400 million tonnes contain about 40 million tonnes of heavy minerals (proved and probable).

Jan 1, 1979

By Toivanen R-M, Leinonen O, Pekkarinen H

This paper presents developments in designing an integrated mine control system at Kemi mine. The aim of this paper is to present the general structure of the system and to outline some features of the process control strategies. The results o

Jan 1, 1998

Since 1969, a substantial number of geophysical methods have been applied in the search for porphyry copper and mesothermal type -sulpha-de deposits. These have assisted with geological mapping as well as the definition of various sulphide depos-its. The application of these methods at the Frieda-Nena deposits, Papua New Guinea, can be used as a case study for exploration in other parts of New Guinea.In 1993, Highlands Gold Limited carried out an intensive geophysical program over the Nena deposit. The methods employed included, CSAMT (controlled-source audio magneto-tellurics), airborne and ground elect-romagnetics, IP/resistivity and ground magnetics. The magnetic method was used as a regional mapping tool as well as a way of mapping alteration zones over both the Nena and Frieda River copper deposits. Electromagnetics, in part-icular FLAIRTEM, is a rapid reconn-aissance tool as well as a detailed mapping tool for the location of Nena-style massive sulphide deposits. IP/ resistivity is an expensive but most useful tool for mapping out Frieda porphyry copper style disseminated sulphides as well as Nena style deposits. It can be used to define drill targets in areas of difficult Access.a

Jan 1, 1994