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By Warner RE

SINCE 1952, when Elliott et a/ first applied the Sherwood correlation for flooding in chemical absorption towers to blast furnaces numerous investigators throughout the world have followed their example and much research effort has been spent to tighten the correlation and recently to extend investigation of flooding to side gas entry conditions. The widespread use of the Sherwood concept of flooding has been such that even the word itself has become an integral part of blast furnace nomenclature. The evidence for the applicability of Sherwood's relationship has been that the flooding limits calculated from blast furnace parameters lie approximately on the Sherwood line. However, the values of many of the variables for the blast furnace calculation are only estimates and at first sight one may wonder at such 'close' coincidence when some of the estimated parameters entering the Sherwood correlation are raised to the power of three or more, as for the bed porosity and the liquid surface tension. It is felt that the explanation of this result lies in the logarithmic: nature of the plot and/or the fortuitous can- cellation of the errors of the estimates in the calculations coupled with the fact that blast furnace fluid ratios lie within a very narrow range of values. The foregoing considerations should in their own right place doubt on the correctness of the Sherwood type flooding correlation applied to the blast furnace. Additional doubt regarding the existence of the Sherwood type flooding in the furnace has been cast by the results obtained in the Tokyo University experimental blast furnace. From the reasoning of both Standish and Colquhoun (p. 20) and Warner (p. 23) it is deduced that flooding in the traditional sense will only normally occur in the upper bosh (somewhere near the mantle), following softening as discussed by Palella et a/ on p. 75, and flooding in that zone is likely to result in furnace irregularity. On the other hand, the concept developed by Warner of slag hold-up above the raceways as a stable phenomenon not affecting furnace regularity is a process unique to the blast furnace and is not described by the Sherwood flooding theory. Recognising the considerable practical implications of slag hold-up above the raceways, this note further explores the physical process of slag hold-up. We envisage that bed of coke above the raceways in almost all blast furnaces would contain some slag held up by the gas pressure gradient. In general the slag would be contained in a ring and gas would bubble through in its ascent through the furnace. The force supporting this slag is the pressure gradient and obviously -much of the blast pressure is dissipated in supporting this structure.

Jan 1, 1975

By J R. Robinson

Prior to mine development, exploration drilling within the Luise Caldera on Niolam Island encountered gold mineralisation to the northwest of the main Minifie and Lienetz orebodies. This mineralisation was referred to as the Kapit orebody, and ten diamond drill holes were subsequently completed over the area to investigate its economic potential. Several significant mineralised intercepts were returned. These were interpreted using the orebody model developed for Lihir at that time which invoked a strong horizontal control to mineralisation. Additional consideration was given to the elevated geothermal temperatures encountered, the proximity of the mineralisation to the ocean, and its perceived depth below sea level, resulting in the Kapit area being given a low priority for follow up investigation. As a result, no further work was completed over Kapit until recently. The Kapit orebody was the target of an intense diamond drilling programme during 2002/2003. Data from this latest round of drilling has significantly improved understanding of the mineralisation and associated geology. The significant orebody now delineated at Kapit substantially differs from past interpretations, and the latest data has upgraded its economic potential. A resource estimate and other critical studies completed in 2003 enabled an updated reserve statement to be issued in February 2004 including the Kapit mineralisation for the first time. Total Probable Reserves at Kapit stand at 25.2 million tonnes (Mt) at 5.28 grams of gold per tonne (g Au/t), for a total of 4.3 million ounces (Moz) of contained gold.

Jan 1, 2004

By Frazer E. J, Lwin T

Measurements of coulombic efficiency (QE) for zinc electrodeposition were carried out under mass-transfer-controlled conditions using a rotating disc electrode in synthetic acidic zinc sulphate solutions. Various methods of solution preparation and purifi- cation were investigated using reagents vary- ing from analytical grade to high purity; the purest solution was obtained-by dissolving 99.9999% zinc (Koch-Light) in sulphuric acid solution (BDH Aristar). Improvements in sol- ution purity did not necessarily increase QE, especially where apparently beneficial impur- ities (e.g., Pb) were initially present. The maximum QE obtainable through variation of temperature (T), current density-(i) and elec- trode rotation rate was established using a statistical optimization technique. The QE was determined principally by T and i, with significant interaction between these factors in the highest purity solution. QE contours, which gave an overall view of solution per- formance, were constructed and predictions about the response under conditions similar to plant practice were made. Wark's Rule (the dependence of QE on zinc/acid ratio) was obeyed in the purest solution over the range of composition commonly encountered in zinc plants. High concentrations of Na2SO4 and K2SO4, which occur in some plant solutions, were found to increase QE marginally ("1.2%). The intrinsic effects of individual impurities such as Cu and Ni were evaluated by additions (up to 5 ppm) to the purest solution. Decreases in QE were found to be minimal at the impurity levels normally encountered in zinc plants.

Jan 1, 1987

By J A. Rumball

Measuring cyanide in the leach liquors associated with high copper and/or sulfide ores is a non-trivial exercise. It is well known that copper complexes with cyanide and reduces the amount of cyanide available for gold leaching. What is not so well known is that the rhodanine end point overestimates the amount of cyanide available for leaching in the presence of copper. Sulfide ions also interfere with a rhodanine end point titration, although this is less of a problem as the black silver sulfide precipitate formed clearly indicates to the operator that something is wrong. Thiosulfate, which forms readily from the alkaline oxidation of sulfides, causes an overestimation of the cyanide available for leaching due to the formation of Ag(S2O3)-. The net result of these observations is that rhodanine is rarely of value as an end point indicator in complex solutions. It generally overestimates the amount of cyanide available, providing plant metallurgists with a false sense of security. Potentiometric titrations are generally much more capable of accurately measuring cyanide in complex solutions. The interfering effect of copper can be resolved and it is even possible to estimate the copper concentration using the inflexions associated with the titration of CN- + Cu(CN)43- versus Cu(CN)32-. Using the potentiometric method sulfide ions can be determined before the cyanide measurement is made due to the formation of AgS2, although the electrode will foul with repeated measurements. Thiosulfate can also be distinguished from cyanide with a potentiometric titration. Rhodanine and potentiometric titrations are both affected by the pH of the liquor. At pH 9.2 half the cyanide will be present as CN- and half as HCN(aq) with only the CN- being titratable. This does not hold in the presence of a buffer active around pH 9. In the presence of sufficient buffer, both the CN- and HCN(aq) are titrated. Ca(OH)+ may buffer the pH when large amounts of lime have been added.

Jan 1, 2007

By Whittaker B. N, Reddish D. J

The rockbolting method of support is employed widely in several countries in different of mines. Hard rock mines use this method extensively. Soft rock mines, such as coal mines, have employed standing supports (steel sets) as the main method, although some countries such as the U.S.A. and Australia have preferred rockbolting. There is increasing interest in extending the rockbolting method in coal mines. The application of rockbolting techniques in an industry which traditionally has not applied such techniques, has required the development of a systematic design approach. This design approach uses extensive monitoring, to asses the viability of the support system in differing conditions. Currently at a number of new and existing mine developments in the U.K., rockbolting is being successfully applied. Although, inevitably some localised geotechnical problems have been encountered and have needed to be taken into account. The effect of faulting on roadway conditions is discussed in this paper and a design approach has been applied using a numerical analysis method, namely the Finite Element Method. The results presented in the paper serve as a useful guide to roadway support designers, and in particular the role played by different bolts in a range of conditions.

Jan 1, 1992

Solar Salt, Lunar Ambitions I Bauerti The title of this paper is `Solar Salt, Lunar Ambitions'. It is largely the result of a lack of imagination and a tight deadline. I was seeking a catchy title to convey the image of being 'here' and wanting to get `there', with `there' being a long way away and our being held 'here' by powerful gravitational forces. I tried `Solar Salt, Lunar Landings', but that implied we had already reached `there' when, on reflection, we had not. A colleague suggested 'Solar Salt, Luna Park' which is a fun park in Sydney and, I must admit, there was appeal in the image of having embarked on a wild roller coaster ride with stomach-wrenching twists and turns and the only reward being a pair of sweaty palms, and a feeling of nausea. That's sometimes how it feels when you launch into change. In the end I settled for the more sedate `Lunar Ambitions'. It contained that suggestion of hope and continual striving which are central to the idea of best practice. I will discuss our experiences in this area shortly, but I would firstly like to provide some background to our business. The salt industry is steeped in history and tradition. As one learned commentator observed, common salt is 'a substance seemingly too ordinary to think about, yet it is the oldest of man's raw materials and the basis of some of his newest inventions' (Multhauf, 1978). From ancient times, salt was recognised as a key necessity of life and it has played a role in the rise and fall of governments throughout history. The Romans recognised its importance when they gave their soldiers money regularly to purchase salt, hence our modern word 'salary'. Today, while culinary use remains important, the main consumer of salt is the chemical industry (Figure 1).

Jan 1, 1995

By A F. Cooper

The northeast-southwest trending ~25 km2 area incorporating Bald Hill is located 18 km northeast of Haast, and 5 - 7 km west of the Alpine Fault in South Westland, New Zealand. The geology consists of Greenland Group greywacke overlain by a Cretaceous-Tertiary sedimentary sequence and fluvio-glacial/marine terrace deposits of Quaternary age. Alluvial gold in Cole Creek, draining west from the summit of Bald Hill, may be derived either from vein mineralisation in basement rocks or from fluvial or marine terraces.   This paper focuses on the potential for in situ gold and base-metal mineralisation in sporadic, siderite-rich quartz veins that cut basement greenschist facies metasediments that have been overprinted by contact metamorphism.   Throughout the area, vein compositions are dominated by quartz and commonly feature zoned plagioclase. Alteration adjacent to veining within the contact aureole is dominated by 1 - 2 mm, coarse grained biotite, with small amounts of sulphide, and is pervaded by abundant siderite veinlets. Outside the aureole, wall rock alteration to veins consists of fine grained chlorite. Trace element XRF analysis has been used to ascertain base metal concentrations within samples of vein and alteration zones collected from throughout the area. Vein and alteration zone mineral assemblages containing <5 per cent sulphide, with low concentrations of As, Cu, Pb and Zn indicate low potential for gold and base-metal mineralisation in the Bald Hill region. Contact metamorphism of Greenland Group basement in the northeast of the region, is likely due to emplacement of a poorly exposed Cr- and Ni- enriched gabbro. The presence of biotite and andalusite in hornfelses indicate contact metamorphism occurred at temperatures >350¦C and at depths <10 km. Widespread vein distribution does not appear to be related to contact metamorphism or gabbro emplacement. Further research is required in order to establish the fluid source from which the veins were precipitated.

Jan 1, 2007

The A J Parker Cooperative Research Centre for Hydrometallurgy has recently been established by a major grant from the Australian Commonwealth Government. The participating institutions in this centre are the CSIRO Division of Mineral Products, Curtin University of Technology, Murdoch University and the Chemistry Centre (WA). The Australian Mineral Industries Research Association is also a partner. Information is presented about the research activities of the Parker Centre, which are focussed on the solid/solution interface. Three research programs have been established in the areas of leaching, precipitation and surface processes (adsorption). The initial projects within these three programs are described. Details are also given of the Centre's education program which include honours degree training, masters and doctoral degrees by research, a masters degree by course work and workshops. The importance of collaboration with industry to the successful operation of the centre is stressed.

Jan 1, 1992

By Vogwill R. I J

The Boddington Gold Mine, operated by Worsley Alumina Pty Ltd, is located about 100 km south of Perth and is one of the largest-producing gold mines in Australia.Multiple open pits are planned and several extend below the water table, through the deeply weathered lateritic profile and into the underlying Archean bedrock. Groundwater related mining problems, such as poor trafficability, wet floor conditions and slope instability began to occur early in 1990.The mine is located within Archean greenstones which are steeply dipping and faulted. Rock types include mafic to felsic volcanics, pyroclastics and sediments. These rocks have been regionally deformed and metamorphosed and are intruded by quartz micro-diorites and post-mineralisation dolerite dykes. Deep weathering has produced a typical oxide profile consisting of laterite, clay and saprolite zones underlain by weathered to fresh bedrock.

Jan 1, 1993

Recent mineral exploration successes in the Proterozoic rocks of the Mount Isa Inlier are unprecedented in the regionÆs history. This new era of discovery, particularly for æblindÆ deposits, owes its origin to perseverance and advances in geoscience and exploration techniques, notably geophysics. Prospective host rocks outcrop over more than 50 000 km2 of the Mount Isa Inlier and extend a further 100 000 km2 below cover. They contain major deposits of copper, lead, zinc, silver and phosphate (Georgina Basin) and significant deposits of gold, uranium and cobalt. The discovery in 1923 of silver, lead and zinc at Mount Isa established the regionÆs world-class mineral potential. Since 1990, major orebodies have been discovered at Cannington (silver-lead-zinc), Century (zinclead-silver), Ernest Henry and Osborne (copper-gold) and extensions to known deposits at Dugald River and George Fisher (zinc-lead-silver), and Esperanza (copper). This success is of global significance and reflects a prospectivity upgrade since widespread copper mineralisation was discovered and mined in the Cloncurry district a century ago.

Jan 1, 1998

By G L. Simmons, K M. LeVier, R Kappes

The low potential hydrophobic state of pyrite in amyl xanthate (PAX) flotation with nitrogen is of particular interest with regard to the N2TEC flotation technology currently being used for the recovery of auriferous pyrite at NewmontÆs Lone Tree Plant in Nevada. Initially, the N2TEC system had been found to operate satisfactorily, but cyanide in the flotation mill water appeared to be responsible for a loss in pyrite recovery. This supposition was confirmed with laboratory experiments, and a program was initiated to study flotation chemistry variables by electrochemically controlled contact angle measurements. Experimental results show that activation of pyrite in such cyanide solutions can be achieved more effectively with lead than with copper. Subsequently, based on these fundamental studies, significant improvement at the Lone Tree Plant was achieved by lead activation, in which case the recovery increased to expected levels. The effect of activator is particularly significant not only with respect to pyrite depression by residual cyanide, but also with respect to collector (PAX) consumption and the initial state of the pyrite surface. Experimental results show the importance of the pyrite surface state and the rather interesting features of the activation process.

Jan 1, 2005

Thermo Fisher Scientific is a supplier of samplers, instruments, analysers and consumables to the mining industry under the Thermo Scientific brand. The critical need to provide a representative sample to the analyser has played a pivotal role in product development. Products discussed are the Analysis and Sampling Station (AnStat) for mineral slurries, the Coal Quality Manager (CQM) and the prototype Bore Hole Analyser (BHX) with optional drill chip recovery system. Analytical techniques used in the above products are XRF, PGNAA and LIBS respectively. The company also designs and supplies conventional mechanical sampling equipment and complete sampling systems for bulk material applications (historical Ramsey brand). These products and application of them are presented.

Jan 1, 2008

Autogenous and Semi-Autogenous grinding has become an accepted method of reducing primary crusher product to micron sizes in a single or a two-stage grinding circuit. The elimination of secondary and tertiary crusher circuits and sometimes rod mills helps to lower overall operating costs and, in many instances, can make uneconomical projects viable. Selecting AG/SAG Mills have been rather a "hit and miss" affair over the years, but now with the many different types of tests available, accurate mill size predictions can be made, provided the test data is evaluated correctly. This paper endeavours to simplify the process of evaluating test data and sets down some guidelines for designers to follow when selecting AG/SAG Mills.

Jan 1, 1991

The Proterozoic Pb-Zn deposits of the Gulf of Carpentaria, Australia, include HYC (McArthur River), Mt. Isa, Dugald River, Lady Loretta and Hilton. Two seamingly incom- patible depositional models have been proposed to account for their origin. Finlow-Bates (1980), Large (1983) and Russell(1983) classify these-deposits as sediment-hosted submarine exhalative deposits. This class includes Rammelsberg, Meggen, Silvermines, Sullivan and others. In contrast, a lacus- trine, shallow-water origin has been advocated by Williams and Logan (1981), Logan and Williams (1984), Muir (1983) and Eugster (1985). The discrepancies between these two models can be removed by creating a separate class, that of continental sediment-hosted exhalative deposits.. HYC., Mt. Isa and Dugald belong to this class and their sediments were deposited in shallow, alkaline lakes. Metal- rich, hot, Na-Ca-Cl brines entered the basins along boundary faults and interacted with pore fluids and sediments, depositing-Cu-Zn-Pb sul- fides. Similar brines entered the Lady Loretta basin after marine flooding, depositing sulfi- des and barite, placing Lady Loretta into the class of marine Sedex deposits.

Jan 1, 1987

By K J. Davey, J T. Woodcock

Australian steelmakers produce up to 30 000 t/yr of electric arc furnace (EAF) dust. Current disposal techniques include sending EAF dust to landfill, stockpiling, and paying zinc smelters or registered waste removalists/processors to take the dust. Many of the complex overseas pyrometallurgical and hydrometallurgical treatment routes cited in the literature are not considered economic. Governmental, environmental and social pressures on producers to consider more sustainable disposal options are mounting, and there is now a strong push to consider recovering potentially valuable or recyclable components, such as zinc and iron units, from EAF dust. As well, there remain strong economic drivers for producers to find lower cost disposal solutions. Characterisation studies undertaken at CSIRO Minerals have revealed important physical differences in the nature of the zinc- and iron-bearing phases contained in domestic EAF dusts. These differences have been exploited using simple and cheap mineral processing techniques such as water washing, wet cycloning and wet magnetic separation. This has allowed a significant upgrade in the zinc content of EAF dust to be achieved, together with a reduction in the levels of key smelter penalty elements, such as chlorides and fluorides. The zinc-rich portion of the dust is now a more attractive smelter feed while the iron-rich part of the dust could potentially be briquetted or pelletised with a reductant and recycled to recover iron, and thus close the loop on dust processing. The basis of the separations tested together with laboratory results from several Australian dust samples are presented and discussed in this paper.

Jan 1, 2006

Bacteria can play a key role in the processing of 'difficult' ores. Bioleaching opens the way to potentially extract copper from vast amounts of otherwise hard to process refractory low-grade chalcopyrite. In my talk I will outline our research philosophy to develop bioleaching as a Precision Processing unit process step. In our view, Precision Processing is a sophisticated approach to mineral processing where the ultimate goal is to measure and characterise the ore body in-ground and in real time during mining, allowing the down-stream unit processes (bioleaching, in this case) to be continuously tailored and tuned via feedback and feed-forward controls to obtain the highest possible recoveries at the lowest possible cost and environmental impact. I will describe some of the work that we are undertaking to better understand the interfacial phenomena underlying the fundamental bioleaching process with the aim of coming to a Precision Processing approach. We use techniques such as interfacial electrochemistry (scanning electrochemical microscopy, SECM), AFM, zeta potential measurement, and synchrotron science to elucidate the parameters that drive bacterial selectivity and adhesion, bacterial metabolism, and dissolution and precipitation processes for model systems and real chalcopyrite ores. As examples of our research, I will discuss in some detail our method to produce and characterise micro-patterned CuxS - silica thin films as model substrates for electrochemical and bacterial adhesion work and our approach to the interfacial chemical characterisation of extracellular polymeric substances of bio-active bacterial cells. I will also cover some of our recent findings relating to measurement and interpretation of bacterial adhesion on sulfidic substrates and its implications for bacterial adhesion and substrate selectivity. After having identified and discussed crucial leaching parameters, such as pH, Eh, T, [Cu2+], and [O2], the talk will go on addressing some of the early achievements and challenges encountered in our work to design and prepare low-cost, rugged sensing devices that allow the in-situ (in this case, in-dump or in-heap) localised measurement of these parameters. I will conclude my talk by painting the picture of how the work of our group might contribute to realising the dream of transforming bioleaching into genuine high-tech Precision Processing of minerals. This is an ABSTRACT ONLY. A full-length paper was not prepared for this presentation.

Sep 13, 2010

The New Zealand experience has shown that the trend in technologi- cal change in gold extraction can be characterised by a systems approach which grows progressively broader with advances in understanding and allowing for an increasing number of factors. The Australian experience has demonstrated that the elements of developing an exportable process include allowing projects to prolifer- ate where substantial entrepreneural involvement is likely to occur. In both countries useful technological breakthroughs were invariably discarded when first tried at operations not well established and under great pressure of achieving and maintaining production. It required the efforts of persistent individuals at operations which had become bedded in and profitable, to follow the initial work up and commercialise it.

Jan 1, 1988

The Perth Mint receives gold and silver from various sources for evaluation and refining. The metals are received in many forms and vary widely in assay. Refining is carried out using the Miller Process and the and the resulting market quality bullion is sold in a range of weights and alloys to suit the international bullion market and public demand. INTRODUCTION The Perth Mint was established in the late nineties as a branch of the Royal Mint, London, to refine the gold from the newly established gold- fields in Western Australia. The branch was opened for business in June, 1899. After refining, the bulk of the gold was used in the manufacture of sovereigns and half-sovereigns. Nowadays, although most of the gold received comes from the W.A. goldfields, some gold is deposited by producers in other states and in Papua-New Guinea, as well as scrap and trade wastes from manufacturing jewellers and old jewellery from the general public. Silver is deposited in the form of old silverware, recoveries from-photographic processes etc. Gold or silver may be lodged at the Mint in person, through a bank or other agency or by registered post. Telegraphic advice is usually given when gold is sent by the latter, so that insurance may be effected.

Jan 1, 1982

By J Stojanovic, V Kasic

Gold-bearing polymetallic sulfide deposits are common in Serbia, and mostly occur in the Karpato-Balkan and, to a lesser extent, the Serbo-Macedonian metallogenic province. These deposits û Coka Marin (Majdanpek), Grabova Reka (Blagojev Kamen), Lece (Medvedja) and Veliki Cip (Boranja) û are dominated by Cu and/or Pb-Zn mineralisation that contains a variety of Pb, Zn, Cu and Fe (¦ Sb, As, Bi) sulfides and sulfosalts, as well as native elements. Gangue minerals are composed of quartz, carbonates and rare silicates and barite. Based on their gold content these deposits can be divided in three groups:1. Polymetallic deposits with a high gold content (>1 g/t).2. Polymetallic deposits with an intermediate gold content (0.1 to 1 g/t), and3. Polymetallic deposits with a low gold content (<0.1 g/t). Gold occurs as native gold or as an alloy with silver. Native gold ranges in size from 5 to 20 ¦m, with a few rare grains over 100 ¦m, as isolated grains or as microveins (in the first group of deposits). Its distribution within the deposit in uneven. Native gold in the second group is smaller in size (1 - 5 ¦m, rarely 20 ¦m), where it is uniformly distributed in a quartz-silicate matrix. The third group is of no economical importance. The subject of research has been the first group of polymetallic deposits.

Jan 1, 2008

The conventional approach to the disposal of fine coal mine tailings, which involves piping the tailings as an aqueous slurry to a storage where they remain in the form of a permanent wet deposit, is becoming unacceptable. This approach is a legacy of a "contain and forget" mentality, which has economic advantages only in the short term. In the longer term, wet tailings deposits occupy large areas of land and present extreme rehabilitation difficulties. Alternative tailings disposal systems, which are sustainable and which facilitate rehabilitation, are required. The possible alternatives include the mechanical dewatering of fine tailings prior to disposal in combination with coarse reject, tailings disposal into spoil pile valleys, and the combined pumping to disposal of tailings and coarse reject. The most appropriate choice of fine tailings disposal strategy will vary from mine site to mine site. The chosen strategy should be optimised to meet increasingly stringent environmental requirements, within the constraints imposed by each mine. The alternative approaches represent significant departures from past practices, and require considerable industry driven research and development before they can be adopted with confidence. All three alternatives involve mixing of the fine tailings and coarse waste streams, aimed at creating a mixture of reasonable engineering properties. Understanding the engineering behaviour of such mixtures is central to the success of these alternative disposal strategies.

Jan 1, 1991