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By Jay W. H, Brown L. J

Several case studies are examined in which analysis of treated ores and extracted metal species by Mossbauer spectroscopy provides information not available by other competing techniques. The cases include poorly crystalline, surface iron oxides in titanium minerals and chalcopyrite, gold in ores and bacterially oxidised ores and the adsorbed species from gold extracted from cyanide and chloride solutions onto activated carbon and polyurethane foams. Some limitations on the use of the technique in terms of sample size, sensitivity and counting time are also discussed.

Jan 1, 1997

By B Leyland

The media in Australia is currently rife with articles and pronouncements on global warming as the most significant crisis of our time, which may æthreaten the future of civilisation as we know itÆ. This has been recently reinforced by release of Al GoreÆs film æAn Inconvenient TruthÆ, and one would be led to believe that the science of global warming is settled. And yet there is a strong body of literature disputing this apparent consensus which suggests that care should be exercised in introducing radical policies to solve a crisis which may not be real. Such policies would have a major impact on those in professions such as engineering (project approvals and design to minimise greenhouse gas emissions), accounting (carbon tax issues) and the law (corporate disputes on greenhouse gas issues are already in train in the USA). This paper addresses the hysteria apparent in the climate change debate by presenting factual evidence relating to climate change and the current phase of mild global warming. Some of the more extreme statements on future impacts are repudiated with published data, and alternatives to the purported role of fossil fuels in temperature change are offered. The potential impact of political decisions on professional activity is discussed, as are the implications of a possible future reversal of the scientific consensus, as has occurred in the past. The paper concludes with a call for the professions to exercise their Learned Society role to ensure that a rational and public debate is held on the broad issue of climate change.

Jan 1, 2007

By J R. Hernandez-Aguilar, C O. Go, C Acuna

The gas dispersion properties that are the subjects of this communication include three measured parameters, gas superficial velocity (gas rate), gas holdup and bubble size, plus derived parameter, bubble surface area flux. Over the past ten years sensors to measure these parameters have been introduced and those originating from McGill University are briefly described. The sensors have seen extensive use in plant campaigns and experiences on four cell types at three sites are discussed. The impact of frother in controlling bubble size by retarding coalescence is illustrated, introducing the need to understand chemistry/machine interactions in interpreting gas dispersion results. An increase in Sauter mean bubble size (D32) with superficial gas velocity (gas rate, Jg) was found, which followed the empirical relationship where Do ~ 0.5 - 0.6 mm and C and n are fitted parameters dependent on the system (machine and chemistry). Following this trend in Db - Jg, consistent bubble surface area flux (Sb) - Jg trends are also observed. The trend in Sauter mean versus number mean (D10) is used to help interpret the nature of the distribution; as the means approach numerically, the distribution is narrowing. Analysing gas holdup versus gas rate shows both a dependence on location in the cell as well as cell position in a bank, factors which must be accounted for when comparing data from different plants and circuits. The instrumentation and methodologies being developed are presenting new opportunities for incorporating cell hydrodynamics into metallurgical diagnostics. A case study at one plant serves as illustration.

Jan 1, 2005

A laboratory size solvent extraction apparatus has been constructed, which incorp- orates three stages of countercurrent extraction, followed by two stages of counter- current stripping. The model uses a gravity flow system from one stage to another and air lift pumps to recirculate organic and aqueous phases. A novel pump/mixer system is used to transfer solutions from the mixer compartments to the settler compartments. The model has proven valuable in the teaching of solvent extraction principles.

Jan 1, 1999

By E Yll÷, O HyvSrinen

Outokumpu has developed a new chloride leach process, called HydroCopper«, to treat copper concentrates. Chalcopyrite is quite refractory in leaching and in sulfate milieu an autoclave of high temperature and pressure is required. However, in the HydroCopper«-process copper sulfides can effectively be leached in atmospheric pressure using strong, aggressive chloride solution and copper (II) ions as oxidant. Copper is precipitated from the purified pregnant leach solution as copper (I) oxide, which is filtered and reduced by hydrogen gas to metallic copper powder, which is melted and cast into copper product. Sodium chloride formed in precipitation is decomposed in a chlor-alkali electrolyser, the products of which are circulated back to the process: sodium hydroxide to copper (I) oxide precipitation, chlorine gas to leaching and hydrogen gas to the reduction of copper (I) oxide. During 2003 - 2004 the performance of the HydroCopper«-process was confirmed in a demonstration plant processing one tonne of copper per day. It has been found to be applicable for different kinds of concentrates and can also tolerate a wide range of impurities. A significant advantage of the process is that gold can be leached as a chloro-complex and recovered with active carbon. HydroCopper« can economically recover copper from concentrates and process to a cast copper product. The best utilisation of the process is in most cases achieved when the plant is situated at the mine site. Higher recoveries are attained by the optimisation of the whole operation chain from the mine and the concentrator to the HydroCopper« plant.

Jan 1, 2005

By D Zielinski-Nicolson

The emergence of affordable, portable and versatile wireless devices has enabled a new frontier in mine safety equipment. Existing solutions provide methods for tracking personnel and assets in underground mines but are not designed to optimally integrate into existing and emerging systems. Mine management are often required to coordinate primarily independent emergency, personal protective equipment (PPE), tracking and collision avoidance systems from multiple vendors. These systems involve a variety of wireless technologies that require separate integration projects that discourage adopting new services and policies.

May 5, 2022

Laboratory scale simulation experiments show that the adsorption capacity of Au(CN)Z- on activated carbon in the presence of organic plant contaminants is dependent on the particle size of the carbon. This observation suggests that fine carbon in a CIP contactor can protect coarse CIP carbon from fouling in a dirty CIP plant. A preliminary test of this concept was made using fine lignite coal as the organic scavenger in the presence of the CIP carbon Calgon GRC22 in an alkaline cyanide solution containing Teric 401, sodium ethyl xanthate and kerosene.

Jan 1, 1991

By Moyle F. J

This paper describes an apparatus which was developed to study solid-vapour equilibria and presents results which were obtained during a study of the FeCI3-AlCI3-CI2 system. Analysis of the results showsthat fractional desublimation might offer a means of achieving a useful separation of the iron and aluminium chlorides produced by the chlorination of bauxite. The results, presented in the form of isothermal vapour pressure curves covering the range of temperature 160-200°C, support the earlier findings of Semenenko et al (Dokl Akad Nauk SSSR, 154: 42-43 (1964)) that the solid phase contains two terminal solid solutions.The equilibrium constant for the formation of the mixed dimer, FeAICI6, was approximately 4. The latent heat of sublimation of aluminium chloride varied from 18 to 26 kcal/mole AI2CI6 for solid compositionsfrom 0.9 to 0·5 mole fraction FeCls3.

Jan 1, 1979

In the future, Illawarra Coal, the primary metallurgical coal producer in the southern coal fields of New South Wales, will face many unique challenges not found in other coal or minerals production areas. To manage these challenges and determine the best strategy for the business, Illawarra Coal has adopted a systematic strategic planning process, which starts from the broadest possible options analysis and culminates in a ægo-forwardÆ operating case that individual mine sites use as the basis for short-term planning. This paper will discuss two major topics. Firstly an overview of the Illawarra Coal and BHP Billiton strategic planning processes. This will demonstrate the range of variables and inputs that are required for the planning process, and the system which is followed to evaluate different alternatives for the extraction of the resource. Secondly, having discussed the primary external and internal factors that must be accounted for in the planning process, and the main issues affecting the viability and likelihood of each alternative, the paper will discuss the particular challenges that Illawarra Coal will face in the coming decades. These challenges include: market and price uncertainty; managing impact on surface features, infrastructure and environment; community interaction; transport and logistics constraints; unknown mining environments; lack of geological knowledge; limited surface access for new mining domains; changing attitudes to longwall mining in the Illawarra; ageing workforce; and cost and overhead management. The paper intends to discuss how these issues impact the business currently and how they are incorporated into Life of Asset plans and overall corporate strategy for Illawarra Coal.

Jan 1, 2007

Exploration risk increases with time, due to a general decrease in prospectivity as the more accessible deposits are found, and be- cause of rising costs and demands due to an improving standard of living. Risk is separated into financial risk, which increases sharply at the development stage, and the risk of failure which is at its peak at the outset of exploration. Risk is also divided into internal and external factors; some of the latter cannot be offset, viz. the systematic overall risk for any enterprise. The recently emergent risk embodied in withdrawal of large areas from exploration access is discussed. An appeal is made for objective multiple land-use policies to be applied so that land remains available at reasonable cost and with appropriate environ- mental safeguard conditions. Risks specific to gold exploration are discussed. As gold now accounts for over 50% of all mineral exploration, and most other metals are depressed, any sharp decline in gold will have grave effects on the ex- ploration industry. Gold exploration will become more difficult and expensive in about five years, after most of the readily accessible deposits in Australia are found. Government's role is important in pro- viding stability and basic data at reasonable cost. Exploration for specific minerals or of particular areas could be stimulated by extending the 150%.tax deductibility of R & D to aspects of exploration of strategic im- portance, particularly in the event of a downturn. Exploration is classic scientific research, at least through to the proving Stages.

Jan 1, 1987

Exploration risk increases with time, due to a general decrease in prospectivity as the more accessible deposits are found, and be- cause of rising costs and demands due to an improving standard of living. Risk is separated into financial risk, which increases sharply at the development stage, and the risk of failure which is at its peak at the outset of exploration. Risk is also divided into internal and external factors; some of the latter cannot be offset, viz. the systematic overall risk for any enterprise. The recently emergent risk embodied in withdrawal of large areas from exploration access is discussed. An appeal is made for objective multiple land-use policies to be applied so that land remains available at reasonable cost and with appropriate environ- mental safeguard conditions. Risks specific to gold exploration are discussed. As gold now accounts for over 50% of all mineral exploration, and most other metals are depressed, any sharp decline in gold will have grave effects on the ex- ploration industry. Gold exploration will become more difficult and expensive in about five years, after most of the readily accessible deposits in Australia are found. Government's role is important in pro- viding stability and basic data at reasonable cost. Exploration for specific minerals or of particular areas could be stimulated by extending the 150%.tax deductibility of R & D to aspects of exploration of strategic im- portance, particularly in the event of a downturn. Exploration is classic scientific research, at least through to the proving Stages.

Jan 1, 1987

By Hyslop W

It is shown that coke has a major influence on the pattern of operation and on the aerodynamics of the blast furnace and that the physical and chemical characteristics of coke, at each stage in the furnace, determine its ability to satisfy requirements for iron production and coke economy. Analysis of coke sampled from operating furnaces is compared with furnace behaviour. The available data suggests the importance of segregation, strength, size change and chemical degradation of coke on furnace performance. Correlations are presented for coke breakdown ratio as a function of coke rate and hearth diameter which shows that breakdown increases with hearth diameter and with decreasing coke rate. It is also shown that the Micum tests do not reflect the coke strength in a predictable way and that solution reactions appear to play an important role in giving rise to a pitting effect on the cell walls of the coke with the resultant deterioration in coke properties. The catalytic effect of activating substances, such as alkalis, is noted and results are presented which show the effect of carbon solution on the coke strength. The importance of coke in the stack and in the bosh is discussed and flooding results are presented for BSC furnaces which show the probable driving limits for the furnaces considered. It is also shown that coke sampled from different tuyeres in a furnace gives quite different flooding limits. Other applications of the coke test work at BSC are also noted and the relevant objectives listed.

Jan 1, 1975

The Airport Link Railway utilises innovative solutions to a number of issues associated with underground development and transport infrastructure planning. It is typical of the major change underway in the countryÆs rail and air transport industry. It involves the private sector providing transport facilities in competition with the public sector, a convergence of planning and transport imperatives, the use of the most technologically advanced engineering practices to minimise construction impacts on the community and a commercialised way of developing and maintaining railway infrastructure and services.

Jan 1, 1999

By J S. J van Deventer

Geopolymerisation is a new technology that processes and transforms aluminosilicate minerals into mechanically strong and chemically stable products. In this investigation, minerals such as fly ash and kaolinite were used as the solid raw materials for geopolymerisation. Inorganic salts were added to the geopolymeric pastes to simulate ionic contamination during processing for building and construction applications. The resultant products were examined and characterised physically. It was found that the early strength development of geopolymeric pastes could be changed according to the nature as well as the extent of the contamination. At a small dosage, the effect of the contamination on the early geopolymeric system depended heavily on the nature of the artificial surfaces that were created in the geopolymeric solution through the addition of the chemical additives. For example, the samples containing MgCl2 and Mg(NO3)2 had shown the same yield stress developments due to the similar surfaces that were formed. The cations of these salts were expected to hydrolyse and form magnesium hydroxide precipitates immediately after the addition to the early geopolymeric systems. The calcium cations of CaCl2 also precipitated upon addition, but the nature of the surfaces of these hydroxides was quite different to those of the magnesium hydroxides and gave rise to different yield stress development. The samples that contained the insoluble salts (in water) demonstrated different yield stress development when compared to each other because of the different nature of the additive surfaces that were exposed to the geopolymeric solution. These results suggested that heterogeneous nucleation could be responsible for the change of the rheological behaviour upon inorganic salt addition. When the extent of the ionic contamination was large, the anions released from the insoluble salts (in water) changed the nature as well as the concentration of the geopolymeric solution and the setting processes were retarded. Oxides, in general, behaved very differently from other salts, indicating the uniqueness of the oxygen anions in a system rich in hydroxyl and silicate anions. The inorganic salt contamination in geopolymers did not show any significant signs of structural change according to the XRD diffractograms collected. The seven-day compressive strength was not lowered by the inorganic salt contamination and it could sometimes be beneficial to the product performance, for example, an increase of 20 MPa was induced by the addition of calcium oxide. Inorganic salts as chemical additives have demonstrated the potential to modify setting times of geopolymers without sacrificing much of the productsÆ strength and integrity.

Jan 1, 2000

By Grynberg H, Lindon P, Wardrop J

The Gippsland Basin is unique in Australia in that it is a major resource based industry centre within a sensitive and special environmental context supplying Melbourne, a major urban/industrial environment with most of its energy 'on-line'. The environmental effects of the supply systems are generally local and mostly affect only those who are directly or indirectly dependent on the upstream systems. The major urban metropolis which is served remains largely unaware of the environmental impacts of the system upon which it is dependent, except when specific attention is drawn to them as in the case of the Latrobe Valley Outfall, algal blooms in the Gippsland Lakes, etc. This paper discusses the environmental context within which the energy industries operate, the environmental legislative framework which applies, the likely environmental impacts and some solutions. The energy resources of the Gippsland Basin occur in an area where the physical environment exhibits a wide variety of inherent energy states in its physical and biological regimes. The off-shore regions of the oil and gas platforms has to be able to withstand the wind and wave energy generated in a shallow sea in a confined waterway lying athwart the main current and climatic stream. The coastline includes the delicately balanced quiescent environments of Corner Inlet with its 'wilderness' tourism industry and the powerful surf and long shore drift and dunes of Ninety Mile Beach.

Jan 1, 1992

This paper gives the background to the development of solvent extraction processes for the recovery of metals from aqueous solutions. Its growing importance in Australia for the recovery of both uranium and copper is dis- cussed, as well as the developments in mixer-settler design as applied to recent plants. The economic significance of solvent extraction as an alterna- tive to cementation is discussed and important features of each process are highlighted by comparison of costs for each process in a hypothetical situa- Tion.

Jan 1, 1971

A BRIEF account of the water-power potentialities of Tasmania is given, together with possible applications of the power commercially. A short history of the Waddamana development is then given, and the main works are described.WATER POWER POTENTIALITIESTasmania is an island of approximately 24,500 sq. miles area (exclusive of small islands). An area of 12,000 sq. miles is at an elevation of over 1000 ft. above sea-level, and of 2300 sq. miles at over 3000 ft. above sea-level. Average annual rainfall varies from' over 140 in. on West Coast to 20 in. on East Coast, and for the whole island averages 48.5 in. The total water-power available, based on conservative figures for run off and efficiency, is 6,000,000 b.h.p. Only a small percentage of this total will, under present conditions, and under likely conditions in the immediate future, be capable of being developed commercially.An extensive hydro-metric and water-power survey is at present being carried out in order to collect information concerning the most promising water-power schemes. Already 400,000 b.h.p. has been located in different proposals, and there is still a large area of very likely country along the West Coast which has not been investigated yet. Tasmania thus has very vast power potentialities, which, combined with good ports and communications and wonderful mineral and timber resources, should augur well for the establishment of the great key industries, particularly chemical and metallurgical.

Jan 1, 1923

By Allnutt S. L, Radojkovic A. M

Century, a major shale hosted zinc deposit in the Riversleigh Fold Zone of northwest Queensland's Mount Isa Basin, was discovered by CRA Exploration in 1989. A total of 322 drill holes, completed by the end of 1992, define a resource of 118 Mt of mineralisation averaging 10.2 per cent zinc, 1.5 per cent lead and 36 grams per tonne silver. Mineralisation is developed in the upper portion of Lawn Hill Formation Unit 4 (Pmh4). The intersection of the Termite Range and Little Range Faults, major regional structures, may have been important in controlling mineralisation development. Three listric normal faults, and an unconformity between Proterozoic rocks hosting mineralisation and overlying Cambrian carbonates, divide the deposit into three distinct blocks. The deposit is essentially blind, outcropping in only two places. The deposit is characterised by an extremely simple sulphide mineral assemblage, sphalerite being the most common sulphide phase. Pyrite, the most common phase in many other shale-hosted zinc-lead deposits, accounts for only five per cent of all sulphides present. Siderite is the principal non-sulphide phase present. Both sphalerite and galena have near stoichiometric compositions. Sulphides are confined to carbonaceous shale horizons. Intervening siltstones are essentially barren. Shale and siltstone beds forming the mineralised sequence can be correlated across the entire deposit area. Systematic grade variation occurs within each mineralised shale bed. Although sulphide laminae parallel primary lithologic layering, the point of most intense mineralisation development transgresses stratigraphy. Bituminous material is intimately associated with sulphide mineralisation.

Jan 1, 1993

Mineral ownership determination is not always straight forward as in many cases the relevant details are not recorded on the latest Land Transfer title held in the local Land Registry Office. To determine mineral ownership can be difficult, time consuming and expensive especially in a confused sector. Non statute minerals can be owned by the Crown, Land Owner or other persons. Statute minerals (Gold, Silver, Petroleum, Uranium) are always owned by the Crown and thus present no problems. In simple terms the only accurate and reliable method of determining the mineral ownership under subject land is to historically search back to the first registration when the land and minerals were definitely intact. Then carefully ascertain from the evidence gathered along the way to the present day whether any legislation or private agreement altered or affected the status quo.

Jan 1, 1998

By Umetsu Y, Su Qing-quan

The electrical conductivity of electrolytes is very important in metal electrowinning and electrorefining processes as it has a very large influence on the energy consumption. There are few measurements of the electrical conductivity of zinc electrowinning electrolytes available. The electrical conductivity of zinc electrowinning electrolytes were measured over the following range of concentrations, 100 to 200 g/L H2SO4, 0 to 80 g/L Zn and 0 to 20 g/L Mg, at temperatures from 25 to 60 C. The specific conductivity of zinc electrowinning electrolytes may be expressed as a function of concentrations of sulphuric acid, zinc and magnesium and temperature by the following equation: k(S/cm) = 0.004 + 0.00115 t + 0.00282 [H2SO4] t - 0.00114 [M] t + 0.3442 [H2SO4] - 0.0451 [1-12SO4]2 - 0.1058 [M]ò[H2SO4] - 0.0224 (M] + 0.0286 [M] 2 where t is temperature (C), [H2S04](moI/L) is sulphuric acid concentration and [M](mol/L) is a sum of zinc and magnesium concentrations, ([Zn]+[Mg]). The specific conductivity of zinc electrolytes is a function of the concentrations of the hydrogen ion and free water molecule, which are calculated by taking into account the second ionisation constant of sulphuric acid and the stability- constants of zinc-sulphate and magnesium-sulphate complexes at 25 C.

Jan 1, 1993