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By Kuzugundenli OE, Nagaraj DR

Organic complexing agents have received special attention over the past few decades in the search for reagents for improved flotation separation of minerals, especially non-sulphides. The majority of such reagents that have been proposed over the past few decades have remained largely a laboratory curiosity, except perhaps alkyl hydroxamates, because their selection is seldom based on commercial viability. In this regard, the choice of complexing agents such as oximes may be more realistic because of their widespread use in solvent extraction of copper. Our earlier studies have confirmed that they are also effective as collectors for copper oxide minerals, including chrysocolla which is the most difficult copper mineral to beneficiate. The flotation behaviour of chrysocolla for several structurally-related hydroxyoximes were studied as a function of pH and oxime concentration and the role of structural features examined. The structural changes studied included substitutions in both chelating and non-chelating parts of the molecule. The results indicated that, contrary to expectations, many of the structural changes in the basic molecule, salicylaldoxime, do not have a positive effect on collector efficiency. The reduction in collector efficiency is rationalised on the basis of possible steric factors affecting complexation and packing of the collector species on the mineral surface as well as effects due to changes in electron density brought about by substituents. Introduction of alkyl substituents on the oximic carbon of salicylaldoxime yielded the highest collector efficiency.

Jan 1, 1993

By Emerson D. W

The search for economic mineral deposits is becoming more difficult as exploration goes deeper in the established mining camps and spread out to the surrounding covered areas, which may have an `overburden' some hundreds of metres thick. Geophysics is finding an ever increasing role in such exploration. When the target is zinc, the task often becomes even more difficult since sphalerite, the most commonly mined mineral, is non-magnetic, resistive, and relatively light compared to other sulphides. Fortunately, sphalerite commonly occurs in association with other sulphides, which are magnetic and/or conductive and/or heavy, thus most zinc-rich orebodies have at least one contrasting physical property to aid exploration. This paper presents the physical properties of sphalerite and other potentially important zinc minerals. Results of petrophysical measurements of samples from various zinc-rich ores are presented together with examples of geophysical surveys over a number of zinc deposits. The results show that the physical properties are not merely dependent upon the properties of the orebodies' constituent minerals. For example, the small (0.4 Mt) and low-grade (five per cent Zn + three per cent Pb + two per cent other sulphides) Flying Doctor deposit at Broken Hill, New South Wales (NSW) is much more conductive than the large (3+ Mt) and high grade (14 per cent Zn + five per cent Pb) Cadjebut deposit in Western Australia (WA). In the former case, tectonic stresses have

Jan 1, 1993

By Derham DW, Newcombe LA

The operations of the Mount Morgan gold tailings retreatment plant were significantly improved in 1984 by the desliming of the CIP plant feed, which reduced cyanide consumption and increased percent gold dissolution. Subsequently, the development of slimes treatment, incorporating gold leaching from slimes solids by copper cyanide complexes in the process water, and gold adsorption on to carbon in an environment lacking free cyanide was successfully implemented. Mount Morgan was initially mined for gold commencing in 1882 on the auriferous ironstone cap to the sulphide ore body. During the history of mining and processing at Mount Morgan the operations have developed through numerous phases of gold and copper production, operating almost continuously through until the final closure in late 1990. The final phase of processing was the retreatment of tailings, predominantly flotation tailings accumulated since the 1930s, for the recovery of gold and minor silver. Tailings retreatment commenced in 1982 with the commissioning of a 10 000 tonnes per day CIP plant to treat some 40 million tonnes of tailings at an average grade of 1.08 g/t Au. The initial operations were hampered by high cyanide consumption and poor gold dissolution on the mixed siliceous/pyritic tailings. The successful development and implementation of the desliming of the CIP plant feed in 1984 (as described by Parsons and Hampshire, 1986) reduced cyanide consumption by 40 per cent, and raised gold extraction by 13 per cent points by virtue of significantly higher dissolved oxygen levels. The finer portion of the reclaimed tailings were deslimed by eighty 100 mm diameter AKW cyclones, with the desliming cyclone overflow thickened in a Warman 30 in diameter thickener for water recovery and slimes disposal. Operation of the desliming plant involved the discarding of a slime fraction representing about 15 per cent of the reclaimed feed. Although gold-bearing, the high content of cyanicides and oxygen consumers within the slime negated any conventional treatment of this stream with free cyanide for gold recovery. The natural lixiviant behaviour of the soluble copper cyanide complexes for gold, which was extremely evident at Mount Morgan, directed efforts in this area. Enhancement of gold leaching with a deficiency or near absence of detectable free cyanide, but with significant levels of copper cyanide complex from recycled process water were examined. Adsorption of this solubilised gold onto carbon in a similarly difficult environment required close examination.

Jan 1, 1993

Magneto flotation is a recently developed method aimed at simultaneous utilisation of the magnetic and flotation properties of minerals in separation processes. In this method, magnetic minerals are prevented from reporting to the froth product while non-magnetic minerals are being floated. With suitable ores, this makes it possible to reduce or entirely eliminate the cleaning and scavenging operations that are otherwise necessary in conventional flotation and magnetic separation systems. This paper describes the testing of magneto flotation on a Canadian magnetite ore. The ore sample used in the experimental work contained a total of 32.89 per cent Fe of which 87.60 per cent was magnetic in the form of magnetite. Magnetoflotation yielded, in a single step, a final concentrate assaying 69.10 per cent Fe and with an overall recovery of 84.84 per cent representing a magnetic iron recovery of 96.39 per cent. Comprehensive comparisons were made with conventional magnetic separation and flotation, and it was found that with these methods at least four processing steps were required to achieve results similar to those obtained with single-stage Magnetoflotation.

Jan 1, 1993

By Mitchell D. S

BackgroundIn March 1990 Pasminco resolved to replace and increase the capacity of the underground pumping system at the Southern Operations, Broken Hill. The existing pump station was built 23 years ago while the rising main had been in service for 38 years and was subject to frequent failure.The old system was a conventional slurry/clear water separation and multi-stage pumping system. It was inadequate in the following areas:ò insufficient capacity to handle current and expected future flows;ò unable to consistently dewater lower production areas; ò pumping capacity restricted sandfilling rates;ò dirty water dams had insufficient settling capacity and were difficult to de-sludge;ò the operating costs of dewatering were high; ò it was labour intensive; andò it did not offer enough protection to the 25 level loading station.

Jan 1, 1993

Direct measurements of liquid contents in foams obtained from (x-terpineol a-T) n-pentanol (AmOH) and n-octanol (OctOH) solutions were carried out using a column of special construction. The column enables to determine the liquid contents by cutting-off foam layers of various thicknesses and measuring amounts of liquid contained in the cut-off foam layers. Liquid contents in the whole foam layers, in the top foam layers of thickness 14 ¦ 1 mm and distribution of water alongside foam height were determined. The average liquid contents were high and reached a level of 30, 35 and 40 per cent for foams formed from cc-T, AmOH and OctOH solutions, respectively. The liquid contents in the top foam layers were much smaller. They were of an order of five per cent for a-T and AmOH and 12 per cent for OctOH. On the basis of the liquid distribution alongside foam height some practical conclusions concerning possibilities of minimising amounts of liquid contained in the collected concentrate are presented.

Jan 1, 1993

Before the arrival of the first Europeans, Aborigines living in the northern Flinders Ranges mined ochre - an earthy form of haematite used for pigment.The discovery of copper ore at Kapunda and Burra in the 1840s stimulated the early settlers to prospect further north along the ranges. Many of the new discoveries were not properly evaluated and companies were floated on the most tenuous evidence.

Jan 1, 1993

By Parker C. J, Mikula P. A

The excavation for the Sydney Opera House Parking Station comprises a large donut shaped underground cavern with a central sandstone pillar. The maximum effective roof span is about 19 m and the rock cover is between 7 m and 8 m. Permanent support for the roof and the various services tunnels consists of a combination of tensioned anchors, and untensioned dowels, and mesh with shortcrete and fibrecrete as the final lining. Steel sets were installed at main intersections.Fundamental to the design philosophy for excavation of these spans at such shallow rock cover was the use of monitoring to check on the adequacy of the installed support. Prior to excavation, extensometers, inclinometers, piezometers and surface settlement survey stations were installed. Underground survey stations, anchor load cells and shotcrete pressure cells were installed as excavation proceeded. Excavation commenced at the crown using an initial heading and three widening stages. Geological mapping during excavation confirmed borehole expectations, namely sandstone beds 1 to 4 m thick interbedded with thin shale units. Bedding plane contacts varied over short distances from tight partings to thick brecciated seams. Jointing was subvertical and joints tended to be bed-limited.

Jan 1, 1993

In 1965, Peter Flawn author of the famous text-book on Mineral Resources (1966) published a paper in Economic Geology with the delightful title `Who took the `Economic' out of Economic Geology?'. He opened this most interesting article with the following paragraph:If one were called upon to cite an example of a fish out-of-water he could hardly pick a better one than a recent graduate of geology of an America university who is suddenly faced with the responsibility of evaluating or appraising a mineral property. And I venture to say that the 'ftsh' with a doctorate - even in economic geology - is not much better equipped than one holding a lesser degree. The new graduate with a major in economic geology probably knows the significance of the various sulphur isotopes, he surely knows a great deal about the chemistry of the ore forming fluids and he recites with ease the arguments which prove deposits are epigenetic rather than syngenetic. However he is a rare bird indeed if he knows anything about the economics of the mineral industry. The truth is that geologists who are engaged in evaluation work are largely self taught. I ask my more distinguished and experienced colleagues - `Has it always been this way? Who took the `economic' out of economic geology?

Jan 1, 1993

In the wake of the United Nations Conference on Environment and Development (UNCED) held in Rio de Janeiro in June 1992, evolved AGENDA 21. This document which was adopted at the Conference, provides a global action guideline for sustainable development into the 21st century.Sustainable mining requires a complete understanding of the `mineral cycle', including government legislation, mineral exploration, mining operations, rehabilitation, product use, re-cycling and waste disposal that takes into consideration associated social and environmental considerations and achieves economic objectives.

Jan 1, 1993

In 1874 a stockman, JE Wright of Foxlow Station, recognised copper mineralisation when he was about 12 kilometres south of the station. The find was on the banks of the Molonglo River. Several small mines were soon operating along the ridge above the river, and the village of Captain's Flat was established.One mining company established in the 1880s was Lake George Mines. It's name was to remain synonomous with the name of the town until mining and treatment ceased on 11 March 1962.

Jan 1, 1993

Elastomeric compression gaskets for segmental tunnel liners are capable of fulfilling all sealing requirements for one pass constructed tunnels.Once the segments are mounted and the gaskets are compressed the watertightness of the tunnel is guaranteed at once and for the whole technical life time.The only prerequisite for effective sealing is that tolerances in the tunnel segments be kept within reasonable limits.

Jan 1, 1993

This work provides a comparison between the most commonly used classification equipment in the treatment of minerals - hydrocyclones and spiral classifiers - considering their applications and costs. Although in use for decades in the mining industry, spiral classifiers have lost a lot of their importance due to the development of cyclones. This trend, however, is now being reversed, and in the last few years there has been an increasing interest in spiral classifiers, in view of their advantages over cyclones, such as: ò possibility of obtaining more thickened solids; ò less by-pass; ò great durability; ò lower operating cost. This work approaches the different aspects related to the installation, operation and costs of maintenance of these machines, giving a critical comparison of the involved costs.

Jan 1, 1993

Using a new type of laser surveying instrument named Particle Dynamics Analyser (PDA), the distributions of the radial and axial components of the mean velocity, the size and the concentration of solid particles at selected positions within a transparent hydrocyclone were directly measured out for the first time, from which profiles of the flow field of solid particles were obtained. And some new points were put forward such as the locus of zero vertical velocity (LZVV) of solid particles was not the same as that of liquid, and some particles in inner helical flow could also be separated. The results are of great significance to farther ascertain the separation principle of hydrocyclones and improve the separation efficiency.

Jan 1, 1993

By Miller JD, Ye Y

The Air-Sparged Hydrocyclone (ASH) has been developed for the fast and efficient flotation of fine mineral particles in a centrifugal field during the past decade at the University of Utah. Over the years, the air-sparged hydrocyclone unit has shown promising potential for the flotation of copper porphyry ore, low-grade placer gold and auriferous pyrite ores, various industrial minerals, and fine coal cleaning. Many fundamental studies including the X-ray computed tomography (CT) analysis have been carried out in order to understand the multiphase fluid flow phenomena associated with ASH flotation. With data available from these studies, it is now possible to construct more accurate ASH flotation models for different applications in order to analyse the behaviour of the system and to optimise design and operating variables. The ASH flotation model developed in this paper is based on the data given in `Air-Sparged Hydrocyclone/Advanced Froth Flotation Fine Coal Cleaning', Final Report, DOE Contract No DE-AC-88PC88853, submitted by Pennsylvania Electric Company (PENELEC), December 1989. Data from several hundred experiments with the two-inch ASH-2C air-sparged hydrocyclone (capacity 0.1 - 0.3 tph dry coal) are available from the report and have been used for this analysis. In the past, a preliminary model based on limited data had been developed. The current study, however, emphasises the global behaviour of the ASH system by utilising almost all the data from the report for the purpose of scale-up and industrial application. There are two parts in the current modeling and analysis effort for ASH flotation of fine coal. The first part is the modeling/analysis of dimensionless ratio of overflow opening area to underflow opening area, A*, and the dimensionless ratio of air flowrate to slurry flowrate, Q . The second part involves the modelling/analysis of all other variables in the system and an expert system for operation and control is introduced.

Jan 1, 1993

By B B. Beamish

Long-hole directional drilling for in-seam exploration was introduced to New Zealand at Huntly West Mine in 1989. Following the success of this initial drilling program the Coal Corporation of New Zealand (CoaICorp) purchased its own drilling equipment and proceeded to adopt the technique with in-housetraining. From July 1991 to September 1992 a total of 15 455 metres was drilled at Huntly West Mine. During this period several modifications were made to the drilling technology to suit the ground conditions. The resulting interpretations of the drill information enabled reliable seam definition to be incorporated in mine planning. Since January 1993, the technique has been transferred to the Huntly East Mine to assist with seam definition for the planned development westwards under the Waikato River. The benefits of this drilling technique to coal mine planning are now well documented in Australia and New Zealand as well as other overseas countries. The possibilities of adapting the long-hole drilling technique to hard rock applications has been illustrated recently with successful cross-measure drilling at Huntly East Mine.

Jan 1, 1993

Today computers are accepted as a standard item in industry and they perform a variety of tasks over a wide spectrum of activities from mine planning and CAD to data processing and spreadsheet work. However many problems particularly in the. area of decision making where there are no clear mathematical models available and usually the output or answer is dependent to some extent on a heuristic approach, don't lend themselves to conventional solutions using standard procedural algorithms. Recently a number of techniques have evolved primarily from the enhanced capabilities of modem equipment, which are capable of solving these problems. This paper is a brief overview of these rather unconventional developments of computer technology in the area of artificial intelligence with reference to their application in mining.

Jan 1, 1993

By Hoberg H, Schnieder FU

The disposal of residues from coal preparation and processing will to an increasing extent require investigation and consideration of the environmental problems resulting as a consequence of this. Different authors (Diingelhoff and Plankert, 1983; Hasenpatt, 1985; Szczepanska and Twardowska, 1987) have concentrated primarily on the content and the mobilisation of inorganic contaminants such as chlorides, metals and heavy metals from spoil tips, while no publications have yet been found on the question of a possible emission of organic contaminants (PCB, PAH, HC HC) from processing residues. Here the flotation residues in particular are able to bind larger quantities of organic contaminants by physi-sorptive means because of their large specific surface and, after disposal, to be re-emitt than into the environment. The flotation agents used in coal flotation are mixtures of technical distillation products with a correspondingly fluctuating composition. As Hey, 1986 showed, they may contain, in addition to the main components (n-alkanes, alcohols, surfactants), over 50 individual trace substances. In conjunction with the structural-chemical similarity of the individual components, this complicates the quantitative analysis of individual components considerably. For the analysis of hydrocarbon content of flotation products by means of extraction with organic solvents in accordance with DIN 38408, H18, the difficulty arises, besides the insufficient sensitivity at low concentrations, that geogeonic hydrocarbons are extracted from the coal as. well and the analysis results are thus falsified. These problems were overcome by the application of the 14C radiotracer method where certain components of the flotation agents are marked with radioactive carbon (14C). By measurement of the radioactivity of solid and liquid samples, the concentration of the marked substance can be measured very sensitively and precisely, whereby the accumulative measurement of similar organic substances is ruled out. Thus the reaction path of certain substances in complex reagent mixtures such as flotation agents can be traced excellently and the conceivable environment burden resulting from flotation tailings disposal can be estimated. In this paper, the adsorption behaviour of typical components of coal flotation agents are investigated for different coals and types of gangue material, the reagent content of flotation concentrates and tailings, as well as the mobility of the reagents adsorbed onto solids. The knowledge of adsorption and desorption mechanisms of unpolar hydrocarbons emulsified in water to solids are also of particular interest for the understanding of processes of organic soil contamination and for the further development of washing processes for oil-contaminated soils.

Jan 1, 1993

The Olympic Dam copper-uranium-gold-silver deposit, located approximately 520 km north-northwest of Adelaide, South Australia (Figure 1) was discovered in 1975 by Western Mining Corporation. A joint venture to facilitate development of the deposit was formed in mid-1979 between WMC (51 per cent) and the British Petroleum Group (BP, 49 per cent). Production commenced in 1988, and current annual output from the mining and treatment of 2.2 Mt of ore is approximately 65 000 t of refined copper and 1400 t of uranium oxide. Significant amounts of refined gold and silver are also produced.

Jan 1, 1993

Your Worship the Mayor, Ron McCullough; the Honourable Tony McGrady M.L.A., Minister for Minerals & Energy; distinguished guests, ladies and gentlemen.It's both a pleasure and a privilege to have been invited by the North West Queensland branch of the AusIMM to speak at a forum in Mount Isa to discuss the potential, and more importantly, the development of the great North West. I spent 25 years of my life proudly living and working in this part of the world, marvelling at its riches, exploring its potential, assisting in its development and responding to its challenges.As President of the North West Queensland branch of the AusIMM in the early 1970's I can clearly recall helping to organize a major symposium extolling the geological potential of the region, revealing the extensions of the Mount Isa copper orebody at depth and describing the potential of the then untapped Hilton Mine. Our optimism in the North West so obviously reflected two decades ago remains today.

Jan 1, 1993