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By M. Aljarrah

The phase equilibria in the Mg-Al-Ca system was investigated experimentally by differential scanning calorimetry (DSC) and X-ray diffraction (XRD) techniques similarly the Mg-Al-Sr system has been studied using DSC and XRD as well as scanning electron microscopy/energy dispersive spectrometer (SEM/EDS) and quantitative electron probe micro-analysis (EPMA). A new ternary solid solution MgxAl4,xSr was confirmed in Mg-Al-Sr system, which is a substitutional solid solution of Mg atoms in Al4Sr. Maximum solubilities of 21.3 at.% Al in Mg17Sr2 and 11.4 at.% Al in Mg were observed. It was also noticed that Mg38Sr9 dissolved 12.5 at.% Al. In the Mg-Al-Ca ternary system, one of the invariant transformations predicted by thermodynamic modeling was verified experimentally and found to occur at 512°C with composition close to 10.8 at.% Ca, 79.5 at.% Mg and 9.7 at.% Al. A ternary solid solution (Mg,Al)2Ca was confirmed where large solid solubility of Al in Mg2Ca was observed.

Jan 1, 2006

By Zhiqing Zhang, Changyun Chen, Qing Liu, Lin Lin, Zhihong Jia, Guangjie Huang, Lipeng Ding

The effect of interrupted quenching (IQ) treatments on natural aging and bake hardening response of Al-Mg-Si alloy was investigated by hardness measurements, tensile test, differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). The results show that interrupted quenching at 100oC could effectively suppress natural aging and improve bake hardening response. The optimized interrupted quenching treatment is 100oC for 45min, which gives the alloy a relatively low T4 temper strength and higher bake hardening response. The formation of highly dense cluster(2) during the interrupted quenching could be the reason for suppressing the natural aging and accelerating the precipitation of ß? phase during the paint bake treatment. In addition, interrupted quenching at higher temperature (170oC) results in unfavorable properties in both T4 temper and paint bake treatment. The formation of large precipitates is responsible for these undesired effects.

Jan 1, 2015

By Gilles Bonin

Structures and serpentinization patterns in the Thetford Mines peridotites are important characteristics indicating the necessary geological conditions which led to the development of chrysotile orebodies in Early Ordovician limes. These structures and serpentinization patterns are reviewed in this paper using the geology of LAB Chrysotile orebodies as a model. Structural aspects include parallel and transverse faults, parallel and transverse granite slabs, and orebodies, some of which trend clearly north-westward parallel to the accretionarymovement. Serpentinization patterns in the peridotite belt, particularly in the harzburgite, include primary pervasive mass serpentinization and secondary complete serpentinization. Listwaenites layers appeared along some faults and along some granite slabs as a result of hydrothermal alteration of the serpentine, following the emplacement of the devonian plutons to the south. These plutons as we/1 as other important lineaments, align with the structural pattern of Thetford Mines ophiolites. It is believed that these plutons are part of a heavy magma tic corridor resembling the Pilote-Mont-Louis corridor in the Gaspe (Doyon and Berger, 1997), and the Buchans' structure in Newfoundland (Hutchinson, 1984), both intersecting the Brompton-Baie Verte line.

Jan 1, 2001

By W. L. Brown

"The Normetal mine is about 7 miles east of the Ontario-Quebec boundary, and 13 miles north of the town of Dupuy on the Canadian National railway. The mine workings are largely on lots 44 and 45 in the south half of range 10, Desmeloizes township.The surface outcrop is reported to have been discovered by a trapper previous to 1925, but the details are obscure. The property was originally owned by the Canadian Exploration Company of Amos, Quebec, and was later transferred to Abana Mines, Limited. The latter Company carried out underground work from two shafts down to the 550-foot level. The property was acquired by Normetal Mining Corporation in 1931 and was reopened in 1933, when development work was carried down to the 800-foot level. The mine was closed down in 1935 because metal prices did not justify production at that time. It was reopened early in 1937 and milling commenced in September of that year. To the end of 1945, a total of 1,497,- 169 tons of ore was milled from which was produced 184,533 tons of copper concentrates containing 84,738,368 lb. copper, 2,744,100 oz. silver, 26,230 oz. gold, and 153,524 tons of zinc concentrates containing 163,752,433 lb . zinc."

Jan 1, 1954

By W. Kunda, J P. Warner

SHERRITT GORDON Mines Limited annually produce 300,-000 pounds of pure cobalt by processing a nickel-cobalt-copper-iron sulphide ore which is mined at Lynn Lake, Manitoba. The ore (containing 0.04 per cent Co) is •concentrated to give a concentrate containing l 1-12 per cent nickel, about 2.0 per cent .copper, and 0.25-0.35 per cent cobalt, which is treated at the Refinery in Fort Saskatchewan, Alberta. The concentrate is leached in an ammoniacal solution of ammonium sulphate using compressed air as the oxidant. After filtration the leach solution contains, besides nickel and cobalt, copper ammines, sulpharnates and salts of various thionic acids. The copper is removed by precipitation as sulphide and the sulphur compounds converted to ammonium sulphate by a combined oxidation and hydrolysis treatment. The purified solution •Containing about 45 gpl of nickel and 1 gpl of cobalt is treated with gaseous hydrogen under pressure at 350°F to precipitate metallic nickel powder, the precipitation 'being terminated when the nickel content of the solution is about 0.8-1 gpl. Only about

Jan 1, 1962

The system of keeping geological plans and sections for the Geco Mine at Manitouwadge, Ontario, is described. Special methods employed to save draughting time with-out sacrificing accuracy, such as the extensive use of black line prints, are discussed. The uses made of the plans and sections by the mine planning engineers in their designs of stopes, and by the blast-hole engineer in ~is preparation of blast-hole layouts, are noted. An unusual scheme for portraying the distribution of .copper, zinc and silver values within the ore zone is de-scribed. The method of estimating the grade of ore to be "blasted in each ring of blast holes is outlined, as is the method of estimating the annual ore reserves. The design of an effective but simple transparent geo-logical and mine development model, used as a display for -visitors, is discussed. A large-scale model used for the study of problems in geological structure is also de-scribed.

Jan 1, 1964

By A. P. Paiva

The solvent extraction properties exhibited by some /V,N'-tetrasubstituted malonamides to efficiently and selectively recover iron(III) from concentrated chloride leaching solutions can be found in the recent literature. The iron(III) extractive chemistry exhibited by some of these derivatives is revisited, in order to compare their chemistry with that shown by a few of the new malonamide compounds. The generally good extraction efficiency towards Fe(III), from >4 M hydrochloric acid solutions, and the relative ease of Fe(III) stripping by distilled water are remarkable findings that are confirmed for the malonamide derivatives described in this work. Furthermore, additional data regarding their selectivity towards Fe(III) extraction over several base metal ions and their behavior when subjected to successive Fe(III) extraction-stripping tests are also presented and discussed.

Jan 1, 2006

By Å. Kruukka, H. F. Broicher

The iron ores of the Kiruna mine in Sweden are of exceptional quality except for the phosphorus content in certain zones of the orebody. The prevention of mixing ores high in phosphorus with those low in phosphorus has always been of significant economic importance. The ongoing introduction of tele-mining and automatic haulage by LHDs requires new means in the field of quality control underground, as the experienced miner as well as the underground laboratory assistant no longer are involved in the process. As of 1998, LKAB has been testing prototypes of LIF (laser-induced fluorescence) analyzers for non-contact and real-time measurement of the phosphorus content of ore being transported by LHDs from the stopes to the respective ore pass assigned to a certain ore quality. The principles of the analysis of laser-induced fluorescence, the different test phases and results are described and conclusions made. With bulk sorting of ore underground, the mining engineer supports the efforts of the metallurgist in the processing plant.

Jan 1, 2002

By A. Pratt

Portland cement is primarily used to solidify backfill in underground mine workings and it represents a major cost in mining operations. CANMET-MMSL has invented an alternative binder technology that does not contain any amount of Portland cement and is made using waste materials, such as development rock and smelter slag. The technology has been successfully tested with many types of base metal and ferrous slag. Research conducted in collaboration with several mining operations in Canada has shown that the CANMET-MMSL binder has considerable potential as a replacement for Portland cement in mine backfill. An integral part of the overall mining operation, backfill is used for two main purposes: safety and environmental remediation. Depending on the mining method used, backfill provides a working surface, stabilizes stope and pillar walls, as well as the surrounding rock mass, and controls caving of stope backs. There are several benefits associated with the replacement of Portland cement in backfill, including reductions in (i) the footprint by placement of slag waste underground, (ii) the environmental effects and long term liability resulting from disposal and containment of slag waste on surface such as acid rock drainage, (iii) GHG as a result of reduced Portland cement usage (the production of 1 ton of Portland cement produces 1 ton of GHG), and (iv) the significant costs associated with reduced Portland cement usage.

May 1, 2010

By I Wilkomirsky, F. Parada, R. Parra, E. Balladares

"The neutral roasting of As bearing copper concentrates is confirmed well established and promising option for the treatment of this type of complex concentrate. The AS elimination by volatilization allows subsequent treatment of the calcines produced in a conventional pyrometallurgical process, by blending this product with standard concentrates.Several tests were performed using the fluidized bed pilot plant at the University of Concepción with different types of concentrates. Calcines, fines from two hot cyclones and flue dust from the ESP were collected. These materials were characterized using QEMSCAN® and the results used for the development of a mass and energy balance which took into consideration the specific chemical transformations that occurred in the reactor.A physico-chemical/kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite. The mechanism involves solid-gas reactions between chalcocite, pyrrhotite and gaseous sulfur that without the mineralogical characterization would not have been possible to propose"

Jan 1, 2014

By Arnold R. Pasieka, George V. Sotirow

"The object of this paper is to outline a computerized net cash flow approach for practical cutoff grade determinations. A cutoff grade carries not only geological but also economic value, in which costs are balanced against revenues. For different situations, cutoff grades are a 'standard of value' that are determined for the purpose of classifying economic or uneconomic mineral reserves in a specified time frame. In a constantly changing technical and economic environment, the decision to develop or maintain a mining operation at its best economic potential, requires an appropriate cutoff grade strategy, a strategy consistent with short- and long-term operational and corporate objectives and one based on realistic marketing and metal prices forecasts. The use of a project evaluation computer program, in combination with specific corporate net cash flow requirements, shows the most promising and flexible team approach for cutoff grade optimization.IntroductionThe recent recession has had a devastating effect on the Canadian mining industry. Exploration and mining R&D expenditures have been critically reduced and now are believed to be below healthy levels. Ore reserves, mine life and cutoff grades are careening in several directions because of low base metal prices, relatively high costs and sensitive precious metal prices.These conditions demand an improved understanding of the terms ""ore"" and ""cutoff grades"" as they are applied to the planning process and day-to-day operations. ""Ore"" or 'ore reserves"" is a dynamic concept, reflecting a cumulative effect of changes in geological, technical and economic conditions in terms of material which can be mined at a potential profit. By contrast, if economics are not the primary consideration, the term ""mineral reserve"" or ""mineral inventory"" should be used to describe the mineral deposit. For different situations, cutoff grade is ""a standard of value"" determined for the purpose of classifying mineral reserves as economic or uneconomic in a specified time frame. The question of mining at average reserve grade or low-grade material during high metal prices is of paramount importance for cutoff grade strategy."

Jan 1, 1985

By R. Burns, A. I. A. Salama, M. W. Mikhail

"Large amounts of oil sand tailings are produced in the Fort McMurray area, including sand, clays, and misplaced bitumen. The objective of the present study (as part of the overall engineered tailings program) is to select and evaluate the role of hydrocyclones in removing most of the solids from the tailings slurry and producing an underflow product containing about 75% solids.Multistage cyclones were evaluated in pilot plant tests. Slurry feeds with different percents solids and increasing ratios of superfines (–44 µm) were used in testing multistage cyclone circuits. A two-stage Linatex separator circuit gave high recovery to the underflow of 98.8% to 99.6% by mass with the desired high solids content in the underflow of 73% to 75% by mass. Changes in feed solids content (20% to 50%) had little or no influence on cyclone underflow recovery and solids content. The keys to achieving such results were the apex control mechanism and operation at relatively low feed pressure (<60 kPa for 23 cm F cyclone) when the feed solids content was high. Increasing superfines above 7% by mass in the feed resulted in a significant reduction in the recovery to the underflow, probably due to the heavy medium generated by excessive amounts of clays in the cyclone. Pilot plant results were better than those predicted by available cyclone simulation models in terms of recovery and solids concentration in the underflow.Increasing cyclone diameter from 23 cm for the Linatex separator to 51 cm for the Krebs cyclone appears to have little or no effect on size cutpoint."

Jan 1, 1997

"Cobalt refining at Vale Canada (previously known as Inco) has been associated with Ni production. Because certain compounds of both metals carry risks for adverse health endpoints by inhalation exposure, it is critical to understand the aerosol concentrations of specific substances and the metallurgical processes through which they enter the air. Vale Canada has therefore decided to describe the histories of its Ni-related operations and to report industrial hygiene measurements when available. This paper describes electrolytic Co operations carried out at Port Colborne, Ontario (1954–1966), and provides aerosol measurements (1995–2008) for current Co electrowinning operations.RÉSUMÉ L’affinage du cobalt chez Vale Canada (anciennement Inco) a été associé à la production de nickel. Puisque certains composés de ces deux métaux comportent des risques d’effets néfastes pour la santé par exposition à l’inhalation, il est essentiel de comprendre les concentrations en aérosol des substances spécifiques ainsi que les procédés métallurgiques par lesquels ils entrent dans l’air. Vale Canada a donc décidé de décrire les historiques de ses opérations liées au nickel et de divulguer les mesures d’hygiène industrielle lorsqu’elles sont disponibles. Le présent article décrit les opérations électrolytiques effectuées sur le Co à Port Colborne, Ontario (1954–1966), et fournit des mesures de la teneur en aérosol (1995–2008) pour l’extraction électrolytique actuelle du Co."

Jan 1, 2015

By G. Granata, C. Tokoro, M. Matsuoka, K. Horiuchi

"Given the high demand of copper and the lack of new high-grade deposits, low grade copper ores containing copper oxides and refractory sulfides need to be processed as well. However, in order to recover copper from refractory copper ores, the leaching performances should be improved. In this study, we investigated the effect of the mechanical activation in the leaching of copper from covellite. The influence of a mechanical treatment by planetary ball milling on leaching rate in sulfuric leaching media was evaluated by using X-ray diffraction (XRD), mineral liberation analysis (MLA) and X-ray absorption fine structure (XAFS). Results showed a significant increase in copper leaching from around 50%up to 100% along with an improvement of the leaching kinetics when using planetary ball milling. XRD spectra showed the disappearance of the covellite peak from (101) face, thus suggesting the amorphization of covellite associated with the use of planetary ball milling. XAFS results showed that the coordination number of Cu changed from 6 to 3, thereby confirming the effectiveness of the mechanochemical effect.INTRODUCTIONDuring the last decades, while the copper grade in copper ores has been decreasing, the concentration of impurities such as arsenic tends to increase, thus requiring for the processing of low grade copper ores. For a suitable processing of copper minerals, hydrometallurgical processes are preferable due to the lower costs, the lower environmental impact and the easier implementation (Watling, 2006). However, for an economical recovery of copper, the leaching performances must be improved.Among the recent advancements in leaching technologies, the mechanochemical activation allows for an improvement of the leaching performances by means of high-intensity grinding(Mohammadabad et al., 2016). In the first place, the improvement is the result of the dramatic decrease of particle size, which results in an increase of the mineral surface area and the consequent enhancement of leaching kinetics. Furthermore, the intense mechanical stress due to the high-intensity grinding could induce the rupture of the crystal structure producing a decrease of crystallinity. Such changes of the mineralogical structure, also known as mechanochemical effect, can lead to more leachable mineral, thereby resulting in a greater dissolution of copper. Last but not least, whereas the mineral surface might undergo passivation during leaching, the high-intensity grinding can continuously refresh the surface of the mineral, thus exposing portions of unleached bulk mineral."

Jan 1, 2017

By R. J. Fruehan

Oxygen steelmaking (OSM) is not only the dominant steelmaking process but defines the structure of the industry. There are a number of myths regarding the future of OSM, which are false. These myths include that the EAF will become the dominant process in the near future, it is less costly to produce steel in an EAF and OSM is a mature technology and no new developments are occurring. These myths are shown to be false. Selected new developments are discussed such as post combustion, recycling of waste oxides, slag splashing and sensors.

Jan 1, 2004

By I. Stanoev, V. S. Stoilov, I. Gradinarov, E. D. Visariev, I. A. Bonchev, Aurubis Bulgaria

"Aurubis is the leading integrated copper group and the world’s largest copper recycler. In Copper smelter Aurubis Bulgaria (Pirdop), the residual copper in the slags from Flash furnace and Converters is recovered by flotation. The slag processing comprises: pit cooling, crushing, two stages grinding (autogenous and ball) and flotation. The copper concentrate is thickened and then is filtrated by vacuum disk filter. The thickener overflow is sent to settler for additional clarification. A resent throughput increase resulted in higher solid content in the thickener overflow due to insufficient thickener area. Different scenarios to overcome the issue were evaluated (new thickener, reagents and reconstruction). An increase of the thickening area by installation of lamella modules was chosen as the most promising option. Three lamella modules (1 m3 each) were installed in conventional thickener for the test. Number of sampling campaigns was done to evaluate the effect on solid content in overflow. Parameters of the dewatering cycle were collected during sampling campaign. The products grain size distribution was defined - thickener feed, thickener overflow with and without lamella. The thickener overflow with lamella modules has 2.12 g/L less solid content. The decrease was 71.8%. According to the tests results, the whole conventional thickener was reconstructed with lamella modules. The thickener area was increased by more than 400 m2.INTRODUCTIONIn Copper smelter Aurubis Bulgaria, the copper in slag from the Flash furnace and the Converters is recovered by flotation. The scheme of slag processing is crushing, two stage grinding (autogenous and ball) and flotation. Till 2010 the grinding cycle in the plant was in two stages: the first stage was AG Mill 70×23 working with a classifier and the second stage was ball mill 3.6/5.5 working with a hydrocyclone. In 2010 a new AG Mill 65×78 with hydrocyclone was put in operation in order to increase throughput of the plant. The second stage of the grinding cycle was not changed."

Jan 1, 2016

By B. R. McEwen, A. N. Samis, J. H. Gray

"The Quebrada Blanca Copper Mine is an open pit copper project located at 4200 m elevation in the Chilean Andes. The deposit is a world-class supergene enriched porphyry with a mining reserve of 89 Mt of 1.3% copper. The supergene zone will produce 6.3 Mt of ore per year for more than 15 years to produce 75 000 t of cathode copper per year.This paper will review the project geology the computer model ling of the deposit, the mine planning process and the property production scheduling. With copper production .fixed by the onsite electrowinning capacity, the planning and scheduling aspects to optimize the project NPV will be discussed. Some of the logistics, equipment. personnel and process difficulties of operating a mine at 42()() m elevation will also be described. IntroductionProject DescriptionThe Quebrada Blanca Copper Mine is an open pit copper project located in the northern part of the Chilean Andes. The project is based on the supergene enriched portion of a porphyry deposit which has a mining reserve of 89 million tonnes at 1.3070 copper. Below the enrichment blanket, the protore represents a further resource.All ore will be leached, the higher grade material will be crushed and stacked for thin layer heap leaching, and the lower grade and oxide material will be dump leached as run-of-mine material. Solvent extraction and electrowinning will be used to produce 75 000 tonnes of cathode copper per year. Power will be supplied by a 40 MW on-site diesel generating plant with the waste heat being used for process heating. The leaching operation will operate in excess of 15 years and may be followed by open pit mining and conventional ore concentration of the underlying primary sulphide mineralization.Because of the dry location water will be piped 37 km from a ground water source at the Salar de Michincha. Water requirements will be approximately 1.5 million m3/year. The operation will eventually employ approximately 550 people on a 7-day-on, 7-day-off rotation with two twelve-hour shifts per day with an on-site camp. Busing will be provided to the port city of Iquique."

Jan 1, 1994

By J. Lu, M. Mohammadi, C. Pelletier, B. Wassink

Chemical reduction of selenate by chromous ions is proposed as a novel method to remove selenate from sulfate-bearing solutions Chromous ions were generated by electrochemical reduction of chromic ions using an electrochemical cell. The investigation was conducted in sulfate medium and under various concentrations of chromous ions (0.0062 to 0.05M), pH 1 to 2.2 and temperature 10 to 60°C. Selenate ions were rapidly reduced by chromous ions to hydrogen selenide. The overall reaction at a chromous/selenate molar ratio of 8 or higher can be expressed by the following reaction. At an initial chromous/selenate molar ratio below 8, the products are hydrogen selenide and elemental selenium. At a lower chromous/selenate molar ratio and pH, more elemental selenium and less hydrogen selenide are produced. The reduction kinetics is controlled by both chromous ion and hydrogen ions concentrations. The reaction rate is first order with respect to selenate, hydrogen ion and chromous ion concentrations. It was found that the selenate reduction rate with chromous is independent of the concentration of sulfate present in the solution. The general rate equation was proposed and the rate constant was calculated as k= 0.38 M-2s-1. An activation energy of 58.7 kJ/mol was obtained in the temperature range from 10 to 50°C. Nearly 100% of selenate can be reduced to H2Se from solution containing 17 ppm selenate in less than 30 minutes at pH 2.2 and 60°C. Various strategies have been tested to remove the produced H2Se from solution. INTRODUCTION Selenium in nature is mostly associated with metal sulfide minerals such as copper, iron, zinc, and lead sulfides (Zingaro & Cooper, 1974). The extraction of metals from ores has the potential for selenium contamination of ground and surface water which can pose an environmental and health concern. Therefore, selenium contamination in the receiving environment is a key issue for many industries (specifically copper industry) and the treatment of wastewater contaminated with selenium is a growing challenge. The effective removal of selenium from contaminated water is very important to support sustainability in the copper industry and the other industries with selenium pollution issues.

Jan 1, 2019

By F. J. Gauthier, R. G. Gray

"The possibilities of expanding the production rate from the Copper Mountain Mine have been examined using computer programs for analysing a complete range of data, beginning with the diamond drill assays and embracing all steps up to the final rates of return.Programs have been developed to calculate the mineralization inventory file, a matrix of blocks containing the grade and the type of mineralization estimated for each block. Given the topography, prices of metals and costs, the pit limits are optimized using a three-dimensional technique. Within the pit, ore reserves at any cutoff can be calculated. Mining of the pit is then simulated using an interactive production scheduling program on a timesharing computer. The annual tonnage and grade figures from the production schedule are input to a financial analysis program, where the present value and the rate of return are calculated at various metal prices. The expansion possibilities can be run through the programs with their respective costs, and evaluated using the rate of return on the marginal cash flow compared to the additional capital expenditure."

Jan 1, 1971

By Mory Ghomshei

Pebble Creek Geothermal Power project is associated with a massive recent volcanic eruption in Southwestern British Columbia Canada. Slim holes drilled to depths 1100 m in the prospect area, show very high temperature gradients around 80?100?C/km. The temperature and chemistry of the Pebble Creek hot springs indicate the possibility of a steam reservoir in the prospect area. In addition to high temperature gradients, presence of host rocks with high permeability, along with abundance of recharge waters (from the Lillooet River) provides clear signature of a high-grade geothermal power reservoir at depth 2000 to 3000 m. Data show that over five hundred Megawatt of green power can be generated from the prospect area in a commercially viable manner. The generated power will be base-load, which in comparison with large hydro has the advantage of lower capital costs and a significantly smaller footprint. The final hurdle to overcome, before starting the development phase, is deep exploratory drilling for resource confirmation. This paper is a summary of the data available on the Pebble Creek geothermal power prospect, presented in the context of viability of the resource for large-scale commercial power generation.

Aug 1, 2013