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By Houchin MR, Jenkins DH

This paper examines the importance of processing to the properties and performance of high purity zirconia ceramics. Many of the principles discussed, however, apply to ceramic processing in general. For fabricated ceramic articles to display their wide range of high performance properties, they must be made fully dense. The precursor powder and postpowder processing requirements necessary to achieve full density in the fabricated body are discussed. Brittleness, the anathema of ceramics, can be overcome in zirconia by incorporation of toughening mechanisms. Transformation toughening and microcrack toughening and their origins in partially stabilized zirconia are reviewed.

Jan 1, 1989

By Mark C. J

Since the commissioning of the BHAS Copper Plant in 1984 the copper electrowinning operations have not fully met expectations. During 1988, a laboratory scale electrowinning unit was constructed to enable an investigation of the effects of process parameters on copper cathode deposition and quality. The process parameters investigated were copper concentration, acid concentration, current density, electrolyte temperature, electrolyte flow, electrolyte impurities and electrolyte additives. The findings of this research program indicate that there is an optimum cathode deposition morphology which results in good quality copper deposits which have improved stripping characteristics. All of the process variables investigated influenced the copper deposition and therefore it was necessary to delineate a suitable operating envelope for the copper electrowinning. As a result new standard operating parameters in electrowinning have been implemented which has enabled the production of higher quality copper cathodes with improved stripping characteristics.

Jan 1, 1989

The process of refurbishment is not a precisely defined one. It is under- stood to mean an upgrading of a plant which is normally performed only once. The application of refurbishment in the field of materials hand- ling equipment poses particular problems because complex plants con- sist of individual components having quite different remaining service lives. For this reason, a systematic, proven procedure is proposed for the refurbishment of large materials handling equipment, designed to ensure economic implementation in accordance with the company goals. Rheinbraun2 has been using materials handling equipment since 1900, the largest units today being bucket-wheel excavators with a daily capacity of 240,000 bank cubic metres of overburden and a service weight of up to 13,500 t (metric tons). Since 1975, more than 50 large-scale refurbish- ment projects have been carried out in the company. In the process, refur- bishment has turned out to be the proven alternative to replacement of large materials handling equipment. Rheinbraun Engineering,3 a Rhein- braun subsidiary, carries out planning, consulting, and supervising work in the implementation of refurbishment projects in Germany and abroad. The most recent example is the refurbishment of Dredger 11 of the State Electricity Commission of Victoria in cooperation with Krupp-Australia, Melbourne.

Jan 1, 1989

By Kavetsky A

In surface mining operations, the ease with which a muckpile may be dug is a dominant factor in mining efficiency. Within broad limits, this is largely dependent on muckpile shape and looseness within a muckpile. Moreover, prediction of grade boundary movement and subsequent dilu- tion is of interest to most open cut mines. Such a predictive tool would enable blast design changes to be made to reduce mixing of certain grade regions. At the very least, a good knowledge of post-blast region bound- aries can reduce layout of the grade boundaries and decrease grade dis- crepancies between pit and plant. The model presented in this paper is able to consider various options for a production blast and predict consequent muckpile shapes and grade boundary movements in a three dimensional manner. The overburden geometry, hole patterns, hole inclination and charge distribution are all explicit model inputs. The model divides the rock mass into blocks and calculates a velocity for each block. Three controlling parameters are used in the model, which are related to the explosive energy per unit length of blast hole, energy attenuation of the rock mass and inter-row delay, respectively. The output of the model is a 3 dimensional muckpile shape (contour or any cross section) and a contour map of grade distribution within the muckpile. The model parameters are site specific, since their values depend on the rock condition and explosive-rock interaction which varies from site to site. In order to "tune" the model to a particular site, parameter values must be found which reproduce an observed muckpile profile shape from a given blast design. This calibration of the model requires at least one surveyed muckpile profile shape from a production blast. The model parameters which best reproduce that shape are found by a pattern search technique, and may then be used to predict the effect of changes in blast design on muckpile profile shape and grade boundary movement.

Jan 1, 1989

Working in thick coal seams presents many problems, included in these is obtaining the maximum recovery of coal under safe working conditions. In order to obtain maximum extraction it is important to understand the behaviour of pillars left for support purposes. However it is not always the practice to maintain pillar stability it is often required to design for pillar failure. The greatest hazard of pillar mining is uncontrolled pillar collapse. Many major and relatively minor collapses of pillar workings have been recorded in the history of mining. Notable among the collapses was that at Coalbrook Colliery in South Africa in 1960 (Bryan et al 1964). This led to recommendations on the design of bard and pillar workings in South Africa. (Salamon 1967) These design recommendations were based on the statistical analysis of stable and unstable pillar workings and introduced the concept of probability of pillar failure and safety factor. On the basis of this study a safety factor of 1.6 was prescribed for production panels in South Africa. A general review of pillar design procedures, reveals that a new phase of reinterpretation and modification is in progress. This takes into account for instance the effect method of working, whether by conventional drilling and blasting or continuous miner, has on coal pillar strength, and the necessity to review the methods for increasing depth of working. Also, as more is being understood about overall rock mass properties and advanced computer modelling techniques become more readily available, the mine planning engineer is faced with numerous approaches to pillar design.

Jan 1, 1989

By Wright S

Single pellets of mixed lead-zinc concentrate containing up to 20 % lead were roasted in the temperature range of 800-1100¦C. Variables studied included pellet size (from 9-8 to 3-2 mm diameter), gas flowrate past the pellet (from 0.05 to 5 ms t), composition of the atmosphere and the effect of additives such as zinc oxide and silica. After defined periods of time, the pellets were removed from the furnace, quenched and submitted for chemical, XRD, SEM and microprobe analysis. The oxidation of the zinc sulphide followed a shrinking core model. Temperature measurements showed that very high pellet temperatures were experienced at the start of an experiment but after 5-10 minutes these approached a constant temperature. The lead loss from the pellets was then constant with time. Thermodynamics predicted the presence of two bands of lead material in the reacted layer of the pellet. These were found in practice. The lead loss from the pellet occurred from the outer oxysulphate layer via the vaporization of lead oxide polymers. The vapour pressure of PbO, and the loss of lead, was dependent on temperature and bulk gas concentrations of SO2 and 02. At 1100¦C the addition of silica greatly reduced the loss of lead from the pellet. Physical factors such as pellet diameter and gas flowrate past the pellet affected the particle dynamics. These results were found to vary in accordance with the predictions of the Froessling equation.

Jan 1, 1989

By Dight P. M, Dugan K. J

Design approaches for the artificial support of open pit walls have been reviewed and the main factors affecting support performance have been identified. An example of passive support in a potentially unstable pit wall has been used to demonstrate the importance of slope displacement as part of the support design process.

Jan 1, 1989

By Peck J. P, Kennedy D

Drill performance monitoring studies were recently completed at the Fording River mine, British Columbia. Microprocessor-based instrumen- tation and data analysis techniques were developed with the objective to improve short and long term mine planning. Data analysis permitted the identification of thicknesses and interfaces between soft/hard zones at depth based upon the recorded responses of the drill. Data clearly con- trast the soft coal seams and harder waste rock units based on variations in recorded drill rotary speed and torque, hydraulic downpressure, bail- ing air pressure and instantaneous rate of penetration. These parameters were monitored and recorded at 10 cm sampling intervals. Processed drill data was correlated with gamma logs, an existing means for locating coal seams and distinguishing between waste units. Current development of a pattern recognition module aims towards automated interpretation of drill data, identifying micro-and macro-geological and geomechanical rock mass characteristics. Delay between acquiring, processing and interpret- ing the drill data for practical use by mine personnel should be minimized. Integration of this technology with the mine's current main-frame based Mine Engineering Application System software will enable more accurate and timely annlication of the nrocessed drill data.

Jan 1, 1989

By Benkendorff P. N

Cement production in Australia approximates 6.5 million tonnes per year. Cement clinker is sourced from 15 plants which operate 28 kilns. Cement grinding is conducted at 14 of the clinker plants plus 7 grinding plants. Average annual capacity per kiln or plant is lower than in many overseas countries, but kilns introduced since 1970's have been of larger size more in keeping with size trends overseas, although still smaller than the large units overseas. Substantial economies in capital and labour costs can be achieved in large production units, particularly with dry process kilns using precalcination techniques in which part of the fuel is introduced in the static preheater section ahead of the kiln while the balance is added to the kiln in a conventional manner. Precalcination techniques have been introduced to the Australian cement industry but as cement transport costs form a major part of supplying diverse market areas, the size of kilns is likely to remain less than maximum owing to balance with distribution costs. The cement industry uses significant amounts of thermal and electrical energy which can be minimised by proper selection of equipment and technology. Labour costs are also significant and can be contained by automation and computer control of the process.

Jan 1, 1989

An improved technique for the quick and accurate measurement of the weight and centre of mass in the horizontal plane of large machines has been developed. On-site weighing of large plant such as bucket wheel dredgers is an important part of the commissioning procedure. The results from the weighing assist in determining the stability of the machine and also enable confirmation of the structural weight distribution used for stress analysis at the design stage. In this paper the techniques previously used for weighing are reviewed and the sources of error using these methods examined. A full descrip- tion of the current technique and procedure is given explaining how the measurement system comprising strain gauge load cells, displacement transducers, wind speed and direction sensors, data logger, computer and software was developed to enable quick and accurate measurements to be made. Proposed modifications to software necessitated by the replace- ment of current measuring instrumentation and computer are discussed. A typical example of measurements from the weighing of a large dredger, illustrating the accuracy of the new technique is given and the calibration technique used to check the accuracy of the force and moment measurements is explained. An outline of how the results are used to certify the machine for operation is given.

Jan 1, 1989

By Denholm W. T

The SMELT-2 package is specifically designed to perform on-line simulation of smelting processes. This paper describes its application to the simulation of continuous matte converting followed by reductive slag cleaning in SIROSMELT reactors. The matte, containing 50% Cu is assumed to be produced at the rate of 20 tph in a continuous matte smelting furnace such as an Outokumpu Flash Furnace, Noranda or Sirosmelt reactor. Two alternative fluxing strategies in the converter are examined, namely: ò conventional silicate slags, ò calcium ferrite slags, and the flow sheets associated with each strategy are discussed. A regular solution model is used in the present study to account for the variations in the activity coefficients of components in the slag.

Jan 1, 1989

By Ryan CG, Cousens DR, Sie SH, Suter GF

Proton microprobe analyses of trace elements have been carried out on a wide variety of ilmenites, garnets and chromites, to improve diamond exploration methods. The results so far show the potential to discriminate between barren and diamondiferous source rocks, and to distinguish multiple sources within single Drainages.

Jan 1, 1989

By Luke K. A

Pressure on production at New Zealand China Clays has led to the development of a dewatering control loop for fine halloysite china clay. The development was based on the analysis of data from the automation of plate and frame filter presses. The analysis of the data has led to process changes, and the ability to quickly solve dewatering problems. As a result of control in the dewatering circuit press times have reduced on average 117% and output has increased proportionally.

Jan 1, 1989

By Plumridge C. L, Lynch J. E, Forresty R. J

The Amanda Bel Goldfield (new name) is an area of approximately 1000 sq. km centred 65km WSW of Ingham and 150km due east of Kidston (Camel Creek homestead to Ryeburn homestead area). Gold mineralisation has been located in tightly folded sediments of the Silurian Greenvale Formation as well as in the Early Devonian Kangaroo Hills Formation and the Early Carboniferous Clarke River Formation. The area is traversed by a major NW-SE structural corridor, with many of the numerous basaltic, andesitic and rhyolitic dykes of the region sharing a similar trend. So far fourteen gold-bearing zones have been located, all of which are new discoveries delineated by bulk cyanide leach sampling and subsequent geological reconnaissance. The region has undergone three periods of deformation with gold mineralisation introduced syn-D1, post D1 - pre D , syn-D and post-D2/D , thereby revealing an involved metall~genic history. Mineralisation types include Sb, Sb-Au, Sb-Au-As, Sb-Au-As (-Pb-Zn) and Au-As. Minor occurrences of W, Pb-Zn-Ag and Pb-Zn-Ag-As-Sn are also present as are alluvial (deep lead) tin Drosoects.

Jan 1, 1989

By Loo C. E

Thirty two polyacrylamide flocculant samples were selected from the wide range offered to the Australian coal industry. An extensive test program was conducted to consider the properties of the flocculants, the substrates, the process conditions and the water chemistry encountered in coal preparation plants. The study indicated that flocculants with molecular weights of 12 to 14 million and degree of hydrolysis around 40% gave the best "average" performance over a wide range of process conditions. The pick-up and filtration of fine coal was demonstrated on a pilot scale to be a critical function of flocculant properties. This study also showed that the agitation intensity during flocculation was a critical parameter in determining the settling rate of the slurry and the clarity of the resulting supernatant. An electronic meter to measure agitation intensity was designed, constructed and tested to demonstrate how, for the first time, laboratory results can be implemented in operating plants.

Jan 1, 1989

By Denholm W. T, Rankin W. J

The reduction of zinc from lead blast furnace slags using hydrogen was studied at 1300¦C as part of a laboratory investigation of zinc fuming. To perform the experiments, 300 g "spent slag" was melted in a crucible. Hydrogen was then injected into the slag through a lance and fresh blast furnace slag was added regularly in small quantities over a period of 40 minutes. Zinc added in the fresh slag was reduced and the zinc level of the bulk slag attained a steady state value of between 1 and 9% after about 10 minutes, depending on the gas injection rate. Because of the high reactivity of hydrogen, bulk supply of hydrogen to the slag was the rate limiting step at the flow rates used and it is believed that the gas-slag reactions in the system were at equilibrium. A partially/stabilized zirconia cell with a Ni/NiO reference electrode was immersed in the slags during the experiments and the steady/state oxygen potentials of the slags were measured. By using the experimental oxygen potential values and calculated values of the steady state concentrations of zinc in the offgas, the activity of ZnO in the slags was calculated from the Gibbs's free energy change for the reaction:

Jan 1, 1989

In 1985 a 2.5-tonne top blown rotary converter was installed in the silver refinery at Cominco's Trail Operation to carry out the final cupellation of burndown metal to Dore metal. The furnace is fired with an oxygen-natural gas lance which is capable of achieving a variety of furnace conditions, varying from reducing to highly oxidizing. Reaction rates are about 4 times greater than using conventional cupel furnaces. The faster reaction rates improve productivity and reduce in-process precious metal tie-up. The furnace is also used to reduce litharge slag for bismuth recovery.

Jan 1, 1989

By French D

In presenting this paper may I preface my remarks by recognizing the presence here to-day of the many delegates from the overseas mining communities throughout the world. That is to say - those delegates not representative of Companies resident in Australia. This does not mean that my comments following are directed solely to the Australian exporter - far from it. The Company which I represent is internationally based. The experiences we have had in dealing and negotiating with our good friends the mineral cargo shippers vary very little in any operational area. However for the purposes of this exercise this address is based on some of our experiences within the Australian trade scene with the emphasis on the fact that we believe it has application to all trading areas.

Jan 1, 1989

By Ryan CG, Ramsden AR, Sie SH, French DH, Griffin WL

Proton microprobe and electron microprobe analysis are being used in combination for in situ determination of the trace element contents of oxide, sulphide and silicate minerals in a sample of the Merensky Reef. Initial results indicate that chromites contain only Ni, Zn, Ga, Zr ar d Nb. Platinum-group elements, if present, are at concentrations less than 2 to 6ppm. Ru, Rh and Pd are the only platinum group elements to be consistently detected in the sulphides. PentLindite is the most important host for these elements with the concentration of these elements being dependant upon the mineral association in which it occurs

Jan 1, 1989

By Collins D. N

The Olympic Dam Copper Smelter Acid Plant is a hybrid plant capable of producing sulphuric acid from either sulphur burning, metallurgical gases or a combination of both. Commissioning of the Acid Plant on sulphur burning commenced in early April 1988 and commissioning on combined sulphur burning and metallurgical gas commenced in August 1988. During commissioning on sulphur burning a number of acid spills occurred due to balancing of tower flows and control of acid dilution. A number of other significant problems were encountered including failure of boiler gaskets, failure of strong acid pumps seals, the fracture of the teflon dilution water injector and the subsequent failing of the acid circulation pump, tank steel failures and various instrumentation problems. The Commissioning of the Acid Plant on metallurgical gases commenced in August and with the exception of the production of oleum in the boiler economizer was relatively trouble free. Oxygen Plant commissioning commenced in May 1988 and was without significant incident. An outline of the basic equipment for the Acid Plant and Oxygen Plant is presented together with aspects associated with the commisisoning of both plants.

Jan 1, 1989