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Most analysts determining tungsten trioxide in low grade samples are aware that colorimetric procedures do not possess the inherent disadvantages of gravimetric methods operating on milligram quantities of tungsten trioxide. Apart from the inaccuracies associated with weighing four or five milligrams of ignited oxide in a platinum crucible of about 30 gm. weight with a large surface area to absorb moisture, using a 5 gm. charge on samples less than about 0·15 per cent tungsten trioxide, it is extremely difficult toget complete or pure precipitation of tungsten with cinchonine, cinchonine plus alpha benzoin oxime, rhodamine B or any other of the commonly used precipitants. Table 2', No. 8, illustrates the low results obtained by gravimetric as opposed to colorimetric procedures. In addition the colorimetric determination requires only a small portion of the time consumed by gravimetric practices and the increased accuracy obtainable in low ranges together with the saving in time made it highly desirable to develop a colorimetric method suitable for King Island ores.The most commonly used colorimetric method is that introduced by Feigl and Krumholz (1932), since modified by various investigators (Grimaldi and North, 1943; Sandell, 1946; Westwood and Mayer, 1947; Gentry and Sherrington, 1948; Freund, Wright and Brookshier, 1951; Grouthamel and Johnson, 1954; and others). Stannous chloride is used to reduce tungsten followed by colour development with a thiocyanate, usually sodium, potassium or ammonium.Other reducing agents have been proposed (Emery and Curtis, 1948), but only in recent years have the conditions governing maximum colour development been fully estab...

Jan 1, 1958

By O Ostrovski

Direct iron smelting reduction has been examined using a modified 50 kg induction furnace. The furnace was equipped with continuous raw material feeding, a top oxygen lance, argon bottom bubbling, and sensors for measurement of gas and bath temperatures, gas composition and other parameters. In the base case, iron ore was charged at the rate of 1.5 kg/h, coke flowrate was adjusted to maintain a char fraction in the slag at 30 wt per cent, the oxygen flowrate was 100 Nl/min and the post-combustion ratio (PCR) was 60 per cent. The PCR was varied from 45 to 75 per cent by changing the lance height relative to the bath surface. Smelting reduction of Whaleback iron ore was investigated at different post-combustion ratios and iron ore feedrates using coke and coals with different volatile matter. The rate of iron oxide reduction increased with increasing iron oxide concentration in the slag, with a slight deviation from a linear function. The post-combustion ratio affected iron ore reduction and partitioning of elements between phases in the smelting reduction furnace. The high volatile coal investigated was found to be unsuitable for iron smelting reduction in the laboratory furnace.

Jan 1, 2000

By Goodheart B

The Australian Mineral Sands Industry has expanded from the initial export of mixed concentrates in the 1930s, through various development stages, to its current position as a leading world producer of individual mineral products and some further processed products. Opportunities for downstream processing of the separated minerals and locating such developments in Western Australia are reviewed, along with the role of the Western Australian Government in assisting resource development projects.

Jan 1, 1986

By Toomey P. T

In many open cut coal mines, rivers and large creeks can cause planning and operating difficulties, both in the terms of the more obvious location of the current watercourse, but, and sometimes more importantly, past meandering of the watercourse. Prevent and past flow regimes may have deposited large alluvial sequences within the current mining areas. The presence of groundwater within the alluvium further complicates the planning and operating practices.A situation exists at Saraji Mine in which alluvial sediments overlie a massive sandstone sequence which in turn lies at about one metre above the coal seam. The problems encountered include high levels of groundwater ingress to the pit, highwall instability, and an unacceptably high rate of blast hole collapse (prior to charging with explosives). Other aspects of the dragline stripping operation were also affected.

Jan 1, 1992

By Liu C. H, Juang Y. F

Coal/gas outbursts were one of the rather difficult safety problems faced in the coal mines of this Country, with coal fields characterized by frequent disturbances of folds, faults and pinch-offs. With average mining depth about 500m below surface, several such accidents occurred with up to 500 tonnes of coal outburst. In recent years, after a series of improving countermeasures had been undertaken, gas outburst accidents had been greatly decreased. The characteristics of gas outbursts in Taiwan coal mines include relating to coal petrography, mining depth and the other deformation forces. All these have been investigated, trying to determine the parameter of outbursts under natural conditions. The preventive countermeasures include predicting tests, de-stressing boring in coal seams, the emergency procedures during outbursts and certain improving options.

Jan 1, 1988

The intent of this address is to look forward into the 21st Century and present certain thoughts as to how underground coal mining might be conducted. The views in this talk are based principally on the author's experience with mining practices in the United States. It may be difficult to accept, but the 21st Century is a mere 12 years away. What new techniques will be available? To develop an understanding of the way in which technology has been and could be changing, a two- stage analysis is made of mining technology for U.S. Coal. The first phase covers the period 1975 to the present, while the second includes 1960 to 1975. This historical perspective includes a view of underground production by mining methods, considerations of labour productivity, and a review of accident and fatality rates. Several topics are important features of this historical analysis. Among the most significant are: (1) the introduction of Ion-wall mining technology into U.S. underground coal mines, (2) the use of computers to assist in mine planning and design activities, (3) major efforts to improve health and safety performance, with emphasis on underground dust control, and (4) improvements in mining equipment with an eye towards increased reliability and up-time performance. Based on that historical perspective, projections are made in three increments. The first being immediately at the turn of the century, the second being a dozen or so years beyond that, and the third being at the quarter point of the 21st Century.

Jan 1, 1988

By T Vizcarra, G Sandoval, C L. Evans

One of the challenges in the development of mineral processing simulators is modelling the liberation characteristics of particles produced by comminution circuits. Understanding the mineral characteristics of these particles is one of the keys to predicting their behaviour in separation circuits. While more fundamental research seeks to model the non-random breakage of ores this work examines whether we can move forward now by using observed characteristics of ores to model the composition of particles generated in comminution processes. Several researchers have noted the similarity of the liberation characteristics for a selected size fraction of particulate material, whether the fraction comes from a coarse material, such as the product from a jaw crusher, or a more finely ground material, such as the product from a ball mill. In most cases these observations were reported as an aside and were not the main focus of the published work. This observed behaviour has the potential to be a useful tool for modelling the particle characteristics in mineral comminution and separation circuits, particularly as we move towards the development of multi-component models. However, before the behaviour can be used widely we need to understand which ore types follow the observed pattern and which do not. The current work examines a range of ores and identifies which exhibit the pattern of similarity of composition for particles in a given size class that has been produced as the result of a variety of breakage conditions. The impact of mineralogy and texture on the evolution of liberation characteristics for both valuable and gangue minerals is discussed.

Jan 1, 2008

By Graham JW, Cullen GV

edicted increase in, Aluminium production and the possibility of a diminishing supply of petroleum coke for anode electrodes in alumina reduction cells makes it desirable to find alternative electrode materials. Brown coal char, with a lower ash content and with an elemental purity similar to petroleum coke, has been produced by leaching in hydrochloric acid, washing with water and charring at 115000. The cost of processing is estimated to be competitive with petroleum coke. Without further processing the bulk density and real density were undesirably low, but. by briquetting the coal before charring and crushing, the bulk density was improved to 92 per cent of the petroleum coke value and the Particle density was improved to 92 per cent of the density of petroleum coke by water-displacement or 75 per cent by mercury displacement. Pre-baked electrodes were prepared from the char alone, mixtures of petroleum coke and char and from petroleum coke alone, all bonded with coal tar pitch. The electrodes were tested for the usual physical properties and were, evaluated for performance in a laboratory size alumina reduction cell. Electrodes based on brown coal char alone were found to be inferior in physical properties, and performance, but mixtures of the char and petroleum coke, despite poorer density, electrical resistivity and carbon consumption on a theoretical basis, in performance tests gave up to 17 per cent better carbon consumption per weight of aluminium produced and 21 percent better electrical current efficiency than the electrodes based on petroleum coke alone. It is suggested that larger scale tests are warranted.

Jan 1, 1970

By Walker K, Burton RC

An outline of the ventilation and refrigeration requirements of deep South African gold mines is presented. This is followed by a brief description of the history of controlled recirculation in mines and the practical and economic benefits such schemes can offer. The potential hazard of a fire in a recirculation system is discussed.The major part of the paper describes the first large-scale field trial of controlled recirculation to be conducted in South Africa. Emphasis is placed on the monitoring system that was used for data acquisition during the trial, and also on a safety system designed to shut off the recirculation fans in the event of a fire.The paper concludes with a review of the latest development work taking place on recirc-ulation safety systems.

Jan 1, 1985

By L Clarke, R N. Campbell, F Bourke, J Anderson

Lithological units have been classified geotechnically with mechanical tests and discontinuity measurements from the GRD Macraes Limited, Macraes Gold Project and Rotowaro coal mine open pits, New Zealand. Using these measurements slope stability probability classifications (SSPC) have been quantified based on an adaption of Hack's (1998) SSPC system which places less influence on rock quality designation and unconfined compressive strength than previous slope/rock mass rating systems. The Hack weathering susceptibility rating has been modified by using the chemical index of alteration values from XRF major element analysis. Slaking and weathering is an important parameter in slope stability in the Waikato Coal Measures and Otago schist lithologies and hence a non-subjective method of assessing slaking/weathering in relation to the chemical index of alteration has been introduced. Other major components of this adapted SSPC system are the inclusion of rock moisture content and rock strength anisotropy effects on slope stability. This paper explains the systematic approach of using the adapted SSPC system to classify slope stability probability. The main modifications of Hack's SSPC system are the introduction of rock intact strength derived from Mohr-Coulomb failure criteria which has been adapted for varying moisture content, weathering state and confining pressure. It is suggested that the subjectivity in assessing intact rock strength within broad bands in the initial SSPC system is a major weakness of the initial system. Initial comparison of rock mass friction angles, cohesion and strengths derived from the adapted SSPC are compared with results derived from modified Hoek-Brown criteria, MRMR and SMR classification systems. The advantage of the modified SSPC system is that slope stability probability, maximum batter and overall slope height and overall slope angle for open pit walls can be predicted in addition to orientation dependent and orientation independent stability. Examples are provided, using the modified SSPC system to predict initial optimum pit slope designs in proposed greenfield mine sites.

Jan 1, 2000

By Kneisley RO

This paper presents a brief overview of current bump mechanics theories and pillar design methodologies, and relates these concepts to experiences at two mines located in a north- central Utah coalfield where different pillar designs were used to control mountain bumps. Experiences gained at the first mine demonstrated the successful implementation of a two-entry, 9.8 m (32 ft)-wide, yield-pillar design. A U.S. Bureau of Mines field study quantified the timing of chain pillar yielding and resulting load transfer from the gateroad. In-mine pillar response, although apparently sensitive to site-specific conditions, compared favorably to estimates derived using two yield- pillar design methods. A second study conducted at another mine located in the same district, but subjected to different geologic conditions, documents the unsuccessful attempts to employ progressively narrower three-entry pillar designs based on successes achieved at the first mine site. This second mine never achieved a true yield-pillar design. Use of pillar widths ranging between 9.1 m (30 ft) and 27.4 m (90 ft) always resulted in violent bumps in the tailgate pillars. The pillars were either too large to yield, or too small to support peak operational loads. Hypothetical gateroad systems were evaluated using both analytical and empirical approaches for configurations comprised of two rows of conventional pillars, and systems incorporating both yield and abutment pillars. Analysis concluded that yield pillars less than 6.1 m (20 ft) wide and abutment pillars ranging between 30.5 m (100 ft) and 39.6 m (130 ft) square would be required to achieve a stable gateroad design. However, results of a field study conducted on a two-entry, 36.6 m (120 ft)- wide abutment pillar concluded that abutment pressures from the first panel overrode the pillar, and that a still larger pillar may be required to preclude bumps in the tailgate during second panel mining. Without the benefit of a demonstrated in-mine success, it is not clear which design would ensure elimination of gateroad bumps.

Jan 1, 1992

This paper describes the effects of physical variables in dewatering of mineral slurries with air as the filtrate displacing medium. Using a mathematical model with material related constants measured in laboratory dewatering curves are simulated for vacuum and pressure filtration. Four different mineral slurries are studied. Basic dewatering curves with variation in air-pressure are shown with iso-energy lines. Variables such as air pressure, feed concentration, cake thickness and cake formation pressure are discussed.

Jan 1, 1989

Uranium exploration over a wide area of the Southern Frame Embayment, South Australia, has defined a number of Lower Tertiary fluvial palaeochannels incised in older rocks. The buried channels contain similar stratigraphicsequences of interbedded sand, silt, and clay, probably derived from the adjacent uranium-rich Olarv Provinee. Uranium mineralization is pervasive within two major palaeochannels, and four small uranium deposits have been found in the basal sands of these channel sequences, at the margins of extensive tongues of limonitic sand.One of the channels is examined in detail with respect to channel morphology, stratigraphy, and rock alteration and the geology and ore controls of the contained uranium deposits are described.A geochemical zonation reflected by variation in limonite, pyrite, carbon, and humic malleI' is defined across one of the deposits. A genetic model is proposed suggesting formation by a uraniferous geochemical cell which migrated down the stream gradient and concentrated uranium on its lateral margins adjacent to the channel bank.

Jan 1, 1978

By Morley I. W

Offshore minerals legislation has been introduced to provide jurisdiction over the exploration and recovery of mineral resources, particularly petroleum, from the territorial waters and parts of the continental shelves adjacent to coastal states. Ratificat- ion of the 1958 Geneva Conventions on the Law of the Sea has provided some measure of international agreement amongst signatory powers. Because the relationship of the Australian States to the Commonwealth in their federal system, the Australian offshore petroleum legislation is of particular interest. The customary role of the States in mineral resources management, which has extended to the offshore, is under challenge from recent unilateral Commonwealth Government legislative actions in the fields of mineral resources jurisdiction. Environmental considerations provide an additional issue, as yet unresolved, with the delay in submission of the Report of the Great Barrier Reef Petroleum Drilling Royal Commissions

Jan 1, 1974

By M Denton, M Rheinlander, S Mundell, M Broadgate

The manufacturing industry reinvented its approach to the manufacturing process by managing and measuring it end-to-end. This improved returns on production assets, improved information quality and reduced delivery time, resulting in larger net profits through cost reduction and improved cash flow. Today this approach is standard in the manufacturing industry. Resource development has many requirements in common with the manufacturing production line. These include: control of the various steps, transparency of the state of the process to various levels of the organisation and the overall efficiency with which the process is executed. The authors argue that the introduction of manufacturing execution systems (MES) concepts and technologies to resource development processes will lead to similar improvements in control, transparency and efficiency and could improve profitability and enable staff to work more effectively and make better decisions.

Jan 1, 2009

By S Grano, J Ralston

Selective oxidation of minerals was used in this study to separate by flotation the copper sulphide minerals of chalcocite, covellite and chalcopyrite from the arsenic copper sulphide minerals of enargite and tennantite. It was found that a satisfactory separation of these minerals was only possible after selective oxidation of their surfaces in slightly acidic pH conditions, or after oxidation and selective dissolution of the surface oxidation products with a complexant in basic pH conditions.

Jan 1, 2000

The Geological Survey of the U.S. Department of the Interior is primarily a domestic agency whose responsibility is furnishing impartial data and analyses to the public, private, and academic sectors of the Nation. The Survey concentrates on earth-science issues, such as mapping the land surface, determining the quality and quantity of water resources, estimating the nation's endowment of fuel and nonfuel minerals, and predicting and mitigating geologic hazards, such as those inherent in the tectonically active Pacific Rim. One of the challenges to managing this program is striking a sustainable balance between concentrating on the problems society wants solved today and investing in the research that seeds our vitality for the future. The Geological Survey's role in the Pacific results from the Nation's geography and the Nation's long standing interest in and commitment to the region. The longest segment of the U.S. coastline borders the Pacific Ocean, one of our states is a Mid-Pacific island chain, our lands are 80 degrees--nearly one-fourth--of the Pacific perimeter, and our Exclusive Economic Zone (EEZ) underlies significant parts of the eastern, northern, and central Pacific waters. Thus, the program of marine and terrestrial science operating in these areas make substantial contributions to the world's growing understanding of the Pacific realm.

Jan 1, 1990

By Mostyn G

In the last three decades various theories have been presented to allow the estimation of the force required to cut rock. These have generally relied on an hypothesised mechanism of chip formation.The paper presents results of an experimental program completed on an unjointed artificial rock in which the force and chip geometry were measured during deep cutting with a quarter scale bulldozer tyne. The program included various depths of cut and artificial rock of varying strength. The experimental results are compared with predictions based on three expressions for cutting force. Generally the measured forces are within the range of those predicted but none of the methods predicts the cutting force with any accuracy. It is considered that the discrepancies are due, in part, to the fact the that actual shape of the chip formed in deep cutting is quite different to that assumed in developing the theories and thus the theories cannot be expected to predict the cutting forces. It is concluded that Evans and Nishimatsu's theories predict lower bound estimates of the horizontal cutting forces. Deliac and Fairhurst's approach appears to over estimate the forces required to cut rock. New methods of prediction are required based on the observed mechanisms of failure.

Jan 1, 1993

By A D. Bugarski, G H. Schnakenberg Jr

An investigation was carried out at a US underground mine to characterise diesel aerosols and to asses the effects of various control technologies on the concentrations and properties of particulate matter and gases emitted by heavy-duty diesel-powered equipment. This study was dedicated to evaluating the impact on mine air quality of contemporary diesel particulate filter (DPF) systems installed on mining equipment. Additional efforts were made to assess the effect of blended biodiesel fuels, yellow grease and soy, ultra-low sulfur fuel, a fuel emulsion and of selected diesel oxidation catalysts on air quality and emissions. The carbon analysis performed on the collected samples showed that the tested DPF systems reduced the mass concentrations of elemental carbon in mine air by between 70 per cent and 92 per cent. In addition, TEOM measurements, collected during these tests, showed that the total diesel particulate matter concentration in the mine air was reduced by greater than 65 per cent when DPF systems were used. The tested biodiesel blends were found to reduce elemental carbon concentrations in the mine air by between 49 per cent and 33 per cent, for the B20 (20 per cent biodiesel/80 per cent #2 diesel) of soy and yellow grease respectively and between 66 per cent and 56 per cent for the B50 (50 per cent biodiesel/50 per cent #2 diesel) of soy and yellow grease, respectively. The water-in-diesel fuel emulsion was shown to reduce elemental carbon concentrations by as much as 85 per cent. NO2 measurements showed an increase in the maximum concentrations of NO2 when catalysed DPF systems were used instead of mufflers.

Jan 1, 2005

By Brasnett TC

A wide variety of problems are encountered on a day to day operating basis in the Isa Mine Concentrators. These vary from complex textural problems in the lead-zinc concentrator and their subsequent effect on grinding and flotation to scheduling of converter slag treatment in a chalcopyrite concentrator. With the advent of process control, metallurgists need to specialise and keep up to date with technology improvements. This paper will attempt to describe the significant problems'faced by a Metallurgist û Control.

Jan 1, 1978