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By P. Babak, E. Insalaco, O. Babak, P. Henriquel

"Detection of outliers is an important primary step in geomodelling. Geological datasets often contain errors due to problems such as measurement device limitations and recording glitches. In this paper, a robust Mahalanobis distance–based approach is successfully applied to particle size distributions of the Joslyn lease, an oil sands development site near Fort McMurray, Alberta, Canada. Automatic outlier detection and geological review were combined. Outliers from the Mahalanobis distance approach were compared with their respective core photographs to determine if laboratory measurements and facies classification were correct. A checking procedure for laboratory technicians is proposed.RÉSUMÉ La détection des valeurs aberrantes constitue une étape primaire importante de la modélisation géologique. Les ensembles de données géologiques contiennent souvent des erreurs en raison de problèmes tels que les limitations des instruments de mesure et des pépins d’enregistrement. Dans le présent article, une méthode robuste basée sur la distance de Mahalanobis a été mise en oeuvre avec succès aux granulométries du bail minier Joslyn, un site de sables bitumineux en développement à proximité de Fort McMurray, Alberta, Canada. La détection automatique des valeurs aberrantes a été combinée à une étude géologique. Les valeurs aberrantes de la méthode de la distance de Manalanobis ont été comparées avec leurs photographies respectives de carottes de forage afin de déterminer si les mesures en laboratoire et la classification des faciès étaient correctes. Une procédure de vérification pour les techniciens de laboratoire est proposée."

Jan 1, 2015

By Oy Leuangthong

Red Dog mine is the world's largest Zn producer. The deposit consists of sulphide ore zones in sedimentary exhalative (sedex) deposits, and is characterized by the presence of multiple metals and multiple ore types. The objective of the case study is to characterize seven different minerals, Zn, Pb, Fe, Ba, sPb, Ag and TOC, within eight different rock types. Geostatistical models were constructed for each variable within the eight rock types, and subsequently assembled to give 40 realizations for six 25ft benches. The stepwise conditional transformation was used to account for the complex multivariate relations. In addition to reproducing the input data, histogram and variogram, the resulting models also respect multivariate relations locally and globally. This paper documents the methodology to construct these models. A thorough validation procedure was implemented. Comparisons with blasthole data show that the conditional simulations and the long-term models agree in expected value. The main advantages of the conditional simulations are (1) the explicit accounting of multivariate relations between the data in model construction, and (2) the ability to quantify variability and uncertainty at any scale. A small exercise comparing the profit from a kriged and a simulated model is also examined. Results show that the simulation approach showed a 3% increase in profit, relative to the conventional estimation approach.

May 1, 2004

By H. Karakul

Determination of P-wave velocity (Vp), which is closely related to intact rock, is a nondestructive, easy and less complicated procedure. Due to these advantages, there is an increasing trend to predict the geomechanical properties of rocks from Vp. In addition to mineral content, cementing material and porosity, degree of saturation (Sr) are also other factors influencing geomechanical properties of the intact rock. However, up to the present, in the studies on the prediction of geomechanical properties of rocks from Vp, the effect of Sr has not been investigated. By considering this issue, in this study, it was aimed to correlate strength properties (uniaxial compressive and tensile strengths) and Young’s modulus with Vp of various rock types under different degrees of saturation. In addition, geomechanical properties of rocks were estimated from theoretical P- and S-wave (Vs) velocities, which were calculated based on their mineralogical compositions. For this purpose, fourteen different rock types were collected from several parts of Turkey and a comprehensive laboratory testing program was conducted. In the statistical analyzes, a series of different prediction relationships were developed by using independent variables such as Vp, Sr and effective clay content (ECC). Simple regression analysis results indicated that although prediction of the geomechanical properties of rocks from Vp at different degrees of saturation was possible, the equations developed would yield some under- or over-predictions. On the other hand, the multivariate equations developed have very high prediction performances and are very useful tools to estimate the geomechanical properties from the measured Vp at any Sr value. In addition to mineralogy, the variation in geomechanical properties with increasing Sr is also associated with the combined effect of porosity and clay content, which is first described in this study by the term Effective Clay Content (ECC). It is also noted that strength properties of rocks at any Sr may also be estimated using the empirical relations based on the theoretical Vp and shear-wave velocity (Vs) values, which are calculated from their mineralogical compositions.

Jan 1, 2015

By Bergh. L. C.

On line monitoring and diagnosis systems of process operating performance are becoming an important part of industrial programs, leading to improve process operation and therefore product quality over time. In processes, such as the contact section of a sulphuric acid plant, a large number of input variables, highly correlated, are presented. These characteristics usually pose more difficulties in modelling the process for monitoring and diagnosis purposes. Multivariate statistical projection methods, such as Main Component Analysis, have been proposed to effectively deal with these situations. The application of these ideas to a section of a 2350 MTD sulphuric acid plant, located at the Caletones Smelter, including dry tower, gas blowers, catalytic reactor and S03 absorber processes, is discussed here. A PCA model with eight main components is used for monitoring and diagnosis of more than seventy operating variables. Hottelling's T2 and Q residuals test were used for detecting measurement problems in relevant variables, and for identifying which set of variables were responsible for driving the process outside its normal operating region. Furthermore, considerable information for the correction of the tested operating problems was given by the use of these techniques.

Jan 1, 2007

By J. F. MacGregor, M. Hou, D. Hodouin

"RésuméDe nouvelles méthodes efficaces sont maintenant devenues nécessaires pour traiter les quantités massives de données en temps-réel que collectent les ordinateurs industriels modemes. Les méthodes statistiques multi variables comme l'analyse en composantes principales et la projection sur des structures latentes sont des méthodes analytiques bien adaptées aux données industrielles bruitées et mal conditionnées. L'efficacité de ces méthodes est illustrée sur des données historiques collectées dans une usine de broyage et de flottation. Trois cent cinquante observations de quarante quatre variables de procède ont été utilisées pour démontrer les aptitudes de ces méthodes pour l'analyse préliminaire de données, la classification des régimes opératoires, le contrôle de qualité et la modélisation empirique des precedes.AbstractBecause of the availability of powerful industrial computers which collect huge amounts of real-time data in mineral processing plants, there is a need for efficient methods to extract relevant information from them. Multivariate statistical techniques, such as principal components analysis (PCA) and projection to latent structures (PLS), are well suited to analyze these large sets of noisy and ill-conditioned data. The power of PCA and PLS is illustrated on historical data from a grinding and flotation plant. Three hundred and fifty observations of forty-four process variables are used to show the capacity of these techniques for preliminary data analysis, classification of operating regimes, process monitoring, and process empirical modelling."

Jan 1, 1993

By Brad Hewitt, Jeff Belke

"Murrin Murrin Operations has not had a successful beginning. Numerous reliability and operability issues many of which are the result of design decisions have been addressed through mechanical and operational changes and the CCD circuit is no exception. Four design aspects of the CCD circuit that have caused and continue to cause operational problems are:1. the inclusion of solution neutralisation gypsum in the CCD circuit feed which was designed solely for HPAL residue without proper investigation of its impact on the achievable underflow density and resulting wash efficiency;2. the decision to construct the thickener base from thickened solids;3. the lack of redundancy in the overflow, underflow and tailings pipe work; and4. the lack of thickener operational flexibility in the central rake-lift and feedwell dilution system.In November 2002, the lack of operational flexibility in the rake-lift and the feedwell dilution system through mechanical modification as follows:•, CCD1 has a modified rake mechanism that now allows central vertical lift of 600 mm;•, CCD1 has forced dilution using the Outokumpu Turbodil® technology and replacing the E-Duc® technology of Eimco;The decision to install, the installation and the results of the CCD1 rake-lift mechanism and feedwell dilution system are discussed in this paper. The installation was justified on improved operational robustness and an increase in the in the underflow density of 1 per cent (per cent w/w). At approximately the same time process modifications in the solution neutralisation circuit were implemented and these changes altered the rheology of the slurry reporting to CCD1. Since the modifications to CCD1 and the solution neutralisation circuit, the CCD circuit has averaged a 2 per cent improvement in the circuit underflow density.The CCD1 modification was completed on time and mechanically has performed well. From a risk point of view, the central rake-lift and Turbodil®dilution system add a degree of freedom and robustness to CCD1 operation that has extended the range of operational confidence. In this respect, the modification has been a success and is complementary solution neutralisation improvements."

Jan 1, 2005

By B. Hewitt

Murrin Murrin Operations has not had a successful beginning. Numerous reliability and operability issues many of which are the result of design decisions have been addressed through mechanical and operational changes and the CCD circuit is no exception. The decision to install, the installation and the results of the CCD1 rake-lift mechanism and feedw ell dilution system are discussed in this paper. The installation was justified on improved operational robustness and an increase in the in the underflow density of 1% (per cent w/w). At approximately the same time process modifications in the solution neutralisation circuit were implemented and these changes altered the rheology of the slurry reporting to CCD1. Since the modifications to CCD1 and the solution neutralisation circuit, the CCD circuit has averaged a 2% improvement in the circuit underflow density. The CCD1 modification was completed on time and mechanically has performed well. From a risk point of view, the central rake-lift and Turbodil® dilution system add a degree of freedom and robustness to CCD1 operation that has extended the range of operational confidence. In this respect, the modification has been a success and is complementary to solution neutralisation improvements.

Jan 1, 2004

By R. A. Hemstock

"Simple classification systems are now being used which will describe adequately the surface vegetation, the topography and the peat for any muskeg condition. Good progress is being made in determining some of the mechanical properties of muskeg and it is apparent that the science of soil mechanics will apply largely to these studies. Correlation is also indicated between shear strength as determined by the shear vane tester and vehicle performance. Several tracked vehicles are now available which perform well in muskeg and advances in this field have come rapidly in the past few years. Testing is under way on the largest of all muskeg vehicles -the thirty-five ton Musk Ox. This vehicle will fill the last gap for the oil industry and will make possible the movement of large drilling rigs at any season of the year."

Jan 1, 1960

The following briefing is intended to provide an overview of the present and future challenges associated with our access to a secure and adequate supply of electrical energy necessary to support safe, productive and sustainable mining initiatives at Musselwhite. Contents ??Site power demand vs. current available supply ??Supply technical deficiencies ?adequacy and security of present supply ??Present internal generation ??Anticipated future internal generation requirements ??Increased requirements necessary for planned expansion ?demand/security ??Goldcorp?s strategy to achieve required supply ?transmission line initiative ??Subsequent benefits to others from the Goldcorp initiative. ??Economic impact of MusselwhiteMine on the northwest region ??Anticipated economic impact of planned expansion ??Expected life cycle of MusselwhiteMine ??Comparative energy costs for similar operations in other jurisdictions ??Conclusions ??Anticipated action plan ??Energy Management Initiatives ??Site Orientation

May 1, 2009

By F. H. Samuel, H. Tahiri, S. Valtierra, H. W. Doty, A. M. Samuel

L'affinage des grains dans les alliages d'aluminium consiste à augmenter le nombre de sites de cristallisation de la phase a-Al afin d'obtenir une structure fine. Les alliages mères de type Al-Ti-B sont largement utilisés comme raffineurs des grains. Cette étude a pour but d'établir des mécanismes convenables d'affinage des grains dans l'alliage A356 en utilisant cinq alliages mères et deux températures de coulée (750°C et 950°C). Les résultats montrent que la phase a-Al prend une forme selon l'alliage mère ajoute; les échantillons coules a haute température montrent une taille de grain plus grosse; les températures de germination et de croissance augmentent avec I' augmentation du Ti ou du B et la taille des grains diminue. L'alliage mère Al-4%B montre une puissance remarquable en comparaison d'autres alliages mères. Pour cet alliage mère, le titane résiduel dans l'alliage A356 réagit avec le bore pour former TiB2 qui, par la suite, agit comme un germe actif pour la phase a-Al.

Jan 1, 2006

By Patrick Chabot

Ce document présente une méthode hybride de long trou favorisant une méthode de minage initiale par chambre-magasin et complétée par une méthode de minage long trou. Cette méthode a été adaptée suite à plusieurs facteurs tels qu?une géologie complexe, une rareté de mineur d?expérience et un haut taux de roulement de main d?oeuvre spécialisée. Cette méthode a permis d'excellents résultats par rapport à la dilution. De plus, la récupération de pilier à haute teneur par forage long trou sera expliquée. Cette méthode permet aussi de récupérer le minerai qui est resté accroché dans les chantiers chambre-magasins. Introduction : La mine Géant Dormant est une mine filonienne d?or située à environ 80km au nord de la ville d?Amos au Québec. Elle est en opération depuis 1988 et à la fin de 2007, elle a produit près de 885 000 onces d?or à partir d?environ 2 400 000 tonnes de minerai pour une teneur moyenne d?environ 11,5g /t Au. Cette mine est la propriété d?IAMGOLD Corporation depuis l?acquisition de Cambior par cette dernière au mois de novembre 2006. Elle emploie 151 employés permanents et environ 41 entrepreneurs.

Feb 1, 2008

By Karl Marquis

La Mine Mouska exploite depuis deux ans certains blocs de réserve à l?aide de la méthode long trou. Même si, à priori, la méthode long trou semble rentable, le contrôle de la dilution ainsi que le respect d?un échéancier serré s?avèrent primordiaux afin que cette méthode d?exploitation puisse être justifiable économiquement. La présentation suivante fera la comparaison économique entre cette méthode et celle de chambre-magasin.

Oct 1, 2001

By D. E. Gill, A. Piche, S. Dufresne

"SOMMAIREUne méthodologie de prévision des coûuts de forage en galeries est proposée. Cette méthodologie a été élaborée pour les perforatrices pneumatiques manuelles. Elle est composée de quatre modèles: (1) un modèle de pénétration conduisant à la prévision du temps de forage; (2) un modèle d'estimation de la durée de vie des fournitures; (3) un modèle d'estimation de fa quantité d'énergie consommée; et (4) un modèle de calcul de couts. Elle fait intervenir la résistance en compression uniaxiale de la roche du massif foré, le diamètre des trous, Ie type de perforatrice utilise, fa pression d'air d'opération, la longueur des fleurets, les temps morts associes au forage ainsi que le rendement des compresseurs, des perforatrices et du réseau de distribution de l’air comprime. L 'application de la méthodologie est illustrée à l’'aide d'un exemple, suivi d'une courte analyse de sensibilité et d'une brève discussion. ABSTRACTA drilling cost estimation methodology for underground headings is described. This methodology has been developed for percussive hand-held drills. It comprises four models: (1) a drillability model used for the prediction of the drilling period; (2) a model for the prediction of bit and rod lives; (3) an energy model; and (4) a cost model. It makes use of the uniaxial compressive strength ofthe rock drilled, hole diameter, drill type used, operating air pressure, drilling rod length, dead times that may occur during the drilling operation as well as compressor, air distribution network and drilling machine efficiencies. The application of the methodology is illustrated with an example, followed by a short sensitivity analysis and brief discussion."

Jan 1, 1994

By D. H. Ryan, J. T. Graham, A. Navarra, J. A. Finch, S. Somot

Pyrrhotite (Po) is widely considered to be the most significant mineral in the self-heating of sulphides. It is therefore desirable to determine the amount of Po in mineral samples. This is commonly accomplished through x-ray diffraction (XRD) or quantitative evaluation of materials by scanning electron microscopy (QEM-SEM). This paper introduces another quantitative method based on Mossbauer analysis that requires limited sample preparation and has the additional potential to detect the sulphur/iron ratio within Po. The technique is explored using pentlandite/pyrrhotite mixtures.

Jan 1, 2009

By K. Hoover, G. Labarre, S. Rantanen

"As part of the Namew Lake project a mill was constructed to treat 1900 tpd of ore grading approximately 0.90% CU and 2.45% Ni to produce copper and nickel concentrates.Nickel occurs mainly as pentlandite and violarite while copper occurs as chalcopyrite. Two main ore types are present1 lower grade disseminated sulphides in a talcose ultramafic gangue and a higher grade solid sulfide with a granitic breccia matrix.Primary crushed ore from underground is treated on surface in a conventional closed circuit crushing plant using 2-stage cone crushing. Crushed ore is conveyed to storage and then fed at a controlled rate to a grinding circuit employing a rod and ball mill with hydrocyclone classification. Rougher flotation separates and cleans nickel and copper sulfides from waste materials followed by a high lime separation circuit to separate the minerals into final concentrates. Dewatering is achieved through use of high capacity thickeners and pressure filters prior to delivery to a loadout area. The crushing and milling control is highly automated.Plant design was based on metallurgical samples obtained from drill cores. After the first year of operations, plant results compared favourably with design projections.INTRODUCTIONThe Namew Lake Project is a joint venture partnership between Outokumpu Mines Ltd. (Canada) and Hudson Bay Mining and Smelting Company Ltd. (60%). The project included construction of a mine and milling complex to treat approximately 500,000 tonnes per year of copper-nickel ore grading o.91% and 2.44% Ni. Known reserves are estimated at 2. 65 million tonnes. The deposit is located approximately 65 km south of Flin Flon (120 km by road) and about 5 km east of the Manitoba-Saskatchewan border. The decision to construct a concentrating facility was made June 15, 1987 and construction started a week later. The facility, designed for 1900 tonne per day throughput, was ready for commissioning in September 1988. Outokumpu Engineering of Finland was chosen to prepare metallurgical flowsheets, select and develop plant layouts, and provide construction management. Kilborn (Toronto) contributed detailed engineering for civil, structural, mechanical and electrical components and outokumpu Equipment of Canada, the design, the supply, and commissioning of the instrumentation package. Hudson Bay undertook the initial metallurgical test work and preliminary design work."

Jan 1, 1990

By Neil R. Burns, Michael Doggett

Abstract - The Nanisivik mine offers a unique opportunity to examine the economics of a mining scenario from its original feasibility study through to closure. In the early 1970s, the Strathcona Sound project (exploration around the Nanisivik mine) had advanced to the point where a significant mineralized body had been defined and a feasibility study was initiated. The study supported development of the Nanisivik mine, with government investment in regional infrastructure, and the mine was constructed and operated for 26 years. Many elements of the feasibility study were difficult to estimate because the project was unique in its high Arctic setting. As a result, many differences were found when comparing the actual mining data to the feasibility study. The majority of these differences were the result of an actual mine life of 26 years instead of the planned 12.5 years. Most of the mining costs were higher than estimated and production occurred at a much higher extraction rate than planned. On a constant dollar basis, the metal prices were, on average, below the feasibility estimates. For the most part, these differences balanced out, with the actual mining being only slightly more profitable than anticipated in the feasibility study.

Jan 1, 2004

By G. D. Hibbard

New regions of material property space can be accessed by combining microstructural design at the nm-scale with architectural design at the µm- or mm-scale. In the first case, large strength increases associated with grain size reduction to below 50 nm have driven extensive research efforts into the development of nanocrystalline materials [e.g. 1-3]. For many potential structural applications, however, the density of a nanocrystalline material is just as important as its strength. In fact, reducing the density is more important than increasing the strength for certain weight specific materials performance indices, and it is especially critical for applying structural nanomaterials in the aerospace and automotive sectors. We have developed a new type of structural nanomaterial wherein the effective density of the parent metal is reduced by more than an order of magnitude by incorporating an internal periodic cellular architecture of open space. In one example a low density cellular nanocrystalline material was created by electroforming nanocrystalline Ni around a rapid-prototyped acrylic photopolymer microtruss, Figure 1 [4]. Microtruss materials have periodic cellular architectures that are specifically designed to undergo stretching-dominated deformation as opposed to the bending-dominated deformation in conventional open cell metal foams [5,6]. This new cellular nanocrystalline hybrid material combined the structural efficiency of microtruss architectures with the ultra-high strength that can be achieved by grain size reduction to the nm-scale. Although it played a critical role as a cathode support during the initial stages of nanocrystalline electrodeposition, the polymer core did not contribute significantly to the inelastic buckling resistance of the composite metal/polymer struts and it may therefore be desirable to remove it post deposition by means of chemical dissolution or thermal decomposition [4]. Nanocrystalline electrodeposition can also be used to reinforce conventional cellular metals (Figure 2), creating new types of cellular composites such as metal/metal microtruss hybrids [7-10] and metal/metal foam hybrids [11,12]. For example, nanocrystalline Ni-Fe alloy sleeve thicknesses of up to 400 µm were used to reinforce an aluminum alloy microtruss that had been fabricated using a stretch-bend approach; the nanocrystalline sleeves had the effect of increasing the microtruss strength by up to a factor of twelve and the specific strength by a factor of three [8]. Alternatively, much thinner sleeves can be electroplated to produce structural coatings. In one example, a nanocrystalline Ni coating was designed to provide both corrosion protection and inelastic buckling resistance [10]. Because the ultra-high strength material was optimally located at the furthest distance from the neutral bending axis, only a thin coating of 50 µm was needed to double the inelastic buckling resistance of the 1.13 mm x 0.63 mm cross-section plain carbon steel struts [10]. Overall, the mechanical performance increase that can be obtained through electrodeposition depends on a complex interaction between the starting cellular architecture and the nanocrystalline sleeves.

Jan 1, 2010

By Manqiu Xu, Songtao Yang, Zongfu Dai, Robert Pelton, Carla Abarca

"Fine mineral particles are difficult to process by flotation because of their low collision efficiencies with air bubbles. Decreasing air bubble size and increasing mineral particle size through flocculation are the most common approaches to improve flotation efficiencies. Herein we demonstrate that nanoparticle flotation collectors can be engineered to selectively induce fine mineral particle aggregation and promote flotation.Flotation tests of clean fine pentlandite (Pn) and Clarabelle Mill (CBM) rock tails and pyrrhotite (Po) tails that contained significant amount of fine pentlandite have confirmed that the nanoparticles can serve as both collectors and selective flocculants for fine pentlandite. In the case of clean fine Pn, the nanoparticle collectors virtually can float almost all Pn fines. Scoping tests on CBM tails have shown significant improvement in nickel recovery. Addition of nanoparticles as a flotation aid can recover 20% of the nickel contained in the rock tails and 40% of the Pn contained in the Po tails compared to current mill operations giving 0% nickel recovery from rock tails and no Pn selectivity from Po tails. Ongoing work includes attempts to identify optimal strategies for employing nanoparticles in fines flotation.IntroductionFine particle flotation is an industry-wide challenge in mineral processing. Fine mineral particles are difficult to process by flotation because fine particles have low mass and thus low momentum, which results in their low collision efficiency with air bubbles (Dai, Fornasiero, & Ralston, 1999). In addition, fine particles have not only high specific surface area but also more active surface area, which causes high reagent consumption. For base metal sulphide minerals, particle size between 10 µm and 70 µm is a typical range where high flotation recoveries can be achieved with conventional flotation chemistry and acceptable cell residence times. For pentlandite, the flotation recoveries decrease sharply when the particle size is below 10 µm and hydraulic entrainment is the dominant mechanism, giving recoveries proportional to water recovery and no Pn enrichment. (Jameson, Nguyen, & Ata, 2007)"

Jan 1, 2015

By Manqiu Xu, Songtao Yang, Zongfu Dai, Robert Pelton

Five years ago, VALE Base Metals (then INCO), approached Pelton's group at McMaster and described a challenging mineral separations problem. The McMaster group has a strong track record in colloids, polymers, and chemical additives for papermaking; however, they had no experience in mineral processing. They proposed employing hydrophobic nanoparticles to replace conventional low molecular weight, water-soluble flotation collectors. Over the last five years, Vale, together with the Ontario Government (OCE) have funded two graduate students at McMaster who have worked closely with flotation experts at Vale. Experiments involving both very clean model mineral suspensions at McMaster and complex ores at Vale, have shown that hydrophobic nanoparticles do indeed function as collectors. Key nanoparticle properties and mechanisms have been identified and the technology has been protected in patent applications. Efforts to commercialize the technology are on-going. We believe that this project is a good case study demonstrating the advantages of industry-university collaboration and the use of outside experts, who may come up with novel solutions to complex problems.

Jan 1, 2011

By Manqiu Xu, Songtao Yang, Zongfu Dai, Robert Pelton

"Hydrophobic polystyrene nanoparticle suspensions were evaluated as potential flotation collectors for pentlandite. Experiments involving both clean model mineral suspensions and complex ultramafic nickel ores confirmed that conventional water-soluble molecular flotation collectors such as xanthate could be partially or completely replaced by hydrophobic nanoparticle flotation collectors. The ability of nanoparticles to induce flotation was demonstrated by floating hydrophilic, negatively charged glass beads with cationic polystyrene nanoparticle collectors. Electrostatic attraction promoted the spontaneous deposition of the nanoparticles on the glass surfaces raising the effective contact angle sufficiently high to promote the adhesion of beads to air bubbles. As little as 10% coverage of the bead surfaces with our most effective nanoparticles could promote high flotation efficiencies, whereas conventional small molecular flotation collector requires ~ 20% or higher coverage for a good recovery. Surface functionalized nanoparticles enhanced the ability for nanoparticle collectors to selectively deposit onto surfaces of the desired mineral particles in the presence of gangue. For example, poly (styrene-co-vinylimidazole) nanoparticles were designed to selectively deposit onto nickel mineral (pentlandite) in the presence of Mg/Si slime. Flotation tests of ultramafic nickel ores at Vale with these nanoparticle collectors have shown improvements in both pentlandite recovery and selectivity. On-going work includes attempts to identify specific applications where nanoparticle flotation collectors might be cost effective.INTRODUCTION Most mineral processing operations include multiple stages of froth flotation to concentrate and isolate the desired product. Before flotation, chemical collectors are routinely added to ground ore slurries, selectively binding to mineral-rich particles, increasing their hydrophobicity thus promoting selective flotation. (Fuerstenau, Jameson, & Yoon, 2007) Conventional collectors are surfactants with a short hydrocarbon tail and a head group, such as xanthate. A typical conventional collector is potassium amyl xanthate (PAX), which is a small molecule with an extended molecular length of about 1 nm. Critical characteristics of a good collector include the ability to selectively adsorb onto desired mineral surfaces and to lower the water/mineral surface energy. Despite the extensive role of flotation in mineral processing, some ores are difficult to process by flotation. For example, ultramafic nickel sulfide ore containing both valuable pentlandite and large quantities of unwanted Mg/Si slime [primarily serpentine, (MgFe)3Si2O5(OH)4] responds poorly to flotation. (Mani, Xu, Quinn, & Stratton-Crawley, 1997) Fibrous hydrophilic Mg/Si slime usually masks the surface of pentlandite (known as “slime coating”) due to electrostatic interaction (Edwards, Kipkie, & Agar, 1980) and dramatically depresses pentlandite flotation. Consequently, new approaches are required for processing these difficult ores."

Jan 1, 2012