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Lead Removal from Contaminated Soils with Chelating Agents

Sep 13, 2010

By V P. Beskrovnaya

Tests for the development of a metals recovery technology from samples of a Russian gold-bismuth deposit were carried out. Gold, silver and bismuth assay reported 5.6 g/t, 3.0 g/t and 0.08 per cent, respectively. Two flow sheet options were pilot plant tested: gravity/cyanidation of gravity tailings with subsequent flotation of cyanidation/carbon-in-pulp (CIP) tailings, and gravity/flotation concentration with cyanidation/CIP of concentrates. Option 1 results showed lower gold, silver and bismuth recoveries (81.3 per cent Au, 55 per cent Ag and 74.0 per cent Bi) due to low flotation efficiency for cyanidation tailings. Therefore, a flow sheet involving gravity/flotation concentration to produce bismuth-gold concentrates (0.8 per cent Bi) with subsequent cyanidation/CIP was recommended. Gold, silver and bismuth recoveries obtained by this method to the combined gravity/flotation concentrate were 90.2 per cent Au, 83.3 per cent Ag and 80.2 per cent Bi of the ore, respectively. Overall gold, silver and bismuth recoveries were 83.0 per cent Au, 40.5 per cent Ag and 80.2 per cent Bi, respectively. Gold and silver recoveries to the cathode precipitate were 92 per cent Au and 48.6 per cent Ag (per operation). Reagents consumed for flotation were 0.1 kg lead acetate/t ore, 0.4 kg butyl xanthate/t ore, 0.2 kg T-80 frother/t ore, 0.02 kg sodium hexametaphosphate/t ore, 0.15 kg copper sulfate/t ore. Reagents consumption for cyanidation was 0.42 - 0.48 kg NaCN/t ore and 0.2 kg CaO/t ore. It was recommended to deliver bismuth concentrates after hydrometallurgical treatment to a smelter. Overall bismuth recovery including bismuth recovery achieved by pyrometallurgy was 60.0 per cent. However, it was obvious that delivery of bismuth concentrates to a smelter and their commercial treatment would be very expensive due to relatively high mass pull of bismuth concentrates (7.6 per cent of the ore weight). For this reason, thiourea leaching and hydrochloric acid leaching with subsequent cyanidation/CIP were investigated as alternatives to cyanide leaching. These two alternatives were proposed to enable optimal recovery of valuable metals from concentrates on-site. Recoveries obtained by thiourea leaching were 91.2 per cent Au, 90.5 - 91.9 per cent Bi and 77.0 - 78.1 per cent Ag. However, that method required considerable capital and operating costs. As an alternative, hydrochloric acid leaching with subsequent cyanidation was investigated. Test results showed improved gold, bismuth and silver recoveries, which were 94 - 95.9 Au per cent, 94 - 96 Bi per cent and 76 - 78 Ag per cent, respectively. Hydrochloric acid consumption was 100 kg/t concentrate or 7.6 kg/t ore. Current efficiency during electrowinning was about eight to 12 per cent. A recommended flow sheet involving hydrochloric acid leaching of concentrates, electrowinning of bismuth from solutions, recycling solutions after electrowinning and cyanidation of hydrochloric acid leaching cakes is described. Overall recoveries achieved by the proposed flow sheet were as follows: 84.8 - 86.5 Au per cent, 75.8 - 76.9 Bi per cent and 63.2 - 64.9 Ag per cent. Based on results from these tests, initial data for a bankable feasibility study and plant designing were developed.

Jan 1, 2007

Jan 1, 2004

Jan 1, 2004

Palaeomagnetic work on the red beds of the Hervey Group from central N.S.W., and on the Mount Eclipse Sandstone from the Ngalia Basin, Central Australia, reveals a pre-deformational magnetization from the Hervey Group, which indicates a semi-equatorial palaeolatitude during the latest Devonian or earliest Carboniferous and a syn-deformational magnetization from the Mount Eclipse Sandstone which places Australia at a palaeolatitude of about 70¦ ¦ 20¦S during the early Late Carboniferous. By comparison with the existing data from Australia, the new results indicate that: (1) Australia (and thus eastern Gondwanaland) underwent a rapid southward movement of about 60¦ during the late Early and early Late Carboniferous, (2) the Lachlan Fold Belt has been part of cratonic Australia since at least latest Devonian or earliest Carboniferous, and (3) the New England region and cratonic Australia were at a similar palaeolatitude during earliest Carboniferous, but they may have undergone the rapid southward movement separately.

Jan 1, 1987

By Mahoney BK

The development of simulation models to reflect accurately the operations of a port and its associated transportation systems can be an expensive and time consuming process. However the complexity of such operations leaves little choice for other than simulation techniques since analytical methods are rarely appropriate. The development of suitable software has now reached the stage that these techniques can be used with confidence. Types of simulation models and their requirements are discussed together with the results from some recent applications to the planning and management of bulk terminals.

Jan 1, 1983

Black coals occur in most of the major sedimentary basins in Australia. In addition to the better known Permian coal occurrences of the Sydney, Bowen, Oaklands and Galilee Basins, coals of Permian age occur in the Arckaringa Basin in South Australia, the Bonaparte Basin in Northern Territory and the Collie, Perth and Canning Basins in Western Australia and the Tasmania Basin in Tasmania. Coals of Triassic age occur in the Ipswich Callide and Tarong Basins in Queensland, the Tasmania Basin in Tasmania and the Leigh Creek area in South Aus- tralia. Coal bearing rocks of Jurassic age occur in the Mulgildie Basin and Maryborough Basins in Queensland and in both the Queensland and New South Wales portions of the Clarence Moreton Basin and Surat Basins. They also occur in the Perth Basin in Western Australia. Rocks of Cretaceous age known to contain coal occur in the Styx, Maryborough and Laura Basins in Queensland, the Gippsland Basin in Victoria and both the Queensland and New South Wales portions of the Surat Basin. The coal measures have been deposited in a variety of sedimentary environments and the coals vary widely with regard to thickness, extent, banding characteristics, maceral and ash content. However, they are generally of low rank and most are suitable only for steaming.

Jan 1, 1975

By Ma F, Yang Q, Ujihira M

The effect of stresses and acoustic emissions on the gas permeability of coal was investigated in the field and the laboratory in order to find an estimative method of the practicability of gas drainage. In the field, acoustic emissions and gas emissions during gas drainage drilling were monitored tentatively at some coal mines in Japan and China.In the laboratory, acoustic emissions from coal specimens in addition to gas permeability were measured during the triaxial compression loading in order to interpret the results monitored in the field. Besides, the opening of gas permeation channels in coal was considered on the basis of the experimental results.

Jan 1, 1991

Partnering has come to prominence in the Australian construction industry in a formal sense this decade. The high level of disputation in the building and civil construction industries in the 1980s drove its development in both Australia and North America. PartneringÆs use has been most prominent in the construction industry, particularly in the civil and construction sectors of the industry. It has found favour in some mining development projects, one of the most notable being BHP MineralÆs Cannington project in NW Queensland. This paper examines the requirements of successful partnering agreements and describes in detail the mine development partnering agreement at Cannington. In particular, the paper discusses the authorÆs experience and recommendations for partnering to avoid contractual problems and achieve win û win project outcomes for all parties to major mining projects.

Jan 1, 1999

Unnamed early prospectors panned gold from creeks drain- ing the Great Dividing Range in the early part of 1851. The first publicised discovery was credited to Edward Hargraves near Bathurst in New South Wales later in 1851 and during the ensu- ing gold rush, prospectors rapidly made discoveries elsewhere in New South Wales and later across the border in Victoria. Reference to the attached graphs of gold production indicates that for much of the first 100 years, gold production came from the easily worked and readily discovered shallow alluvial deposits, many of which were located in the creeks draining mountainous regions of Victoria, New South Wales and Queensland (Fig. 1 and 2). As these deposits were exhausted, prospectors turned their attention to outcrop lode deposits which led to the development of underground mining techniques and a significant boost in over- all gold production. With the discovery of the rich Golden Mile lodes in Kalgoorlie in 1893, gold production increased signifi- cantly and peaked around the turn of the century. At that time, the enormous potential of the great Witwatersrand deposits in South Africa had only just been appreciated and for a few years, Australia led the world in gold production (1855-1863 and again in 1903). Underground mining continued in the Eastern Goldfields area of Western Australia, the Bendigo-Ballarat region of Victoria and in northeast Queensland. Very few of these operations continued beyond the Second World War, except the larger producers in the Kalgoorlie region where recovered grade had dropped to about 6 g/t Au. By the early 1970s with the gold price fixed at US$35 per ounce, most of the operations were shut down as labour costs escalated, with only the low cost bulk mining operation at Mt. Charlotte and the high grade reefs at Norseman continuing in Production.

Jan 1, 1988

By Tamura S, Maekawa M, Nagai C, Deguchi M

Heavy fuel oil has been injected into blast furnaces in order to reduce the coke rate, to improve productivity and to control the furnace heat condition. However, in the first oil crisis at the end of 1973, it became necessary to develop an injection technique of new fuels into blast furnaces to reduce oil consumption. In Kobe Steel, Ltd., it was thought that the injection of a coal-oil mixture (COM) into blast furnaces could be developed in a shorter time than pulverised coal injection. The development of this technique was under- taken in 1974, and COM was injected through two tuyeres of the No.3 blast furnace at the Kobe works in 1977 and 1978. In addition, in order to study the combust- ibility of COM and the phenomena in the tuyere zone, the development of a gas sampling method was under- taken in 1975. In this paper, the results of the injection tests and gas sampling tests are reported.

Jan 1, 1981

By P Voigt, B Lumsden, P Lines, I Gurnett

Plant tests of magnetic conditioning have shown increased flotation recovery of paramagnetic sulfide minerals (chalcopyrite, sphalerite and pentlandite) in the -38 ¦m size fraction within rougher and cleaner flotation circuits. A statistical plant test was undertaken in the Mount Isa zinc flotation circuit where magnetic conditioning was tested simultaneously in both the rougher circuit and the cleaner retreat circuit (cleaner scavenger). This test resulted in a normalised increase of 1.60 per cent in the rougher circuit zinc recovery and simultaneously a normalised increase of 4.60 per cent in the cleaner retreat circuit zinc recovery - to a very high level of statistical confidence. Interestingly, in a novel approach, it was possible to verify the plant test results in two ways. Firstly, detailed MLA analysis of the tails confirmed the statistical plant test results and showed that the greatest effect of magnetic conditioning was on the sphalerite in the C3 - C6 size fraction, where there was a reduction of around 15 per cent in zinc in tails. Moreover, there was a reduction of around 15 per cent in liberated sphalerite across all -38 ¦m size fractions, but only a seven per cent reduction in non-liberated sphalerite in the tails. Secondly, plant modelling showed that increasing the rougher zinc recovery would cause an increase in zinc feed grade to the cleaner retreat circuit. The increase in the zinc feed grade to the cleaner retreat circuit with magnetic conditioning was demonstrated to a very high level of statistical confidence.CITATION:Gurnett, I, Voigt, P, Lumsden, B and Lines, P, 2012. Magnetic conditioning of sphalerite at XstrataÆs Mount Isa Zinc Operations, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 233-240 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By Fourney W. L, Dick R. D

Tests were conducted in plexiglass and Rockite models to determine if crater blasting could be improved by changes in charge geometry or by alterations to the borehole. Circumferential grooves were placed at various locations in the borehole in an attempt to control the initiation site of the crater. Grooves located at or above the top of the cylindrical charge had no effect on the resulting crater. Grooves placed too low in the borehole were successful in controlling the initiation site but the growth of the fracture system was not sufficient to reach the upper surface. Grooves located at a height of two thirds of the charge length were quite successful in that resulting craters were bigger by at least a factor of six than the normal crater. Testing was conducted in Rockite models to investigate charge geometry. Spherical charges in ungrooved boreholes resulted in crater sizes that were three times larger than those caused by cylindrical charges.

Jan 1, 1990

By Rowley M, Bradford P

Plutonic Resources Limited (formerly known as Pioneer Mineral Exploration Limited) delineated, developed and operates the Plutonic Gold Mine located 180 kms northeast of Meekatharra, Western Australia. Gold mineralisation was discovered in the Marymia greenstone belt by Great Central Mines NL (GCM) in 1988. There was no previous, recorded gold mining activity in the area. In May 1989, Plutonic Resources Limited (PRL) entered into an agreement to acquire a 51 per cent interest in the three Mining Leases containing the Plutonic deposit from GCM. Subsequently in December 1989, PRL acquired the remaining 49 per cent interest in the Mining Leases. PRL and GCM are also involved in a 51:49 regional joint venture on extensive Exploration Licences in the vicinity of the Mining Leases. Following due diligence validation, reserve delineation and testwork, a feasibility study was undertaken in conjunction with JR Engineering Services, which led to the financing and development of the project for operation in August 1990.

Jan 1, 1991

Mispah form (FAO: Lithosol) soil contaminated with >380 000 mg kg-1 creosote was co-composted with sewage sludge and poultry manure for a period of 19 months. The soil was mixed in a ratio of 1:1 (v/v) with wood chips to improve aeration. The soil-wood chips mixture was then mixed in a ratio of four soil-wood chips mixture: one compost material (sewage sludge or poultry manure). Compost heaps were set up in triplicate on wood palettes overlaid with double layers of nylon straw bags. Control experiments, which contained the contaminated soil-wood chips mixture without sewage sludge or poultry manure were set up in triplicate. Moisture, temperature, pH, ash content, C:N ratio of the compost and the creosote concentration of the soil was monitored monthly. The concentration of selected creosote components in the soil was also determined at the end of the incubation period. Temperature was observed to rise to about 60¦C in the poultry manure and about 58¦C in the sewage sludge within two months of incubation, while temperature in the control fluctuated between 15¦C and 35¦C throughout the incubation period. Creosote concentration in the control was reduced by 17 per cent at the end of the incubation period while concentration of creosote in the sewage sludge and poultry manure compost was reduced by about 99 per cent. The percentage rate of creosote reduction in the poultry manure compost was initially lower than observed in the sewage sludge compost. However, the reduction rate became similar towards the end of the treatment period. The concentrations of selected creosote components were reduced by about 100 per cent within the same period. Respiration of compost microorganisms and counts of microbial populations showed that microbial activity correlated with reduction in creosote concentration.

Jan 1, 2004

By Aylmore M. G

Samples have been taken from a two-stage industrial gold roaster treating a pyrite/pyrrhotite/arsenopyrite concentrate, in order to describe the mineralogy, composition and surface area of the calcines. Sulphides oxidised to produce a porous magnetite in the first stage and a porous hematite in the second; pyrite predominantly roasted via a pyrrhotite intermediate. Sulphur was eliminated in both the first and second stages whereas arsenic was eliminated in the first but retained in the second, partly as rims on hematite particles. The finer sized particles from the cyclones and electrostatic precipitator, while having the greatest surface area, were the most refractory with respect to gold solubilisation, probably as a result of incomplete decomposition (through short-circuiting) in the first stage, and through a combination of factors such as overheating and entrapment of sub-microscopic gold in the second stage.

Jan 1, 1992

By Aylmore M. G

Samples have been taken from a two-stage industrial gold roaster treating a pyrite/pyrthotite/arsenopyrite concentrate, in order to describe the mineral- ogy, composition and surface area of the calcines. Sulfides oxidised to produce a porous magnetite in the first stage and a porous hematite in the second, pyrite predominantly roasted via a pyrrhotite intermediate. Sulfur was eliminated in both the first and second stages whereas arsenic was eliminated in the first but retained in the second, partly as rims on hematite particles. The finer sized particles from the cyclones and electrostatic precipitator, whilst having the greatest surface area, were the most refractory with respect to gold solubilization, probably as a result of incomplete decomposition (through short-circuiting) in the first stage, and through a combination of factors such as overheating and entrapment of sub-micro- scopic gold in the second stage.

Jan 1, 1991

Based on twenty years of experiences of applying computers in mine water engineering in Hungary, a program package was developed for home utilization and for other users abroad as well. This program package has been adapted to the CAD System of Coal Mining of COMECON countries. The main features of the "mine water subsystem" in the CAD System of Coal Mining and short descriptions of the key programs of the package are presented in this paper. Foreword The serious water problems of Hungarian mining pressed and/or stimulated its professionals to apply computers for supporting their problem-solutions. The first trials of these computer applications in mine water engineering were dated from the sixties. Owing to its twenty years of experiences in computer appli- cations in mine water engineering the Central Institute for the Development of Mining in Hungary was requested to work out the "Subsystem of Mine Water" for the Computer Aided Design System ('CAD) of Coal Mines in COMECON countries. This paper gives a brief presentation on the main features of this "subsystem"with reference to significant components.

Jan 1, 1988

By Grey D, Turner R, Capsanis J

Coal fines are recognised to have a major impact on the cost and efficiency of the recovery of saleable coal. Fines affect the productivity of the whole mining cycle because of the low yields obtained in washing this material as well as affecting the moisture content and handling characteristics of the final product.In 1990, Coal and Allied Hunter Valley Mine initiated an internal study into coal fines based on the assumption that a reduction in fine coal in ROM material will lead to increase yields in the preparation plant. The initial results of this study indicated that the level of fines in the ROM coal can be reduced by more than 40 per cent by simple changes in blast design and implementation.

Jan 1, 1992

An investigation was performed to determine the sequence of events which caused the 1987 surface subsidence and related damage to several homes in Walker County, Alabama, USA (see Figure 1). Surface affects compared to mine maps indicated the subsidence to be mine related. However, two coal seams had been worked under this area. The upper seam, the American seam ranged from 250 to 280 feet beneath the surface in the area in question. It was mined-out before 1955 by room-and-pillar method leaving in place narrow-long pillars to support the overburden strata, and abandoned in 1955. The lower seam, the Mary Lee seam, ranged from 650 to 700 feet beneath the surface. The Mary Lee seam had been abandoned in 1966 and subsequently became flooded. The dewatering of the Mary Lee seam workings in 1986 caused the submerged pillars to be exposed to the atmosphere. Due to multiple seam mining and the fact that workings had been inundated then dewatered, a subsurface investigation ensued to determine the sequence and ultimate cause of surface subsidence. Core sample tests with fracture analysis in conjunction with "down-the-hole" TV camera inspections provided necessary information to determine that the subsidence started in the lower seam and progressed through the upper coal seam to the surface. Evidence from the investigation program established that dewatering of the lower seam workings caused the marginally stable support pillars and the roof to collapse. This failure triggered additional subsidence in the upper seam which broadened the area of the influence at the surface.

Jan 1, 1992