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By Lawrence PR, Hoffman W

The dissolution of gold from various ore-bodies is discussed in terms of extraction rates and reagent consumptions during leaching. Gold dissolves slowly in cyanide but reagent consumptions are usually satisfactory. In almost all cases where excessive cyanide consumptions occur, similar high consumptions result with other lixiviants. Recovery of gold from cyanide solution is well established and comparatively simple technology.Gold dissolution in thiourea is faster than cyanide but significant consumptions of thiourea, due to both adsorption and oxidation, occur. Gold recovery from thiourea solutions is likely to be more difficult than from cyanide.Chlorination of gold is very fast in acidic conditions but excessive consumption of chlorine occurs for ores containing greater than 0.5% S. Reprecipitation of gold and handling of acidic chlorine solutions are both significant problems. The mechanism of gold reduction onto activated carbon creates difficulties in the carbon in pulp process for recovery of gold but means a simplification in the production of bullion from loaded carbon.

Jan 1, 1984

Eco-Efficient Gravity Separation Solutions in India Sustainable development and social responsibility issues are a principal aspect of mineral processing operations around the world. With the need for more environmentally effective technologies, some gravity separation systems have provided eco-efficient mineral processing solutions in places where it is not otherwise viable because of lack of fresh water or for other environmental reasons. Advanced spiral separation technologies developed in Australia offer a cost effective and environmentally viable way to process minerals. In particular, we review recent case studies of spiral plants commissioned in India where environmentally sustainable solutions to design problems included the use of spirals operated with sea water and the use of high capacity (HC) spirals to provide low consumption of energy and materials and a reduced plant footprint. This paper evaluates the performance of various spiral plants in India and how critical environmental issues which affect the overall viability of wet concentrating processes where resolved.

Sep 13, 2010

By R N. Humphries

The aim of this paper is to question the need to develop bespoke monitoring and assessment methodologies and criteria, thereby ‘reinventing the wheel’, when designing and assessing the success of important natural habitat and ecosystem restoration schemes at mine sites in the UK and Australia. It draws attention to the existence and applicability of the Phase I Habitat, National Vegetation Classification (NVC) and Condition Monitoring methods in the UK and similar approaches used in Australia. These are long accepted established methodologies and have published accounts for describing, assessing and managing natural vegetation communities, habitats and ecosystems. They are often used at the environmental impact stage, but seemingly rarely, if at all, in restoration design and management at mine closure. Their application to mine restoration and closure is illustrated and discussed by reference to a surface coalmine in South Wales, UK.It is concluded that the application of a combination of the Phase I Habitat, NVC and Condition Monitoring methods is highly relevant to the expectations of the Convention on Biological Diversity (CBD) and its implementation in the UK, and probably in Australia too. The methodology and criteria described could be incorporated into the guidance and specified in the mining permits so that there is clarity as to the expectations and requirements for monitoring and assessment for bond release. Their use could be of wider application where there is a requirement to assess the success of restored CBD assets and ecosystems.CITATION:Humphries, R N, 2014. Why reinvent the wheel when there are established methodologies to aid the design and assessment of restored natural ecosystems on mined land?, in Proceedings Life-of-Mine 2014 , pp 675–692 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By S R. Grano, M Vera

This paper deals with two separate case studies investigating the froth phase performance and characterisation of two industrial rougher/ scavenger flotation circuits. Froth phase performance was quantified using a mass balance approach to estimate froth zone recovery. Measured characteristics of the froth phase included frother solution concentration determined by gas chromatography, and the time taken for an equilibrium froth sample to decay to one-half of its original froth height. The latter measurement is referred to as the æfroth half-lifeÆ and is strongly linked to froth stability. Special methods and techniques developed to preserve frother in solution and to measure froth half-life are briefly described. The frother type in the first case study was a mixture of straight and branched alcohols, whilst the frother type in the second case study was a mixture of alcohols, aldehydes and triethoxybutane. The first case study focussed on a flotation circuit treating a low-grade ore containing only a small fraction of floatable copper sulfide minerals, while the second case study focussed on a flotation circuit treating a higher grade complex sulfide ore containing significant quantities of chalcopyrite, galena, sphalerite and pyrite. It was found that froth zone recovery of valuable mineral generally decreased down-the-bank of the two industrial rougher/scavenger circuits. Moreover, decreases in froth zone recovery significantly limit the overall cell recovery of valuable mineral achievable from the plant scavenger cells. However, the decrease in froth zone recovery could not be linked to the removal of frother from the pulp solution to the concentrate product in the preceding rougher flotation stages. Measurements of residual frother in solution suggested that, approximately, only five to ten per cent of the added frother was removed into the rougher/scavenger concentrate, with the remainder appearing in the scavenger tailings. This finding suggested there was apparently adequate frother in solution in the scavenger stages.

Jan 1, 2005

Development of Cost-Efficient Environmentally Sound Technology for Enhanced Gold Recovery from Rebellious Gold-Containing Raw Materials Study of biochemical leaching performances in gold-bearing sulfide minerals processing enabled to develop environmentally sound technology of enhanced gold recovery from rebellious gold-containing raw materials. It was found that the ?-10 IMO bacteria activity contributes to increasing system oxygen concentrations and incrementing in rates of oxygen delivery onto surface of gold-bearing minerals. Bacteria activity products, ie, amino acids (?), support the formation of such heterocomplexes as [A-Au-CN]- , providing additional gold recovery into solutions. Technological properties of proposed bacteria solutions were studied. It was found that the proposed bacteria inoculants are capable to growing directly in process of raw materials leaching within a large pH range of media containing cyanides and thiosulfates. They oxidise the sulfur to the sulfate, as well as the antimony (III) and arsenic (III) sulfides to the pentads. For the first time, the hydrophobic cell properties, metabolites emulsifying efficiency, adsorption properties, wetting ability, surface tension and electro-kinetic potential of new bacteria strain solutions were studied as compared with chemical solutions. It was found that the proposed bacteria inoculants reduce surface tension at the solvent-mineral and solvent-concentrate phase boundaries. All aforementioned effects enhance mass transfer processes efficiency. IR-spectroscopy of new bacteria strain culture liquid allowed identifying available amino acids which substantially contribute to heterocomplex anion [A-Au-CN]- formation. Active involvement of heterotrophic bacteria in gold dissolving processes was identified. It was shown that the structure of metals complexes is substantially modified at intensive pulp agitation and during long-term storage. Fractional order reaction in biochemical and chemical gold leaching was identified. It evidences that the gold and impurity metals dissolving processes advance in synchronism. The both processes are running in diffusion zone. Biochemical leaching has advantages over chemical leaching, ie it provides enhanced rates of precious metals dissolving, improved gold recovery by 20 - 30 per cent, decreased cyanide consumption by 50 per cent. At the same time it allows to decontaminate dangerous substances contained in productive solutions produced in rebellious gold-containing raw materials processing. Basic parameters of flotation concentrates leaching by heterotrophic bacteria-assisted processing technology were tried and tested. Technology of gold sorption from leaching solutions was successfully tested.

Sep 13, 2010

In redesigning the cyanide plant at Mount Torrens, in conjunction with Mr. L. W. Grayson, the manager, several minor alterations were introduced in order to have the operations under thorough control, and these having proved serviceable may be of sufficient interest to merit a description here. The lixiviation vats, though only 8 feet in diameter, were retained, but the pipes leading away from the bottom were reduced from two inches to half-an-inch in diameter, and had a fall to the zinc boxes of about 4 feet. As these small pipes were completely filled by the solutions fiowing away from the vats, they exerted a suction equal to their fall and thus hastened the rate of flow, so that tailings containing a larger proportion of slimes could be treated than was possible where the larger pipes were used, as, there not being sufficient fiow of solution to keep the latter filled, no suction could be obtained with them. It was found that with'most of the tailings treated a sufficient flow could be obtained from the half-inch pipes when the taps on, them were only one-third to half open. The lower end of each of these pipes was connected by means on indiarubber tubing with the sille hole of 11 in aspirator bottle, and to the mouth of this bottle a few feet of similar tubing was connected, so that the solutions coming through could be directed into either of the fixed tubes leading respectively to the waste water tank the strong solution zinc boxes or the weak solution zinc boxes.In working the vats, the following method was found to give good results. While filling the vats with tailings the taps were left open, so that the water might drain off into the waste water tank the surface of the tailings was carefully levelled. When the strong solution was run in at the top, the air contained in the interstices of the tailings was forced through the half-inch pipe at the bottom as a strong blast, instead of, as I believe js usual, escaping by means of channels formed by it through the tailings, and thus tending, it would appeal, to render the disposition of the tailings less even and to make.

By Fuerstenau DW

The flotation of pyrite in ethyl xanthate solutions is presented along with electrokinetic results. The results have been analysed in view of recently published thermodynamic calculations as well as other published data on the pyrite-xanthate system including adsorption and voltarnmetry studies. The flotation response of pyrite in xanthate solutions is characterised by two maxima, one at pH 4 and the other at pH 8-9. The acidic maxima is also associated with a reversal in the electrophoretic mobility of pyrite, probably due to the formation of ferric xanthate on the pyrite surface through chemisorption of xanthate ions while the basic maxima is not associated with major changes in the mobility and flotation at this pH can probably be attributed the adsorption of dixanthogen. It is concluded that there is not sufficient experimental evidence to conclusively attribute the lack of flotation response in solutions at near neutral pH to any particular phenomena, either kinetic or thermodynamic.

Jan 1, 1993

By Thirumalai K, Peluso R. G

The United States has more than 45 billion tons of economic coal reserves in seams above 10 feet thick and current underground production from thick seams represent less than three per cent of the total production. A tripling of underground production from thick seams is necessary within the next 10 years to meet U.S. coal production demands. An analysis of underground accident and production data is presented in the paper. A study of accident and injury distribution in different coal seam heights in the eastern and western part of the United States in seams ranging in thicknesses from 5 to 15 feet indicates that the seam thicknesses do not produce adverse impact on underground injury incidence. Accidents associated with roof falls and haulage account for about 70 per cent of underground mining injuries.

Jan 1, 1976

The Marvel Loch Operations (MLO) plant was treating ores from up to six MLO sources and in addition needed to blend externally sourced ores with its own ores. This presented a metallurgical accounting dilemma, which was subsequently addressed by the design, implementation and testing of an automatic sampling system. The MLO automatic sampler was well designed and has been the subject of previous internal and external reviews. The sampling action is fully automated and the unit is essentially self cleaning particularly when sampling primary ores. The purpose of this paper is to document the rationale behind the design, the specific details of the sampling station, its use for ore purchase purposes and an assessment of the sampling system to meet the needs of the operator.

Mar 1, 2010

Remnants of Plio-Pleistocene hot spring systems in Northland, New Zealand contain sulfide minerals, principally pyrite, marcasite and cinnabar. The climate is warm temperate to subtropical, with up to 3 m of rainfall per annum, and rocks are deeply weathered. Decomposition of the iron sulfides in natural outcrops and human excavations results in acid rock drainage with pH typically between 2 and 5, and locally down to pH 1. Deeply weathered basement greywacke is clay-rich and has negligible neutralisation capacity. Some overlying volcanic flows have resisted weathering, and pH is kept near neutral by relict secondary calcite in small areas. Natural rainforest soils commonly have pH between 4 and 5 over mineralised and unmineralised greywacke. Mineralised zones are enriched in arsenic, which occurs in solid solution (up to 1 wt per cent) in sulfides and phosphate minerals. Mercury also occurs in solid solution in some of these minerals, as well as in cinnabar. Base metals are present in low (background) concentrations only. Decomposition of the iron sulfides and phosphates releases the solid solution arsenic and mercury into the acid rock drainage solutions. Arsenic is readily adsorbed on to iron oxyhydroxides formed in acid rock drainage situations, and can be effectively removed from the biosphere. However, this arsenic is released back into the environment if the pH rises, as adsorbed oxyanions become less strongly bound and are displaced by hydroxyl ions. Behaviour of dissolved mercury is similar to that of arsenic but less well understood in these settings. Both arsenic and mercury are readily leached into pH 6 solutions from solid material collected from acid rock drainage sites. These observations suggest that neutralisation of acid rock drainage sites is undesirable in this setting, as arsenic and mercury will become more mobile in the environment. The naturally low pH of 4 to 5 of the forest floor, or even lower pH of natural acid rock drainage, is a preferable management option.

Jan 1, 2003

An account is given of experimental apparatus for generating a short duration high velocity water jet and the effect of its impingement on various rock samples under air or water cover. The penetration was found to be highly dependent upon the rock structure; in general material with closely interlocking grains was resistant.The damage sustained by a stationary sample held close to the jet did not vary greatly whether the sample was in air or confined under a water layer; but when the sample was translated under the jet there was a marked increase in the damage sustained.Some consideration was given to the possible practical application of a water jet for deep hole drilling and an estimate made of the power requirements and transmission losses for such a system.

Jan 1, 1969

By Williams D. J

The boundary element method is one of a number of tools that have found wide application in geomechanics for mine design and stress analysis. Two examples are presented in this paper, illustrating the use of the boundary element method to find potential problem regions in large-scale excavations. These examples are from a Papua New Guinea open cut mine and an Australian sub-level caving operation. Because of the scale of the mines and the complexity of the excavations, the boundary element method is the only practical numerical modelling technique to account for the major influences. Although the boundary element method uses only linear elastic models of the rock mass, the paper illustrates techniques for dealing with non-homogenous and anisotropic rock masses, as well as clasto-plastic effects associated with an excavation.

Jan 1, 1995

By Ogilvie M

South Bulli is the oldest and largest underground coal mine in Australia. Two longwall units are in operation and current production is 2.5 to 3 million tonnes of run of mine product per year with a workforce of 600. Prior to 1984 a workforce of around 1,200 produced 1.5 million tonnes. Advances in technology can. of course, account for some of this gain, but the changes made in the human resources area are also seen as playing a major role in South Bulli emerging as a reasonably stable operation.The human resources strategy adopted recognises the value of the workforce and is aimed at not only fostering cooperation as all levels, but also making employees aware of the direct contribution they can make to the success of the enterprise.

Jan 1, 1991

By Moore A. J, Evans R

Blast vibration control and assessment techniques have been developed which supplement traditional charge mass scaling methods. The improved techniques, which can be used to predict air and ground vibration levels at the planning stage, and to assist in the control of blasting operations, have reduced the level of operating risk concerning blast vibration. In addition to such factors as charge mass, distance and blast vibration levels, these additional techniques take account of orientation of the blasting face, topographic shielding, wavefront reinforcement, and meteorological conditions. They have assisted in compliance with specified blast vibration levels for environmental licence and mining lease conditions, the reduction of blast vibration nuisance to residents in the area surrounding a mine, and control of building and rock structure response in adjacent areas on the mine lease area.

Jan 1, 1994

An understanding of the way that solutes are transported in mining or natural environments is essential to the development of sound strategies for managing waste disposal. Research on miscible pollutant movement in unsaturated porous media is carried out both experimentally and numerically. Results of numerical modelling are obtained by solving the groundwater flow equation and the solute transport equation. The finite element method is employed and comparisons between simulation results and experimental data are found in remarkable agreement.

Jan 1, 1995

By B Oostendorp, R van der Merwe, P

In order to assess whether polysaccharide depressants are strongly or weakly and reversibly bound to the surface of talc, a series of experiments was conducted on New York talc in which the floatability of the talc in a microflotation cell was determined. The talc was conditioned in solutions of carboxymethyl cellulose (CMC) or guar gum in 10-2 ionic strength Ca(NO3)2 or Mg(NO3)2. The talc was then washed with four successive aliquots of water, or cation solution, to try to remove the polymer and the flotation response of the talc was assessed. CMCs of different charge (DS) were used to assess the effect of charge on the strength of bonding. The results show that CMC and guar gum could be removed to a large extent from the talc surface by washing with water (the floatability was restored), however very little could be removed from the surface by washing with cation solution. The higher charge CMC was easier to remove from the talc planes in the absence of cations than the lower charge CMC. Thus CMC bonding to talc has been shown to be irreversible or very slowly reversible only if cations are present, implying that cations are necessary to keep the polymer bound to the surface of the planes to effect depression. The presence of ions in solution also had the effect of maintaining surface coverage of the talc by guar gum.

Jan 1, 2005

By Wilson GR

Pellets were produced from carefully sized iron ore and silica sand fractions, under controlled moisture conditions, using a sealed balling drum. The strength of these pellets was measured as a function of moisture content and particle size. The results showed that the strength of the pellets could be adequately described by a model which equates the strength of the pellets with the negative pressure developed within the porous mass, provided that the particle size distribution was narrow and the mean particle size relatively large. However this model failed to account for the observed strengths of pellets produced from systems containing even small quantities of ultrafine particles (

Jan 1, 1972

By R C. Schodde

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Over the last decade (2005–2014), a total of 439 significant deposits of gold and base metals were found in the world. Twenty (or 4.6 per cent) of these deposits were in the Pacific/South-East Asia (Pacific/SE Asia) region. In terms of contained metal, the region accounted for 1.6 per cent of gold and 13.8 per cent of copper found in the world. With regard to nickel and zinc/lead, the region’s contributions were insignificant.Over the same period, the Pacific/SE Asia region accounted for 6.6 per cent and 12.6 per cent of all gold and copper exploration expenditures in the world respectively. After adjusting for by-product credits, unreported discoveries and likely growth in resource, the unit discovery cost for the region was US$199/oz (compared to a world average of US$50/oz). For comparison, the unit discovery costs for the previous decade were US$55/oz and US$25/oz respectively. The region’s unit discovery cost for copper was US$0.036/lb (versus a world average of US$0.040). For comparison, the unit discovery costs for the previous decade were US$0.026/lb and US$0.008/lb Cu respectively.The region’s mediocre discovery performance doesn’t reflect its distribution of known mineralisation. Some countries within the region have a very good endowment per square kilometre.It is noted that the intensity of exploration (and resulting success) would be boosted if governments provided a more mining- and investment-friendly business environment and generated better precompetitive geological data sets (to identify new exploration targets and boost the country’s perceived mineral prospectivity). A multivariable regression analysis of a decade of data from the Fraser Institute’s mining company surveys found that a ten point increase in the Policy Perception Index or a 0.1 point increase in the Mineral Potential Index could boost (in the short term) exploration expenditures by 1.9 per cent and 2.7 per cent respectively. The resulting economic benefits of an expanded mining sector would be significant. The same story applies elsewhere in the world.CITATION:Schodde, R C, 2015. Discovery performance for gold and base metals in the Pacific/South-East Asia – 2005–2014, in Proceedings PACRIM 2015 Congress, pp 25–34 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Koch D. F A

An electrochemical study of the dissolution of gold in aerated cyanide solution shows that the dissolution rate is determined by the nature of the surface. A passive film (probably a basic cyanide) formed at -0·6 V vs a saturated calomel electrode inhibits both the anodic dissolution of gold and the cathodic reduction of oxygen. Thallium has an "activating" effect on these reaction mechanisms.INTRODUCTIONIn general the dissolution rate of a solid in a liquid is studied by weight loss measurements or analysis of the solution at known time intervals. However, if the solid is a metallic conductor, on which a redox reaction can occur at the metal-solution interface, it can be studied by electrochemical techniques. Electrochemical measurements have the advantage that the overall reaction can be separated into its components, in some cases by electrical measurements alone, and in others by a combination of these with analytical determinations.The overall equation for the dissolution of gold in aerated cyanide solution may be written4Au + 02+ 8CN- + 2H20 = 4Au (CN)2- + 40H- ..... (1)which can be separated into the two electrochemical componentsrepresenting the oxidation of gold and the reductionof ogygen respectively.4Au + 8CN-,= 4Au(CN)2- + 4eand O2+ 2H20 + 4e = 40H- These two reactions occur at the gold-electrolyte interface and it is the purpose of this paper to discuss the mechanism...

Jan 1, 1964

Members of The Australasian Institute of Mining and Metallurgy are engaged in locating, extracting, processing, marketing and converting the worldÆs mineral wealth for its consumption in a useful form. We have an ethical responsibility as professionals to carry out our roles in such a way that we seek to optimise the recovery of that wealth for the benefit of the community, not only now, but also in the future. To be able to optimise, we must be able to measure with confidence the value of the commodity through the various stages of treatment from discovery of a geological anomaly to the end use. This introductory paper will provide an overview of some aspects of the issue, including the possible extension of the coverage of The InstituteÆs Codes to production accounting and reporting.

Jan 1, 2002