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By F. Ford, J. Dong

"Laboratory and miniplant testwork was carried out to reject uranium from an Iron Oxide Copper Gold (IOCG) deposit that contains an average of 60-70 ppm uranium with high variability. The dominate copper bearing mineral is chalcopyrite with minor bornite and trace covellite. The main gangue minerals are iron-rich chlorite, quartz and magnetite. The main uranium-containing mineral is uraninite (UO2). Downstream processes require the maximum uranium level of no more than 80 ppm in final copper concentrate.Mineralogical examination reveals that uraninite particles are finely disseminated with grain size of less than a few microns in the deposit requiring fine regrind in order to liberate uraninite from chalcopyrite particles. A lab flowsheet was developed to include ultrafine regrind of the rougher concentrate to the particle size of 80% passing 11-13 µm with up to four stages of recleaning in flotation columns. Finer regrind to 80% passing 5-6 µm may continue to improve liberation but does not decrease uranium level in the final concentrate. In each of the successive recleaning stages by flotation column after fine regrind, uraninite is rejected into the column tailings, with the final copper gold concentrate containing less than 70 ppm uranium from a feed containing 83 ppm uranium. The conceptual flowsheet was further tested in an integrated, continuous miniplant showing average 94% copper recovery with average 74 ppm uranium. The uraninite particles that report to the final concentrate are either locked with chalcopyrite or entrained as liberated particles of less than 5 µm in size."

Jan 1, 2016

By M. Keen

The backfill system at Cleveland Potash?s Boulby Mine places waste filter cake underground in the form of a high concentration slurry in worked out areas of the mine reducing the mine?s environmental impact. The backfill system delivers slurry approximately 1100 m down the mine and up to 11 000 m horizontally underground. The Boulby backfill system is unique in that the placed backfill waste is not used for the usual purposes such as support, pillar extraction or reducing ventilation requirements. It was specifically implemented for environmental reasons. This influenced the design and resulted in some unique features of the system. A previous paper (Wilkins et al., 2004) described the design and commissioning of the backfill system. This paper describes the operational experience with the backfill system and backfill placement since commissioning in May 2003 and looks at lessons that can be applied in other backfill designs.

May 1, 2007

By H. Tsuruta, A. Fujibayashi, I. Sumi, A. Murao, R. Murai

Injection of biomass into blast furnace as alternative reducing agent is so effective for the purpose of mitigation of carbon dioxide emissions from steel industries, because biomass is considered to be carbon neutral raw materials. Certain amount of Palm Kernel Shell (PKS) is abandoned after Palm oil extraction process. To use as a reducing agent of blast furnace, PKS was carbonized and classified by 100 mesh sieve. To examine the gasification behavior of PKS carbide under the blast furnace conditions, several combustion experiments were conducted using hot model experimental furnace. The experimental results showed that the gasification efficiency of PKS carbide increased as the quantity of volatile matter increased. This tendency is the almost the same for the pulverized coal, so carbide of PKS can be used at blast furnace at appropriate amount of volatile matter that can be controlled by carbonization condition. In addition, the pressure drop of the furnace tends to decrease because the amount of ash in PKS carbide may be smaller than that of pulverized coal. PKS carbide is a suitable reducing agent in that respect.

Jan 1, 2015

By G. B. Hudson

Previous papers (1, 2) pertaining to the treatment of uranium-bearing ores were concerned with the flotation of the radioactive minerals. In this investigation, the application of flotation to the removal of acid-consuming minerals from uranium ores was considered. Two pitchblende-bearing ores, which, because of the presence if dolomite were abnormally high acid consumers, were studied. In both in-stances commercial reagents of widely varying fatty acid composition proved satisfactory as flotation col-lectors, particularly at a pH of 10.5, for the carbonate minerals. From an economic viewpoint, however, Neo-Fat 42-12 was favoured. A mixture of sodium tripolyphosphate and citric acid was an effective depressant for the pitchblende in the ores. The tailings remaining after the removal of the dolomite by flotation contained, in one case, 88.5 per cent of the uranium in the original sample, and, in the other, 93.8 per cent. Analyses conducted on these tailings and on the original ores showed that

Jan 1, 1963

By P. Su

Friction stir spot welding of a range of Mg-alloys is investigated (AZ91, AZ31, AM50 and AM60). The peak temperatures during friction stir spot welding of all Mg-alloys are close to their solidus temperatures. Also, the apparent material viscosity of Mg-alloy sheet is lower than that when Al-alloy sheet material is spot welded. This is important since it means that the widths of the stir zones forming during spot welding of Mg-alloy sheet are smaller than those when Al-alloy sheet is welded (when identical welding parameter settings are applied). These lower apparent viscosity values must be taken into account during numerical modeling of the Mg-alloy spot welding process. The efficiency of energy utilization is very low when Mg-alloy sheet is spot welded and is of the same order as that when fabricating Al-alloy sheet. The energy generation contributions of the rotating pin and the tool shoulder are investigated. When the spot welding operation is carried out without the application of a dwell period, the contribution made by the rotating pin vis-à-vis energy generation is around 66%. The contribution made by the tool shoulder increases to about 65% when a dwell period of four seconds is incorporated during the spot welding operation. This increase results from a longer contact time between the tool shoulder and material within the stir zone, The failure load during overlap shear testing increases when the bonded area and the energy input increase during spot welding. Sample failure initiates from unbonded regions and from discontinuities at the edge of the stir zone. The formation tendency of discontinuities is increased when Mg-Alloy sheet is spot welded because of the limited deformation characteristics of the base material at lower temperatures.

Jan 1, 2006

By S. M. J. Mirazimi, F. Rashchi

Recovery of vanadium from LD (Linz-Donawits) converter slag was evaluated by means of microbial leaching. Vanadium leaching was performed in two stages. In the first stage, the bacteria were grown in a culture medium and in the second stage; vanadium containing slag was added to the metabolites produced by bacteria. Bioleaching was performed using heterotrophic bacteria Pseudomonas Putída. Control tests without bacteria inoculation were also performed and the results were compared with bioleaching outcomes. Optimal conditions for the bioleaching of vanadium containing slag were determined.

Jan 1, 2011

By L. Hacini

The start-up is the most critical phase of the cell life, as an uncontrolled start-up could lead to early infiltrations, instabilities, and in some cases to the cell death. Lots of efforts are put to increase the lifespan of cells, as it has a major impact on both the operating costs and the environmental footprint of the aluminum industry. Obviously, a true size test on a cell is a resources- and time-consuming approach that could be used only to validate mature concepts. Moreover, numerical modelling is a low-cost and versatile tool capable to test a wide range of potential ideas and concepts. In the present article, a thermal electrical mechanical slice model is presented. This model describes the preheating and bath periods of a P155 aluminum cell start-up, as used at the Grande Baie smelter. The impact of sodium diffusion and expansion is also included in the model. This model will be useful to study different problematical issues such as the global behaviour of lining materials, shell and cradle deformations during start-up and several start-up scenarios. Such a model will also be able to answer some interrogations regarding early infiltrations and their impact on the lifespan of the electrolysis cell.

Jan 1, 2011

By C. J. Brown

Since its commercialization thirty years ago, the Recoflo® short bed ion exchange process has been extensively utilized for the recovery of a wide variety of acids and metal salts. In addition to a reduction in resin bed height from 200 cm to 300 cm to 15 cm to 60 cm, the process has a number of features such as utilization of fine mesh resins in a compressed bed which together make it ideal for a number of applications. The process has been extensively exploited, for example, in the metal finishing industry for recovery of valuable chemicals from electroplating, anodizing, etching and pickling wastes. More recently, it has also been applied in the primary metals industry for purification of copper electrolytes and metals recovery from leachates. The paper discusses several of these applications and some of the issues that were found to be key to their success.

Jan 1, 2004

By T. W. Bingay

The production of both lead and zinc in Canada has steadily increased during recent years until today Canada ranks among the world's leading producers of both of these metals. The high prices which they have commanded have led to an energetic search for new deposits and also to an investigation of abandoned properties which, under the present conditions of better prices and more efficient methods of treatment, offer chances of commercial success. It is confidently expected that during the next few years success in both these lines of activity will further increase Canada's lead and zinc output, giving her a still higher ranking among the world's producers. In 1926, approximately 140,000 tons of metallic lead was produced from ores mined in Canada, and of this, 125,000 tons was refined in Canada at Tadanac, B.C. During the same year the production of metallic zinc from Canadian ores amounted to 68,000 tons, of which 62,000 tons was refined at Tadanac. History Of Lead and Zinc in Canada The production of lead in Canada is much older than that of zinc. The chief source has always been the interior of British Columbia. As earl y as the 'eighteen twenties', Indians and Hudson's Bay Company's trappers had discovered an outcrop of lead ore on the site of the present Blue Bell mine on the east shore of Kootenay lake, but it was not until1865 that active prospecting for lode deposits began. In the early nineties the activity of the silver-lead-zinc region of the Slocan reached its culmination and a steady production has been maintained down to the present time. Up to the end of 1924 the Slocan area produced over 38 million ounces of silver, nearly 300 million pounds of lead, and almost 122 million pounds of zinc.

Jan 1, 1927

By M. Kucharski

The model of the Outokumpu direct-to-copper process deals with a steady-state process the parameters of which do not depend on time. To give a prediction for the process outcome, "a modified black box" method, which ignores most of the chemical reactions in the furnace, was used. This method takes input and output parameters into consideration. The presented model describes the Outokumpu direct-to blister process in the form of the set of linear equations which give mass and enthalpy balances as well as the distribution of elements between blister copper and slag. However, only major substances where quantities in the feed charge exceed a certain level (for example 0.5 kg/ lMg of smelted concentrate) are taken into consideration. Minor elements are distributed among slag and metal phases in a different way. Some of the equations are derived from distribution coefficients. The value of distribution coefficients can be calculated from plant production data.

Jan 1, 2007

By Marie-Eve Boucher

The slag in iron ore pellets allows wet sintering during firing and leads to suitable bounding. The process of slag formation differs whether it takes place in the core or in the external zone of a pellet. In the core, hematite can be reduced to secondary hematite, depending on the temperature and on the carbon monoxide/dioxide partial pressure ratio. The reaction rim that appears at the outskirts of a silica particle in contact with the FeO bearing magnetite is considered as the slag precursor in the core of the pellet. By contrast, in the external zone of a pellet, where O2 is available and CO partial pressure is very low, the first step towards slag formation is flux decomposition, mainly dolomite and limestone. The CaO liberated through this reaction will be available to react with hematite by solid diffusion to form calcioferrites, which play an active part in the slag evolution process. These two slag formation paths will be explained.

May 1, 2007

By Frank Ebbutt

In this paper it is proposed to point out certain structural factors that; have an important bearing on gold deposition. The subject will be treated; more or less generally. Although the writer has had access to a great many; of Canada's gold mines he does not wish to take the liberty of discussing; details of any particular mine or mines; the aim will be to discuss controls; that are evident in many places.

Jan 1, 1954

By B. Chareyre, H. Pourpak, L. Scholtès, E. Papachristos

"Numerical methods used to study hydraulic fracturing in low permeability rock masses need to take into account the interaction between the progressive failure mechanism of the intact rock matrix and the pre-existing natural fractures. A fully coupled hydro-mechanical 3D discrete elements model dealing with such interaction is presented here. The ultimate objective is to grasp the role of the rock-matrix failure on the propagation of the main fluid driven fracture under different stress fields and pre-existing fracture orientations. The proposed method provides the spatiotemporal distribution of the induced crack events which can be tracked during the simulations, making possible the identification of the local mechanisms leading to macro-failure in the rock matrix or reactivation of the discontinuity planes. Fluid flow inside a fracture, pressurized crack and hydro-fracking experimental tests were simulated as part of the validation process of the model and, are presented in this paper.INTRODUCTIONWith the expansion of shale gas and geothermal reservoirs exploitation, the technique of Hydraulic Fracturing (HF) has been widely used over the past years (McClure, 2012; Britt, 2012). Despite recent advances in micro-seismicity analysis or numerical modeling (Nagel et al., 2013), the way progressive failure of rocks affects the fluid flow depending on the in situ stress conditions or the rock heterogeneities is not fully controlled yet (Zoback, 2010).In this work we focused on setting up a three-dimensional discrete elements model to study fluid driven fractures propagation. The intact rock is modeled by a discrete element method (DEM) able to reproduce fracture initiation and propagation (Scholtès and Donzé, 2013, Garcia et al., 2013). The pre-existing fractures are explicitly modeled and can be individually defined or be part of a discrete fracture network (DFN) (Harthong et al., 2012). Their mechanical response is fully coupled with the fluid within a HM-DEM framework. The fluid flow and it’s interaction with the intact matrix and the pre-existing discontinuities is modeled through a Pore-scale Finite Volume (PFV) scheme specially enhanced for fractured rock modeling (Chareyre et al., 2012, Catalano et al., 2014) ."

Jan 1, 2015

By James F. A. Hatley

Northern Saskatchewan comprises an area of about 350 000 km2 and boasts some of the world's largest known high-grade uranium deposits. The successful mining of these deposits, however, can not be accomplished without overcoming technical challenges. Not only is the high grade of the uranium ore challenging, but mining methods need to be developed to deal with groundwater at very high pressures, and ground conditions that vary substantially from excellent to wholly unconsolidated clays and sand. This paper discusses the various mechanisms of inflows at the three of the Cameco Corporation Mines in Northern Saskatchewan. The risk of inflows is quantified in terms of unique challenges from hydrogeologic conditions, rockmass integrity, and uncertainty in geologic conditions. Mitigation strategies in case of an inflow are also briefly described. The paper concludes by addressing the impact of institutional rules (corporate standards) on minimizing, monitoring, and controlling the probability and/or impact of unexpected inflows.

Aug 1, 2010

By C. B. Webber, L. S. Diaz

"The paper presents the approach taken by Craigmont Mines to grinding circuit control. A detailed description is given of a fully automatic control system which bases its control actions on the continuous measurement of particle size in the cyclone overflow stream. The control system holds a specified particle size in the cyclone overflow, and grinds rod mi 11 ore feed at increased rates. The principles of operation of the system used for continuous measurement of particle size are described, end the improvements in mill throughput and copper recovery over several months of continuous operation are presented.INTRODUCTION Craigmont Mines Limited is located in the south-western interior region of the province of British Columbia, approximately 230 road miles north-east of Vancouver, and ten miles west of the town of Merritt. A moderate climate, good roads and service facilities provided by the Canadian Pacific Railway, Inland Natural Gas Company, and the B.C. Hydro and Power Authority, have provided a very favorable mine and plant site.The preliminary metallurgical design of the Craigmont mill was based on the test results of samples obtained from the original 2500' level drift during 1959. Pilot plant runs and other research testing for design pur¬poses were conducted at the Canadian Exploration Ltd. Laboratory, at Salmo, B.C. The design flowsheet was altered in progressive stages from 2,000 to 3,000, and finally 4,000 tons per day as the ore reserves became better defined. Construction work on the 2,400' level mill site commenced in late 1960. The official opening of Craigntnt Mines Limited took place on September 15, 1961, a little over two years from the time of the metallurgical assessment of the original ore samples.Mill throughput to date has varied widely both on a daily and a monthly basis, due to the varying hardness of the mine ores. The grindability af the ore appears to be related to the oxide iron content, which varies from lows of 9% to highs of 20%. Daily tonnage has ranged from 5,000 tons per day with 10% iron in the feed, to 6,000 tons per day with 20% iron feeds."

Jan 1, 1973

By Martin Encinas, Jesús L. Valenzuela, Jose R. Parga, Salvador Aguayo, Roy G. Lewis

Continuous laboratory solvent extraction of gold from cyanide solutions using LIX?79 guanidine based extractant has been investigated. Different variables that affected the selectivity and extraction include aqueous pH, extractant concentration, and modifier concentration. The extraction isotherms of the aurocyanide complex with respect to the other cyano anions were compared, and the following order of selectivity Au > Ag > Zn > Cu > Fe was observed. According to the pH isotherms, aurocyanide can be extracted in an alkaline media, and a better separation with respect to the other cyanoanions was obtained in the pH range 10.5-11.2. From the McCabe Thiele diagrams, better recovery was predicted when using LIX?79 extractant and tridecanol modifier at 10 vol.%. Stripping of the gold from the loaded organic was carried out at pH > 12 using NaOH and NaCN solution. The continuous tests indicate that a two-stage extraction followed by a single stage strip is adequate to obtain an overall process efficiency of >90%. Better results were obtained using a copper wash stage before gold stripping.

Jan 1, 2014

"An atmospheric process for the synthesis of scorodite(DMSP®)has beendeveloped,in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. Under optimum conditions, the synthesized scorodite (FeAsO4?2H2O) was well crystallizedand the crystals were faceted; the particle sizes were as large as 15 to 20 µm. In thisstudy, iron (II) sulfate heptahydrate (FeSO4·7H2O), arsenic (V) acid (60mass%H3AsO4) solution, and distilled water were used to prepare the original experimental solution (700 ml), in which the contents of Fe(II) and As(V) were 55.9 g/L and 50.0 g/L, respectively. The effects of various synthesis conditions, such as the type of oxidizing gas (oxygen or air), gas injectionrate, temperature, and the initial pH of the solution, on the size and shape of the scorodite particles wereinvestigated. From the experimental results, the changes in the shape of the scorodite particles wereclarified for each synthesis condition.INTRODUCTIONDOWA has developed a processfor synthesizing well-crystallized scorodite (FeAsO4•2H2O). Theprocess is named andtrademarked as DMSP® (Fujita et al., 2008; Fujita et al., 2008; Fujita et al., 2009; Fujita et al., 2009; Fujita et al., 2009, Kubo et al., 2010). In this process, oxygen gas is injectedinto a sulfuric acid solution containing large amountsof As(V) and Fe(II). Facetedscorodite crystals as large as 15–20 µm weregeneratedthrough the pre-formation of a gel-like precursor. However, it is known that the synthesized scorodite particles become smaller and more aggregatedwhen the synthesis conditionsdeviate from the optimumconditions.In this study, the effects of various synthesis conditions, such as the type of oxidizing gas (oxygen or air), gas flowrate, temperature, and initial pH of the solution, on the size and shape of the scorodite particles were investigated. The experimental resultsclarified the changes in the shape of the scorodite particles for each synthesis condition."

Jan 1, 2016

By J. A. Brown, F. P. Kerr, M. A. Archer

Extensive testwork on Global Atomic’s Dasa Project in Niger has been conducted at SGS Minerals laboratory in Lakefield, Ontario. Much of this testwork has focused on a two-stage counter-current leach as a means of improving leach efficiency and decreasing reagent consumption. The ore contains uranium mineralization requiring relatively high sulphuric acid concentrations during leaching to achieve acceptably high extractions. Excess free acidity in the leach solution may be utilized by recycling the high acid solution and contacting it with fresh ground ore. The resulting pregnant leach solution (PLS), now higher in uranium concentration and depleted in free acid, is forwarded on to uranium recovery by solvent extraction. The first stage residue proceeds to the second stage leach where fresh acid and oxidant are provided to leach the remaining uranium. This paper presents the results of the testwork conducted on both a Master Composite and Variability samples.

Jan 1, 2020

Agenda ? Introduction ? Inmet?s Operations and Closed Properties ? Inmet?s SECA Philosophy ? Inmet?s SECA Framework ? The Business Case for TSM ? Inmet?s TSM Reporting ? Inmet?s 2004 TSM Performance ? Opportunities for Improvement ? What Have We Learned From The TSM Process So Far? ? Summary Introduction ? Inmet has evolved into a strong TSM supporter ? Inmet is confident that TSM can be successfully and cost effectively implemented by smaller companies ? Inmet?s reporting on economic, environmental and social performance was raised significantly in our 2003 Annual Report ? a signal our commitment to good performance and improvement in these areas ? Our 2004 Annual Report has been further enhanced with the inclusion of our TSM performance

Apr 1, 2005

By Patrick Wong, Gareth Hatch, M. A. Halim, V. I. Lakshmanan, Darcy Tait

"This paper describes development of an integrated chloride process for separation and purification of REEs. The process includes atmospheric leaching of ore/concentrate with mixed chloride lixiviant containing HCl and MgCl2 followed by bulk recovery of REEs, dissolution of the bulk intermediate product, and separation of individual REEs by solvent extraction (SX) process steps. Mixed chloride leaching technology provides the opportunity to regenerate the lixiviant, while the addition of MgCl2 in HCl enhances the hydrogen ion activity by orders of magnitude increasing REE extraction efficiency at a lower concentration of HCl. An individual REE separation process developed by Innovation Metals Corp. is being piloted at a state-of-the-art facility at Process Research ORTECH Inc. in Mississauga, Ontario, Canada. The SX process includes the separation of light REEs (La – Nd), medium REEs (Sm – Gd) and heavy REEs (Tb – Lu plus Y) from leach liquor followed by individual REE separation. Each SX circuit proceeds by multistage extraction followed by scrubbing and stripping. The process is chloride based and reagents are recycled, reducing waste generation and optimizing water usage to reduce environmental impact.INTRODUCTIONRare earth elements (La to Lu plus Y) exhibit a range of unique magnetic, electronic, catalytic and optical properties. Due to these special properties, the application of REEs is increasing and they are found in components for wind power generation, hybrid electric cars, catalytic converters, and many electronic devices.Rare earth elements (REEs) are commonly divided in two groups: light rare earth elements (LREEs) and heavy rare earth elements (HREEs). Light rare earth elements include elements from lanthanum (La) to neodymium (Nd). Although promethium (Pm) is considered an LREE it is unstable and scarcely occurs in nature and is generally excluded. Heavy rare earth elements include elements from samarium (Sm) to lutetium (Lu) plus yttrium. Although rare earth elements are not rare and the rare earth oxides are scattered around the globe, over 95% of REEs+Y are currently produced in China (Pitts, 2011). On one hand the Chinese government is restricting the export of rare earth elements and on the other hand the demand for REEs+Y is increasing in the rest of the world. This has created an imbalance in the supply and demand of rare earth elements and has led to a rush for developing new rare earth projects."

Jan 1, 2016