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By M. D. Viera

The purpose of the study is to show, through real cases of companies in Chile, the different problems concerning valuing or economically appraising a mining ore resource with the traditional techniques. The study demonstrates that, with the risk analysis and real options theory application, one could determine the most probable value for a mining resource or mining business, and the risks cover of uncertainty scenarios. The study discusses different methods and criteria employed in the ore resource evaluation or mining assets. It also shows a comparative analysis of the different methods in order to explain various distortions, errors, risks and imprecisions of each of them. the companies are becoming aware of the risks' importance and the impact they have on the commercial value and resource estimation models. Now, the real options are the techniques that somehow make it possible to value and control the risk cover of the business. The company valuation could help respond questions like: ? How much is my business worth? ? How much has the investment profitability of my business been? What could be done to improve this profitability and create value?

Jan 1, 2007

By D. Zagidulin

Short term electrodeposition experiments (up to 80 min.) at two current densities 220 and 275 A/m2 with varying concentrations of thiourea and glue were performed to determine the optimum levels of glue, thiourea and current density for industrial copper electrorefining. White Light Interference Microscopy was used to acquire digital images of the morphology of the electrodeposited copper. Scaling analysis was employed to pa-rameterize the morphological information encoded in the images. The limiting rough¬ness, *, the critical scaling length, Lc, and the aspect ratio, 4*/ Lc, were determined as a function of the deposition time and the amount of organic additives. These parameters were used to calculate the dynamic exponent, B, the roughness exponent, 1/z, and the as¬pect ratio exponent, y, plotted as a function of glue and thiourea concentrations. These 3D plots allowed us to find conditions corresponding to the minimum of B and y, at which the deposited copper is characterized by a small roughness and a dense structure.

Jan 1, 2007

By Dave Bulled

"This paper describes the design of an SABC grinding circuit using CEET technology applied to grindability data produced from testing 100 samples and distributed across the blocks of a mine plan using a geostatistical approach. The data distribution required the identification of the location of the sample points and a geological plan of the 130 million ton Ruby Creek orebody together with a mine plan of about 11000 blocks to be mined during the proposed 18 year life of the mine. The mill design was then made with consideration for the estimated hardness of each block in terms of both SAG and Ball milling with allowance for annual periods when the ore is harder to grind. Operating specifications were selected to achieve an optimum of capital and operating costs through use of the CEET program. The geostatistics assigned the statistical error that arises from having a limited amount of sample testing data to the hardness estimate of each block of ore in the mine plan. The final design could then include a quantification of risk and determination of safety factors based on the accuracy of block hardness estimates and CEET model fitting.INTRODUCTIONThe traditional approach to plant design involves the extensive testing of a single large composite sample or a small number of composite samples that are reputed to represent the ore body. It is accepted that the tests used can accurately measure in the laboratory the grindability of the sample by a process representing that to be used in the plant. The size of equipment required to achieve a specified throughput and product size is then calculated from one of a variety of models that have been developed by metallurgists over years of trial and error. Since these tests and models are tried and tested, they are accepted as reasonably precise; however during the operation of the resulting plant the design is sometimes found to be inadequate. It is then suspected that the flaw in the design process lies in the samples not being sufficiently representative of the ore body, since using only a single or small number of composite samples does not recognize the variability of the hardness of the ore, nor does it allow for the lack of precision in the hardness value used in the design.This paper outlines a design procedure suited to an orebody that is described by a geostatistical analysis of a reasonably large number of small samples of drill core. The analysis required the identification of the location of the sample points and a geological plan of the orebody, together with a mine plan of the blocks to be mined during the proposed life of the mine. The mill design was then made using the estimated hardness of each individual block with an allowance for annual fluctuations in the grindability of the ore. The geostatistical analysis assigned a statistical error to the hardness estimates of blocks and of each production year such that the final design included risk estimates and safety factors based on the possible errors that arise from having a limited amount of sample data (Kosick et al. 2002)."

Jan 1, 2007

By G. Riveros

A new, continuous fire refining process for copper has been developed and tested at the 5 tph pilot scale. During oxidation, the blister copper flows through a packed bed of crushed refractory bricks counter-current to a hot oxygen containing gas. The resulting desulphurized copper flows then directly into a packed bed of charcoal for deoxidation. By controlling the air to natural gas ratio, both temperature and reducing conditions can be controlled. Based on extensive laboratory scale measurements of the rate of copper oxidation and reduction, the process concept was developed aided by process modeling and simulation. The industrial-pilot scale installation built at the ENAMI Paipote smelter in Chile, consists of two cylindrical, compact reactors, operating in line, with a designed capacity of 5 t/h of blister copper. The results of the industrial-pilot tests confirmed the feasibility of the new process. The blister copper processing capacity was increased to 10 t/h with satisfactory sulphur removal. The degree of oxidation as well the copper temperature was controlled with relative ease. The specially designed siphon block allowed for smooth tapping of the oxidized copper and separation of refining slag. The reduction of oxidized copper in the packed bed of charcoal appeared to be very effective while control of the degree of reduction according to the height of the bed ensured control of the oxygen content in the refined copper at the required level.

Jan 1, 2007

By I. Takahashi

Recently, electronic devices have become smaller for some kinds of electronic devices, thermal dissipation and electrical conductivity of conventional Fe based alloy becomes insufficient. We selected the Cu-Fe based alloy CDA19400 and optimized the wire manufacturing process. Precipitates during aging treatment were observed by TEM. The size and distribution of the precipitates varied according to solution treatment temperature. With solution treatment at 950°C, the precipitates of y-Fe as fine as 10 nm were distributed dense in the copper matrix with coherency. For the solution treatment at 750°C, y-Fe of approximately 200 nm was observed. Comparing heat resistance of drawn wires, the material at 950°C treatment was superior. Electrical conductivity decreased from 63% IACS upon aging to 29% IACS by drawing. It is considered as particular phenomena for wires where materials are drawn with high reduction ratio. By the optimized manufacturing process, we successfully developed a new wire that has superior in strength, thermal conductivity, electrical conductivity, heat resistance and repeated bendability.

Jan 1, 2007

By F. J. Guevara

A two-dimensional mathematical model for fluid flow and heat transfer in a sixin- line electric smelting furnace was developed to study the effects of temperature on slag viscosity in both the liquid and mushy zones. The model focused on the fluid dynamics of the molten slag and the effects on the formation of a slag freeze layer on the hot face of the furnace wall. Previous experimental and mathematical work, carried out under Ra number of 109 and using a fluid with Pr number of 65, showed that it is possible to mathematically describe the freeze layer formation over a vertical wall using a fixed-grid model. The chemical composition of the slag was taken into account through its effect on the viscous activation energy as well the solidus and liquidus temperatures. The results show that the flow pattern is strongly modified in areas of high viscosity, in front of the cooling system and at the slag-matte and slag-calcine interfaces. The results are discussed in terms of heat flux over the refractories and their effects on cooling system design.

Jan 1, 2007

By L. Byszynski

The results of a three month evaluation of the application of EMEW® technology at the KGHM Glogów II Smelter tank house bleed stream are presented. The current, conven¬tional electrolyte decopperization process has some limitations, including: only a fraction of its production is commercial grade cathode copper, significant operating costs, low current efficiency, low current densities resulting in low copper depletion rate, and arsine gas and sulphuric acid emission. The EMEW® cell technology developed by Electrometals Technologies Ltd. can overcome many of these limitations. Tests were performed on a pilot EMEW® installation comprising 30 cells at ambient temperature on electrolyte bleed, using current densities between 100 and 600 A/m2 , with copper concentrations between 45 and <1g/dm3. Results showed that a high grade copper can be obtained to the level of 7 g/dm3 of copper concentration in electrolyte. The use of EMEW® technology allows the direct and efficient recovery of over 85% of the copper contained in the bleed electrolyte. Glue & thiourea addition were tested in order to improve the parameters of the copper depletion process. The behavior of Arsenic and Bismuth was observed and a means for their elimination from the system proposed. On-line copper concentration monitoring is proposed to improve control and performance.

Jan 1, 2007

By H. J. McQueen

Friction stir welding (FSW) generates complex microstructures in the nugget and thermomechamically affected zones (TMAZ) that have led to diverse explanations. However, consideration as an extension of microstructure development in piercing/extrusion can lead to a better understanding of flow patterns and microstructures during FSW. Furthermore, the intense strains in the nugget/TMAZ can be interpreted by comparison with ultra-high strains in torsion that exhibit dynamic recovery as extending into regions with high angle boundaries strongly serrated with spacing near the subgrain size defined by the high temperature. The subgrain diameter and extrusion pressure have been shown to be dependent on the Zener-Hollomon parameter Z (=t exp(Q/RT), Q activation energy, R gas constant) combining temperature T and strain rate E in the same mariner as for torsion and compression. Moreover, such tests exhibited steady state stress os above a certain strain Es (rising as Z increases) in which T, , subgrain diameter and dislocation spacing remain constant. Due to the subgrain boundaries (SGB, low angle <5°, i.e.,LAB), continually rearranging by migration, decomposition and reformation, the subgrains remain equiaxed in elongating grains, whose boundaries (GB) become serrated as they migrate to absorb SGB. As confirmed by straining in torsion at constant T and Z. , more subgrains bordering the greater GB area have several high-angle facets (HAB) ; these small cellular regions with a mixture of HAB and LAB facets are designated HAB-subgrains. As serrations in neighboring grain boundaries impinge, the grains pinch off becoming shorter; this occurs at higher strains as subgrain size decreases with rising Z. The pinching-off makes the neighbors thicker so the grains never become thinner than about two subgrain diameters. In conjunction with such geometric dynamic recrystallization (gDRX), GB&apos;s undergo a net migration into grains with denser substructure, enlarging those with larger subgrains. Consequently a better name has been proposed: grain dimensioning dynamic recovery (gDRV).

Jan 1, 2007

By C. Sartain

In recent years market pressures have been building on companies to develop the next era of mining projects to follow the previous boom in copper projects of the mid 90&apos;s. However the response from the industry has been slow in coming, and somewhat muted. It is clear that there simply have not been the obvious quality projects waiting to be rapidly developed. Many of the known undeveloped copper projects have particular characteristics that have previously prevented their development, including mineralogical complexity in the ore bodies, environmental challenges or particularly difficult geographic locations. This paper describes how the Copper Division of an international mining company, Xstrata plc, is preparing to progressively develop an impressive pipeline of projects, armed with an array of proprietary technologies and with a strong approach towards sustainable development and community engagement. The approach being taken is enabling Xstrata to complement its acquisitive corporate philosophy with a management emphasis on project development and operational optimization and enhancement.

Jan 1, 2007

By R. P. Zahn

The need for quantitative mineralogical data to characterize ore types before they are processed is becoming increasingly necessary. Mineralogical data (modal abundances, grain size, liberation/locking characteristics, mineral textures and associations) can provide invaluable information to facilitate the identification of metallurgical issues that may arise during processing of a particular ore. This paper will discuss the use of QEMSCAN analysis in conjunction with bench scale flotation test work to determine metallurgical characteristics for several ore types that will be fed to the Morenci concentrator upon commencement.

Jan 1, 2007

By S. L. Chen

The Kumera Technology Center developed a unique type of steam dryer for drying copper concentrate in the mid 1990s. The dryer has been chosen in several copper smelter projects since 1999. To expand production capacities, the Norddeutsche Affinerie smelter, the Pirdop smelter of Cumerio, the Toyo smelter of Sumitomo Metal Mining and the Tamano smelter of Hibi Kyodo Smelting have carried out projects in which Kumera Steam Dryers were installed. The capacity of a single steam dryer varies from 70 t/h to 160 t/h. This article summarizes the latest operation results of the Kumera Steam Dryers in these smelters and introduces the progress of the ongoing projects in Yanggu Xiangguang Copper, Guixi smelter of Jiangxi Copper, Jinlong Copper, Boliden Harjavalta, and Onsan smelter of LS-Nikko Copper.

Jan 1, 2007

By E. Rezaei

Glue is an animal protein that is used with other organic agent such as thiourea, in copper electrorefining. The concentration of glue has to be controlled carefully, because the electro-deposition process is often very sensitive to small fluctuation in the operating variable. This additive (glue) prevents rough and nodular copper cathode deposits. The nodular deposits may grow causing short circuits, which results in losses in production. Addition agents are effective in controlling metal growth; they modify the normal nucleation and lattice growth steps and refine the grain structure. In this research glue concentration was determined in an industrial copper electrolysis plant. A non-linear model with high capability was constructed and after optimizing its parameters, the accuracy and precision of the model were evaluated. For determination of glue concentration, electrochemical voltammograms in optimum condition (Differential pulse voltammetry technique, Hpulse=50 my, scan rate=10 mv/s) were plotted. Some information from voltammograms was transferred to the model as inputs and the calibrated model analyzed the information and the glue concentration was determined with high precision and accuracy. In this way there is no need to separate or add agents to remove interferences. This method has been successfully applied at Sarcheshmeh copper complex.

Jan 1, 2007

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By A. N. Shen

Fe3A1 intermetallics are potential inexpensive candidate for hot applications. In this project, torsion tests on hot-rolled and annealed Fe3A1 (Fe-15.5A1-5.8Cr-1.0Nb¬0.05C) were carried out over the ranges 750-950°C and 0.01~1s-1 . The experimental results showed that when peak stress op>90MPa (LogZ>16s-1 , Z: temperature-compensated strain rate), specimens cracked at randomly low strains. Optical microscopy exhibited original elongated grains and many grain boundary cracks associated with segregation. With op<40MPa (LogZ<16s-&apos;), specimens deformed with low random op but considerably high fracture strains; slowly propagating cracks may explain the reduced flow stress. Optical microscopy showed both elongated grains and equiaxed subgrains with some indications of geometric dynamic recrystallization (gDRX) and of static recrystallization (SRX). Compression tests gave higher stress with little effect of the preexisting cracks. The activation energy Quw of current material in satisfactory torsion and compression tests is about 10% higher than previously published. Fe3A1 has body-centered cubic structure in the experimental range, so it was compared with ferritic stainless steel 434C (Fe- 16.55Cr-0.96Mo-0.21Ni). Constitutive constants and restoration mechanism are compared between these materials. While Fe3A1 is hardly a light metal, it is considerably lighter than most steels. Furthermore, like the other body centered cubic metals (BCC) (a-Fe, ß-Ti, ß-Zr and ß-brass), it exhibits a high degree of dynamic recovery (DRV) like Al alloys, producing easier hot workability than that of austentic stainless steels.

Jan 1, 2007

By Steven W. Wilson, Brigitte Lacouture, Nichola A. McKay

"The Aqqaluk deposit is a lead-zinc ore body that lies immediately north of the Main Pit at Teck Cominco’s Red Dog Mine in Alaska. It is scheduled to begin production in 2011 or 2012. A project team was formed in late 2004 to plan and implement an ore characterisation and metallurgical evaluation on the Aqqaluk ore. The main objective of this program was to facilitate the transition from Main Pit to Aqqaluk ore in the Red Dog concentrator. The program will develop a detailed, spatially-oriented characterisation of the Aqqaluk deposit attributes including lithology, ore geochemistry, bulk mineralogy, ore texture, as well as evaluating the metallurgical characteristics of ore hardness, process water geochemistry, bench-scale floatability and mineral liberation in ground feed, concentrate and tails. Developing correlations between the metallurgical response and the ore characterisation data is key to the emerging science of geometallurgy. This on-going program is a technical due diligence study that aims to reduce the risk associated with processing a new ore and to provide predictive information for mining and stockpile preparation.The test work to date has focused on characterising the five ore zones currently identified in the Aqqaluk deposit, namely: Siliceous (sub-divided to High Zn:Fe and Low Zn:Fe), Vein, Median Plate and Baritic ores. It identified a number of challenges associated with surface oxidation, or weathering, of the core samples and outlined a program for future sample collection and storage. Metallurgical testing evaluated ore hardness by a variety of methods. Preliminary floatability studies have been completed and some initial links have been established between the ore characteristics and the flotation response. Soluble mineral weathering products, the relative abundance of pyrite and marcasite and the iron content in the sphalerite grains have all shown a correlation to mineral recovery.As new core is received, both the ore characterisation and the metallurgical testing will be continued with a view to strengthen the existing correlations and develop new links."

Jan 1, 2007

By L. E. Gutiérrez

A new filtration model based on porous media transport theory is presented. It predicts capacity and final moisture content in the filtered cake as a function of design and operational variables at the plant. FilterSim® is the computer code where this new model is programmed. Application of FilterSim® to ten-month operation of an industrial copper concentrate filtration plant is shown on a daily basis and using a single set of internal parameters for the whole period. Average error is less than 5%, both in capacity and moisture estimation. FilterSim® abilities to optimize industrial filtration plants as well as to estimate future budgets are illustrated with several real examples.

Jan 1, 2007

By L. Treadgold

The KOV, Kananga and Tilwezembe copper-cobalt deposits in the Democratic Republic of the Congo have lain dormant for over ten years due to lack of funding by the State-owned mining company, Gecamines. Nikanor Pic through its operating company DCP has secured the mining titles from the DRC government and has commenced redevelopment of these large copper deposits. DCP plans to produce 250,000 tonnes per annum of LME Grade "A" copper cathode and up to 30,000 tonnes per annum of cobalt salts. This paper describes the geology, re-development of the KOV mine and the two smaller mines, Kananga and Tilwezembe, the design of a new copper-cobalt processing facility and the challenges in refurbishing the associated infrastructure.

Jan 1, 2007

By M. Ruel

In today&apos;s highly competitive worldwide market, it is becoming extremely important for managers to make sure that all resources are used where needed the most. That way, all resources are generating added value, process control equipments are maintained in an optimal state for best performance, and final product is produced at least cost. Performance monitoring is the only way to ensure that everyone is working on top priorities toward the same goal. How can we add value to these warehouses of data? The data is there and the information is hidden; it is just waiting to be extracted. A process performance monitoring system is able to determine if a loop, a system, a unit, or a plant meets the expected performances. The system prioritizes the areas that need attention. It also provides historical reports of the plant status by areas, by loops, and by identified problems. This information is provided to different categories of users in an appropriate format for each one. The system also includes diagnostics and tools to detect and analyze problems.

Jan 1, 2007

By C. Ciriello

Six Sigma methodology, as applied within Xstrata (formerly Falconbridge and Noranda), involves a disciplined approach to managing projects, solving problems, improving performance, and leveraging information. The four (4) cornerstones of Six Sigma are the use of Philosophy (customer driven, desire to improve and discipline), Metrics (measurement systems), Methodology (scientific method and sequence of deliverables), and Tools (such as statistics, change management, and root cause analysis). This paper will outline the general steps of the Six Sigma methodology and demonstrate how each phase directly applies to a real plant metallurgical project aimed at reducing nickel losses of the rougher flotation circuit at Raglan. The main concepts of Six Sigma are described, along with the specific challenges, successes, and deliverables related to the project. It is also the authors&apos; aim to demystify the basic Six Sigma principles.

Jan 1, 2007

By Ch. Wenzl

Anodes must have a certain physical and chemical quality in order to provide uniform anodic corrosion and meet the requirements of electrorefining, i.e. to achieve a high current efficiency, low energy consumption, low amount of anode scrap and low effort together with high cathode quality. Various properties of the anodes can be influenced directly by the casting process, which is the interface of pyro- and hydrometallurgy of copper. The aims of anode casting ? high output and long mould lifetimes ? are not consistent with good physical anode quality. The physical requirements of an anode are smooth surfaces, uniform weight and thickness, minimal edge effects, minimal distortion of the body and the lugs, as well as a homogeneous microstructure, in order to achieve uniform dissolution behaviour. The chemical quality of the anode copper is a task of electrorefining operations, but the elemental distribution within the anodes, which should be as homogeneous as possible in order to provide uniform anodic corrosion, can be influenced by the casting process.

Jan 1, 2007