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By S M. C Verryn

Through the application of the Rietveld method, X-ray diffraction analysis has developed into a fully quantitative method for phase analysis of metallurgical products. The Rietveld method itself has progressed from an unstable method that required constant operator intervention to a stable and robust method suited even for routine process control. Knowledge of the crystal structures of the major phases is essential for Rietveld analysis, and these are well known for most minerals and major phases in metallurgical products. It provides the basic structural information necessary for the determination of mineral stoichiometry and for elucidating solid solution behaviour. Modern methods, such as simulated annealing and charge flipping, permits the determination of crystal structures from powder data. Unit cell data can be used where conventional microchemical analysis is unable to provide an answer to the extent of solid solution in ilmenite roasting. Unit cell data (by XRD) is used to determine the amount of roasting necessary for the development of magnetisation to be able to separate chromite from an ilmenite concentrate. Phase quantification is probably the most widely used application of XRD analysis. It is used for materials balance in the minerals and cement industries, and it is finding novel applications in the iron and steel industry. Applications of XRD in high-temperature metallurgical processes are increasing. In this paper the phase chemistry of iron ore sinters, the evaluation of subsolidus reactions in titania slags and the identification of furnace accretions are discussed. Despite the success of the Rietveld method in phase quantification, the method still needs further development in the quantification of closely related or polytypic phases. The quantification of pyrrhotite phases using various Rietveld programs still gives ambiguous results. This is also true for the different SFCA phases in iron ore sinters. Clearly the analysis of similar phases, differing only in the presence of weak superlattice reflections is still problematic.

Jan 1, 2008

By Gao K, Wu C, Langley J. M, Waugh B, Farrell K

The dissolution of carbon from carbonaceous materials into molten iron is a key step in various ironmaking operations. For example, in new direct smelting processes, carbon in the form of coal is injected into the molten iron bath, which leads to the dissolution of carbon. In foundry operations, typical recarburizer materials can range from high purity graphite to chars. The dissolution performance of these" materials is critical to the operation and could dictate the efficiency and economics of the process.Dissolution kinetics has been studied by various investigators to explain the influence of melt conditions and carbon type (Sahajwalla et al, 1994; Shigeno, Tokuda, and Ohtani, 1985; Orsten and Oeters; 1988; Ganguly and Reid, 1992; Wright and Taylor, 1993). The influence of melt sulphur content on the dissolution kinetics has been characterised (Sahajwalla et al, 1994), with sulphur retarding the rate of carbon dissolution. The carbon dissolution from different sources is seen to vary significantly even under similar melt conditions. This observation has been explained by investigators on the basis of the varying ash content present in the carbonaceous materials. However, ash content alone cannot account for the variability in dissolution kinetics reported in other studies. One such study is presented below.In a recent study (Sahajwalla et al, 1994), pulverised carbonaceous materials were injected into the molten iron bath and the" dissolution kinetics was established. The dissolution of graphite and glassy carbon, which contain almost 100 per cent carbon, was seen to be significantly different when the molten iron contained sulphur. The influence of melt sulphur content was explained on the basis of different wetting behaviour observed.Importantly, the study showed that even pure carbon sources dissolved at significantly different rates. Hence, their performance could not be explained on the basis of ash content.The key difference between graphite and glassy carbon is in their atomic structure. Graphite is highly ordered whereas glassy carbon has relatively poor ordering in its atomic structure. This study showed that the atomic structure in carbonaceous materials can have a significant effect on their dissolution performance.The focus of the present investigation which stems from the past study described above (Sahajwalla et al, 1994), is to investigate the influence of atomic structure of carbonaceous materials on their dissolution into Fe-C-S melts.The specific objective of this study is to determine the relationship between dissolution kinetics and crystallographic character of carbon sources. In order to accomplish this goal, a range of different materials representing a spectrum of carbon sources have been chosen for the investigation. These materials include brown coal char, two types of Auscarb (A and B), and commercial graphite. Auscarb is prepared by calcining Auscoal at 1000°C. Auscoal is made from chemically cleaned Australian coals (Bowling, Chandler and Waugh, 1990). Part 1 of this paper details the dissolution performance of the materials studied, while Part 11 describes the X-ray diffraction study. The relationship between the atomic structural dimension and dissolution rate constant is discussed in light of the results obtained.

Jan 1, 1996

Exploring the Breakage Environment in Mills with Discrete Element Methods

Sep 13, 2010

By M Begbie, R J. Norris, D J. MacKenzie

The Otago Schist is crossed by numerous deformation zones that formed in the latter stages of metamorphism and uplift of the metamorphic belt. These deformation zones are long (tens of km) linear features at the regional scale, and are generally narrow (km scale or less). Many of these structural zones separate schist domains with different rock types and structural/metamorphic histories. The Hyde-Macraes Shear Zone is one such deformation zone, and this zone hosts the active Macraes gold mine. The Rise & Shine Shear Zone, 80 km NW of Macraes, is also enriched in gold and has been mined historically. Mineralisation in both these shear zones occurred during the transition from ductile to brittle deformation as the schist belt was uplifted from greenschist facies metamorphic conditions. Recrystallisation of quartz and micas in the early stages was overprinted by cataclasis, with sulfide and gold precipitation throughout. Many of the other late metamorphic deformation zones formed under similar greenschist to sub-greenschist facies conditions, with similar overprinting of recrystallisation textures and folds by more brittle textures such as breccias. Under these conditions, originally regionally pervasive deformation at the highest metamorphic grades was evolving towards more focussed high strain zones at lower temperatures and pressures. Shear zones initially focussed fluid flow along microshears and mineral grain boundaries, resulting in 1 to 100 m scale alteration and replacement in the host schist, with only local development of quartz veins. Fluid flow was not controlled by open fractures, and the rate of fluid movement was probably slow and pervasive. After uplift into the brittle regime, the schist belt underwent tectonic extension. Extension was accompanied by development of swarms of steeply dipping veins, with localised mineralised normal faults. Hydrothermal fluid flow throughout this uplift history was a normal consequence of late stage devolatilisation of the metamorphic belt. Hence, all late metamorphic deformation zones should be considered prospective for gold accumulation.

Jan 1, 2005

By B Hayter, M Carr, K Williams, C Wheeler, W Chen

Current trends into mining iron ore have seen an increase in the exploitation of problematic orebodies that would typically be disregarded. These bulk materials cause problems within all facets of the material handling stream, from remains left in train wagons to transfer chute blockages, which can cause costly downtime to mining operations (Roberts, 1998). These problematic bulk materials are referred to as wet and sticky material (WSM) due to the adhesive and cohesive nature they possess. Their characteristics can be computationally expensive to model. With the development of discrete element modelling (DEM), in conjunction with advancement in computational power over the past decade, it is now more feasible to model WSMs into the DEM technique.This research will couple two different contact models that can represent the characteristics of a WSM. These models include the Simplified Johnson-Kendall-Roberts (SJKR) and the Easo liquid bridging contact models. The SJKR contact model is an expanded form of the classic Hertz model. This model includes the tensile forces that are in the contact zone between two bodies when they are separated, which the Hertz model failed to capture (Johnson, Kendall and Roberts, 1971). The Easo liquid bridging contact model accounts for the capillary effects and surface tension that will form between two bodies, such as that of a WSM (Soulié et al, 2006). Both of these models were coupled to give the best representation of a WSM, which was simulated using MoleculeX™ (Chen and Williams, 2017) as the software platform.Additionally, this research also investigated the adhesion of problematic iron ore samples onto impact plates under dynamic conditions. An experimental set-up consisting of an apron feeder and inclined impact plate was utilised, to gain an understanding of the way the material builds-up and the possible modes of failure that could be experienced. This was undertaken for different wall liner materials, wall liner angles and moisture contents of the iron ore samples. From this, a series of DEM calibration simulations were conducted on the experimental set-up and particle size distributions (PSD) of the iron ore samples. This enabled forming of a database of parameters, which can be scaled for on-site applications in relation to geometry of the plant and PSDs that would represent run-of-mine ores.CITATION:Carr, M, Williams, K, Chen, W, Hayter, B, Roberts, A and Wheeler, C, 2017. The dynamic adhesion of wet and sticky iron ores onto impact plates, in Proceedings Iron Ore 2017, pp 511–518 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By B K. Hebblewhite, F T. Suorineni, J D. Tibbett

Block caving is an underground mining method that can provide high production capacities at low operating costs. This enables the profitable extraction of massive, low-grade orebodies and attracts industry towards the method. Block caving operations require significant initial capital investment and predictable cave propagation is crucial to safety and economic success. Lack of access to observe the caving process hinders our ability to learn how the rock mass and geological structures are reacting to mining. Virtual reality scientific visualisation (VRSV) enables the integration and investigation of multiple, large caving data sets and provides a viable alternative to visualise rock mass response without physical access to the cave. Point instrumentation is incapable of providing an overview of cave performance and seismic monitoring, while providing an overview of the rock mass and the response of structures to caving, is only useful when linked to the caving activities. The integration of point instrumentation data with seismic monitoring information, coupled with scientific visualisation of the mining system in a virtual reality environment, provides a powerful means for understanding caving performance.This paper describes the use of a VRSV module at UNSW Australia, designed for investigating the block cave mining system from a case study operation. This module has been used to investigate the location and chronological evolution of seismicity to understand sources of damage resulting in seismic space-time sequences (SSTS) in the caving system. The events within an SSTS represent damage that is spatially and temporally related. An SSTS group represents a collection of microseismic events from a reasonably competent region of the rock mass that has experienced a stress change significant enough to cause sequential damage. SSTS group locations have been seen to be the path of subsequent cave propagation. Thus, SSTS analysis enables insight to further our understanding of rock mass damage in caving geomechanics through analysis of historic data. Such insight has operational potential to learn from recent rock mass activity for optimising the management of undercut advance, draw front advance and cave draw patterns.CITATION:Tibbett, J D, Suorineni, F T and Hebblewhite, B K, 2016. Understanding damage source mechanisms in a caving system using virtual reality scientific visualisation, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 439–452 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By M Wagner, H Assimi, F Neumann, C Garcia, B Koch

Run-of-Mine (ROM) stockpiles are the inventory of valuable materials extracted from the mine. Depending on the customer requests, a selective addition of ore from stockyards should be selected at the required tonnage. In the stockyard, stackers and reclaimers are the machines which load and unload ore, respectively. Currently, humans determine the reclaiming/stacking planning sequence in the stockyard by rules of thumb. However, this is a complex task subject to multiple operational constraints, such as where undesirable mineral properties should not exceed certain limits in a request. Human planning can lead to limited decision support and lower ability to consider the upcoming blends and requests. This kind of decision making can cause perturbations in the assumed profit and unexpected loss in practice. Therefore, an intelligent decision-maker and sequence planner would be highly valuable to automate stacking and reclaiming operations in practice. The benefits are reducing variability in decision-making and operation costs. This paper considers a stockyard with available mineral information in the stockpiles using load and dump locations from GPS data feeds. We present an optimisation problem to find a solution which results in reclaiming more ore in a shorter time. To solve the problem, we develop an automatic search strategy based on the greedy search algorithm independent of the type of machine used in reclaiming. The proposed method plans a sequence for stockyard recovery blend optimisation to meet multiple customer demands in a timeframe. Blend optimisation is subject to various constraints such as the elemental composition of the valuable materials and penalty elements. We present three case studies using EKA’s simulator, to fulfil two to four requests from four stockpiles. We compare the obtained results with a pilgrim step reclaiming heuristic and we show how our proposed search strategy outperforms the current strategy used in practice.

Nov 10, 2020

By Reid K. J, Restarick C. J

The breakage and flow characteristics of quartz, ground as a minor constituent with calcite in a continuous wet ball mill, have been determined by carefully controlled grinding tests.A mathematical model, combining the simple functions which describe these characteristics, has been used to predict both steady state and non steady state results.The calculated results are compared with experimental data.

Jan 1, 1966

By Morrison J

Considerable confusion is to be found in the methods of estimating mineral reserves. The solution appears to be more cooperation between industry and government to agree upon a classification system with guidelines to overcome the problem of the many variable factors affecting reserves. The classification system proposed by the United States Bureau of Mines and the United States Geological Survey (USBM/USGS) together with the guidelines similar to those suggested by the Australasian Institute of Mining and Metallurgy/Australian Mining Industry Council (AusIMM/AMIC) is recommended for reporting mineral reserves to government.

Jan 1, 1979

By S Sineva, E Jak, M Shevchenko, D Shishin

This study represents a part of comprehensive research aimed at integrating nickel into a thermodynamic database constantly developed at Pyrosearch. The behaviour of Ni in calcium-ferrite slags is considered. An integrated approach combining experimental and thermodynamic modelling methods has been employed to predict phase equilibria in the NiO-CaO-FeO-Fe2O3 system under oxidising conditions and in equilibrium with the metal FeNi phase. The compositions of liquid slags and coexisting solid solutions have been determined through the analysis of equilibrated and quenched samples by electron probe microanalysis technique (EPMA). The research results are presented in the form of liquidus projections on the corresponding phase diagrams, considering both oxidising and reducing conditions. The solubility of Ni in spinel, dicalcium ferrite and calcium oxide as well as solubility of Fe and Ca in Ni monoxide, have been examined under several atmospheric conditions. Additionally, the compositions of the NiO-FeO monoxide in equilibrium with metal phase have been studied. The experimental data not only support the outcomes of thermodynamic modelling but also validate the parameters of the applied thermodynamic models, thus confirming the reliability and accuracy of the integrated approach.

Aug 21, 2024

By E Mielczarski

Determination of the adsorbed layer composition and structure at molecular and atomic levels and understanding adsorption mechanisms and dynamics are vitally important for the preparation of surface layers with specific functions. Direct information, at a molecular level, about mineral surface composition, its structure and surface distribution is crucial to perform an efficient separation process for mineral beneficiation. This information is equally important for modifying surface properties of industrial minerals for specific applications such as: fillers, composites, weathering resistance, etc. An understanding of the mechanisms and kinetics of the interaction of first adsorbed organic molecules with mineral surfaces is a fundamental requirement for the prediction and control of the macroscopic surface properties governing the efficiency of separation technologies or new material formulations. The developed infrared external reflection technique has a unique ability to study interface phenomena, at a molecular level, on heterogeneous substrates. The variety, precision and reliability of information about the interface phenomena delivered by this technique is superior to any other single technique. The experiments are fast and non-destructive. High sensitivity (starting from 20 per cent of the monolayer) in situ collected information in a multiphase system, even in the region of strong absorption of the substrate, makes this technique a very valuable experimental tool. The complexity of the recorded reflection spectra, their sensitivity to variations of the optical properties of all bulk and surface components and their spatial distribution in the system under investigation, are in fact the major strengths of this technique. A few examples of the application of this multi-diagnostic technique, for monitoring surface modifications of semi-soluble minerals for selective flotation, will be discussed in detail in this paper.

Jan 1, 2005

Of all of the processes in the mining cycle, blasting has the greatest impact on the efficiency of both mining itself and the initial stages of ore processing. The cost of blasting can be readily accounted for, but the true benefits of an effective blasting operation are seldom measured or reported. This means that blasting is seldom optimised in terms of its overall economic impact on an operation. Blasting operations have evolved according to the environment provided by mine management. Most operations seek to minimise the unit cost of each component process (overburden removal, blasting, excavation and transport, crushing or grinding) without recognising the impact that blasting performance has on subsequent activities. The creation of æcost centresÆ or æmanagement unitsÆ that isolate blasting from its downstream impacts reinforce this trend. Modern blasting technology is regarded as sophisticated by virtue of the mechanical design of the drills, the chemistry of the explosives and the flexibility and reliability of modern blast initiation systems. However, blast performance is controlled by the nature of the rock mass and there is generally an inadequate appreciation of how blast designs should be tailored to suit different rock mass conditions or to meet different blasting objectives. Most operations utilise a limited suite of standard designs without routinely tailoring designs to suit the actual conditions at hand or the objectives of each blast. Mining operations would benefit from tackling the following specific challenges:What is the appropriate target performance for blasting operations to generate the maximum economic benefit for the operation as a whole? How should designs be configured to suit the changing rock mass conditions and operating constraints? What compromise (if any) should be allowed from the ideal to assist conflicting scheduling or other operational requirements? How can blast performance be measured and reported to provide appropriate guidance to future operations? These challenges can be tackled through the process of æblast engineeringÆ. This paper discusses the potential impact of blasting performance on the economics of mining operations and the author argues that very considerable benefits over and above those currently being achieved could be realised by improving the routine engineering of mine blasts. The paper then explores how the industryÆs failure to recognise the economic importance of blasting has resulted in the engineering of blasting operations receiving less management and technical support than is appropriate. Finally, a simple approach to the engineering of routine blasting operations is described as an example of how these challenges can be tackled.

Jan 1, 1999

For several decades miners have been obliged to maintain a vast supply of sharp steels at the working face to meet the hungry needs of rock-drills. In medium and large size mines this has meant the setting up of an organisation to store steels, to make and sharpen bits with all the complication and skill of forging, hot milling and heat treatment, and to transport sharp and dulled steels to and from the working face with all its labour, wastage, and inconvenience to other mining operations.In a mine with 250 rock-drills in use, a flow of more than 60,000 sharpened steels each month has to be maintained to keep the machines fully employed, so some idea of the magnitude of this problem may be grasped.For a long time it has been apparent that it is mainly the bit itself that wears, and many attempts have been made to reduce the enormity of the problem by providing detachable steel bits which could either be used once and rejected, or sharpened three or four times before rejection.At the same time metallurgists have striven to 'improve the quality of the steel and the heat treatment afforded it so that a bit, readily workable In a normal mine drill-shop, could be produced having a high resistance to wear and fatigue; but, although various alloy steels have been marketed, it is still usual to find many mines relying on a "straight" carbon (0.6 - 0.9% C.) steel for their drill steels.Since 1915 increasing use has been made of tungstencarbide as a cutting implement in the engineering industry. Where, on account of its great hardness and long life, it...

Jan 1, 1948

By T Berryman

The Fimiston reserve is being depleted at the rate of one million ounces per year; most of which is processed by the Fimiston plant, with the remainder being stockpiled. As for most other large open cut mines around the world, Fimiston has an excellent dispatch and tracking system. Reconciliation is used to determine how the various models used in mine planning (such as a reserve, budget and schedule models) are tracking against production. It is also used to gauge the performance of grade control estimation against production; however, analysing the results of this can be complicated and, at times, misleading. The reconciliation process involves adjusting the monthly production data to equal the mill reported tonnes and grade, plus the change in stockpiles. This adjusted number is then compared to the grade control reported tonnes and grade, the scheduled model (monthly planning model) tonnes and grade and against budget (Reserve) tonnes and grade. This paper includes explanations of all assumptions made in the reconciliation process, including the end of month closing stocks balance, the application of adjustment factors to the dispatch data to create a new balanced set of production data and the monthly sign off to comply with the Sarbanes-Oxley requirements of the North American owners. The reserve is reconciled by proved and probable classification. This tool is used to assess the robustness of the classification scheme utilised and identify any reconciliation issues as they arise. Within the Fimiston deposit there are still issues that are clouded by the assumptions made concerning the scale of observation, poor data support and the mining of the narrow lode areas of the deposit. The declared ore mined (DOM) number (which is defined in the paper) can be significantly affected by these assumptions, and these need to be clearly stated and understood when looking at the reconciliation data. The DOM tonnes and grade is a good indicator of real mine performance as it adjusts mined tonnes and grade to take into account the milled tonnes and grade each month, and prevents cumulative errors from building up in mine predicted dispatch numbers or end of period stockpiles. This number allows monthly monitoring of the mine to mill performance and allows valid comparisons to be made back to budgets and reserves over a period of time. KCGM uses three month rolling averages to monitor performance against reserve and budget models. This ensures that monthly distortions in the figures due to stockpiling issues or over mining in a particular period do not lead to false conclusions. Reconciliation performance over a longer period (12 - 18 months) is used to adjust reserve models should significant variance be observed. By closely monitoring the reconciliation performance at the Fimiston operation, fine tuning of all aspects of the grade estimation process from reserve through to grade control can be made. This allows the most accurate data to be used when planning from reserve data for the Life of Mine Plan through to grade control data for short-term mill feed.

Jan 1, 2006

By K Faure

At Sams Creek a gold-bearing, peralkaline granite pophyry dike intrudes Ordovician-Silurian metapelite and quartzite. These metasedimentary rocks have undergone three phases of folding: a first phase of recumbent folds (F1), a second phase (F2) of northerly-trending inclined folds with a prominent crenulation cleavage, and a third phase (F3) of steeply plunging folds. The granite porphyry dike has a thickness of up to 40 m and intrudes thin lamprophyre dikes along its contacts. Deflection of the crenulation cleavage around the granite dike, shearing within the dike and its sinuous outcrop pattern indicate that the granite dike has been deformed during F2 and F3. The granite has been hydrothermally altered, with a first stage of magnetite-ankerite alteration. This first stage is cut by a second stage of quartz-pyrite veins and a third stage of sulphide, quartz and ankerite veins, accompanied by pervasive silicification represented by quartz-perthite-albite-rutile¦pyrite-ankerite-sericite assemblages. Lamprophyre is altered to an ankerite-chlorite-sericite assemblage. The sulphide veins are composed of arsenopyrite + pyrite ¦ gold ¦ galena ¦ sphalerite ¦ chalcopyrite ¦ pyrrhotite. The altered granite and the veins have been deformed and recrystallised. The competent sulphide minerals pyrite and arsenopyrite are fractured and brecciated, with fractures locally filled by galena, a ductile sulphide mineral. Vein quartz shows local cataclastic and mortar textures and develops pressure shadows around arsenopyrite. Alteration and mineralisation are confined to the granite porphyry and adjacent lamprophyre. These features together with the style of veining and the sulphide mineralogy indicate that the mineralisation was formed from a magmatichydrothermal fluid that was sourced from the granite. Oxygen, carbon and sulphur isotope values of the vein minerals (quartz, ankerite and sulphides) are also consistent with a magmatic source.

Jan 1, 2003

By Glaessner M. F

The island chains of the Western Pacific (Fig. 1), on account of their related origin, and the similarity of the rocks that compose them, constitute in the main a most homogeneous mineral province. They lie in a complex "mobile" zone of the earth's crust, that formed a geosynclinal area separating the continental margins of Australia and South-Eastern Asia (the so-called Sundaland) from each other, and from the margin of the Pacific Ocean proper (FIg. 2). The whole region was drowned at the close of the Ice Age, as a result of the rise of sea-level that accompanied the melting of the great ice caps in the polar regions, leaving only the higher portions as islands and peninsulas, many of them separated only by shallow seas or "shelves."The geosyncline was infilled with Mesozoic and Tertiary sediments that have undergone varying intensities of folding and metamorphism, and has been subject to intermittent periods of volcanic activity, continuing into the present. Midway between the two continental margins there is a narrow belt of pronounced negative gravity anomalies, with an extraordinary S-shaped convolution in the vicinity of the Banda Sea and Celebes, that marks the core of this unstable region. The folding within the "mobile" zonetrends parallel to it, so that the islands in its vicinity, which are regions elevated by folding, are all elongated in the strike direction of the folds. This explains not only the linear shape of Sumatra and Java, but the arc of islands enclosing the Banda Sea, and the peculiar shape of Celebes.Parallel to the belt of negative anomalies, at a close remove from it, is the line of Recent, or active volcanoes, that extends along the whole length of Sumatra and Java...

Jan 1, 1947

A recently discovered high temperature (22G-2800°C) reaction between glycerol and the oxides and hydrous oxides of iron produces a green, well-crystalline complex glycerato-iron, whereas hydrous nickel oxides an) reduced by the glycerol to metallic nickel. When nickel isomorphously substitutes for iron within the goethite lattice this high temperature glyceration allows a separation of the two metals whereby the nickel can be extracted by solution techniques.

Jan 1, 1971

Process Study on Some Ag-Cu-Pb-Zn Polymetallic Ore in South China

Sep 13, 2010

By G Chitombo, M Ruest

In surface mining, studies of the kinematics of blasted rocks using high speed film/video image analysis have allowed the estimation of the starting time, direction and magnitude of visible movement of fixed sections of the free face. Horizontal displacement versus time plots from discrete targets at the face generally report changes in slope over very small time intervals. These changes indicate step increases in velocity due to the action of explosive gases. In practice, the onset of rock mass movement, different to localised spalling, has been associated with a response time which exceeds the combined times of detonation, propagation and reflection of stress waves. This time is referred to as minimum response or burden movement time. As an engineering index, burden movement time has been used to provide guidelines for the selection of inter-hole and inter-row delay sequences in production blasting. With respect to improving breakage and fragmentation, it has been demonstrated that the delay interval between adjacent explosive charges should be less than the expected burden movement time. Similarly to reduce confinement between rows, delay intervals should exceed the expected burden movement time. The Hybrid Stress Blasting Model (HSBM) is a modelling framework that dynamically links an ideal and non-ideal explosives detonation code to a geomechanical rock model. This blast simulation tool is aimed at analysing the role played by different explosive formulations in fragmenting and/or damaging various rock types under different degrees of confinement. In the current framework, the rock behaviour under extremely high pressures and loading rates is calibrated from shock tests and the role of the explosive in fracture growth is accounted for and assumes a compressible fluid flowing through the explicit fracture network. The model is being developed as part of an international collaborative research project funded by a consortium of companies comprised of explosive and equipment suppliers and major mining houses. As part of the development and validation of the HSBM project, data from literature addressing the kinematics of the rock mass (ie burden displacement, face velocities and response times) has been collated and used to evaluate the current version of the code. A series of numerical experiments have been conducted with the view to: evaluate the response of the rock mass to changes in burden distance given by the impact of both stress waves and radial gas flow pressure;compare the modelling outcomes in terms of displacement, response time and face velocities to documented field observations; andcompare stress induced and stress/gas induced modes in terms of burden displacement outcomes. Results from these experiments have shown that in its current form the model is able to capture the trends observed and measured in practice. This is with respect to the simulation of burden displacement, response time and average face velocities for different geometries and charging conditions. The experiments have served as consistency checks which form part of an ongoing and comprehensive evaluation and validation of the HSBM code also aimed at addressing some of its current limitations.

Jan 1, 2007

By K Friese, H P÷llmann

Clinoptilolites, modified with sodium, produced a material which has been tested for the ability to remove Hg (II) from aqueous nitric acid. The amount of adsorption depends on contact time, acid concentration of aqueous solution and initial mercury concentration. The study of the kinetics of mercury uptake revealed that all sorbents exhibit a fast rate of sorption. The highest sorption capacities were observed for sodium forms, and were up to five times higher than for the unmodified zeolite. The maximum sorption capacity toward mercury is determined as 0.093 ¦g/g at an initial concentration of 10.0 ¦g/L for a clinoptilolite from Tsagaantsav deposit (Mongolia). The sorption of Hg (II) has an ion-exchange nature and consists of three stages, ie the adsorption on the surface of microcrystals, the inversion stage and the ion exchange in the interior of the microcrystal. Sorption capacity decreases with the increase of mercury concentration. The presence of other metal ions such as Cd (II), Cu (II), Ni (II) and Zn (II) increases Hg (II) uptake capacity. Finally, sorption for Hg (II) was investigated in batch systems to evaluate the short-term stability of the sorption properties.

Jan 1, 2008