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By E. S. Yan, R. Graley

"The StackCell was developed to overcome the engineering and design challenges that are commonly associated with existing flotation technology such as pneumatic, self-aspirating cells, mechanical cells, and flotation columns. These challenges include high energy consumption, large floorspace requirements, and size. They are most evident when designing systems to process streams containing a high volumetric flow rate coupled with a significant float yield. Unlike many metalliferous and industrial mineral applications, fine coal flotation circuits are typically characterized by feed streams containing a low solids content (<5%, by weight) where up to 85% of the feed can report to the product launder. With input from major engineering houses and end-users, the Eriez Flotation Division (EFD) developed the StackCell technology with the goal of providing an additional flotation option for end-users. This technology was designed specifically to overcome these challenges by providing an efficient method of separation in terms of metallurgy, but also with respect to equipment size, energy consumption, and installed costs. Besides being placed in tandem with existing cells to provide cost-effective supplemental capacity, this technology can be installed in a stand-alone arrangement as recently demonstrated at Patriot Coal’s Kanawha Eagle preparation plant. This manuscript provides an understanding of the underlying fundamentals of this new technology and presents data from Kanawha Eagle in addition to other industrialscale installations.INTRODUCTIONOver the past decade, column flotation has continued to gain acceptance as an alternative method for recovering fine coal due to superior metallurgical performance as compared to mechanical flotation cells. This point has been proven on numerous occasions by comparison of plant flotation data with the release analysis separation curve (Dell et al., 1972). Data from a release analysis test approximates the ultimate flotation response of a coal sample. In North America, a number of investigations have been published that document bottom-line improvements achieved using column cells (Luttrell et al., 1999; Kohmuench et al., 2004; Baumgarth et al., 2005). According to these reports, the benefits are derived from an overall increase in plant yield that can be achieved due to the improved product grade in the flotation circuit. In particular, the application of wash water to a deep froth utilized in column flotation minimizes the nonselective recovery of high-ash ultrafines that are hydraulically entrained in the froth by conventional flotation machines."

Jan 1, 2013

By B. D. Pandey, D. Bagchi, Premchand

During the separation and recovery of metals from the ammoniacal leach liquor of Indian Ocean nodules by solvent extraction-electrowinning (SX-EW) in close-loop operation, the copper electrolyte containing ~40g/L Cu, 20 g/L Ni and 180 g/L sulphuric acid is bled-off to control the impurities. The recovery of copper and nickel as powders has been examined from the copper bleed solution following partial decopperisation, crystallization of mixed sulphate of the two metals and aqueous hydrogen reduction. From the dissolved sulphate solution containing 17.68 g/L Cu, 18.83 g/L Ni and 0.03 g/L Fe, the copper powder was precipitated at initial hydrogen pressure of 26 bar in an autoclave in 90 min at 140 °C. The residual copper from the spent solution was removed as sulphide and nickel powder was then recovered (99%) in two stages from a solution of pH 4.5 at 40 bar pressure and 190 °C. However, 98% nickel recovery in one stage was achieved when hydrogen reduction was carried out from an ammoniacal solution in the pH range 9-11. Copper and nickel powders were produced from the bleed solution with acceptable purity and specifications suitable for P/M applications.

Jan 1, 2004

By R. Matusewicz, A. Kaye

Ausmelt Top Submerged Lancing (TSL) Technology has gained widespread commercial acceptance in non-ferrous applications, including the processing of lead and zinc primary concentrates and secondary (post-consumer) materials. TSL is highly flexible and efficient, and is one of the few technologies which can process primary and secondary feeds, and use varying fuels, to deliver high recoveries and excellent environmental performance. With the recent high value of both lead and zinc, and an escalating awareness of the sustainable use of resources, focus on the processing of secondary feed material sources has surged. Ausmelt Technology has proven to be well suited to the economic recovery of values, with twenty-two (22) Ausmelt furnaces processing lead and zinc bearing feed sources now in operation, under design or construction. This paper describes Ausmelt&apos;s progress in the fields of lead and zinc processing, and developments in new processing areas such as EAF dust processing and linking to innovative hydrometallurgical technology. Ausmelt has recently committed to the Whyalla Zinc project as the owner/operator of a facility for the treatment of zinc bearing secondary feeds. This project is due for start up in the first quarter of 2008.

Jan 1, 2008

By François Robert

"The Eastern Abitibi Sub province (Quebec segment), contains two main types of gold deposits: the common quartz-vein type and the rare pyritic type. Both occur in areas dominated by volcanic rocks and are spatially associated with major fault zones.Quartz-vein gold deposits consist of simple to complex networks of quartz-carbonate-pyrite veins in reverse shear zones and extensional fractures. They occur in areas dominated by mafic volcanic rocks and are commonly associated with small syn- to late-tectonic porphyritic felsic intrusions. Associated alteration, which postdates peak metamorphism, is dominated by carbonatization, sericitization and pyritization of the wallrocks. These deposits formed late in the geologicalevolution of the Abitibi.Pyritic gold deposits range from deformed massive sulphide lenses to zones of syntectonic pyrite-rich veinlets and associated pyrite disseminations. These deposits occur in environments dominated by felsic volcanic rocks that are typically converted to sericite schists near the deposits. The associated pre-metamorphic aluminous alteration is now characterized by metamorphic sericite, andalusite, kyanite and chloritoid, overprinted by a late retrogression of alumino- silicates. These deposits probably represent deformed volcanogenic massive sulphide deposits, but the timing of gold introduction in these is not fully understood.The differences in geological attributes reflect significant differences in the genesis these deposits: the pyritic deposits probably have a multistage genesis, including a pre-tectonic stage, in contrast to a single stage late-tectonic genesis for the quartz-vein deposits.RESUMELa partie Est de la Sous-Province de l’Abitibi( segment québécois) renferme deux types de gites d' or: ceux de type ""veine de quartz"" et ceux, plus rares, de type ""pyriteux"". Ces deux types se trouvent dans des secteurs particulièrement riches en roches volcaniques et mantrent une association spatiale avec des zones de failles majeures.Les gites de type ""veine de quartz"" correspondent à des réseaux de complexité variable de veines de quartz-carbonate-pyrite se développant dans des zones de cisaillement inverse et des fractures de tension. Ils se concentrent dans les régions dominées par des roches volcaniques mafiques et s’associent fréquemment à de petites intrusions porphyriques felsiques syn- a tardi-tectoniques. L’altération associée ace type de glte est postérieure à la phase majeure du métamorphisme et consiste en une carbonatisation, une sericitisation et une pyritisation des épontes. La mise en place de ces gites est tardive par rapport à l'évolution géologique de l'Abitibi.Les gites d' or de type pyriteux consistent en des lentilles de sulfures massifs déformes, des zones d' abondantes veinules pyrite uses syntectoniques, et des zones de pyrite disséminée. Ces gites se retrouvent dans des empilements contenant surtout des roches volcaniques felsiques qui sont transformées en schiste à séricine pres des gisements. L’altération a l’umineuse pre-metamorphique associée a ce type de glte a donné naissance, lors du metamorphisme regional, a la sericite, a 'andal ousite, a Ia lcyanite et au chloritoi""de; par la suite, les alumino-silicates ont été affectes par une alteration retrograde tardive. Ces gites representent probablement des depOts de sulfures massifs volcan gènes déformes, mais la chronologie de la mise en place de l'or dans ceux-ci est encore mal comprise.Les caractéristiques géologiques propres à chacun de ces types de gites reflètent des conditions de formation différentes: le type ""pyriteux"" montre une histoire génétique polyphasée, incluant une étape pre-tectonique alors que le type ""veine de quartz"" s’est développe au cours d’une seule phase tardi-tectonique."

Jan 1, 1990

By John Wightman

LOCATION OF PROPERTY THE property of Caribou Gold Mines, Limited, is situated in the north-eastern part of Halifax county, seven miles south of the Canadian National railway line at Upper Musquodoboit. Approach to the village is by a secondary road, improved recently by waste rock from the mine dump. A two-wire telephone line, seven miles long, built and owned by the present operators, provides communication to the nearest telephone exchange, Parker&apos;s Corner. HISTORY In 1870, the Caribou area was recognized as a proclaimed gold district. From then on, operations were intermittent, with periods of considerable activity by small companies until there were no fewer than seven mines in a district two miles long by three-quarters of a mile wide. These were the Holman, Truro, Caffrey, MacDonald or Elk, Lake, Dixon, and Hilchey properties, all of which have had separate stamp-mills, and have produced gold for varying periods. Depths of the workings range from 100 feet to 1,000 feet. Power was generated at each property by means of steam boilers. At the present time, the Consolidated Mining and Smelting Company of Canada, Limited, controls all the leased areas, approximately 800 acres, and is operating by means of one central vertical shaft. GEOLOGY The district in and about Caribou Mines has an elevation of approximately five hundred feet above sea level. The area is fairly well wooded, with rock outcrops here and there. These outcrops, along with information from test-pits and shafts, have been the basis for the very excellent geological map of the district prepared by E. R. Faribault some years ago. The rock structure, which is one of the best examples in Nova Scotia of an elliptical dome, has its anticlinal axis in a northeast-southwest direction, and flat plunges in the same directions.

Jan 1, 1938

By M. J. McLeod, D. R. Lux, R. P. Taylor

"The Mount Douglas Granite constitutes the eastern part of the Saint George Batholith and contains the youngest, most differentiated phases of the batholith. It also contains extensive endogranitic, low-grade. Sn- W-Mo-bearing sheeted vein systems. Early phases of the Mount Douglas Granite are coarse- to medium-grained, seriate granites that represent the slowly cooled carapace of the intrusion. Late phases are medium- to fine-grained, equigranular and porphyritic granites that were accompanied by repeated and widespread fracturing of the carapace and injection of mineralizing fluids. These granites represent a highly differentiated suite with ""A "" type affinities developed in a ""within plate"" transitional to ""syn-collision"" tectonic setting. 4oAr/ 39Ar dates for biotites from the various phases indicate emplacement circa 367 Ma.The linear distribution of some phases in the Mount Douglas Granite and the systematic orientations of sheeted veins along tensional fractures indicate structural control on granite emplacement and vein distribution. This type of relatively passive endogranitic mineralization is unique in the granites of southern New Brunswick and contrasts markedly with highly fluidized systems operative elsewhere in the area. IntroductionInvestigation of Sn-W-Mo occurrences in New Brunswick has shown that most of this mineralization is associated with late, highly differentiated phases of post-orogenic (Acadian) granitoid magmatism that occurred during Devonian and Early Carboniferous time (Ruitenberg and Fyffe, 1982; Taylor et al., 1988). The polymetallic Mount Pleasant Sn-W-Mo deposit (Ruitenberg, 1967, 1972; Kooiman et al., 1986)and the Burnt Hill W deposit are two orebodies of this type in New Brunswick. Numerous smaller deposits associated with these granitoid rocks in southwestern New Brunswick have been documented in previous investigations (Ruitenberg, 1967, 1968; Ruitenberg and Fyffe, 1982; Taylor et al., 1985; Lentz, 1985)."

Jan 1, 1988

By Jerry Gagnon, Matt Burr, Timothy Ellis, Abbas Mirza, Larry Webb

"The mechanical properties of RSR anode alloys (lead-calcium-tin, 009+ and lead-strontium-tin) were investigated as a function of time with an objective of developing lead anodes for use in high temperature electrolytic processes such as in copper liberator cells and in cobalt and nickel electrowinning. At a temperature of 70 oC, the mechanical properties of rolled RSR lead-calcium-tin (PbCaSn) alloy currently used in copper electrowinning decreased gradually while the mechanical properties of rolled RSR lead-strontium-tin (PbSrSn) decreased relatively quickly and stabilized at low strength levels. Cast PbSrSn started off as the weakest alloy but its properties remained stable with time. Rolled RSR 009+ anode alloy showed improvement in ageing properties over the other alloys tested. However, its mechanical properties did not stabilize in the study timeframe of 284 days. Further investigations are planned to study the effect of alloying elements on mechanical properties of RSR 009+ anode alloy over several years as a function of time at 70 oC. The mechanical properties will be evaluated to determine the time at which they stabilize. Comparative plant trials with rolled RSR PbCaSn and RSR 009+ will also be performed in copper liberator cells and in cobalt and nickel electrowinning tankhouses to determine their mechanical and electrochemical performance at temperatures of 65-75 oC.INTRODUCTIONLead-based alloys are the primary anodes used in the electrowinning of copper, zinc, nickel, cobalt and manganese from sulfate-based aqueous systems. Lead anode technology has evolved over the years migrating from pure lead and lead-antimonial alloys to the present day PbCaSn alloys for copper and PbAg and PbCaAg alloys for zinc electrowinning (Prengaman, Ellis and Mirza, 2010). It has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new lead anode alloys and production processes for lead anodes to be used in copper electrowinning, the industry still has some unresolved issues. These relate to the necessity of having higher mechanical properties especially for the lead anodes in liberator cells in copper electrorefining and for cobalt and nickel electrowinning as these tankhouses operate at temperatures of 65-75 oC compared to 40-45 oC in case of copper electrowinning."

Jan 1, 2016

By J A. Gilliand

Mineralogical cross sections of orebodies on the 300-,600- and 900-foot levels of the Coronation mine have been interpreted in terms of centers of mineralization. The maximum concentration of chalcopyrite occurs closest to these centers, with pyrite and pyrrhotite concentrated some distance away. The magnetite concentrations are farthest removed from the centers. A hydrous halide fluid model is established. Attempts to explain the observed mineralogy by the action of temperature gradients on the fluid model were unsuccessful. Likewise, the action of diffusion alone on the fluid model cannot explain the observed mineral distribution. The concept of attenuation is introduced-i.e., the rate of diffusion of a particle species is related to the product r2 I/ M, the attenuation coefficient, where r is the particle radius and M its molecular weight. Attenuation, acting on the fluid model alone, will not produce the observed mineral distribution, but, when considered together with the action of temperature gradients, the observed mineralogy can be well explained by the combined effects of these two processes on the assumed fluid model.

Jan 1, 1965

By M. Hamamoto, M. Furuta, S. Tanaka

The Tamano smelter and refinery has expanded its production from 228kt/y to 260kt/y since 2006. It was not a big jump, but efficient and economical improvements were executed. These were not only de-bottlenecking and modernization of the smelting plant, including the acid plant, but also additional processes were commissioned, e.g. slag cleaning furnace and steam dryer. On the other hand, a conversion to permanent cathode process in the #2 tank house made the biggest impact on production efficiency for the refinery plant. In order to overcome the drastic change of copper business, although each scale is not so big, continuous improvements are very important to survive. This paper mainly describes the recent improvements of the smelting plant.

Jan 1, 2007

By Rob Sloan, Simon Yu, Rob Robison, Mark Schmidt

"In 2000-2009, Highland Valley Copper (HVC) tested new generation 660 mm cyclones supplied by various manufacturers in an aim to replace existing first generation 762 mm cyclones without success. Due to plant infrastructure limitations, new generation larger (838 and 800 mm) cyclones were not feasible. In 2010, an approach of testing hybrid 800 mm diameter cyclones was initiated by HVC. The hybrid cyclone consists of an 800 mm cyclone upper head section and the use of existing 762 mm cyclone conical sections. Three hybrid 800 mm cyclones were engineered and fabricated, targeting a throughput of 850-950 mtph and were installed in the E line cyclone cluster. Since starting operation on September 20, 2011, three hybrid 800 mm cyclones have been running at combined throughput ranges of 750 to 1050 mtph. Based on plant Daily Met Reports, the test hybrid cyclones demonstrated a decrease in misplacement of coarse copper bearing material to the cyclone overflow and better cyclone efficiency when compared to the existing 762 mm cyclones at the same throughput. The hybrid 800 mm cyclones also demonstrated significantly higher capacity per unit when compared to the existing cyclones. Based on the improvement demonstrated in the full plant trials, HVC decided to install the new hybrid 800 mm cyclones in all five grinding lines starting in July, 2012. A more detailed discussion of the full plant trials and initial results of the first complete retrofit of E line will be presented. INTRODUCTIONHighland Valley Copper Partnership (HVC) is Canada’s largest base metals mine and one of the world’s largest producers of Cu-in-concentrate. The mine, located in the central interior of British Columbia, is owned (97.5% interest) and operated by Teck Resources Ltd. In 2011, HVC produced about 210 million lbs. of Cu and 8 million lbs. of Mo. HVC’s Mill Modernization Project (MOP), which was budgeted for $475 M, is currently under intensive construction and is scheduled for commissioning in Q1 2014. The following description was valid at the time of writing this paper.The operation has been expanded a number of times since the startup of the original Lornex mill in 1972. The plant started up with two 9.75 m (32 foot) diameter primary SAG mills. It was expanded in 1981 with the addition of a 10.36 m (34 foot) diameter SAG mill. In 1988, the Highmont concentrator grinding mills and flotation section were moved and attached to the Lornex mill site. This added two10.36 m (34 foot) diameter AG primary mills to the Highland mill. This brought the total number of primary mills to five referred to as Line A, B, C, D and E: three SAG mills (A, B and C) each with two ball mills in parallel and two AG mills (D and E) each with one ball mill. Each AG mill line is equipped with one short head pebble crusher. Ball mill circuits are classified using 8 clusters of ten Linatex 762 mm cyclones to reach a target P80 330 micron (equivalent 43% +100 mesh), before the cyclone overflow product advances to the bulk flotation circuit."

Jan 1, 2013

By H. D. B. Wilson, W C. Brisbin

The Thompson-Moak Lake nickel belt lies along the root of a Precambrian mountain range of the island-arc or alpine type. This range coin-. cides with the boundary between the Superior and Churchill blocks of the Canadian Precambrian shield. The nickeliferous peridotites and nickel ores occur along a negative gravity strip, which also coincides with strong thrust faulting and the axis of greatest deformation of the mountain range. Similar structures and highly nickeliferous peridotites occur in present-day island arcs. Much of the belt is covered by Paleozoic rocks, but a length of 270 miles may be explored by present-day methods. Nickel deposits have been located along 60 miles of the belt. The length of the favorable structure and the size of the known deposits suggest that this will be one of the world's major nickel regions. The regional gravity anomalies, which consist of a branching negative strip bordered by two positive strips, are best explained by major warps of a crust consisting of a granitic and basaltic layer. The ore deposit

Jan 1, 1961

By A. Kraly, M. Complojer, P. Paschen, K. Gamweger, H. Antrekowitsch

Increasing quality of aluminium alloys and continuous optimization of the production process leads to an improvement of the gas purging systems. The application of porous plugs for the treatment of liquid aluminum is nowadays not widely used in the aluminium industry especially in Europe. The Department of Nonferrous Metallurgy and the Christian Doppler Laboratory of Secondary Metallurgy of Nonferrous Metals intensified the research and development of refining and alloying processes by gas treatment during the last years. CFD-modeling supports these experiments, which should lead to lower hydrogen content, lower suspended particles and a better distribution of alloying elements in the melt. Different parameters such as temperature, bubble size, gas amount and which kind of gas is used influence the quality of the products.

Jan 1, 2006

By Schrade F. Radtke

THE law of our present industrial society is the law of the jungle. By this I mean survival of the fittest. I do not refer to man or animal or the development of superior genetic strain. Rather do I refer to one's product, one's process, or one's material of construction. Each must perform in a superior manner or it is doomed to extinction; it must be steadily improved so that it can meet the competition of ether materials, of other equipment, or other processes. We have before us the classic examples of the horse and buggy vs the automo-bile, cf silk vs nylon, of the steam locomotive vs the diesel engine; in each case, a superior product has virtually wiped out its predecessor. Furthermore, a product, process, or piece of equipment is sold on its performance, together with engineering data which define its •characteristics and performance. For the most part, the present day sales-man must deal in terms of engineering performance of his product; he must know competitive materials -their strength and limitations as well N either old fashioned salesmanship, tradition, nor custom could have saved the horse and buggy from extinction; a superior product which has been steadily and con-sistently improved won out, 'and in turn, this change-over caused a dramatic• change in our whole way of life.

Jan 1, 1960

By Peter Hayes, Evgueni Jak, Taufiq Hidayat, Gary O’Connell, Denis Shishin, Jeff Chen, Francis Letarte

"Knowledge of slag properties is required for the optimisation of smelting operations. The phase equilibria and viscosities of the Al2O3-CaO-FeO-Fe2O3-MgO-MnO-NiO-Cr2O3-SiO2 slags at conditions of interest to Koniambo Ni-laterite smelting operations have been investigated. High-temperature re-equilibration phase equilibrium experiments of industrial slags followed by rapid quenching and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) have been undertaken in the olivine and pyroxene primary phase fields at temperatures between 1475 and 1600°C and SiO2/MgO weight ratios between 1.57 and 2.09. Phase equilibria predictions were performed using FactSage thermodynamic software. A slag viscosity model available in the FactSage thermodynamic package has been used to calculate the viscosities of the liquid slags. The Einstein-Roscoe equation combined with the predicted phase equilibria data have been used to estimate the viscosities of the slag slurries (slag + solids). The information provided can be used to assist in the evaluation of the furnace performance, to assess further optimisation of slag composition and to explore possibilities of targeted feed changes.INTRODUCTION One of the key steps in the production of ferronickel from nickel laterite ore at Koniambo Nickel SAS involves reduction and smelting of pre-dried nickel-bearing saprolitic ore (high Mg and Si) in an electric furnace at temperatures up to 1650°C. The characterisation of the slag properties as functions of key operational parameters, such as, temperature and composition, including liquidus, the proportions of solids and viscosity, is essential for improving control and optimisation of the operations. The slag produced in the smelting process is a complex oxide system with the major chemical components including Al2O3, CaO, Cr2O3, “FeO”, MgO, “MnO”, “NiO” and SiO2. Characterisation of these multi-component systems using a solely experimental approach becomes increasingly complex as the number of components is increased."

Jan 1, 2017

By Tony Lipiec, Greg Gosson

"When it comes to new mines being developed, there is a general industry consensus that most low-hanging fruit has been picked. Many projects currently in the mine development pipeline have been around for decades, but were held back because of technical challenges. Future development of these deposits will likely require access to the public capital markets, and in Canada that means providing scientific and technical disclosure on these deposits in compliance with NI 43-101. As many of these “challenged” projects have metallurgical issues, the companies that own the projects need to ensure their metallurgical Qualified Persons provide transparent disclosure regarding proposed solutions to those issues.This paper provides an overview of the disclosure requirements under NI 43-101 that are pertinent to metallurgists, and other Qualified Persons who prepare technical disclosure regarding the metallurgical characteristics of a mineral project. It lists the triggers for a technical report under NI 43-101 and Canadian stock exchange policies, and identifies the sections of the report that should involve input from a metallurgist or process engineer. It briefly outlines new civil liabilities under Canadian securities laws that increase the possible consequences for not complying with the technical disclosure standards.These materials are provided for general information purposes only and do not constitute legal advice. Readers are advised to seek specific legal advice from their own legal counsel in relation to any decision or course of action contemplated."

Jan 1, 2010

By J. P. Wiser

THIS paper discusses testing and quality control of milled asbestos fibre. It has been composed with the intention of: (I) Summarizing past, present and probable future methods of testing and classifying the various grades of commercial asbestos produced by the Quebec asbestos industry. (2) Acquainting those unfamiliar with the methods used for evaluating, testing and controlling the grading and the quality of Quebec chrysotile asbestos fibres with some of the physical and chemical procedures currently used for that purpose. (3) Discussing some of the complications facing the producers, such as variations in the orebody and special requirements of asbestos manufacturers. ( 4) Detailing some of the present quality control methods. SUMMARY OF PAST, PRESENT AND PROBABLE FUTURE TESTING METHODS Past During the first years of production of commercial asbestos in the Province of Quebec, fibre testing and quality control were based principally on dry screen analysis and visual inspection. These methods were gradually expanded during the period from 18, 90 to 1932. In 1932, standardization

Jan 1, 1962

By A. Drouin, D. Lemieux, C. Chouinard

"A gold bearing pyrite concentrate was treated at the demonstration scale (15 t/d) for the extraction of gold using a cyanide-free process. The pyrite was depressed in the flotation circuit in order to promote the flotation of copper and to achieve a sufficient copper grade to meet the copper smelter criteria. However, the recoveries of copper were 80% and only about 50% for the gold was found in the copper concentrate. The balance of the gold (50%) and copper (20%) contained in the pyrite concentrate as a reject from an overall flotation circuit. The gold grade in the pyrite concentrate is 5.40 g Au/t and copper about 0.77%. About 170 tons of pyrite concentrate were processed in the DST demonstration plant. The concentrate was first oxidized using a fluid bed to produce a calcine. Copper was then extracted as copper sulphate using diluted sulphuric acid. The residual solid was submitted to the DST chlorination process for gold extraction. Thereafter, the gold was recovered from the pregnant brine by precipitation over silica using DST proprietary process. The maximum gold recovery by chlorination was 90%. The average gold recovery by cyanidation of these calcines was 71%.IntroductionDundee Sustainable Technologies (“DST”) has developed a chlorination process as an alternative to the conventional cyanidation process for the extraction of precious metals from ores or concentrates. The technology offers viable and efficient gold recoveries and the ability to handle refractory ores and contaminated material (As, Hg, etc..). The process was successfully demonstrated on hundreds of samples provided by various mines, exploration and development projects and has evolved from laboratory experiment to demonstration at an industrial scale.DST’s chlorination process operates in a closed loop circuit, which implies that no liquid effluents are generated. The chemistry and process design allows precious metal deposits containing base metals to be treated viably. The tailings from the process are inert and non-toxic, sulphide depleted and thus non-acid generating. The efficiency of the process has demonstrated excellent gold recoveries within a fraction of the time needed for cyanidation to obtain similar results. The company completed in 2015 the construction of the first industrial demonstration plant operating with the DST technology. The plant has a capacity of 15 tons per day of mineral concentrate, and the ability to extract gold and silver utilizing DST chlorination technology.DST has tested its chlorination technology at demonstration scale on the refractory pyrite concentrate containing 5.40 g Au/t and 0.8 %copper. This auriferous pyrite concentrate, was by-product of copper concentrate respecting the copper smelter norms, is produced in a country where cyanide is prohibited and refractory to cyanidation. The pyrite concentrate was initially processed successfully (gold recoveries: > 90%) by the DST technology at laboratory (2011: 20 kg) and pilot (2014: 5 tons) scales to extract gold. About 170 tons of this pyrite concentrate were processed in the DST demonstration plant located in Thetford Mines."

Jan 1, 2017

By H. Reimer

The rates of return on investment are examined for several major Canadian mining companies. Because we are dealing with a highly cyclical industry, subjected to widely fluctuating metal prices, rates of return are examined over a 20-year period. Conveniently, the first decade examined reflects the period when the industry enjoyed incentives to develop deposits; during the second decade, incentives were reduced and the industry became the most heavily taxed industry in Canada. The high rates of inflation since 1973 have distorted the real rates of return on investment if one considers replacement cost.

Jan 1, 1977

By Chuan-Jian Zhong

Gold-based nanoparticles in the size range of a few nm have attracted increasing interests in catalysis, sensors and biomedical applications. The study of the unique catalytic properties of nanosized gold was inspired by the pioneering work of Haruta on the nanogold-catalyzed CO oxidation (1-4). There have been a number of excellent reports discussing both fundamental and application aspects of gold nanoparticles in catalysis (3-8). Our work reported herein is aimed at investigating the preparation and application of gold and its alloy nanoparticles for potential applications in fuel cell catalysis. Fuel cells operating by electrochemical oxidation of hydrogen or methanol fuels at the anode and reduction of oxygen at the cathode are attractive power sources due to their high conversion efficiencies, low pollution, lightweight and high power density. While methanol offers the advantage of easy storage and transportation in comparison with hydrogen fuel cell, its energy density (~2000 Wh/kg) and operating cell voltage (0.4 V) are much lower than the theoretical energy density (~6000 Wh/kg) and the thermodynamic potential (~1.2 V). The poor activity of the anode catalysts and inefficient activity or issue related to "methanol cross-over" at the cathode electrode are associated with the loss of about one-third of the available energy at the cathode and the other one-third at the anode. Extensive studies have been focused on Pt-group metals (Pt+Pd+Rh+Ru+Ir (PGM)) for both anode and cathode catalysts. A major problem is the poisoning of Pt by COlike intermediate species (9,10). Recently, oxide-supported gold nanoparticles in the <10 nm size range have emerged as one of the best catalysts for CO oxidation (1-3,11), and for water gas shift reaction in reforming stage using 5 nm Au on Fe2O3 (6). Gold and its alloy with other metals in the nanosize range present new alternatives (2,12). Whether the unique properties of gold nanoparticles can be exploited for addressing these problems is a focus area of our work. The ability to harness the large surface area-to-volume ratios and the unique surface sites of nanoparticles in <10 nm size range, especially in heterogeneous catalysis, constitutes a major driving force in fundamental research and practical applications of nanoparticle catalysts. It is this size range over which the metal particles undergo a transition from atomic to metallic properties. The understanding of factors controlling the morphological and surface reconstitution associated with such a size range is of fundamental importance to the ultimate exploration of nanostructured catalysts. We have been investigating the interfacial structures and properties of core-shell types of nanoparticles consisting of gold or alloy nanocrystal cores and organic monolayer shells that were prepared by twophase synthesis (13) and processing (14) protocols. Important attributes of such nanoparticles include controllable size monodispersity, processibility, and stability towards size- and composition-tunable catalysis (15-21). Some of these attributes were studied for understanding their electrocatalytic properties in the oxidation of methanol and reduction of oxygen, which are of fundamental interest to fuel cell technology.

Oct 1, 2003

By P. H. Reynolds, S. Liaghat, A. Zarasvandi

"Darreh-Zerreshk and Ali-Abad are two relatively small porphyry copper-type deposits in Yazd Province in central Iran. They are located within the central Iranian volcano-plutonic belt, formed above the collisional convergent margin of the Iranian lithospheric plate from the late Eocene to the Miocene. This paper discusses the geochemical characteristics of the igneous rocks, and 40Ar/39Ar geochronology of plutons and alteration phases associated with the Darreh-Zerreshk and Ali-Abad deposits. The deposits are spatially associated with igneous complexes that consist of older and barren granites intruded by intermediate-composition granitoids, which are the carriers of Cu mineralization. The granites have relatively high content of Nb, Y, and K, a prominent negative Eu anomaly, and were probably derived from melting of, or contamination of mantle-derived magmas by, continental crust. Porphyritic diorites, quartz monzodiorites, and granodiorites show enrichment in light rare earth and large-ion lithophile elements, depletion in middle rare earth elements, and have no negative Eu anomaly. These intermediate-composition granitoids were derived from melting of the upper mantle or lower crust, and their differentiation was controlled partly by fractionation of hornblende. A pilot K/Ar whole-rock dating study suggests that the pre-ore granites were emplaced in the Oligocene. Dating by the 40Ar/39Ar method of nine samples of secondary biotite and sericitized rocks from drillcore within the mineralized and altered zones in both deposits yielded a well-defined age of ca. 16 Ma. This date is interpreted to be the time of hydrothermal alteration and of porphyry copper type mineralization in this part of Iran."

Jan 1, 2007