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By R Shaw, R Williamson

Global iron ore demand, sparked by ChinaÆs rapid industrialisation and emergence as the worldÆs newest steel market, has seen iron ore groups investing heavily in production capacity as well as infrastructure. The success of these new projects depends heavily on reliability, competitiveness and quality control in an increasingly demanding trading environment. Furthermore, the iron ore industry continues to improve its competitiveness in mining practices, technology innovation and management processes. The continued fine tuning of these sectors will be critical to the success of the industry in the years ahead, and this mining sector will continue to demand process improvements from their service suppliers to maintain competitiveness. Automation offers a real solution to these demands. A crucial quality control element in mining, beneficiation, stockpiling and shipping stages is ensuring representative samples of ore are taken along each step of the process. When these samples reach the laboratory it is imperative that the sample is representative of the entire stream and that no induced errors occur. Examples of automation start with mechanical primary and secondary samplers in the run-of-mine processes through to sample tower and laboratory crushers, dividers and collectors. Automation is widely used in many forms to provide reliable and repeatable samples for analysis whilst providing a safer working environment. Laboratory automation systems in use today vary from simple linear systems to sophisticated robotic cells. Sample automation in the iron ore industry has resulted in many benefits for both producers and their customers. The most significant benefits have come in the form of higher safety standards whilst reducing sample error, sample handling and sample contamination during collection. These benefits have been further augmented by reliability and repeatability of automating the final sample preparation and analysis stage. Today these benefits are reflected in reduced costs of sampling and improvement in both turnaround time and quality of results, whilst complying with Australian safety and ISO sampling standards.

Jan 1, 2007

Silica and limestone fluxing levels in copper smelting slags were studied. Copper concentrates with flux additions were smelted to matte (55.5 per cent Cu) and slag in a pilot scale submerged combustion furnace.Results indicated that oxidic and sulphidic copper levels in slags were minimised with a slag Si02 level of 36 per cent and a SiO2/CaO ratio of 5.5. Total copper losses in slags were 0.6 per cent under these conditions.To produce the desired slag chemistry, additions of bulk silica and limestone to copper concentrates of fluctuating grades were predicted numerically. The method employed the solution of two simultaneous equations, each respectively for silica and limestone calculations.The predicted flux additions were applied in a further series of tests and the resultant stages were found to be satisfactory. The method is applicable to smelting 'operations which employ two flux bins, with weigh feeders, so that slag chemistry may be controlled with the flux/concentrate feed mix.

Jan 1, 1985

Biologically-mediated phenomena are involved in many of the natural processes by which mineral deposits are formed and ore bodies transformed and degraded. They may facilitate the environmentally-damaging effects of mining and mineral-processing operat- ions. Under contrived and controlled conditions, however, these phenomena can form the basis for economically- attractive processes for the recovery of metals from low-grade deposits by dump, heap or in situ leaching. They have application also in processes for the regeneration of leaching reagents and some potential for'-the recovery of metals from dilute solution. The micro- organisms concerned are potential sources for the production of novel flotation and solvent-extraction reag- ents. Perhaps the greatest opportunity for biotechnological processes in min- ing and metallurgy lies in the possib- ility of the evolving of novel proced- ures for the substantially complete recovery of metals from process tail- ings by the unlocking of recalcitrant and complex mineral assemblages, and for the beneficiation of some mineral materi,hls.

Jan 1, 1982

ecent work on decoppering lead is reviewed; CuS is formed rapidly even from dilute solutions of copper in lead. he mechanism of decoppering is discussed, and an explanation for the retention of metals such as silver in lead is dvanced. As decoppering tin appears to be an analogous process, the Cu-Sn-S system is studied at 300¦C. CuS, hich is not, an equilibrium product, is found in decoppering drosses. In the removal of nickel from lead, Ni3pb2S2 formed; preliminary measurements show the equilibrium nickel content to be greater than that obtained by tirring in sulphur. Decoppering bismuth is thermodynamically favoured, but is complicated by the occurrence of uBiS2. The Cu-Pb-S system is the only one of the four studied where the equilibrium can be calculated simply, as ' resence of ternary sulphide or other phases invalidates calculations based on binary data.

Jan 1, 1970

By Houlihan RN, Landau J

A reciprocating plate column is described in which two sets of perforated plates are mounted alternately on two shafts and are reciprocated with a phase difference of 1800 between them. It is shown that such a column is mechanically superior to the previously proposed types: under practical operating conditions the pressure fluctuations at the base of the column are only a small fraction of the static head. Furthermore, mass transfer experiments with the system tributyl phosphate in kerosene- acid aqueous solutions of uranyl nitrate show that both high specific throughputs and reason- ably good efficiencies can be attained in this type of column. A comparison with the more conventional extraction equipment (mixer -settlers, pulsed columns) on the basis of residence time per equilibrium stage indicates the potential of reciprocating plate columns in hydrometallurg- ical application, especially in which the requirements of separation efficiency are modest while the scale of operation is large.

Jan 1, 1975

By Woodcock J. T, Millett R. N

It was shown that manganese dioxide could be used as an oxidant in acid thiourea leaching of a gold ore. Manganese dioxide could generate high redox potentials and was as effective as hydrogen peroxide in the leaching process. Results obtained under closely controlled leaching conditions confirmed that high redox potentials enabled faster dissolution of gold to be obtained but led to extremely high reagent consumptions (thiourea, acid, and manganese dioxide). Additions of sodium sulphite solution in an attempt to lower thiourea consumption by reducing formamidine disulphide back to thiourea were only marginally successful. Although thio- urea consumption was slightly decreased, the consumption of acid and manganese dioxide was substantially increased and there was no net benefit in using sulphite. Tests in which a single addition of mangan- ese dioxide was made before addition of thiourea minimized overall reagent consumption and gave only a slightly lower dissolution rate of gold. This is a promising technique for further Investigation.

Jan 1, 1987

By Hendrix JL, Nelson JH

Three ores (sulfidic, oxidized and carbonaceous) were analyzed to determine the effects of leaching time, ore depth, and ore mineralogy on cyanide species concentration. NaCN solutions were percolated through opaque columns filled with milled ore. Column design made liquid sample collection possible from various depths at specific times. The concentrations of weak acid dissociable(WAD) and total cyanide, Fe(CN)63 , Fe(CN)64 , SCN , and Cu(CN)43 were determined for each sample. Extended percolation time led to increases in WAD cyanide concentra- tions and decreased SCN and Cu(CN)43 concentrations regardless of ore depth. WAD cyanide concentration decreased while Fe(CN)64 concentra- tion increased with ore depth. Highest concentrations of Fe(CN)64- SCN and Cu(CN)43 were found in the sulfidic ore, with expected low WAD cyanide concentrations. Lowest concentrations of Fe(CN)64 , SCN 3 and Cu(CN)4 were found in the oxidized ore. Intermediate concentra

Jan 1, 1988

Comparison of the Zadra, Anglo-American and organic solvent procedures for desorption of gold from activated carbon loaded in carbon-in-pulp gold circuits indicates that the Anglo American and the organic solvent procedures are considerably more effective than the commonly used Zadra procedure. Organic solvent elution procedures, particularly those using acetonitrile and acetone, can provide effective gold elution and very high concentrations of gold in eluate solutions. The operational simplicity and effectiveness of the Anglo American procedure would appear to make it the most satisfactory procedure available at the present time but this may change as the solvent elution procedures become better developed. INTRODUCTION The carbon-in-pulp technique has been introduced into the gold processing industry to by-pass the often lengthy CCD and filtration steps required in the conventional Merrill Crowe cyanidation procedure for gold recovery. Adsorption of gold on to carbon is also a valuable technique for recovering trace amounts of gold from low level waste streams from conventional processing procedures.

Jan 1, 1982

Research on Reduction-Magnetic Separation of Bayan Obo Ore

Sep 13, 2010

By H J. J Boshoff

Mine closure planning integrated into life-of-mine (LOM) planning during the operational phase consists of many subcategories. One of these subcategories that needs to be fully integrated into the LOM planning is that of water management planning. Issues arise when mine water management infrastructure, which is required post-mine closure, is only considered closer to the end of LOM. Once the mine is closed monitoring is focused on water quality as an indicator of closure performance, hence inadequate upfront post-mining water management planning or integration into operations will result in environmental harm. The lack of considering post-mining water management is not uncommon in LOM planning. Poor mine site water management and planning are a wide reaching problem for the mining industry. Numerous active mines have been issued with environmental notices and penalties for contaminated water discharge; including issues with abandoned mines now being cared for by governments all over the world.Mitigating sources of water contamination caused by existing and closed mine sites that are leaching pollutants might be impractical, due to inaccessibility to the contaminants or final landform topography. The opportunity to consider and introduce post-closure required mine water management infrastructure is lost once the waste facilities are constructed. Mitigating contamination is made more problematic with mines located in remote areas, serviced by dedicated roads, water supply, electrical supply, etc. It is expected that these services will be decommissioned or drastically reduced, once closure is reached making remedial work much harder. Inadequate planning, to ensure access and easily maintainable water management infrastructure, could lead to erosion and contamination going unnoticed. There are numerous examples of poor mine water management practices in Africa, Asia, Australia, South and North America. In the United States more than 23 000 km of streams are affected by pollution sourced from some 50 000 abandoned or mature mine sites (DeGraff, 2007).CITATION:Boshoff, H J J, ?2014. Inadequate water management planning resulting in long-term closure liabilities, in Proceedings Life-of-Mine 2014 , pp 233–246 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

Influence of Grinding Media on the Flotation of Carbonate Using Sodium Oleate as Collector

Sep 13, 2010

By L Klemettinen, A Jokilaakso, D Attah-Kyei, P Taskinen, M Tiljander, D Sukhomlinov, D Lindberg

In this study, the use of carbon neutral biochars as reducing agents in the pyrometallurgical treatment of nickel slag was investigated at 1400°C in order to recover valuable elements such as copper and nickel from the slag. A large amount of slag is generated during the nickel matte smelting. Nickel slag contains valuable elements such as copper, nickel and cobalt, which can be recovered. Disposal of this slag results in loss of resources and may cause pollution of the environment. It is important to retrieve these metals for environmental and economic reasons. In this study, the slag was reacted with non-fossil reducing agents (biochar) which were produced from hydrolysis lignin and black pellet biomass pyrolyzed at 600 and 1200°C and with metallurgical coke for comparison. The reduction experiments were done at 1400°C for 15, 30 and 60 mins under inert gas atmosphere. The samples were quickly quenched and analysed with Electron Probe X-ray Microanalysis (EPMA). The results showed that the use of biochar resulted in faster reaction kinetics in the reduction process compared to coke. The fast reaction kinetics is attributed to the relatively high content of volatiles in this biochar, leading to gas formation and thus mixing of the sample material. Moreover, thermodynamic modelling was also performed using FactSage™ to simulate equilibria with different amounts of biochar. The metal to slag distribution coefficient calculated from the results of thermodynamic modelling were consistent with experimental results. In addition, thermodynamic calculations confirmed that nickel is reduced rapidly and it deports to the metal alloy phase. As the reduction progresses or extra reductant is available for reactions, more iron is deported to the metal phase. The calculations also revealed that Zn vaporises into the gas phase.

Jun 19, 2024

By S J. Kim, S W. Kim, L Tomas da Rocha, S Jung

Al2O3 has been regarded as a harmful gangue component in iron ore, especially causing reduction degradation in industrial sintering of iron ore. The current study aimed to utilise low-grade iron ore containing high Al2O3 content in sintering process. In order to counteract the adverse effect of Al2O3 on reduction behaviour of iron ore sinter, mill-scale and calcined dolomite were chosen as FeO- and MgO-bearing materials. Firstly, mill-scale was added to high Al2O3 sinter and addition was optimised as 10 wt per cent, then calcined dolomite was added further. Magnetite and magnesio-ferrite were identified as the major phases in iron ore sinter when adding mill-scale and calcined dolomite. As the dosage of calcined dolomite increased beyond 4 wt per cent of in sinter mix, unreacted MgO particles were observed, which is ascribed to the limitation of MgO dissolution into magnetite matrix. Both mill-scale and calcined dolomite were effective in improving compressive load and Reduction Disintegration Index (RDI) of iron ore sinter although its reduction degree was highly decreased. The addition of both FeO and MgO-bearing materials to high Al2O3 sinter has a potential to improve the sinter quality, also contribute to the recycling of industrial by-product. However, the amount should be optimised in views of phase development and deterioration of reducibility.

Jun 19, 2024

By G Harbort

The use of geological data for optimisation of operating plants has become a significant part of the modern process mindset. The underlying principle is to convert spatial geological data into metallurgical information to drive production and mine planning, blast design, blending strategies and plant set-up. Increasingly the process designer is required to interface with geological and mining staff to propose the best investment strategy for a project’s benefit.The geometallurgical model development for the Zafranal copper-gold project commenced in March, 2010, several months after the start of a major drilling campaign by AQM Copper Inc. The initial evaluation stage required review of historical Teck RC data to determine areas of metallurgical interest within the project. As drilling transitioned from RC to diamond drilling, core that was considered representative of the resource was selected and subjected to MLA mineralogy analysis. When coupled with sequential copper analyses this allowed calibration of an assay derived mineralogy model, allowing process concept options and a preliminary test program to be developed. This Phase 1 test program provided a preliminary process design, operating costs and anticipated concentrate grades and recoveries. Both this data and resource estimation were used to generate a preliminary Whittle pit optimisation based on maximising net smelter return, which in turn fed into a preliminary mine plan. The preliminary mine plan, in conjunction with geological logs and core results was used to develop a phase 2 metallurgical test program, where variability tests were conducted throughout the resource and composites formed to investigate specific years of the mine plan in locked cycle flotation. In addition comminution tests were modelled against geometallurgical domains allowing comminution components values to be calculated for 36?000 m of core. A flotation geometallurgical model was developed and incorporated into the resource model allowing concentrate grades and recoveries to be estimated on a block-by-block basis.

Sep 5, 2011

Jan 1, 2004

By Grieveson P, Terry B. S

Carbothermic reduction of sulphide minerals for achieving a selective separation of metallic species from complex minerals has been discussed by considering the prevailing oxygen potential during the course of reaction. Construction of univariant plots for the reduction of sulphides with carbon monoxide gas or carbon and in the presence of either lime or anhydrous calcium sulphate is the key feature of this work. The theoretical calculations for univariants in the Cu-Fe-S-O system indicated a preferential separation of metallic copper and iron by imposing a chemical potential. This is evident from a logarithmic plot of sulphur dioxide partial pressure against reciprocal temperature. The results are compared with empirical data for the reduction equilibrium. The reduction behaviour of the constituent sulphides are also discussed together with the experimental results and theoretically predicted phase stability diagrams.

Jan 1, 1992

By P N. Duan, Z G. Liu, M S. Chu, X X. Xue, B Liu, G J. Cheng, T Jiang, J X. Liu

High-chromium vanadium-titanium magnetite has not been exploited and made full use of on a large scale so far due to the immature utilisation technology and the reality that the utilisation efficiency of valuable metals still urgently needs to be improved. In the present paper, the isothermal reduction kinetics and mechanism of high-chromium vanadium-titanium pellets were studied at 800–1100°C. The mineral composition transformation of pellets before and after reduction was analysed by means of X-ray diffraction (XRD), and the microstructures were examined by scanning electron microscope (SEM) equipped with energy dispersive X-ray (EDX) to reveal the elemental distributions. The effect of reduction temperature on the volumetric swelling degree and cold crushing strength was also studied. It was found that reduction temperature has a large effect on the reduction rate of pellets, and the increase in reduction rate is more obvious in the range 1000–1100°C than 800–1000°C. The volumetric swelling degree of pellets increased with increasing reduction temperature, while the cold crushing strength decreased. The transformation of mineral species can be expressed as Fe2O3 ? Fe3O4 ? FeO ? Fe, Fe2O3·3TiO2 ? Fe3O4· (2FeO·TiO2 ) ? 2FeO· TiO2 ? FeO·TiO2, (Fe0.6Cr0.4)2O3 ? FeO· Cr2O3 ? Cr2O3 , and Fe2O3· VO/V2O3 ? VO. The apparent activation energy of the reduction reaction was calculated to be 44.3 kJ/mol, and the reduction rate is controlled by the combined effect of interfacial chemical reaction and gas diffusion through the porous product layer. The rate controlling steps were further studied by calculating the resistance percentages. The interfacial chemical reaction was found to be predominant in the initial reduction stage, with the percentage effect of gas diffusion through the porous product layer gradually increasing during reduction.CITATION:Cheng, G J, Xue, X X, Liu, J X, Liu, Z G, Chu, M S, Jiang, T, Liu, B and Duan, P N, 2015. Reduction kinetics and mechanism of pellets prepared from high-chromium vanadium-titanium magnetite concentrate, in Proceedings Iron Ore 2015, pp 349–358 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

The Effect of Bulk Iron Concentration on the Copper Activation of Sphalerite at pH 9

Sep 13, 2010

By M Littlefair, D Gribble, R Rounsley, I Te

Low-density explosives (LDE) have applications where the explosive properties of ANFO are not well matched to the rock. In particular, rocks that are of low strength and/or well fragmented in situ. Dyno Nobel Asia Pacific (DNAP) has developed a new LDE, BlastLiteTM, which can be used as a cost-effective replacement for ANFO with excellent detonation characteristics. The product is based on ANFO with the addition of a bulking agent. The key to the product lies in the ability of the bulking agent to form a homogeneous blend with ANFO without the need for any emulsion matrix to bind the product together. This results in an LDE of low cost and high weight strength compared to existing commercial LDE products. The product has been trialled extensively and has proven to provide results that are equivalent to, and often better than, ANFO with reduced powder factors. This paper details the laboratory development and results of field trials for DNAPÆs LDE solution: BlastLite.

Jan 1, 2004

By E Jak, J Chen, B Hogg, S Nikolic, S Nicol

The quantity of post-consumer ‘waste’ materials generated each year is rapidly increasing. These materials can contain significant quantities of critical metals and present an environmental challenge if landfilled. The ISACYCLE™ technology is a proven solution for the processing of these materials. In the ISACYCLE™ furnace, the post-consumer materials are processed to recover energy along with any contained critical metals, in the form of a base metal alloy or matte. In addition, a clean aggregate (slag) is generated, which has the potential to be used for a range of applications in the construction industry. This slag is commonly based on a fayalite slag but is modified to manage the complex feed. This paper will review the fayalite slag system and the theoretical modifications required for treating urban wastes. Slags from an ISACYCLE™ furnace processing urban wastes have been sampled and characterised. The chemistry of these samples will be reviewed and compared to the expected theoretical modifications required.

Jun 19, 2024