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By G P. J Dijkema, M A. Reuter

From a material cycles perspective all processes are interconnected and consequently a process can never be evaluated as an isolated and independent unit. This also holds true for the evaluated co-incineration options. Environmental and sustainability issues for example, such as raw material and energy utilisation or air pollution, are a resultant of the whole system of industrial activities. It is therefore important, not to optimise a single process or industrial activity, but rather the whole system. Although engineering procedures for the design of individual industrial units are well developed, the problem of determining the best arrangement of these interconnected units is often far more difficult. Regulation that manages the arrangement of the units for waste processing is still under construction. In the evaluation of co-incineration, analogous principle from process control can be used: feedforward control. This principle includes the determination of which outlets can be used for all process outputs, hence avoidance of any æunusableÆ products or wastes possibly arising from co-incineration. To establish the extent, to which produced wastes are usable, a system overview is necessary, in addition to in-depth information on the subsystems, which produce and can consume wastes. Material cycles modelling can be used as the basis for a tool that supports the development of a suitable playing field. It should provide overview of the system and in-depth information on its subsystems. This tool then represents an attempt to bridge the gap between æholisticÆ industrial ecology and process engineering.

Jan 1, 2000

By A Scott

Long before a modern mine commences operations it has already become a wealth of information. After start up, it can generate enormous quantities of data û especially with semi-automated data acquisition by instrumented mine equipment. However, much of this data is of limited use for evaluation of (potential) performance unless it links in some way to the site business model. An underlying reason for this waste of data is that the different cultures, financial, technical, community, environmental, etc not only have many areas of interest but also have very different conceptual models by which they evaluate performance. It is too ambitious to attempt to bring all of these cultures together û in a single step. However, the success of the Mine to MillTM project has demonstrated that substantial operational value can be added by using a more integrated approach to comminution. The next logical step is to integrate measurement and then to track performance from orebody model to saleable product and waste disposal. From resource to product also represents a path from very sparse, highly variable data to much more detailed measurement and more representative sampling. However, in both cases the data collected is strongly focused on the technical requirements û not on the business model. This paper considers how to define at least some of the key decision points in terms of some case studies. Performance data from many areas might be used to derive simple models which can then be used for forecasting and optimisation of planning.

Jan 1, 2002

Deep hydrothermal fluids adjacent to the Alpine Fault move through the brittle-ductile transition to mix with convecting fluids from near surface environments. These tectonically driven fluids evolve mainly from prograde metamorphism at mid crustal depth (ten kilometres) within the ductile regime which has been elevated due to advection and drag on the fault plane. Through the onset of brittle failure and cataclasis within Alpine Fault mylonites, fluid overpressuring results in hydrofracturing and localized implosion. Along the length of the Alpine Fault, hydrothermal alteration varies on most levels (Table 1). There is an observable increase in Fe-Mg carbonate between the Waitaha and Taramakau Rivers (between Ross and Aurthur's Pass, respectively). Field studies concentrate to the north east of the Arahura River, noted for historical mineral wealth. Late meteoric fluids move through cataclasite, brecciated mylonite, and other open fractures. Chloritisation is the major retrogressive phase. Dolomitic hydrofracture veins (Figure 1) within coherent mylonites contain iron and copper sulphides. Notably, the enrichment in Fe-Mg carbonate towards the Alpine-Hope Fault intersection seems to represent a region of enhanced permeability possibly related to shallow seismicity, increased regional faulting, footwall variation, strike-slip dip-slip distribution, and/or topographical anomalies (ie saddles). Isotope studies identifying an 'Inboard Fault Gouge Calcite Zone' correlate to values from the Main Divide region at the headwaters of the Arahura River (Browning Pass-Wilberforce Valley) (Becker et aI, 2000). These correlations are supported by rare arsenic anomalies (avg l06 ppm n = 5, Figure 2) found in both regions which suggest that fluids may be interconnected at depth.

Jan 1, 2001

By G W. Wilson, C Panidis

Potentially acid forming (PAF) waste rock contained in dumps formed as a result of open cut mining of metalliferous orebodies are conventionally sealed or covered using a near-saturated, low permeability compacted clay layer, protected with a mulch layer and/or vegetated growth medium. The purpose of the compacted clay layer is to limit oxygen diffusion and the infiltration of rainfall into the dump. Where the aerial extent of the PAF waste rock dump is large, or where suitable clayey material is in short supply, it may be difficult to source sufficient suitable clayey material to form the cover. The paper describes a laboratory-based investigation of combining inert waste rock and tailings to form an alternative seal or cover material. The inert waste rock was sourced from the trafficked surface of a non-acid forming (NAF) waste rock dump, with a maximum particle size of about 100 mm. This was combined with NAF thickener underflow tailings slurry in various mass ratios, and the resulting mixtures tested for their particle size distribution, compaction characteristics, soil water characteristics (relationship between suction and volumetric moisture content), and saturated hydraulic conductivity. The mixtures tested ranged in consistency from those dry enough to be compactable, to those with the consistency of wet concrete that lend themselves to placement without the need for compaction. The laboratory test results showed that the suitability of the mixtures as seal or cover materials is very dependent on the particle size distribution of the mixture, with well-graded mixtures having substantial fines performing best.

Jan 1, 2003

By Gillies A. D S, Lee A. H

The major operational objectives of a mine water resource management system (WRMS) are to supply the water needs of the mine and mill, to minimise disturbance to mining due to rainfall flooding or seepage and to dispose of excess water. Historically, company management have placed a significantly lower emphasis on managing the WRMS as compared to managing production. Changing Government legislation concerned with the disposal of water from mine sites is, in many cases making mining companies look more closely at how they manage their water. For example, within the next few years it is likely that prior to mining approval by the Government, mining operations will have to submit water management plans/budgets and contingency strategies in addition to operational plans. While the formulation of a comprehensive water management plan/budget is an additional cost to the company at the mine establishment stage, such plans can be beneficial to the operation in the longer term.The two keys for the efficient design, operation and development of a WRMS are the establishment of written goals which have managerial priority and secondly, access to appropriate good quality data. Managerial priority towards the WRMS will increase as a consequence of the education of mine operators in the benefits to the operation of good WRMS management or less desirably as a requirement to meet Government legislation. The collection of appropriate WRMS data is a more complex issue and to obtain information efficiently and cost effectively relies on the clear definition of the data application.

Jan 1, 1992

Christmas Island "C"-grade phosphate consists essentially of the minerals crandallite and millisite. Although containing over 25% P205, this material is not suitable for the manufacture of water-soluble phosphate fertilizers by conventional processes, because of its high iron and aluminium content Cover 25% total R203). In order to produce a water-soluble fertilizer from such material it is necessary to separate the iron and aluminium from the phosphate, which must report in a product acceptable as a fertilizer. Several processes were studied in detail. The first used ion exchange for dissolution and separation and yielded diammonium phosphate; processing costs were high compared with conven- tional processes based on apatite. The latter processes have basically simple flowsheets and cost of processing is low when compared with the costs of the raw materials. The need to separate iron and aluminium from the phosphate introduces additional complexity into the treatment of the C-grade material. The higher processing costs might be justified, however, if alumina could be produced as a byproduct. Two proposed processes have been developed in which: 1. hydrochloric acid is used for dissolution, and solvent extrac- tion for the separation of ferric chloride from phosphoric acid. Aluminium chloride is precipitated and hydrolysed to recover alumina and hydrochloric acid. 2. sulphuric acid is used for dissolution and aluminium is crystallized as ammonium alum. The phosphate is produced as an ammonium phosphate-sulphate fertilizer. High purity alumina can be obtained by treatment of the recrystallized alum. The technology of these processes is described, and their broad economics discussed briefly.\

Jan 1, 1971

The inauguration of a geological department for the mines of North Broken Hill Limited necessitated the provision of accurate plans and sections upon which geological facts and projections might be plotted.Unfortunately, the basic data were very inadequate. For the British Section, sill survey plans were available, but no regular stope plans. Filling surveys had been preserved for many stopes, but on innumerable pieces of tracing linen, without heights of any kind, and not altogether reliable (as indicated by the finding of very inconsistent duplicates). For the bulk of the old stopes no plans exist at all. The expenditure of much time and patience has resulted in the co-ordination of most of the existing stope data, but the British Section must for the rest of its life continue to have surprises in store, as has been the case for many years past. Manufacture and preservation of stope records has, of course, been on a sound footing during recent years. No reliable cross-sections of the British Section were available.The Marsh, Junction, and Junction North Sections have for the most part very poor data. In the North Section, level plans were fairly reliable, and cross sections of the lode made for ore reserve purposes have been preserved for quite a few years. No floor plans of stopes were kept, however, until a couple of years ago.Diamond Drill records vary in quality. Practically none exist for the Junction and Junction North Sections. Logs have been kept for the British Section drill holes, but are...

Jan 1, 1940

By P J. Scales, D Boger

Technological advancements in mineral processing have increased the feasibility of refining low-grade ores. Because of this progression and continual depletion of high-grade ore deposits, much larger volumes of waste material are produced. At the same time, increasing environmental legislation and cost competitiveness dictate that these wastes be disposed of in a manner that is both environmentally acceptable and economically viable. To achieve these criteria, many mineral processing industries are dewatering waste streams in order to reduce the volume of tailings and increase water and reagent recovery. The subsequent dry disposal of these highly concentrated mineral tailings requires a thorough understanding of the effects of dewatering on the flow characteristics. Dry disposal represents a paradigm shift in engineering. The tailings are engineered to suit the disposal requirements, as opposed to engineering a facility to accommodate the tailings. It is therefore important to understand how the material properties and operational parameters can be modified to produce the desired tailings flow and deposition characteristics. As concentrated suspensions usually exhibit non-Newtonian behaviour, determination of the disposal plant operating conditions requires a thorough understanding of the rheological characteristics of the material. The implementation and optimisation of dry disposal methods involves three concurrent and interdependent rheological studies to determine:the concentration required to achieve the optimum spreading and drying characteristics of the tailings once deposited; the optimum conditions for pipeline transport; and the feasibility of dewatering the slurry to the required concentration. The paper presents an overview of the issues pertinent to management of the flow properties and processing of dewatered waste streams.

Jan 1, 2002

By Y Zha, J L. Walshe, A Ord, N J. Archibald

The purpose of this paper is to discuss the concept of Geodynamic Modelling as an exploration tool and to provide a specific example, namely, the Century Zinc deposit in Northern Queensland. Geodynamic Modelling is an attempt to become more quantitative in the way we develop exploration models. It is a systems approach to ore genesis which examines the complete four-dimensional mineralising system of interest, rather than individual site specific ore deposits. The goal is to establish a predictive capability that enables the explorer to predict grade, tonnage, mineralogy, alteration patterns and precise location of a potential orebody given a particular exploration model. The process consists of two well-defined stages: firstly, a æsoftÆ modelling stage where all available data on lithospheric architecture, geodynamic history, fluid chemistries, fluid flow mechanisms and mechanisms of metal transport and deposition are collected; and secondly, a æhardÆ modelling stage where the system is modelled using fully coupled deformationûfluid flow-thermal transport-chemical reaction computer codes. In the case of the Century Zinc Deposit we point to its existence on the boundary between two fundamental blocks of Proterozoic mantle lithosphere. This boundary has controlled Pb/Zn mineralisation in Northern Australia from the Proterozoic through into the Paleozoic. Detailed thermal, chemical, fluid flow, deformation modelling of the Century System points to an origin involving mixing of crustal oxidised fluids bearing zinc, with reduced fluids bearing H2S and CO2 from the lower crust or mantle. We use this modelling to define critical exploration criteria for another Century type of deposit.

Jan 1, 2000

By J Chßvez, J Rosa del Castillo, J Rui

Environmental Impact Assessment (EIA) and Feasibility Studies (FS) were carried out to evaluate the potential use of treated acid mine drainage (AMD) occurring at the Kingsmill Tunnel in the Central Andes of Peru. The 11 km long tunnel drains the underground works of the Morococha Mining District and discharges about 1.25 m3/sec of AMD directly into the Yauli River in the Amazon Basin. The communities living downstream cannot use the Yauli River water due to its low pH and elevated concentrations of metals (eg Cu, Zn, Fe, Mn, As, Cd) and sulfate. Studies carried out for this project included technical feasibility, EIA, economic viability and social impact assessment phases. During the æTechnical FeasibilityÆ phase, the treated AMD was produced by simulating a high density sludge (HDS) lime neutralisation/ precipitation process and was evaluated for various potential uses. Mining companies located in Morococha, in particular Centromin Peru SA, and the Water Works Company of the City of Lima (Sedapal) collaborated with Golder Associates during the studies. The Canadian International Development Agency (CIDA) provided the financial assistance. The results of the physical, chemical, biological and toxicological analyses demonstrated that the AMD could be sufficiently treated to be potentially used to supplement the drinking water supply of Lima, and for agricultural (eg irrigation and livestock) and recreational purposes. Process design and scale-up parameters were also determined for implementation of the full-scale treatment facility at the site. The use of the treated AMD as a drinking water supplement would be economically feasible.

Jan 1, 2003

The Martha Mine is an open cut operation situated in the midst of Waihi town which has been operating since 1987. Since then it has produced some 700,000 ounces (oz) of gold and 4,000,000 oz of silver from an epithermal vein system. It was previously worked by underground methods from 1880 to 1952 to a depth of 600 m producing 5 million ounces (Moz) of gold and 30 Moz of silver. The licensed reserves are scheduled to be mined out early in the year 2001. An additional economic resource of over 750,000 oz of gold has been identified which can be accessed by deepening the pit a further 50 m along the main Martha vein. This would extend the mine life to the year 2007. Applications were lodged on 4 July 1997 for the necessary resource consents, discharge permits and variations for the current Mining Licence conditions. The extension project requires approval from the District Council, Regional Council and the Ministry of Commerce. The consent and permitting process is extensive because of the urban setting of the mine. An approach to keep the extension as similar as possible to the current operations was adopted to give the community and authority confidence in the proposed extension. This paper summarises the extension detail and the permitting requirements it has had to address despite the extension being "more of the same". The permitting process has been exhaustive with little recognition of the standards already achieved in protecting the environment which are recognised worldwide.

Jan 1, 1997

By V N. Rudashevsky, N S. Rudashevsky

Characterisation of platinum-group element (PGE) deposits and their process products has many challenges for the process or applied mineralogist. It is now well established that the PGE distribution for such samples is variably divided between submicroscopic concentrations of PGE in sulfides, tellurides and related minerals occurring as discrete platinum-group minerals (PGM), of which there are a large number of species, many with partial replacement between the PGE and between anions. Each PGE deposit type requires a targeted approach but fundamentally, there are two general methodologies in vogue. One way is to make a large number of polished or polished thin sections for detailed scanning electron microscopy (SEM)/optical examination to determine the PGM distribution and their associations and grain sizes. The other is to make concentrates of representative crushed or processed samples, thus having fewer subsamples to examine. Our method of choice is to use hydroseparation (HS) for concentration. HS provides representative concentrates of sizes down to ~10 ¦m, not possible by other techniques. Various microbeam methods have been used for analysis of trace quantities of PGE (EPMA, micro-PIXE, SIMS and LAM-ICPMS). We prefer LAM-ICPMS (laser ablation microprobe û inductively coupled mass spectrometry) because of the relatively large analytical volume sampled, the ability to measure all the PGE, monitor up to 20 elements, together with detection levels in the tens to a few hundreds of ppb. We provide typical results derived in studies of stratiform PGE ores and tailings, and a massive Ni-Cu sulfide ore.

Jan 1, 2008

The Cadjebut Mine is located 80 km southeast of Fitzroy Crossing. Cadjebut is owned 58 per cent by BHP Minerals and 42 per cent by Billiton Australia. Cadjebut is a 'Mississippi Valley Type' (MVT) deposit. Minerals present are sphalerite, galena and marcasite in a sedimentary host of dolomite and siltstone. The ore contains few deleterious impurities and no silver. The mill was commissioned in the first half of 1988 at a rate of 320 000 tonnes per annum. An expansion in the latter half of 1989 has since increased production to 550 000 tonnes per annum. The initial geological resource at the commencement of mining was 3.8 million tonnes at 13.5 per cent Zn and 4.4 per cent Pb. There is sufficient ore left to sustain operations to 1995 at a grade of 11.2 per cent Zn and 3.9 per cent Pb. The ore from underground is stockpiled on the surface via a drift conveyor and from the stockpile is fed into a grinding circuit consisting of a SAG and ball mill. Cyclone overflow at a Pgp of 90 pm gravitates to the flotation circuit. Lead and zinc are sequentially floated to produce an 80 per cent Pb grade at 90 per cent recovery and a 61 - 62 per cent Zn grade at 96 per cent recovery. The concentrates are thickened and filtered before being trucked to the port of Wyndham 600 km away. From Wyndham the concentrates are shipped to smelters in Asia, Europe and Australia.

Jan 1, 1992

The Bradford Process, Australian Patent No. 11253, has had considerable application in the treatment plants of Broken Hill mining companies, and is at present being used by the North Broken Hill Limited for the treatment of weathered slime accumulations.The "Mining and Scientific Press," of 28th September, 1918, describes the Bradford Process at Broken Hill, specially featuring its application to slime material at the Proprietary mine-the home of the process.The points then stressed for galena flotation were acidulated slime pulp (0.025 to 0.030% H2S04) at temperature 85° to 90° F. and suitable time contact, with 1.5 to 2 lb. of sodium hyposulphite (per ton on slime) to permit the released S02 to "wet" or depressthe blende mineral. Also 1.0 to 1.3 lb. of crude sulphur (per ton on slime) was burnt, to supply S02 for keeping the lead concentrate clean during flotation. Pulp density varied from 23 to 26% solids. Since 1918 the process has been simplified in its application.Acidity of circuit, temperature, and sodium hyposulphite have been dispensed with, and now the S02 is practically all obtained by burning crude sulphur. I The plant units now employed for control and absorption of S02 gas constitute the main advance made in process, and these, with other details, are fully explained in this paper.APPLICATION AT BROKEN HILL NORTHThe existing North Broken Hill Limited gravity mill commenced operations on 9th September, 1909.

Jan 1, 1929

The Mary Kathleen uranium deposit occurs in 1740-1780 M yr-old calc-silicate melasedimentary and mela-igneous rocks of lhe Corella Formalion which have been tightly folded into lhe Mary Kathleen Syncline. The Corella Formation consists of malic and felsic tuffaceous(?) calc-silicates, quartzile, and minor marble, conglomerate and basic volcanics. Garnet-rich rocks form semi-concordant and transgressive masses in the middle and upper portion of the sequence. Granite, gabbro and acid porphyry dykes also occur in the syncline.Uranium-rare earth mineralisation is closely associated with certain malic rocks and occurs wilhin or close to garnet-rich masses. At Mary Kathleen, uraninite grains are enclosed mainly by allanite which is dislribuled through massive garnet as an irregular honeycomb of interconnected shoot and lenses. The mineralisation occurs along strike from dioritic rocks and conglomerate and lies close to the axis of the Mary Kathleen yncline and adjacent to a major faull zone. All other localities allanite-uraninile mineralisation is broadly stratiform.The mineralisation is interpreted to occur at or near centres of basic volcanism. Garnet formation and uranium-rare earth concentrations are believed to be caused by the volcanism, and to be contemporaneous with it. The former is seen as alteration of a hot, saturated pile of volcano-sedimentary material and the latter as intermittent hydrothermal exhalation.Deposition, volcanism, garnet formation, uranium and rare-earth mineralisation, granile and gabbro formation, and tectonism are seen as a continuum of interrelated processes which operated throughout the period of format ion of the rocks in the Mary Kathleen Syncline.

Jan 1, 1985

From 1980 to February 1991 the Rosebery concentrator purchased ore from Aberfoyle's Que River Mine. Following the termination of the contract the concentrator reverted to treating Rosebery ore alone. Since that time it has become apparent that the circuit configuration employed was no longer optimum for zinc metallurgy. The circuit was designed to treat a difficult, slow floating sphalerite; however, the opposite was now found to be true. The sphalerite is fast floating and the circuit was cumbersome. During 1992 extensive circuit changes led to the provision of a simple open circuit flow sheet. The circuit is now easier for operators to understand and lends itself to improvements in process control. Middlings streams have been minimised, which produces a far more stable circuit. Significantly, it must be noted that the key to achieving potential results must lie in reducing variations within the process. A significant ore characterisation program has been undertaken, providing an insight into the metallurgical compatability of the ore to be mined. Using the information collected in this program, metallurgical recoveries and grades can now be predicted with a geater accuracy. Ore characterisation data suggests that an improvement from a 54 per cent zinc concentrate to a 57 per cent zinc concentrate should be achievable. By understanding the size-by-size mineral assemblage, a strategy for concentrate grade improvement has been developed. The requirements of the customer must in all cases determine the quality of the product. Pasminco is a fully-integrated zinc producer and as such significant gains can result by tailoring the concentrates to suit the Smelters.

Jan 1, 1993

By Hartley JS, Wills KJA

The Thalanga massive sulphide deposit is hosted by Upper Cambrian rhyolites and volcaniclastics of the Mt. Windsor Volcanics near their contact with overlying dacites, rhyolites and sediments of the Trooper Creek Formation. The ores and host rocks have been subjected to a single strong deformation and to lower to middle greenschist facies metamorphism. A main lens with surface gossan dimensions of 55U m x 6 m dips steeply, plunges shallowly to the west and is offset by a series of normal faults. It is flanked by smaller lenses to the east where the mineralized horizon is stopea out by granite. The area to the east and south of the gossan is masked by Tertiary cover. A complex exhalite package is represented by banded sphalerite-pyrite- galena-chalcopyrite, massive pyrite and chalcopyrite and assemblages dominated by dolomite, chlorite-actinolite, tremolite, talc, barite and rare gypsum. Accessory tetrahedrite, arsenopyrite, bismuthinite, magnetite and native gold are associated locally. Pods of quartz-magnetite formed distally. The ores are underlain by strongly to moderately pyrite-silica-sericite altered rhyolites with the strongest alteration closest to an interred synvolcanic fault. This alteration is characterised by an enrichment in MgO, Na2O, FeS2 and base metals with a depletion in CaO and Na2O. There is a general enrichment in Pb and Zn towards the hanging wall with some enrichment of Cu near the base of the main lens due to replacement by ore tiuias near vent discharge sites. Zonation of Cu to 2n-Pb in also evident over narrow intervals

Jan 1, 1987

By Garland W

Access to geoscience reference informa- tion including mining and mineral processing has increased considerably in the last five years in Australia. This has been due principally to the use of computer-based information storage and retrieval systems. The main reference data base for the mineral and petroleum industries and disciplines in Australia is the Australian Earth Sciences Information System (AESIS), cooperatively developed and coordinated by the Australian Mineral Foundation (AMF). AESIS is created on the CSIRO computing network (CSIRONET) which has a CYBER 76 host computer located at the CSIRO Division of Computing Research (DCR) at Canberra. Data entry was until recently carried out by AMF using a dedicated line through the Adelaide CSIRONET node to the CYBER 76 interactive system. Data entry is now done directly at the AMF on a DEC PDP 11/44 mini computer that is also a host work station on CSIRONET. Data collection via magnetic tape media input from other computer-based systems is under development. The software used for data entry and management of the data base was developed by CSIRO CILES Systems Development Group. For public interactive online use the AESIS data base is transferred by tape to AUSINET - the Australian information net- work run by ACI Computer Services, Melbourne, where the data base is converted to a form suitable for the IBM STAIRS software. CSIRO facilities at DCR Canberra are used to produce computer type-set camera ready products and output in microform, on magnetic tape or as graphic display. Keywords: Earth sciences information, Computer applications, Information storage and retrieval, AESIS, Data bases, Australia.

Jan 1, 1983

By H Bartosiewi, M Kuruppu, F Mashiri

Wire ropes are one of the most heavily used components in a dragline. They are subjected to harsh conditions during the regular usage of a dragline in a mining operation. Hoist ropes are subjected to fatigue due to the cyclic nature of load handling as well as due to rope bending over the sheaves and the drum under load. This leads to wire breaks due to fatigue. Accumulation of a number of wire breaks close to each other can have a detrimental effect on the rope. Furthermore, to allow for the increasing demand for higher load capacity coupled with the inconvenience of having very large ropes, the factor of safety is often compromised, which increases the wear rate. Drag ropes are also subjected to heavy loads. More importantly, they are allowed to drag along the rough mine surface subjecting them to external physical abrasion. This makes the life of drag ropes one of the lowest among those used in a dragline. Suspension and IBS ropes are relatively uniformly loaded during their regular usage although they need to withstand dynamic load cycles as well as bending. Hence they tend to last for a number of years on average. The paper analyses the wear types and their severity of each of these rope applications, and suggests methods to determine rope wear rates and the resulting rope life. The paper further gives suggestions for good operating and maintenance practice that can extend the rope life and help reduce the large expenditure associated with every major rope change in a dragline.

Jan 1, 2005

By Kelley BC, Filmer AO

The chemical oxidation kinetics of sphalerite by Fe(III) was studied at various temperatures and size fractions in sulphate media. The kinetics of Zn extraction followed a pore diffusion control mechanism with an apparent activation energy of 54-58 kJ mole. This figure, although high for a pore diffusion control process, is consistent with other studies carried out in sulphate media. An empirical statistical model, relating the extraction time to % Zn extraction, average particle size and temperature, is described by log 1 = 12.22 - 0.017% Ext. - 1.76 log D Av t - 2954 T Parallel studies were also carried out investigating the biological oxidation of sphalerite utilizing the acidophilic autotrophic bacterium Thiobacillus Ferroxidans. The effect of such kinetic parameters as pulp density, particle size and Fe(III) on bacterial growth rate and consequently zinc extraction rate, were studied and where appropriate, optimum conditions for bacterial growth were specified. Based on the results of chemical and biological leaching studies, it was apparent that rapid zinc extraction from sphalerite was predominently due to oxidation by Fe(III). The biological oxidation process catalyses the oxidation and regeneration of Fe(III). The proposed combined chemical-biological leach system was simulated in semi continuous fashion. The sphalerite oxidation rates obtained in this system were similar to that predicted by the chemical leach empirical model. 1. Senior Research Metallurgist, CRA Research, Boolaroo, N.S.W. 2. Group Leader-Hydrometallurgy, CRA Research, Boolaroo, N.S.W. 3. Senior Research Scientist, Biotechnology Australia, Roseville, N.S.W. 4. Senior Experimental Officer, Biotechnology Australia, Roseville, N.S.W.

Jan 1, 1986