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By J Heyes, G A. Maddocks, R J. Stewart, G D. Corder

Mining is an international business and vital contributor to national and global economies. It depends on the trust and confidence of investors and stakeholders for its financial and operational well-being (Committee for Mineral Reserves International Reporting Standards (CRIRSCO), 2016). The Social Licence to Operate (SLTO) is an increasingly multifaceted and multistakeholder risk that can impact investment decisions. Community challenges to broader political and economic decisions have given rise to protest delaying or stopping projects or closing mines and has led to loss of life (Ernst and Young, 2016). Some governments are now giving greater powers to stakeholders to make the final decision on approving mining and metals activities (EY, 2016). With billions of dollars in project investment at stake, ongoing engagement, collaboration and effective communication with stakeholders is crucial and mutually beneficial solutions are increasingly expected (EY, 2016). It is therefore essential that the industry communicates the risks (and opportunities) associated with investment effectively and transparently in order to earn the necessary level of trust with investors and stakeholders to underpin its activities (CRIRSCO, 2016). Despite this need, investor and stakeholder trust in the sector has eroded in recent years.CITATION:Maddocks, G A, Corder, G D, Heyes, J and Stewart, R J, 2016. The social licence to operate and drivers for change – resource reporting and mine material characterisation, in Proceedings Life-of-Mine 2016 Conference, pp 183–187 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

o Resource production is essential for society. o Demand for resources will increase as population grows.o Resource industries are the main consumer of trained geologists.o The lead time from(1) training to productivity(2) research to resource production is measured in years.o An adequate supply of well trained geologists and successful geological research is an important agent in ensuring cost effective, adequate supply of mineral resources for society. Therefore the main beneficiary of geological education is society itself.o Society is paradoxically apathetic or antagonistic to the resource industry because (1) it represents change(2) lobby groups working for other causes have successfully moulded a bogey man image for the resource industry in the public eye.Professional training and research for resource industries consequently lack popular support. Funding is at an absurdly low level in comparison with the economic importance of resource supply.

Jan 1, 1990

By Liu Q, Siefken T. C, Misra V. N

Investigation of the differential flotation characteristics between arsenopyrite and pyrite in a ore concentrate have been carried out on a laboratory Leeds flotation cell. Experimental results indicate that some limited separation between arsenopyrite and pyrite is possible by differential flotation under the conditions of high pH and low pulp redox potential. The best performance in this testwork was achieved by using an oxidizing agent at pH 10.7. Of the oxidizing agents tested, NaOCI gave better oxidizing effect than KMnO4. It has also been observed that the pulp redox potential depends on the pulp pH value. At high pH values a hydroxide layer is formed on the arsenopyrite surface, which has the effect of a depressant on the arsenopyrite.

Jan 1, 1992

By E R. Ramanaidou, M A. Wells

Reflectance spectroscopy is now an established technique for mineral exploration and ore characterisation. The efficacy of the technique as a tool to characterise the main iron ore and gangue mineralogy at African Minerals Ltd’s Simbili iron ore deposit in north-central Sierra Leone was tested through reflectance spectroscopic analysis of 13 000 pulped drill reserve samples using CSIRO’s HyLogger-1™ system. Specifically, integration of reflectance spectral data with more traditional methods of analysis, such as geochemical analysis and Satmagan measurements, characterised the mineralogy (ie hematite versus goethite) of the oxidised ore at Simbili, quantified the Al associated with goethite and hematite and evaluated the distribution of the main gangue minerals – kaolinite and gibbsite. Relative changes in the Fe2+/Fe3+-bearing oxide and silicate mineralogy, based on mineral indices derived from reflectance spectroscopic measurements, appeared well-related to changes in the ore profile mineralogy consistent with the main ore types identified at Simbili, as representative of an oxidised banded iron formation sequence. Spectral calibration models, developed from a well-characterised training set of mineral mixtures, representative of the oxidised ore zone mineralogy were used to quantify the distribution of Al associated with kaolinite and gibbsite and the iron oxides, goethite and hematite. Combining these mineral spectral parameters with compositional data enabled the differentiation of Al-substituted goethite and hematite and resulted in the identification of low Al-bearing, or ‘clean’, goethite and hematite from high Al-bearing, or ‘dirty’, goethite and hematite. Spectral quantification of the iron oxide Al composition provides a far more rapid means of quantifying the Al substitution in iron oxides at the deposit scale compared to traditional techniques such as X-ray diffraction analysis. It also enables a level of volumetric characterisation and the potential for large-scale (ie three-dimensional) mapping, which was not previously possible with other techniques. The potential of the technique was also highlighted when mapping the distribution of the main Al-bearing contaminants (gibbsite and kaolinite) identified in the oxidised ore zone at Simbili. Delineation of such zones provides a guide to managing the most appropriate processing options (ie upgrade potential) within a mineralogical framework. Three-dimensional modelling of the gangue phase distribution may also allow the mapping of lithological and/or structural controls that may be prevalent at Simbili. This work highlights the value in the application of HyLogging™ technology for rapid resource characterisation, particularly for volumetric identification and mapping the distribution of both the economic and gangue phases, which otherwise would be difficult to achieve. As such, the technique can provide a fast and inexpensive means to evaluate ore and gangue mineralogy at the deposit scale and provide a first-pass assessment of the mineralogy and compositional attributes, with the potential to better predict ore metallurgical properties.CITATION:Wells, M A and Ramanaidou, E R, 2015. Waste not, want not – delving deeper into the Simbili iron ore deposit using HyLogging™ scanning technology, in Proceedings Iron Ore 2015, pp 337–346 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By T Christie, A Swain

Patterns of quartz veining in epithermal gold-silver deposits at Wharekirauponga, Neavesville and Ohui in the Hauraki Goldfield, have been analysed to determine the effects of different lithologies on vein distributions. At Wharekirauponga, quartz veins are hosted in rhyolite and minor andesite, with the andesite containing slightly higher gold grades. Local basement andesite, rhyolitic tuff and silicified black shale host gold-bearing quartz veins at Neavesville. At Ohui, quartz veins are hosted in rhyolite, rhyolitic tuff and andesite. Fractal analysis was used to quantitatively describe the distribution of veining. The fractal dimension (D) of veining in silicified tuff is 0.25, moderately silicified rhyolite has D = 0.23 - 0.26, clay-altered andesite has D = 0.3, strongly silicified rhyolite has D = 0.3 - 0.39, silicified andesite has D = 0.4, and silicified black shale has D = 0.43. The D values are related to the composition of the host rock, and appear to be controlled by its competency. Hydrothermal silicification results in increased competency and higher D values. Vein thickness frequency plots for different lithologies show that andesite at Ohui, and to a much lesser degree at Wharekirauponga, contains more thick veins than rhyolite and tuff. Gold grades show a strong to fair correlation with higher vein density in three drillholes at Wharekirauponga. The fractal dimension of veining is an important control on fluid flow and gold deposition within an active epithermal system. Vein systems with higher D have a greater density of veining which would have favoured increased fluid-rock interaction. Lower D vein systems have more clustered arrays. The increased fluid-rock interaction induced by a high D vein system, when combined with a reactive host rock, results in an environment which is highly favourable for gold deposition. This situation is seen in the andesite at Wharekirauponga.

Jan 1, 1994

By R Symes

The Fosterville Goldmine in Victoria Australia employs the BIOX« Process to liberate gold from its sulfidic flotation concentrate through bacterial oxidation. Gold occurrence is primarily as submicron particles in pyrite and arsenopyrite and has been described as being in æsolid solutionÆ and therefore not amenable to direct cyanidation. Once liberated by the oxidation process, the gold is then available for cyanide leaching. During the oxidation process it has been found that a portion of the liberated gold becomes suspended in the liquid phase in what appears to be a colloidal state. This liquid becomes a waste stream during washing of the oxidised solids and the suspended gold is therefore lost. A method was previously developed using an addition of quebracho tannin to significantly reduce this loss by formation of an iron-tannin precipitate which captures the gold which then reports to the cyanide leach circuit with the oxidised concentrate solids onto which it is adsorbed.This paper discusses the development and plant trial of a second processing step to further enhance gold recovery by use of flotation tailings essentially as a source of extra surface area to capture residual tannin-iron precipitate and its associated gold not recovered in the first step.CITATION:Symes, R, 2012. Recovery of colloidal gold from oxidised concentrate wash liquor - Further improvement, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 383-388 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By P J. Sack, L V Danyushevsky

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Regional-scale exploration for sediment-hosted gold deposits is hampered by the challenge of evaluating the fertility of ancient sedimentary sequences that host these deposits. Recent developments in laser ablation inductively coupled plasma mass spectrometry allow for the evaluation of the gold fertility of sedimentary sequences using chemistry of early-formed sedimentary pyrite. We present a case study from the Selwyn basin area of Yukon, Canada, where significant sediment-hosted gold exploration has been ongoing for the last five years. Data from sedimentary pyrite in some Neoproterozoic shales are anomalous in Au and As compared to a global data set of unmineralised sedimentary pyrite. If at least some of the gold and associated trace elements in sediment-hosted gold deposits are derived from recrystallisation of early sedimentary pyrite, it follows that strata containing anomalous sedimentary pyrite should be more prospective. Based on this premise, our data clearly show that Yusezyu Formation Neoproterozoic shales in the Selwyn basin area of Yukon are a fertile source rock for sediment-hosted gold deposits, while pyrite from Nadaleen formation shales are strongly anomalous in Hg and Tl, but not Au. We suggest that the area warrants continued exploration for sediment-hosted gold.CITATION:Sack, P J, Gregory, D D, Large, R R and Danyushevsky, L V, 2015. Using sedimentary pyrite chemistry to inform regional exploration for sediment-hosted gold deposits – a gold fertility case study from the Selwyn basin area, Yukon , in Proceedings PACRIM 2015 Congress, pp 69–76 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

The excavation of a tunnel through rock and mixed ground of basalt and silty clays presents a challenge to engineering organisations. Such was the situation facing the Melbourne and Metropolitan Board of Works (MMBW) in constructing the 15.3 km, 5.5m dia. tunnel component of the new Western Trunk Sewerage System. The tunnel geology showed that there were two distinct components to the excavation - rock and mixed ground. By drawing on extensive experience in the use of Tunnel Boring Machines (TBM's) used previously by the MMBW and using techniques developed for predicting TBM per- formance, a comparison of the options of drill and blast versus TBM was made. The conclusion was that TBM methods would provide the best solution to the problem. Tenders were called for the supply of a TBM. A performance specification was used to attract tenders offering designs which re- flected the state of the art on an internation- al level. Particular features required by the MMBW were included in the specification. The excavation planning and operation are described in this paper. The production achieved has shown that the TBM can very adequately handle rock excavation (best weekly production 167.9m). Extreme conditions of mixed ground with heavy groundwater inflows have been handled using an auxiliary thrust system to maintain gripper reaction through the soft ground encountered.

Jan 1, 1987

A review of the motivation of personnel in the open cut mining industry. The effect of social, geographic, environ- mental, organisational, union and other factors on employees' motivation as assessed from job experience and from an attitude survey. An appraisal of where we should be heading and what influence management can have on the motivation of employees.

Jan 1, 1980

A study was undertaken to investigate the relationship between the quantity and value of economic demonstrated resources discovered for 12 mineral commodities over a ten year period and the expenditure required to yield such mineable resources. The results showed that for every dollar spent on exploration, there is an apparent in-ground average value of around $54 dollars contained in the economic resources found. While this appears to be a satisfactory return, it should be remembered that more than 99.9% of exploration programs are judged to be failures because a viable ore body or mineral deposit was not proved up. What is behind this seeming paradox?   The fundamental truth behind mineral exploration is the fact that the more you explore, the more you find, and that one success will often lead to further discoveries. It appears that one rich and viable deposit creates such surplus that its inherent high value ('the pot of gold') makes up for all the failures. In short, mineral exploration is a high risk business with uncertain returns. However, with skill, enthusiasm, experience and venture capital, it can yield larger than normal returns for the brave and the fortunate.   Analysis of exploration expenditure and economic resources discovered for the period 1987 to 1996 revealed that the apparent in-ground value of economic ore discovered per dollar of exploration expenditure varied from a high of $429 for iron ore and $261 for bauxite to a low of $22 for gold and for lead, and $5 per dollar of diamond exploration expenditure. Preliminary conclusions drawn on the reasons for the variations observed include the inherent ease or difficulty of discovery for different mineral commodities which may in some cases, relate to the natural prospectivity of Australia as a whole. Layered deposits like iron ore and bauxite appear to yield higher in-ground value returns on the exploration dollar. To some explorationists, this may be considered as seemingly obvious, but it may have more to do with very large-exploration tenement grants pursued by various Australian State Governments in the early 1950s and 1960s than the apparent ease of delineating a stratabound deposit.   Despite the apparent relatively low in-ground value produced by the gold exploration dollar of $22, the 5660 tonnes of gold discovered in this ten year period was worth $9.1 billion and representing over a quarter of the new mineral wealth created in the ten years to 1996. This contribution, along with that from the other minerals discovered over the period, led to a significant boost to Australia's export income and standard of living.   It is concluded that, given the nexus between the amount of mineral exploration expenditure and the quantity of new resources likely to be discovered, this knowledge may help policy makers seek to influence the rate of resource discovery in countries like Australia for the benefit of the nation.

Jan 1, 2004

By H Peiming, W Sakurai, Y Matsuhisa, H Shimazaki, Y Fukahori

Oxygen and carbon isotope mapping of hydrothermally altered wall rocks was applied to the blind ore prospecting of skarn Pb-Zn deposits in the Kamioka mining district, centralJapan, where the wall rocks consist of heterogeneous rock units. The results (d18OSMOW of -1.1 to +17.3ë and d13CPDB of -5.0 to +4.8ë for limestones, and d18OSMOW of -0.8 to +12.5ë for silicate rocks) show isotope zonations of the wall rocks with depletions in heavy isotopes (18O and 13C) toward the centre of mineralization. The isotope zonations likely formed by interaction of migrating thermal waters with the wall rocks during the mineralisation. The heavy-isotope depleted zone, which indicates higher temperature or higher water-to-rock ratio of the system, occurs in the footwall of a fault, indicating that the fault played the role of main conduit of the ore-forming fluids. A heavy-isotope depleted zone was also found in an area, where significant mineralisation had yet to be identified. Recent drilling in this area has intercepted a zone with a grade of 16.0% Zn, 0.8% Pb, and 35g Ag per metric tonne at a depth of about 360 m.

Jan 1, 1995

Much of the theory upon which the Sublevel Caving (SLC) method is based was developed in Scandinavia many years ago. It was based mainly on æbinÆ theory and æellipsoid of drawÆ configurations derived from sandbox models. In many cases, classical SLC layouts influenced by these early theories obtained relatively poor results. Early dilution entry, low tonnage factors and low recoveries were commonly experienced. SLC soon gained the reputation of being a high dilution, low recovery and development intensive method. This led to SLC falling into disfavour generally, other than as a pillar reclamation method used at the end of the life of mines. More recently a number of mines, notably those in Australia, have adopted SLC as a primary extraction method and have achieved good recovery results. The reason for the better results is believed to be an outcome of modifications in some of the basic design parameters and operational procedures. This has led to questions being raised regarding the original æbin theoryÆ assumptions and classical SLC layout designs. It is clear that the fragmentation and flow characteristics occurring in a choke blast situation (compaction of waste, variable size and shape of fragmentation throughout the ring) conflicts significantly with the assumptions of regular loose flow of uniform, fine grained, material in a bin. Interactive versus independent draw conditions can also materially effect the outcome of a SLC operation. The good results obtained more recently can only be explained by using ænewÆ models of behaviour, which have to a large extent been borrowed from block caving. If these models are correct, they point to a number of design and operational changes that can be applied to improve the effectiveness of SLC. This paper discusses the factors that may not have been fully considered in early SLC design and modelling. It emphasises the importance of delayed dilution entry as a primary objective of sound SLC design and provides a basis for efficient SLC design and operation.

Jan 1, 2000

By F Pirajno

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. China’s mineral deposits are the result of metallogenic processes associated with the geodynamic evolution of tectonic plates and eventual amalgamation into their modern configuration. The principal tectonic provinces of China comprise the North China Craton, Yangtze Craton, Cathaysia Craton, Tarim block, Altay-Tianshan-Hinggan orogens (part of the Central Asian Orogenic Bel), Central China orogens, Songpan-Ganze orogen and Alpine-Himalayan fold belts, which are part of the huge Tethysides. These tectonic elements are testimony to a complex geological history spanning more than 3000 million years. This contribution will focus on selected areas of the Altay-Tianshan, the fold belts surrounding the North China Craton and Yangtze Craton and the mineral systems along the Ailaoshan-Red River fault zone. Mineral deposits in these provinces include gold, copper, molybdenum, tin, antimony, nickel, platinum group elements, lead and zinc.CITATION:Pirajno, F, 2015. Metallogeny and related tectonic settings in China , in Proceedings PACRIM 2015 Congress, pp 17–24 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By D Craw, P Lindsay, B Peake

The geochemical properties of Kaiata Mudstone and Brunner Coal Measures are evaluated in order to determine their suitability for placement at the proposed Cypress and existing Stockton mines. Correct scheduling of this waste material is needed in order to prevent sulfide oxidation and the generation of acid rock drainage. The Kaiata Mudstone has both acid generating and acid neutralizing properties. Results from this study and previous research from Kingett Mitchell Ltd (2003), indicate that within the Kaiata Mudstone sulphur content decreases with distance away from the Brunner Coal Measure/Kaiata Mudstone contact, while calcium carbonate content increases; sulphur values range from 0.33 to 4.23 wt %; and the acid neutralizing capacity ranges from 0 to 10.4 wt %. The Brunner Coal Measures have a low capacity to neutralize acid and sulphur content is variable ranging from 0.25 to 3.5 wt %. Appropriate control measures are therefore needed for the Brunner Coal Measures and any Kaiata Mudstone within close proximity to its contact. Tests have been undertaken to develop a rapid field or laboratory procedure to define the potentially acid-forming from the non-acid-forming Kaiata material. Results indicate that paste pH, Net Acid Generation (NAG) and Carbonate Bomb tests are suitable. Results from the Carbonate Bomb Test show a strong relationship with the Acid Neutralizing Capacity (ANC) and the Net Acid Production Potential (NAPP), indicating that this method may efficiently determine non-acid forming material in the field within fifteen minutes. Ongoing research includes kinetic column and shake extraction tests. These tests will quantify what trace elements could be leached from the waste rock and provide information on the usefulness of alkaline producing products such as Bauxsol, Limestone and Cement Kiln Dust.

Jan 1, 2004

GENERALTHE coal deposit, where it is being worked, consists of a bed of brown coal varying in thickness from 120 ft. to 200 ft., covered by an overburden of clay, drift, loam, etc., of a thickness of 22 ft. to 40 ft., and averaging 28 ft.The overburden is first entirely removed from the coal, and then the coal is excavated by. large revolving shovels which work at the bottom of the hole or open cut in the coal and deliver it in shovel bucketfuls to the transport system. The shovels owned by the Commission and available for this coal excavation are two Bucyrus steam revolving shovels, one being type 150B, weighing 150 tons, having a 21-cub. yd. bucket, and capable of digging a 47-ft. face; and the other being type 175B, weighing200 tons, having a 31-cub. yd. bucket, and capable of digging a 61-ft. face.In addition to these two steam shovels, the Commission has recently obtained a No. 250 Ruston electric revolving shovel weighing 340 tons, and having a bucket of 10 cub. yd. capacity, and capable of digging a 75-ft. face. When this electric shovel has been erected it will replace the steam shovels on the coal excavation, and the permanent transport system has been designed to take delivery of the coal from its bucket.The duty to be performed by the transport system is to take the coal from the shovels, elevate it out of the open cut, transport it to the screening house, deliver it iuto the hoppers at the top of this building, then to take the coal after it has passed over the screens and distribute the required grades to the power house and to the briquetting plant.

Jan 1, 1924

By Hinkley JT, Smitham JB, Nicol SK

Historical investigations of mineral flotation have highlighted the many factors which affect flotation. Some of these are related to the mineral, its degree of liberation (however defined), solution chemistry and flotation reagents. The complexity of the interactions between these factors often leads to uncertainty over whether the final grade/recovery results obtained in either laboratory or pilot scale tests are in fact the maximum recovery at a specific grade. The reason for this is that there has not previously been a general technique for establishing the floatability of an ore. This study describes the further development of the 'tree' flotation technique for minerals other than coal, and in particular its application to iron ores. Oxides have been chosen as a system of intermediate complexity between the simple coal system and sulphide minerals to illustrate the principles and develop the concepts. The 'tree' flotation procedure consists of the progressive flotation to completion of successive froth products, followed by reflotation to remove entrained material. It therefore represents an 'equilibrium' approach to floatability rather than a kinetic approach. By ordering the various products and tails in order of increasing grade, a cumulative curve of grade and recovery can be constructed against which an isolated batch or plant result on the same ore can be compared. In this investigation, a Jaspilitic iron ore was tested at various grind sizes to determine the 'best' flotation grade-recovery that could be obtained with a given set of reagent conditions. The separation characteristics of a process are best measured on a system which contains particles which behave as 'middlings' with respect to the process in question. For this reason a natural ore was chosen in preference to model systems in order to relate more readily to plant situations.

Jan 1, 1993

In the five years since Great Central Mines Limited (GCM) commenced exploration in the Jundee and Bronzewing areas of Western Australia's Yandal greenstone belt, the Company has been transformed from a junior explorer into Australia's fourth largest gold producer with annual production of approximately 440 000 ounces and mineral resources of seven million ounces of gold.The growth in resources has been driven by a high quality geoscientific approach, supported by a substantial budget for drilling and strong management commitment. In 1997, the Company expects to spend US$30 million on exploration in the Yandal greenstone belt.

Jan 1, 1997

Arising from prospecting success, the underlying worth of the shares of a publicly listed mining exploration company can increase many-fold. Prompt and accurate reporting during the exploration stage is therefore essential. While there is scope for varying degrees of optimism or caution in statements about the future economic prospectivity of a mineral deposit which has been discovered, the directors of a mining exploration company have both a legal and ethical obligation to keep their shareholders and the general public fully informed as to the state of progress of, and significant factual results arising from its exploration efforts. Suggestions are made as to the desirable form and content of exploration reports up to and including the time when the orebody has been delineated in terms of assured tonnage and grade. The benefits which will flow from this greater disclosure are discussed.

Jan 1, 1979

By N Anderson

The world-class Golden Mile gold deposit in the Eastern Goldfields of Western Australia is part of the Kalgoorlie Consolidated Gold Mines (KCGM) operation, which is wholly owned by Northern Star Resources Limited. Current mining operations across the Golden Mile is dominated by the large Fimiston Open Pit, which is over 4 km long, 1 km wide and 600 m deep. It is part of a larger mineralised system that stretches over 8 km and includes the Mt Charlotte Underground Mine, which is also operated by KCGM, as well as numerous historical open pit and underground mines. This mineralised system has been continuously mined for over 125 years and is set to continue well into the future. The Golden Mile deposit is in the Norseman Wiluna Greenstone Belt which is made up of a series of mafic volcanic and sedimentary rocks that have been structurally deformed and intruded by granitic rocks. There are two main styles of mineralisation across the Golden Mile. Firstly, the Fimiston style, which consists of shear hosted Golden Mile lodes with abundant sulfides and tellurides and secondly, the Charlotte style that comprises younger stockwork veins. Fimiston style mineralisation is the primary style of mineralisation within the Fimiston Open Pit. Historically, in excess of 3500 m of underground development and over 755 stopes were mined prior to the consolidation of the area and the commencement of Fimiston Open Pit operation. Old underground workings, known as voids, are either empty or backfilled and extend to more than 1.2 km below surface. Although they are a routine part of mining operations at KCGM, voids pose a significant challenge for the geology team in terms of planning and executing exploration and grade control drilling, geological modelling, grade and tonnage estimation, drill and blast design and execution, marking up ore block designs, mining, and reconciliation. This paper will discuss the various challenges faced by the geology team due to the presence of voids, solutions used to overcome some of these challenges and the results of these activities.

Mar 22, 2022

By Gupta R. C

Direct reduction of iron ore by solid reducing agents have been studied extensively and summarised by several authors (Otsuka and Kunii, 1969; Abraham and Ghosh, 1979; Frauhan, 1977; Rao, 1971; Kawasaki, Sanscainte and Walsh, 1962; Ghosh, 1970; Rao, 1979). While studying the reduction behaviour, it is generally agreed that the reduction occurs via gaseous intermediate, generated by carbon gasification reaction which involves mass transfer, heat transfer nucleation and growth, etc through a) reduction reaction occurring at solid reductant, and b) reduction reaction occurring at solid iron oxides, thus making the overall reduction process very complex in terms of clearly defining the reduction kinetics of the system. In addition to this, practical difficulties like correctness of reaction temperature, (Seaton, Foster and Velasco, 1983) difficulties in isothermal temperature studies of reduction, difficulties in monitoring the reduction process while using gaseous reductants and separation of reduction by volatile matter from overall reduction process make the reduction kinetics more complex (Misra).

Jan 1, 1999