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By W. de Klerk, M. B. Thorpe

Golden Star Resources Bogoso operates in Ghana’s Western Region. The gold recovery plant includes; a flotation circuit producing a concentrate for the BIOX® process that oxidizes sulphides before a CIL circuit; and a dedicated CIL circuit. BIOX® uses bacteria, therefore water from the BIOX® and CIL plants remained separated; CN water could not be introduced into the flotation / BIOX® circuit. The operation built a process water inventory with high TDS and installed a process water treatment plant (PWTP). Water was released in compliance the permits but containing some thiocyanate. The PWTP brine was returned to the TSF, further exacerbating the TDS. The operation experienced a drought removing the traditional water sources; the team evaluated the options to maintain production - various water streams were laboratory tested provided options for water use. The paper presents the story (treatment chemistry and process chemistry) of continued operations by treating stored water and PWTP discharge water with peroxide; brine usage within the CIL circuit, which increased gold recovery (laboratory testing) and reduced the TDS. Water flows were further modified to include hydraulic tailings re-mining to a CIL circuits. Details of the recovery, basic chemistry and costs savings are provided.

Jan 1, 2014

Applying DEM to prediction of tumbling mill performance is challenging because several different modes of breakage are active in the process. As our knowledge of breakage and computational capacity improve, it is worth revisiting previous simulation tasks which did not produce a satisfactorily realistic description of a measured process. At SAG 2006, we reported the simulated and measured outcomes of treating a well characterised ore in a 1.2 m diameter mill. This well instrumented, pilot scale mill at the University of KwaZulu-Natal has been combined with some new approaches to ore testing to allow different modes of breakage to be tested. The mill design allows the rate of generation of fine material to be measured in close to real time for autogenous and SAG mill charges. The updated simulation model estimates mass loss with particle evolution and embeds the cumulative damage and breakage. The simulated results are compared with the measured results. Issues such as relating modelling inputs to particle breakage characterisation data and the accuracy of the predictions of the models are discussed.

Jan 1, 2012

By Raja V. Ramani, Sukumar Bandopadhyay

"The dispersion of diesel contaminants into the mine atmosphere is a variant of general class of diffusion-dilution problems relevant to underground mining practice. The equipment operations in underground mining are characterized by different activities with different time duration s, i.e. varying duty cycles. Therefore the volume and quality of diesel emissions and consequently, instantaneous concentrations are quite variable. Design of mine ventilation systems under these conditions becomes complex. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport in the design of ventilation system are discussed.IntroductionThe turbulent diffusion of suspended matter in an atmosphere is not only a topic of considerable intrinsic interest to the mathematical physicist and meteorologist, but also a problem of great practical interest. Release of particulate matter into the atmosphere at large has created o ne of the acute problems of the present day. Pollution of environment by industrial and domestic smoke, fumes and grit is widespread and has necessitated extensive studies in order to determine the concentration and distribution of pollutants in various areas. Pollutants discharge from stacks, whether chemical or radioactive, give rise to similar, but more localized, problems. The laws which govern turbulent diffusion in the atmosphere are also applicable to the study of the diffusion of toxic gases and the deposition of radioactive dust from nuclear explosion.The dispersion of diesel contaminants into the mine atmosphere is but a variant of a general class of diffusion-dilution problems relevant to underground mining practice. Most of the mine air pollutants, such as respirable dust, methane, diesel exhaust, and blasting fumes are produced in the face areas and haulage ways. Understanding of their dispersion in the mine airways is important to calculate their concentrations. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport are discussed. The over-all objective of this research effort is to evaluate the impacts of dieselization on production and ventilation systems and to aid in mine planning and design, as shown in the flow model in Figure I."

Jan 1, 1983

By W. J. Bennett

"I AM very happy to have this opportunity of speaking to the Montreal Branch of the Canadian Institute of Mining and Metallurgy.I have selected as the subject of my remarks transportation in that area which is at present our only source of uranium -Northwest Canada. Considering the widespread interest in atomic energy, the end-product of uranium, it may be wondered why I have not chosen to speak of a more spectacular aspect of the development. I hope it will be evident from what I have to say that transportation plays a very dominant role in our effort to maintain a continuing supply from Eldorado's producing property at Port Radium on Great Bear lake and from its coming producer at Beaver lodge Lake in Northwest Saskatchewan. Moreover, transportation has such a bearing on the entire mineral development of the Northwest that it cannot help but be of concern to an organization of this kind. Finally, the transportation problem, of which I shall try to tell you something, is quite unique and the story of its solution or partial solution is, I believe, an interesting one.Transportation experience on this continent indicates that the cheapest method of moving freight is still by water -with •rail, highway, and air transportation following, and in that order •of economic significance. Excluding rail transportation, since the area has as yet no railway lines, this order also applies in the Northwest. I shall direct my remarks to the two kinds of transportation which serve our uranium producers -water and air."

Jan 1, 1952

By P. K. Frempong, S. D. Butt

"A case study for the application of a novel geostatistical technique for resource estimation of a narrow steeply dipping, gold-silver mineralized quartz vein deposit is presented. The technique is novel in two respects. First, mineral grades are kriged directly rather via the accumulation method more often applied to vein deposits and, second, a modified 2D ordinary kriging algorithm is used that allows the calculation of a single grade and variance for irregular shaped blocks of varying sizes. The objective of this investigation was to evaluate the suitability of this novel geostatistical technique for resource estimation of the Poura mine deposit and, if appropriate, to lay a firm foundation for future geostatistical work at the mine.The reserve estimation concentrated on the remnant ore blocks and pillars in both underground and surface workings. The data, which was collected in 2D coordinates with grade and vein thickness values, was first analyzed statistically and used to compute experimental semi-variograms. Appropriate semivariogram models were fitted and various aspects of the estimation technique were evaluated using cross-validation error analysis, with acceptable results. A block kriging computer program called Krige2D was developed to implement the modified 2D kriging algorithm and calculations. Production data were not available to evaluate the computed block resources, but they were compared with a previous resource data determined using an arithmetic approach. The geostatistical technique estimated slightly higher grades but lower overall tonnages as compared to the earlier arithmetic estimates."

Jan 1, 2004

By Sergio Fuentes

During the past fifteen years, mines utilizing the block caving method have improved performance and systematically reduced total mining costs. This paper describes improvements in mine design, mine planning and mine management, including methods enabling the Chilean and International mining industry to ensure cost savings and productivity growth while using the block caving method. These improvements have encouraged the re-evaluation of underground operations at operating and closed open pits, and challenge surface mining applications as the only low cost mining method. This paper describes a strategy to estimate the optimum open pit to underground transition time during the life of a mine.

May 1, 2003

By H. A. Dakin

"An introduction to the metallurgical requirements of the Flin Flon concentrator reveals the magnitude of ore blending which is required in its operation of three flotation circuits. The resulting variability in flotation heads which has in-creased the separations complexity justified the development of an on-line analysis system.This paper provides a summary of the development and operation of that system. Particular attention is devoted to the problems encountered and where possible their solutions; as the requirements of accurate information and minimum downtime of the sampling system and x-ray analyzer are considered essential. The addition of a recess central computer has provided information in a more easily understood form and as well has allowed the start of automatic reagent control.An indication of the on-line analysis system's value to the concentrators' operation is provided by an examination of the plant in metallurgical data and reagent costs in previous years.The metallurgical plants of Hudson Bay Mining and Smelting lie adjacent to the city of Flin Flon on the Manitoba-Saskatchewan boundary. Plant operations commenced in 1930 treating copper-zinc ore from the local mine. In recent years ore bodies near Flin Flon and in the Snow Lake area, about seventy-five miles east, have been brought into production.By the beginning of 1973 the number of producing mines had increased to nine; with all the ore being handled by the Flin Flon concentrator. Figure l, showing mine ore assays during 1973 indicates the variation in metal content possible."

Jan 1, 1974

By Imre Gombköto, Barnabás Csoke

"Raw material management means not only mining and processing of primary raw materials like ores, but means also collecting and processing secondary sources of raw materials. Recycling is one of the most developing field of raw material management in Europe, and its solutions are derived from mineral processing roots and principals. Complexity and challenges of the field of recycling results innovative solutions of material processing- Since European Union identified 20 raw materials as critical (CRM) due to lack of primary sources within the border of the EU, recycling become more recognised as source of different raw materials. WEEE is the waste streams contains many of the critical elements and along them at least 15 different species of plastics of which recycling is delayed by a lack of effective separation technique. Most paper deals with separation methods based on different specific gravity, triboelectric charge or surface properties of plastic species. Plastics however have differences of thermal properties and thermoplastics, duroplasts and elastomers can be recognised. The experiments described in the paper aimed to determine thermo adhesive behaviour of plastic species often identified in WEEE streams for separation purposes. According to the results, some plastic types as PS, PP. PC or PVC and PET pairs are possible to easily separate from each other, however different additives are changing thermo adhesive properties of most of the plastics that makes industrial process difficult to develop. Along thermo adhesive behaviour, combination of physical interaction can be used to enhance separation selectivity.INTRODUCTIONPlastics has a relatively long term of history as a light, multi-functional material in construction, packaging, automotive industry and electric and electronic products. There are a numerous types of plastic species can be used for various applications therefore they amount are growing from year to year. This quantity however become part of the waste stream and while metal recycling has been done for decades due to its economic value - cheap plastic parts are less desirable as secondary products. In 2013 an annual 5% of plastic production growth has been estimated with a base data of 265 million tonnes at 2010 (Guiqing & Zhenming, 2013). Since landfill requirements are increasing while—especially in Europe where actual regulations are trying to deflect waste from landfills - landfill capacities are decreasing, costs are become more and more expensive, Applications like energy production based on plastics as a fuel or recycling are some of the options can be applied. Direct incineration of plastics are applied at many plants - in most cases where waste consist of dangerous substances are incinerated because plastics high calorific value helps correct average mixture composition enable operators reaching high enough temperature for combined power and heat generation while most of substances—like PAH, PCB or dioxins—are destroyed. Another path is using low temperature reductive cracking due to pyrolysis process, however the chance having higher concentrate of carcinogen substances in the products are higher since it applies around 400°C during the process."

Jan 1, 2016

By John G. McCamis

The Maritimes Carboniferous Basin is the largest intermontane basin in the Appalachian Mountain System, occupying a total area of 57,200 square miles and containing up to 30,000 feet of late Devonian through Permian .sediments. Deposition began with continental elastics in late Devonian and early Mississippian. Marine deposition is represented by a limestone-evaporite sequence of late Mississippian age. Pennsylvanian and Permian continental rocks deposited largely in flood-plain and swamp environments complete the succession. Marine seismic data disclose several varieties of structure, both halokinetic and tectonic in origin. Recent exploratory drilling in the offshore part of the Basin encountered good reservoir rocks in the Riversdale sandstones, which also provided encouraging shows. The most likely source rocks of hydro~ arbons in the Maritimes Basin are shales in the Horton and Riversdale groups. Potential recoverable reserves of the Maritimes Basin are estimated to be 400 million barrels of oil or 7.8 trillion cubic feet of gas, based on the volume-of-sediment method of calculation.

Jan 1, 1973

By S. M. C. Santos

Preliminary bench-scale studies were carried out on the leaching of a zinc sulphide concentrate from Somincor, Portugal, and the purification of the resulting pregnant solution using solvent extraction techniques. The sulphide concentrate contained 36% Zn, 36% S, 2% Fe and 4% Cu. The leaching was carried out with sulphuric acid in the presence of ferric sulphate as the oxidant. Important leaching parameters, such as the effect of reaction time, the solid-liquid ratio, temperature and concentrations of acid and oxidant, were investigated. After leaching, the recovered solution was contacted with an organic phase containing Acorga 5640 to remove the copper. Subsequently, the removal of iron from the leaching solution was achieved with a mixture of Cyanex 272 and TBP. This solvent mixture was relatively selective for iron over zinc. The stripping of the loaded solvent was performed with 200 g/L H2SO4. Six countercurrent extraction stages achieved a separation of about 99% of the iron from the leaching solution. The iron-free leachate can be further treated to recover minor metals by cementation, and finally, zinc by liquid-liquid extraction. The advantages of the suggested process relative to the traditional jarosite process are discussed.

Jan 1, 2006

This paper comprises a description of on-stream analysis instrumentation, including sample handling, X-ray optics and data processing. It also includes a discussion of some typical applications of an on-stream analyzer as related to the mineral processing industry. Introduction T WO automatic X-ray spectrometers have been developed for the simultaneous analysis of as many as six elements in a given sample. These instruments, namely the On-Stream Analyzer and the new Vacuum Simultaneous Spectrometer, have been designed specifically for process control in industry where large numbers of static samples or a number of flowing sample streams must be analyzed continuously with both speed and accuracy. This paper is concerned particularly with the application of these instruments for the continuous analysis of dynamic samples. The Instruments The On-Stream Analyzer and the Vacuum Simultaneous Spectrometer are intended to serve industry by offering two basic approaches to the problem of continuous sampling of flowing sample streams. The On-stream Analyzer (Figure 1) is designed for the completely automatic and unattended analysis of flowing sample streams in a programmed cycle of operation.

Jan 1, 1965

By T. Lux, H. -J. Krassnig, I. Filzwieser, E. Hecker, R. Degel, A. Filzwieser

Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions for the primary copper production lines as well as for non-ferrous metals starting with the primary smelting of concentrate and ending with the electrolysis. PolyMet Solutions provides the process know-how whereas SMS group supplies the plants and equipment and Mettop the key components. SMS group and Mettop also cooperate in the field of tankhouse technology. Together with Montanwerke Brixlegg AG, Mettop has developed together with a parallel flow technology (METTOP-BRX Technology), allowing a current efficiency of above 98 % at a current density of 420 A/m², which is a milestone in copper electrolysis. For the secondary copper production route, SMS group and PolyMet Solutions developed an innovative refining furnace (PolyRefine) for the smelting and refining of copper scrap. The refined copper is directly charged to the Contirod line to produce copper rods and wires. The innovative cooling solutions of SMS and PolyMet Solutions come into play where furnaces have to stand the highest loads and stresses, for instance in areas of very high temperatures or temperature fluctuations, aggressive exhaust gases and slags, or at critical spots such as taphole areas. Custom-tailored cooling systems for furnace vessels make sure varying loads are compensated in a targeted and effective manner. The solutions include air cooling, spray cooling, cooling technologies with integrated copper elements such as CFM (Composite Furnace Modular) cooling systems, plate and finger coolers. The major innovation in the field of furnace cooling is the ILTEC (Ionic Liquid Cooling) Technology which paves the way for increased plant safety. This revolutionary, patented cooling technology is jointly marketed by Mettop and SMS group. It permits water-free cooling to be implemented and thus makes operation safe wherever it is applied. INTRODUCTION Non-ferrous metals or NF metals are changing the world. There is no modern industrial sector that can do without these valuable metals. Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. The importance of the non-ferrous metals market is reflected by two figures. In 2018, the production of non-ferrous metals was worth more than 237 billion Euros. This contrasts with 255 billion Euros of the value of iron and ferro- alloy production in the same year (International Organizing Comittee for the World Mining Congresses, 2018). Hence, the NF metal industry is almost as important as the iron and steel industry. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions and to enhance customer value. The prices of nearly all metals have come under pressure during the past few years. Therefore, competitive technologies are regarded a crucial factor to achieve success in this critical market situation respectively to stabilize the market position.

Jan 1, 2019

By M. Drozd, M. Somppi, Z. Yamak

"Granular activated carbon is widely used in the gold mining industry for gold extraction from aurocyanide-containing slurry. The extraction process can employ carbon as part of the gold recovery operation for various circuit designs including carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) circuits. However, various qualities of activated carbon exist and the durability of the material can change significantly from source to source. Handling this expensive reagent can pose challenges when fine carbon losses occur in the CIP, CIC, and CIL circuits. Additionally, any gold that is adsorbed to these carbon fines can also be lost by various mechanisms including carbon attrition and fracturing, inefficient coarse-fine separation, and poor carbon fines capture. With the above in mind, a series of tests were conducted to investigate standardizing simple laboratory methods for testing carbon quality. A standard procedure beyond or enhancing ASTM methods can serve as additional starting points for evaluating carbon specific to the gold industry. The investigation focused on size distribution, flatness, wet attrition resistance, surface area, gold kinetics, and gold loading. The final results provided information to generate an equation for ranking carbon samples to plant performance.IntroductionActivated carbon for use in gold extraction is amongst the most commonly found processes in modern gold-milling plants. Although gold losses are inevitable in the milling process, operators often focus on the importance of maximizing gold recovery. One focus area that is important in gold recovery is optimizing the use of activated carbon and examining potential changes to realize improved economics for carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes."

Jan 1, 2017

By S. P. Narayan

The hot deformation behavior of Pure Mg and Mg-0.29Ce alloy were studied by isothermal hot compression tests in the temperature range of 250 - 500°C and strain rate range of 10-3 - 102 s-1 in a computer-controlled 50kN servo hydraulic universal testing machine (UTM). The results show that the flow stress of Mg pure and Mg-0.29Ce alloy increases with strain rate and decreases after a peak value, indicating dynamic recovery and recrystallization. Process efficiency was increased by nearly 10 to 12% by addition of Ce in Mg. Mg pure exhibits instability zones between 250-275°C at 10 ? 102 s-1 and 400¬500°C at 101 ? 102 s-1 temperatures and strain rates respectively, rest is the safe deformation zone. Wherein, Mg-0.29 Ce exhibits two low efficiency zones from 250 ? 300°C at 10-2? 10° s-1, 400 ? 500°C at 101 ? 102s-1 and high efficiency zone at 450 ? 500°C at 10-3? 10-1s-1. 4D process maps were generated for the above said alloys which illustrate contours of power dissipation and instability in the 3D space of strain rate, temperature and strain.

Jan 1, 2011

By B. Lueger, D. Shen, M. Sedighy, R. Rand, R. Saleh, J. Cheung, M. Rifai, I. Khan, W. Sauri, D. Setianto

The world’s first active power demand stabilization system for a 3-electrode electric arc smelting furnace was commissioned at PT Vale Indonesia in December 2012 on Furnace No. 2 using an SPLC (Smart Predictive Line Controller). The SPLC technology in combination with the Furnace No. 2 rebuild and other upgrades has enabled PT Vale to increase the electrical input to the furnace by up to 20% on a stable and sustainable basis by eliminating peak powers that overload and trip out the electrical equipment, and by reducing power unbalances. The SPLC technology maintains smooth arc power using a continuously variable thyristor controlled series reactor. The SPLC compensates variations in the furnace arc with predictive changes in the circuit reactance at a speed of up to 60 times a second. The system started up quickly and has been shown to be easy to operate and maintain by PT Vale. PT Vale’s Operations Team has been testing the new system at set points of up to 90 MW on the newly re-built Furnace No. 2. Over the last 12 months, the throughput of Line 2 has increased by approximately 10% on an annual average; however, debottlenecking in other design areas of the operation is required in order to achieve 90MW operation on a sustainable basis. This outstanding success results from a combination of the furnace and other upgrades, the SPLC active power stabilization, and the skill of PT Vale in quickly adopting new technologies and maximizing the combined benefits of each technology in their operation.

Jan 1, 2014

By T. Nyabeze

This paper presents the experiences and views of women involved in the mining industry as determined from a questionnaire that was circulated across the Canadian mining industry. Globally, there have been significant studies done to understand the historic and global variety of women?s participation in this industry1. The reason for focusing on women?s experiences here in Canada is because women?s percentage representation at 14.4% in the mineral industry workforce falls below the overall labour force average of 47.4%2. Notably, a recent article in the Globe and Mail newspaper points out that adequate representation of women in leading of organizations is more of a matter of competitiveness and innovation rather than purely a ?women?s issue?3. This paper will provide some insight into the reasons why women join and stay in the mining industry and shed some light into the reasons for the overall low representation in this sector. The authors believe, as stated in a study from the London Business School, that a gender-balanced workforce is one way of providing the best results in areas that drive innovation4. Women represent a key stakeholder group that can help enhance the mining industry?s sustainability through innovation. The women who responded to the questionnaire represent many different areas within the mining industry, including a broad range of roles in industry, government, academia and in the supplies and services sector. The paper is intended to raise awareness about issues that women encounter that contribute or detract from career satisfaction in the mining industry. The survey provides an overall understanding of why women pursue or work in mining, and why women either remain or choose to leave it. The advantages and disadvantages experienced by women are highlighted, along with a summary of the possible initiatives that could be undertaken by employers as opportunities to improve the attraction of the mining industry for career minded women. As well, the survey provides a summary of the top ten features that are already in place at various organizations and community groups that have been identified as key for supporting and encouraging women to join and remain in the industry. Not surprisingly, the survey identifies that one of the key ingredients for retention of women in mining is the provision of mentors and sponsors. Another key aspect for retention is the provision of progressive employment policies that address the need for a degree of flexibility in work hours and a culture of balance between work and personal life demands. The survey and results are portrayed only from a female perspective since it is largely women?s perceptions that will inevitably be transmitted to others who plan on entering the field.

Oct 1, 2010

By Z. Trojanová

The deformation behaviour of ternary magnesium alloys AJ (Mg-Al-Sr) and AX (Mg-Al-Ca) were investigated in tension as well as compression tests. The samples were deformed at temperatures between 20 and 300 °C and at an initial strain rate of the order 10-4 s 1. The flow stress decreases with increasing temperature. The macroscopic work hardening rate decreases with increasing flow stress and temperature. The stress and temperature dependence of the work hardening rate is a result of the hardening and softening processes. Stress relaxation experiments were performed in order to reveal features of the thermally activated dislocation motion. Internal and effective stress components of the applied stress were estimated. A decrease in the internal stress was observed at elevated temperatures, which indicates recovery process (-es). A more detailed analysis of the estimated values of the activation volume and activation energy helped to interpret the thermally activated processes during plastic deformation. It is concluded that the deformation behaviour of the alloys depends on the activity of non-basal slip that is strongly influenced by temperature.

Jan 1, 2007

By Parissa Mirjafari, Ron Martel, Susan A. Baldwin, Luke Moger

Mine drainage contains metals and sulfate, which may be toxic to aquatic life at certain concentrations and should be removed to acceptable levels before release of any drainage to the environment. One method for treating mine drainage is passive treatment, which is increasing in popularity due to lower construction and operating costs. This method is based on the activity of sulfate reducing bacteria (SRB) respiring on sulfate while using fermentation products from decomposing complex organic materials. The product of this biological process is hydrogen sulfide, which reacts with metals in mine drainage and precipitates them as metal sulfides. However, in practice passive treatment systems are not always effective, reducing the reliability of this approach. In this study, a mixture of hay, cow manure and wood chips was tested in continuous flow experiments for efficacy at sustainable treatment of sulfate and selenium containing water from a mine tailings pond. Factors that contributed to a decline in performance included lowering of the pH due to acids leaching out of the organics, re-oxidation of sulfide back to sulfate and a reduction in dissolved organic compounds over time. In this paper methods are described to overcome these problems so that treatment is made more reliable.

Jan 1, 2011

By A. G. Scobie

A spectrographic method for the determination of small amounts of gold and the platinum metals in ores has been developed. By means of this method, an assay of 0.001 ounce per ton on one assay ton samples is possible, and by seecrrographic adjustments the sensitivity may be increased to 0.0001 ounce per ton. All the prec10us metals may be determined from one spectrographic arcing with an accuracy of about 5 per cent average deviation from absolute values, and the complete analysis of an ore or similar product may be reported five or six hours after receipt of sample.

Jan 1, 1945

By Golaleh Riahi

An original method is used to obtain stable nanoparticles of gold-based mono- and bimetallic systems supported on an acidic zeolite. This approach has been applied to PtHY (1wt% Pt) and to bimetallic Pt-AuHY containing 1% of platinum to which is added the amount of gold required to give Au/Pt molar ratios of 20,40,60 and 80%. Metal clusters of Au or Pt-AuHY are formed inside the supercages of the zeolite framework by the thermal reduction of cations by the ligands (en = H2N-CH2-CH2-NH2) under inert gas flow at a temperature depending on the metal. The use of acidic zeolites favours the dispersion of the metal and the thermal stability of the particles. This stability is explained by chemical anchoring of metal clusters by the Brønsted sites of the support. Several techniques have proved that for a molar ratio of 20% metal particles of Pt-AuHY are bimetallic. The segregation of Pt and Au starts for molar ratio =?40%. The catalysts tested on the methylcyclopentane hydroconversion reaction reveal that the addition of gold to platinum leads to an increase in the activity and an improvement in the selectivity for isomerization of the skeleton (cyclohexane and benzene) to the detriment of hydrogenolysis. Similar results were obtained for the dodecane isomerisation to isododecane. These catalysts were also tested in CO, propene and propane oxidation. The activity of fresh catalysts is rather low. It increases after their pretreatment in oxygen or hydrogen atmosphere. In propene oxidation in the reaction mixture O2 ? H2, beside total oxidation of propene to CO2, also propene hydrogenation was observed, particularly at low temperatures. The presence of Au enhances the hydrogenation properties: high selectivities (> 90%) to propane and high propane yields on PtAu HY are observed up to ~150oC, whereas for Pt HY catalyst the selectivity and yield to C3H8 decreases rapidly with the temperature beginning from ~100oC.

Oct 1, 2003