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The only simple sulphide mineral of antimony of importance is stibnite, SbS3, containing 71·8% antimony when pure. It is lead-grey, has a densityof 4·5 to 4·6 and melts at 546°C. It is both friable and sectile (Hardness 2 on Moh's scale) and, as a result, slimes very readily during milling.It is commonly associated with pyrite and arsenopyrite other minerals occurring with stibnite in minor quantities are chalcopyrite, galena, and scheelite. The latter mineral occurs in sufficient quantity at the Yellow Pine Mine, Stibnfte, Idaho, to justify the production of a scheelite concentrate.Stibnite mayor may not contain gold. Other minerals such as pyrite or arsenopyrite may contain gold. At Wiluna at the main mine nearly all the gold is asociated with arsenopyrite the stibnite being almost free from gold, whilst at the Moonlight Mine both arsenopyrite and stibnite carry gold.The mineral, tetrahedrite, which is a complex sulphide of copper and antimony; must also be considered an economic source of these two metals.Part of the copper may be replaced by iron, zinc; silver; or mercury, whilst part of the antimony is often replaced by arsenic.CLASSIFICATION OF ANTIMONIAL GOLD ORESFor the purposes of this paper antimonial gold ores may be conveniently classified as follows: CLASS 1. Ores from which a satisfactory gold extraction may be obtained by fine grinding, followed by cyanidation and which contain insufficient antimony to justify tIie production of an antimonial concentrate.CLASS 2. (a) Ores in which a satisfactory gold extraction may be obtained by straight cyanidation, but which contain sufficient antimony to justify the production of an antimonial concentrate.CLASS 2. (b) Ores from which the gold extraction by straight cyanidation is unsatisfactory. This type of ore requires the production of an antimonial concentrate for reasons which will be considered later.In deciding whether an ore belongs to class 1 or 2 (a) it should be remembered that the normal price of star antimony is about £1.00 sterling per ton and that the value of each 1% of antimony recoverable as metal is worth about £1 per ton.The antimony content of antimonial gold ores is liable to be considerably...

Jan 1, 1944

By H J. Dalstra

High-grade iron ore may be derived from banded iron formation (BIF) through four fundamentally different processes:1. syngenetic precipitation of chert free BIF,2. residual enrichment by removal of gangue minerals from BIF to form bedded (residual) ironore,3. mechanical erosion of iron oxide and chert from bedded iron ore or BIF and re-deposition andupgrading as detrital iron ore, and4. chemical removal of iron from BIF and precipitation elsewhere as a secondary (channel) irondeposit.Finally, the BIF itself may constitute iron ore if a high-grade concentrate utilised for pellets or sinters can be derived from it through mechanical (industrial) separation of iron oxide by means of crushing/milling and mineral separation.Historically, exploration for high-grade BIF hosted iron ores was focused on the residual (bedded) deposits and driven by supergene concepts. Exploration for detrital and channel type iron ores was mostly secondary to exploration for bedded deposits, but recently, a more focused exploration effort has led to the discovery of enormous moderate to low iron grade deposits in the Pilbara region of Western Australia. Exploration for high-grade iron ores using syngenetic concepts has been limited,but together with exploration using hypogene concepts offers the best hope of fi nding concealed deposits. Exploration for BIF sources suitable for concentrate ores commenced in the ‘old’ iron ore provinces after the high-grade resources were depleted and has only recently gained importance in Australian BIF provinces, mainly as a result of high iron ore prices in the last decade.

Jul 11, 2011

Failure of rock materials is a process of crack propagation. Crack initiation takes place when the crack tip stress intensity K reaches a critical value called fracture toughness, K1C. The rock fracture toughness is known to be affected by the surrounding environment such as temperature, confining pressure and humidity. In order to examine the effect of humidity, a series of semi-circular bend tests were performed under various water vapour pressures in a rock material that is known to be anisotropic. Water vapour promotes stress corrosion of rock and therefore the fracture toughness was found to have a decreasing trend with increasing water vapour pressure. The rate of decreasing the fracture toughness depends on the microcrack density that promotes the migration of water vapour into the rock. Also in an anisotropic rock, the fracture toughness depends on the direction of crack in relation to the anisotropy of the rock material.

Dec 6, 2010

By Best R, Poulos H

This paper discusses the results of an Australian Coal Association Research Program project into the development of a routine analytical design method for roof support in underground mines. Simple design tools have been developed using a combination of elastic solutions, free body diagrams, and pile theory. An approach to the design of roof support in layered strata based on the ability of bolts to resist shear stresses is outlined. It is shown that pre-tensioning and angled installation are effective ways of increasing the effectiveness of bolts in such a situation. In highly stressed strata, macroscopic failure is predicted and a design based on the support of surcharged rock wedges is proposed. The methods are applicable to both coal and metalliferous mines.

Jan 1, 1995

By H Allday

The mining industry’s attention has shifted over the last decade with the recovery from the downturn resulting in greater development of innovation and new work methods in a bid to remain competitive and deliver higher productivity. The emphasis on cost reduction to improve profit margins has primarily been the focus of the “work smarter” campaigns embraced within the industry. But is this strategy holistically the best-for-business, or does it place a ceiling on revenue opportunities and inhibit mining companies from truly maximising value? Businesses need to maintain a balance between active cost management and revenue generation often resulting in cost reduction strategies at site level. These strategies have merit, assessing areas of cost wastage across operations and creating space for opportunity. However, this potentially can create distractions from the goal of enabling growth and lead to the sacrifice of quality and delivery. Focusing too heavily on cost reductions without addressing revenue generation is an unprofitable lens to look through, and the relationships between cost, revenue, quality and profit margin can often be overlooked resulting in missed opportunity to maximise value. How these relationships are effectively employed by mining companies to reap the rewards from an overarching corporate perspective down to site level remains a fluid concept depending on the nature, operating market and strategy of the business. A common directive from businesses to their operations is to strive for greater profitability and productivity. The quantification of these requirements, and the nature of the cascading message delivered, impacts the methods employed by the operational team to meet the expectations of the business. Cascaded strategies, if not delivered with appropriate participation and buy-in can often be perceived to be knee-jerk and create frustration for operations who are squeezed to deliver on expectations by slashing site costs. This squeezing is not only felt by the mining operation but at the individual level and can result in increased team stresses. In some cases, this may also steer behaviours towards activities that result in corner cutting and an elevation of operational risk, potentially increasing associated incidents and injury. Driving down costs by any means can create an unhealthy tunnel vision where value is no-longer assessed for best-forbusiness results. By flipping the viewpoint to a value-based approach revenue opportunity may be realised and potentially exceeded, however this opportunity may be missed if value is over shadowed by a cost heavy focus. By analysing a selection of real operational cases (ranging from mining contractors through to in-house mining giants), it becomes apparent that practical revenue maximisation strategies are not only key to an increase in value and cash flow but to a stronger understanding of business drivers for sites and operators alike. In the cases evaluated additional revenue opportunities are foregone in favour of cost reduction strategies resulting in negative impacts on the associated operations and wider businesses. Alignment towards value generation is king. If strategies are not implemented focusing towards value and revenue maximisation, the opportunity loss experienced by mining operations could continue be great and the question should be posed; when the next up-turn hits will operations be ready to reap the rewards or still have a glass ceiling above their heads?

Mar 15, 2021

By A V. Ozsever

The selectivity in flotation columns involving the separation of particles of varying degrees of floatability is based on differential flotation rates in the collection zone, reflux action between the froth and collection zones, and differential detachment rates in the froth zone. Using well known theoretical models describing the separation process and experimental data, froth zone and overall flotation recovery values were quantified for particles in an anthracite coal that have a wide range of floatability potential. For highly floatable particles, froth recovery had a very minimal impact on overall recovery while the recovery of weakly floatable material was decreased substantially by reductions in froth recovery values. In addition, under carrying-capacity limiting conditions, selectivity was enhanced by the preferential detachment of the weakly floatable material. Based on this concept, highly floatable material was added directly into the froth zone when treating the anthracite coal. The enriched froth phase reduced the product ash content of the anthracite product by five absolute percentage points while maintaining a constant recovery value.

Jan 1, 2005

Gold in the stibnite veins of Costerfield, Victoria, was described in 1922 1, prior to any mineragraphic examination, as (a) free yellow gold (b) free rusty gold and (c) combined gold. The free yellow gold occurs in quartz and will amalgamate with mercury. The free gold of dull, rusty or copper-red colour occurs in massive stibnite and has been stated to resist amalgamation with mercury. The dull colour is only skin deep and the colour is bright when the rusty gold is scratched. The appearance of the rusty gold is spongy or cellular and it generally occurs near small cavities in the stibnite. The suggestion that the cellular character indicated the removal of a certain amount of stibnite leaving a residue of se.condary gold cannot be sustained.It now appears probable that the rusty gold is formed by the primary dissociation of a gold antimonide and is distinct in origin from the normal yellow gold which is deposited with quartz or stibnite from auriferous mineral solutions.The combined gold referred to in the earlier paper was the gold contained in the stibnite as revealed by assay. Such gold was at first thought to be either dissolved in the stibnite or else present as free interstitial particles too minute for observation in transmitted light in thin sections.Subsequent examination of numerous polished,surfaces disclosed the small particles of gold occurring in the grain boundaries in aggregates of fine grained stibnite 2. The assumption that all the gold in the stibnite, as revealed by assay, occurred in this way is now known to be incorrect, because limited amounts of a gold antimonide have been found in the veins.

Jan 1, 1952

By P J. Willems, B J. Junor

Blackwater Mine is in the central-southern Bowen Basin, immediately south of the township of Blackwater on the Capricorn Highway. The current open cut operation extracts coal from three main seams, designated Top, Middle and Lower, in the Late Permian Rangal Coal Measures cropping out on the eastern flank of the Comet Ridge. Complex geological structures, dominated by E-W normal faults and N-S reverse faults, have significant detrimental effects on coal mining operations. Historical exploration before 2010 involved several types of drilling only to understand structure, coal quality and washability. Hence, although drilling data was combined with limited pit mapping and observation, unknown structures were still often encountered during excavations and led to mining surprises. In 2010 BHP completed 200-line km of closely spaced 2D seismic survey to capture gross and detailed structures followed by fit for purpose structural drilling to confirm major structures in the northern part of the mine. In 2018 a high density 9.2 km2 3D seismic survey was completed in the southern part of the mine. Subsequently, a 17.2 km2 survey was completed in 2020 to cover the northern active mining area. It allowed geoscientists to successfully map previously unknown major faults and seam splits, which could potentially impact the mineability of the area. It is important to note, that faults interpreted using modern high-density 3D data can be interpreted with dramatically higher confidence in the fault dip and azimuth orientation in comparison to the legacy 2D data. Along with targeted drilling, pit mapping and structural interpretation, the outcome adds value to mine planning and operations. This paper outlines recent successful seismic 3D data acquisition and interpretation. In detail, the paper presents case studies on how the data can be incorporated into a structural model to improve geological knowledge, enable geotechnical assessment, and support safe and efficient coal mining in a large and structurally complex mine.

Mar 22, 2022

By J Bang, I-H Jung

Ti is an important constituent for steels and superalloys. During the continuous casting process and ElectroSlag Remelting process (ESR), Ti in molten steel and superalloy can have chemical reactions with casting flux and ESR slag containing CaO and CaF2. In order to investigate such exchange reactions, the understanding of the (Ca,Ti//O,F) reciprocal slag system is prerequisite. In the present study, a coupled phase diagram experiment and thermodynamic modelling of the (Ca,Ti//O,F) reciprocal system was performed. In particular, the phase diagram of the CaF2-TiO2 system was experimentally investigated by Differential Thermal Analysis (DTA) experiment and quenching experiments followed by Electron Probe MicroAnalysis (EPMA) phase analysis. The Gibbs energy functions of all solid and liquid phases in the (Ca,Ti//O,F) reciprocal system were optimised to reproduce the present data and all available reliable experimental data in literature.

Jun 19, 2024

By Frfas C, Parrilla F, Regife J. M

A project to develop the Zinclor electrowinning cell to industrial size is being conducted at Tecnicas Reunidas' Research and Development Centre with Spanish Ministry of Industry support. This project is the final development phase in zinc electrowinning from a chloride medium, the highest ZINCLOR technology development level prior to the industrial scale having already been reached. This paper covers the outcomes and conclusions corresponding to project Phases 1 and 2: Process Selection and Industrial Electrodes (1 m2) design and testing. The most important achievement reached is that there are presently available industrial cathodes and anodes for the Zinclor diaphragm cell giving an optimum response for zinc chloride electrowinning with unit power consumptions between 2.65 and 2.80 kWh/kg Zn, depending on the diaphragm type. Standard electrolysis conditions were: 65 g/L ZnC12, 3 g/L HCl, 160 g/L NaCl, 350 g/t Zn arabig gum as the addition agent, 36¦C, and 400 A/m2 current density. The selection of electrodes, diaphragms and organic additives for the industrial scale tests have been optimised. The complete electrowinning cell development, with electrodes having an active area of I m2, enables the evaluation of Zinclor Technology application for industrial processes.

Jan 1, 1993

By A Agasty, O Langefeld, MáKellner, E Clausen

The lowering of the pollutant concentration limits at the workplace subjects the mining industry to higher requirements for dilution; this situation is worsened with the current discussions within the European Union (EU) to set new stricter exposure limits for nitrogen oxides in the workplace. This is directly reflected in the performance of the mine ventilation system, which may need to be revised to meet the new standards. The after blast re-entry time, being inversely proportional to the threshold limits, will be higher for a lower limit. This in turn increases the down time for production from the blasted area.Numerical tools have been very useful in predicting the effectiveness of ventilation. This study aims at analysing the dilution time for NOx gases from an ANFO blast in a room and pillar panel. The effect of changing the ventilation on the dilution time is studied next, which helps with the selection of a suitable ventilation system.CITATION:Agasty, A, Clausen, E, Kellner, M and Langefeld, O, 2013. After blast re-entry time for a room and pillar operation, in Proceedings The Australian Mine Ventilation Conference , pp 179-186 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By N Van Buc, E Coroiu

The rapid socio-economic growth of Hanoi City coincides with a corresponding growth of the transport demand. Today, the transport in Hanoi is completely dependent on private modes of transport. Because of the lack of an efficient public transport system and the expected rapid increase in traffic volumes, the movement of people and goods in the urban areas of Hanoi will cause congestion in the present city transport network. The solution of the construction of new roads, or the widening of the existing streets, is very expensive in urban areas and usually causes many social problems due to the resettlement of people. From the point of view of the number of inhabitants, Hanoi City is now over one million. Above this number the international experience shows that the public transportation must be a mass transport system with large capacity, commercial speed and also independent as much as possible from the street network. According to the Hanoi Master Plan for 2020, the Hanoi urban population will be over 3.5 million persons. Also, in the next 15 years, the distances between centre-destination points will be doubled by comparison to 1995.

Jan 1, 1999

By D A. Deglon

Solids suspension is important in the design and operation of mechanical flotation cells, and is a necessary precondition to particle collection. Most of the fundamental hydrodynamic research that incorporates some aspect of solids suspension was done by Arbiter, Harris, and co-workers, or Schubert and co-workers. However, a need for research into solids suspension in mechanical flotation cells exists, since very little has been done since the late 1980s; a time that also coincides with the advent of round mechanical flotation cells and the subsequent dramatic increases in maximum flotation cell sizes. In this work, concentration profiles and critical impeller speeds, Njs, were measured in a 0.124 m3, round cell fitted with a 0.150 m, Bateman impeller mechanism. Two solids size fractions (75 - 106 and 150 - 250 ¦m) were tested, in ungassed and gassed conditions (JG = 0, 1 cm/s) and at various impeller speeds (300 - 900 rpm). The effectiveness of solids suspension was quantified in three ways in terms of extent of off-bottom solids suspension, suspension height (extent of solids distribution), and variation within the solids distribution, which together present a complete quantitative picture of solids suspension and distribution within the cell. Consistent trends were found when these effectiveness criteria were considered against relative impeller speed, in terms of percentage of critical impeller speed, N/Njs. Off-bottom solids suspension is complete at or above 100 per cent of Njs, with significant sedimentation occurring as the impeller speed drops below 60 per cent of Njs. Suspension heights consistently reached a level equivalent to 90 per cent of the tank diameter at the critical impeller speed, and dropped off significantly as N/Njs dropped below 60 per cent. The variation in the solids concentrations within the sampled profiles showed consistent trends in two-phase but not under three-phase conditions. The paper concludes that the critical impeller speed, Njs, commonly used in the design and operation of standard stirred tanks, is a very useful solids suspension benchmark for describing all aspects of solids suspension in mechanical flotation cells and should be correlated to system conditions.

Jan 1, 2005

An intensely sheared and mineralized zone occurs in the quartz dolerite greenstone (or younger greenstone) mass on the western limb of the Kalgoorlie syncline. This zone comprises the western part of the Golden Mile and has produced the greater part of the 33,000,000 oz of gold produced to date from the main mining belts. A study of the general geological and structural features suggests that the lode shear system will continue southward on a pitch similar to that of the main syncline. Although payable ore has been found recently further to the south, the expectation of large quantities extending southward from the present mining areas is problematical.INTRODUCTIONUntil the late 1930's the principal mining activities in the western lode system were centred on three major ore-shoots formed on the No. 4, No. 3 and to a lesser extent on the No. 2 lode shears (Fig. 1). With the gradual reduction of grade in depth on these main ore shoots, increasing attention was paid to the "Minor Lode" system of lode shears known to exist in the same area. A large quantity of payable ore was found on these "Minor Lodes" particularly in the central part of the mining area. In recent years more attention has been given to exploration in a southerly direction.ROCK TYPES AND STRUCTURESThe western system occurs on the western flank of a dragfolded, south pitching syncline. The rock succession consists of Black Flag sediments overlying the younger greenstone horizon which overlies the fine grained older greenstone horizon. The axis of the syncline is regarded as a tight infold of the overlying Black Flag sediments. This infold has been faulted and intruded by albite porphyry resulting in the formation of a composite body of slates...

Jan 1, 1964

By J Heyes

Historically mining engineers haven't spent enough time planning waste dumps, but waste movement costs often outweigh ore haulage costs. There is a real incentive to plan waste dumps right the first time to minimise rehandle and final closure costs. At BHP Billiton Iron Ore there has been an increasing sophistication in waste dump design and they are becoming as important as the pit design. Closure landforms are now included in mining studies. Closure is embedded in the business planning cycle. The results from the recent life of mine study at Whaleback is a case in point where a base case of the shortest hauls with no closure constraints was compared against a closure case. A properly planned and executed waste plan revealed that no rehandle was required and haulage costs were eight per cent less if closure design implementation was carried out concurrent with mining. At cessation of mining the landforms were such that decommissioning of critical acid rock drainage dams and coverage of exposed pyrite areas could occur straight away, without the need for additional rehandle.  The paper also covers design and scheduling elements of waste design both in-pit and ex-pit, management of potentially acid forming material (PAF) and trends in PAF management and designing for final landform closure. This paper illustrates that there is value in terms of costs savings, sustainable outcomes and reputation if the mine planners are involved in the closure planning process.

Jan 1, 2009

By P Bourke, S Ronkainen

Since the early days of flotation, process technicians have known that the speed at which the froth is recovered over the lip of the cell has a very direct and consistent influence on the grade and recovery of the circuit. No plant would deny that, even to this day, one of the most important aspects of a process technicianÆs job is ensuring that the froth is moving at a desired and controlled speed over the lip. Unfortunately, process technicians cannot watch the froth throughout the entire shift, as there are always other problems to attend to. A considerable amount of work has thus been done to develop a æsystemÆ that automatically measures the speed of the froth. This measurement would then be used in simple controllers to emulate the steps taken by the process technician in correcting deviations of the froth speed from its desired level. Many of the earlier attempts to measure speed were ineffective, as they were unable to cope with turbulence on the froth surface. The FrothMasterÖ instrument makes use of machine vision technologies to measure the speed of the froth over the lip of a cell at a very high sampling rate. This instrument produces an extremely reliable and accurate measurement of the froth speed (as well as other parameters such as bubble size and froth stability). As we will show, the effectiveness of the speed measurement in controlling the performance of the plant is a testimony to its reliability. Three FrothMasterÖ units have recently been installed on the Cadia Hills Gold Mine in New South Wales (Australia). The objectives of this installation were:to control the mass-recovery of two Tank Cells in series on the same level where differences in the hydrostatic head between the two cells result in the cells pulling inconsistently with respect to each other; control of the concentrate grade (per cent copper) from the first rougher; reduction in the frother consumption in the rougher circuit by monitoring the froth speed. A simple controller was designed to react to disturbances in the same way that human operators react. This was done after consultation with the metallurgists and the process technicians at Cadia. The controller had two functions: Stabilisation: The stabilising controller made use of three manipulated variables (level, frother addition rate and aeration rate) to control the froth speed to a setpoint. Optimisation: The optimising controller adjusted the froth speed setpoint based on deviations of the grade (measured in real-time by the OSA) from a setpoint. The plant metallurgist adjusted the grade setpoint based on information about the ore. The results from a 21-day trial have shown the following:The ratio of concentrate mass-recovery between two cells in series on the same level has been successfully balanced, thereby overcoming problems due to differences in hydrostatic heads. It is possible to control the speed of the froth, in mm/s, to within five per cent of its setpoint using the aforementioned manipulated variables. It has also been shown that, for reliable control, it is necessary to control more than just one variable (eg level or air). The grade of the first rougher concentrate has been controlled to within 0.3 per cent of the grade setpoint for long periods of time, which has important implications for the circuit recovery. The frother consumption has been reduced significantly. This paper will thus show that substantial progress has been made to demonstrate the value of using on-line froth speed measurements in flotation plant control to obtain real financial benefits.

Jan 1, 2000

By M Berner, N A. Sifferlinger, E Fimbinger

Today, the advance rate of underground roadway development by drill and blast operation is limited by the need to ventilate the toxic blast fumes after each cycle. In deep mines this usually is only possible during shift changes when the related mine sections are free of persons. This results in roadway development advance rates of 4 m per shift, or 12 m per day. For long roadways this is a limiting factor in mining development in deep mines. Companies like EPIROC, KOMATSU, ROBBINS and SANDVIK are making serious R&D efforts to disc-cutting mobile miners to overcome this bottleneck. However, today, the achieved advance rates are less than 12 m per day in hard rock. If we achieve full robotisation and/or teleoperation from a safe place for drill and blast operation of an underground roadway development section, we could eliminate this bottleneck. Poisonous blasting fumes do not affect robots and machines as long as these fumes do not create aggressive acids. If we can keep the blast fumes isolated in the roadway development section for the shift until the next ventilation opportunity (eg shift change or designated ventilation times), we can do the drill and blast cycle more often in a shift, which will significantly speed up the advance rate. This requires robotisation of all work steps in the section: surveying, drilling, charging of explosives, blasting, loading and transporting material, roof support, installation of infrastructure etc. Also, cache storage for the material is needed. Special care for the ventilation system to keep the blasting fumes under control in the section is necessary. The paper discusses the aspects needed to achieve this robotisation and the related technical and operational tasks.

Sep 1, 2024

By T Y. Ko, Y S. Kang, S J. Park, J H. Hwang

The lunar subsurface, particularly the lava tubes formed by ancient volcanic activity, presents a promising environment for establishing safe and sustainable human habitats on the Moon. Tunnel Boring Machines (TBMs), widely used for excavating tunnels on Earth, offer a potential solution for developing these subsurface spaces. However, the unique lunar conditions, including extreme temperatures, high vacuum, radiation, and the extraordinary strength and abrasiveness of lunar rocks, necessitate significant adaptations to existing TBM technology. This study investigates the feasibility of utilising TBMs for lunar subsurface exploration and base construction, addressing the challenges posed by the harsh lunar environment. We review previous conceptual designs for lunar TBMs, highlighting their strengths and limitations in addressing these challenges. Additionally, we explore innovative excavation methods, such as microwave-assisted rock weakening and undercutting techniques, to enhance the efficiency and effectiveness of lunar TBM operations. By evaluating the geological characteristics of the lunar crust and analysing the potential of lava tubes as launching points for TBM operations, this study provides a comprehensive assessment of the technical requirements and operational considerations for lunar TBM implementation. The findings of this research contribute to the growing body of knowledge on lunar base development and pave the way for future human exploration and utilisation of the Moon’s subsurface resources.

Sep 1, 2024

By A P. Tinnelly

This paper explores the structural/physical and policy based issues that have lead to the apparent resource conflict between Forestry and Mining on the West Coast. Both industries are important to the West Coast and bear many similarities, particularly at the corporate end of the mining scale. However there are very distinct structural differences which set the scene for friction at the boundaries. Examples of how mining impacts upon forestry illustrate where some of the friction arises and provides some insight as to where some solutions are or may be found.

Jan 1, 1996

By K C. Corin, C T. O’Connor

In recent years it has been shown that the concept of using partial molar excess Gibbs energy (G̅ex) to explain the behaviour of collectors in the recovery of minerals can be usefully applied to explain flotation performance. Fundamentally this is because hydrophobicity of a mineral particle on which a collector is adsorbed may be strongly related to the fact that the alkyl chain associated with the collector behaves in the same way as any hydrocarbon would in an aqueous medium. This hydrocarbon-water system represents a classical non-ideal mixture, and such mixtures are quantified thermodynamically by determining the activity coefficient of the hydrocarbon moiety of the collector and hence its G̅ex in the mixture. It has been shown that G̅ex is a more rigorous indicator of the contributions of various alkyl groups of a collector than HLB (Corin and O’Connor, 2014) and was also able to explain aspects of froth behaviour (Harris and O’Connor, 2017) and hydrophobicity (O’Connor, 2021). The present paper is aimed at extending the above concepts in two different ways. Firstly, a study is undertaken of a range of results previously reported in which various reagents containing different alkyl groups were analysed in terms of their effect on contact angle and their performance as flotation reagents in terms of recovery. These results sustain the previous observations that there is a robust positive relationship between hydrophobicity as indicated by flotation recovery and contact angle and G̅ex of the alkyl group associated with the collector. Secondly, on the basis of the observation that increases in G̅ex are indicative of increases in the hydrophobicity of the mineral particle-collector aggregate, a study was undertaken to examine the effect of ions typical of electrolytes in water as well as the effect of the presence of alcohols and of pH on G̅ex of the collector alkyl group. In the former two instances the absence of any correlation between G̅ex and recoveries supported the proposition of the respective authors of these studies that the major effect of these electrolytes and added alcohols may be on particle–bubble attachment rather than on the hydrophobicity of the mineral/collector in the aqueous system. On the other hand, the effect of pH on G̅ex correlated reasonably well with changes reported in the literature on the effect of pH on recovery and contact angle.

Aug 24, 2022