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By K. Fumimura, T. Nishimura, M. Kohno

When applying numerical techniques to problems of deformation of rocks, the body to be analyzed is divided into small portions and is represented by a system of points linked together with the neighboring points. In the so-called distinct element modeling, the particles in the system are directly connected by springs and a contact law is used to specify forces on the particles to simulate the mechanical behavior of the body. The relation between the spring stiffness and commonly measured material properties, such as the Young’s modulus and the Poisson’s ratio, should be known a priori. For the general case of a random packing of particles, the relation is found by means of a process in which a system of particles and set of parameters are prepared to simulate a set of specimen-size test and then the input parameters are chosen to match the measured material properties. The validity of the numerical result is only demonstrated by comparison model behaviors with the measured responses. The process includes trial-and-error manner, therefore, no model is complete to reproduce the mechanical properties. In this paper, a relation between the spring stiffness and the elastic constants; the Young’s modulus and the Poisson’s ratio, is introduced to a three-dimensional distinct lattice spring method. Two simple numerical examples will be presented to demonstrate the performance of the method with the procedure for the determination of the spring stiffness.

Jan 1, 2015

By Orlando C. Gaspar

Abstract - The presence of fine-grained mineral intergrowths, the complex distribution of deleterious minor elements, and the variable base-metal contents in some assemblages commonly pose technical problems for the processing of volcanogenic massive sulfide ores. The beneficiation of most massive sulfide ores from the Iberian Pyrite Belt requires extremely fine grinding to liberation sizes of K80 = 15 µm to 25 µm. For several deposits, mapping of the ore types and metal zoning patterns has shown that the different ore types are distributed as ore lenses within the massive sulfides. Mineralogical, textural, and metallogenetic studies have provided an understanding of the distribution of both the vertical and the horizontal metal zonation in the orebodies. Because the efficiency of ore processing is affected by ore textures, and because the same mineral commonly has different textures and varies in chemical composition, a relationship between textures of the feed and the middlings must be established for all ore types defined at the deposit scale. Quantitative mineralogical methods have been developed to provide, on a timely basis, the information needed to optimize the concentration processes for the massive sulfide ores at the Aljustrel and Neves-Corvo deposits, Iberian Pyrite Belt, Portugal.

Jan 1, 1997

By Orlando C. Gaspar

The presence of ?ne-grained mineral intergrowths, the complex distribution of deleterious minor elements, and the variable base-metal contents in some assemblages commonly pose technical problems for the processing of volcanogenic massive sul?de ores. The bene?ciation of most massive sul?de ores from the Iberian Pyrite Belt requires extremely ?ne grinding to liberation sizes of K80= 15 µm to 25 µm. For several deposits, mapping of the ore types and metal zoning pat-terns has shown that the different ore types are distributed as ore lenses within the massive sul?des. Mineralogical, textural, and metallogenetic studies have provided an understanding of the distribution of both the vertical and the horizontal metal zonation in the orebodies. Because the ef?ciency of ore processing is affected by ore textures, and because the same mineral commonly has different textures and varies in chemical composition, a relationship between textures of the feed and the middlings must be established for all ore types de?ned at the deposit scale. Quantitative mineralogical methods have been developed to provide, on a timely basis, the information needed to optimize the concentration processes for the massive sul?de ores at the Aljustrel and Neves-Corvo deposits, Iberian Pyrite Belt, Portugal.

Jan 1, 1997

By Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"In natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the content of MoO3 varies from 2% to 10%. As a result, the flotability of seyrigite (scheelite with molybdenum) turns to be weaker. One seyrigite mine, which has been built for 3 years,still could not produce qualified seyrigite concentrate due to the weak flotability of seyrigite (Mo-bearing scheelite) in raw ore. In our experimental research, through adopting new seyrigite collector TA-3 and advanced mineral processing technology, the seyrigite concentrate with a grade of 65.62% WO3 at a recovery of 87.47% was obtained for the raw ore containing 0.19% WO3 and 0.074% Mo. By applying the new technical achievement, for the raw ore containing 0.272% WO3, the seyrigite concentrate assaying 68.03% WO3 with a recovery of 77.56% was obtained in industrial production.INTRODUCTIONIn natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the scheelite is changed to be seyrigite (Ca[(W,Mo)O4]) (Ma, Bian, & Wang, 2013). The content of MoO3 in seyrigite varies from 2% to 10% usually, the content of MoO3 in some of the seyrigite even reaches 34%. The flotability of seyrigite is weak (Zhang, 2007), and the seyrigite is difficult to be recovered by flotation with common collectors and regulators. One scheelite mine in Anhui China, which is a skarn type seyrigite mine, has not produced qualified concentrate yet since 3 years it has been built due to the limit of beneficiation technology. Therefore, it is necessary to conduct research on the collectors with high efficiency and developing advanced processing flow for this kind of ore."

Jan 1, 2016

By M. Boussuge

Ceramics and refractories have many common constituents and consecutively exhibit several analogous properties. For example, concerning the thermomechanical properties this paper will focus on, the type of creep that can be observed in both materials is often the same (kinematic hardening). Changes in microstructure (phase transformation, dehydration, sintering, crystallisation,...), induced by heating and/or cooling, can also drastically modify the mechanical behaviour of ceramics and refractories. But the coarse granulates, the porosity and the impurities contained in industrial refractories may lead to specific responses of this material to thermal and/or mechanical loadings. In particular, some differences can be observed with technical ceramics in the main type of damage observed in service : diffuse damage in refractories (microcracking) and localised damage in ceramics (macrocracking). In this paper, the possibilities of transferring a part of knowledge from ceramics to refractories will be discussed, in the field of thermomechanical properties : experimental characterization techniques, mechanical behaviour models. Finally, some problems caused by scale effects and by the integration of thermomechanical properties of refractories in the numerical simulation of industrial structures will be evoked.

Jan 1, 2004

By Ross I. Kelly

Carbonate rocks are widespread throughout Ontario and provide raw material for more uses than perhaps any other rock type. The principal carbonate rocks that are used by industry in Ontario are Paleozoic era limestone and dolostone. Limestone is a sedimentary rock that is composed mainly of the mineral calcite (CaCO,) while dolostone, also a sedimentary rock, is composed mostly of dolomite [CaMg (CO,),l. The majority of the province's limestone and dolostone extraction occurs from Paleozoic era rocks located in southern Ontario. Calcite and dolomite are also found in Precambrian marbles, calcite veins and carbonatites, however, utilization of these rocks by industry has been less common. Calcite and dolomite-rich rocks are utilized for a wide variety of uses including raw materials for cement and lime manufacture, chemical and metallurgical stone, fillers and construction aggregates (Derry, Michener, Booth and Wahl and OGS 1989a). For some uses chemical and physical requirements are very important. In the manufacture of glass, for instance, the chemical requirements of source materials are very important and very stringent. In other uses physical criteria such as whiteness may be more important. Although carbonate rocks are quite plentiful within the province, deposits that contain high concentrations of calcite or dolomite are somewhat limited. For that reason, this paper focuses on deposits that are known to, or may contain, a high percentage of calcite and/or dolomite. The paper emphasizes potential sedimentary limestone and dolostone resources, as these are the carbonate rocks most commonly utilized by industry in Ontario.

Jan 1, 2001

By P. C. Holloway, M. J. Collins, K. R. Buban

Historically, there has been little incentive to process copper-arsenic concentrates by leaching, rather than via established smelting operations. However, with ever tightening environmental emission standards and more arseniferous concentrates being produced, increasingly sophisticated and upgraded off- gas handling facilities are required in smelting operations, generating greater quantities of challenging metallurgical dust. In this context, oxidative pressure leaching offers distinct advantages. The current state of pressure leach technology delivers high extractions from copper concentrates, while producing an environmentally stable process residue, without atmospheric emissions of sulphur dioxide or arsenic. However, as was shown in an earlier study, copper extractions and environmental leach residue stability are impacted negatively by arsenic levels above 2.5 to 3.0 wt%. In further studies on pressure leaching of copper concentrates, Sherritt has developed process conditions that allow even highly arseniferous (> 7 wt% As) feed materials to be converted into environmentally stable residues, with excellent copper extractions. At the same time, pressure leach residues can be generated that are amenable to silver recovery via direct cyanidation, without pre-treatment by lime boiling or hot curing. The results of pilot plant test work are discussed. INTRODUCTION As the production of copper has expanded over the years, resource exploitation has extended beyond relatively clean, high grade and easily accessible ores, and copper sulphide concentrates increasingly come with higher levels of contaminants, such as As, Hg, Sb and Bi, and lower copper and sulphide sulphur concentrations. However, as concerns on the impact of the emission of such contaminants into the natural environment have mounted, import/export restrictions have made the trading of copper concentrate more difficult, and, in particular, the export of concentrates with greater than 0.5 wt% As; under ever tightening environmental emission standards, these lower quality concentrates can be a significant strain on the off-gas handling facilities in smelting operations. The processing of arsenic bearing copper concentrates is, therefore, an increasing challenge as copper producers seek to exploit more complex mineralization and to extend the life of their operations. In this environment, processing arsenical copper concentrates with high temperature pressure leaching (>200°C) must be considered as an alternative to pyrometallurgical processing. Leaching kinetics for copper minerals at these temperatures are rapid and acid is generated for potential use in heap leach operations. Pressure leaching of copper concentrates eliminates gaseous emissions of arsenic and sulphur, while generating environmentally stable residues, as measured by the Toxicity Characteristic Leach Procedure (TCLP) (Kalanchey et al., 2007). Both medium and high temperature pressure leaching of copper concentrates have also proven themselves technically on an industrial scale (Marsden et al., 2004) with high copper recoveries.

Jan 1, 2019

By L. Nastac, Y. Xuan

"The metal-matrix-nano-composite (MMNCs) in this research work consists of an A356 alloy matrix reinforced with 1.0 wt. % SiC 50 nm diameter nanoparticles that can be dispersed within the molten alloy matrix via ultrasonic stirring technology (UST) and induction melting and stirring processing. The necessary ultrasonic parameters to achieve the essential cavitation for adequate degassing and refining of the A356 alloy as well as the optimum fluid flow characteristics for uniform dispersion of the nanoparticles into the A356 alloy matrix have been investigated in this study by using computational fluid dynamics (CFD) modeling with a magneto-hydro-dynamics (MHD) model and an UST cavitation model.The MHD model accounts for turbulent fluid flow, heat transfer and solidification, electromagnetic field as well as the complex interactions between the solidifying alloy and nanoparticles by using ANSYS Maxwell and ANSYS Fluent Dense Discrete Phase Model (DDPM) and a particle engulfment and pushing (PEP) model.INTRODUCTIONAluminum matrix nanocomposites can offer outstanding properties, including low density, high specific strength, high specific stiffness, excellent wear resistance and controllable expansion coefficient, which make them attractive for numerous applications in aerospace, automobile, and military industries field (Bozic, 2010, De Cicco, 2009, Elshalakany, 2014, Goh, 2006, Jia, 2013 and 2015, Liu, 2014, Reihani, 2006, and Su, 2010).As shown in literatures (Aki, 1999 and Mussert, 2002), it is highly advantageous to use nano-sized ceramic particles to produce metal matrix nano-composites (MMNCs) since similar ductility and higher strength with the metal matrix can be achieved. Currently, there are several fabrication methods of MMNCs, including mechanical alloying with high energy milling (Chen, 1997) , ball milling (Filho, 2003), nano-sintering (Groza, 1999), spray deposition, electrical plating, sol-gel synthesis, laser deposition, etc. The mixing of nano-sized ceramic particles is normally lengthy, expensive, and energy consuming.Ultrasonic Stirring Technology (UST) has been extensively used in purifying, degassing, and refinement of metallic melt (Jian, 2005, Khalifa, 2008, Eskin, 2002, Xu, 2004, and Meek, 2006) mainly because introducing the ultrasonic energy into a liquid will induce nonlinear effects such as cavitation and acoustic streaming. SiC nanoparticles are widely used as reinforcement particles due to their relatively good thermal and chemical stability. Ultrasonic vibration can improve the wettability between the reinforced nanoparticles and the metal matrix (Lan, 2004, Cao, 2008, and Yan, 2011), which will assist to distribute the nanoparticles more uniformly into the metal matrix. Ultrasonic cavitation in liquids causes high speed liquid jets of up to 1000 km/h. Such jets press liquid at high pressure between the particles and separate them from each other (Hielscher, 2005)."

Jan 1, 2016

By John W. Korczak

The use of geological and grade block models has been standard practice in mine design for many years now, with a wide range of software available for creation and analysis. Although geotechnical parameters are of vital importance to mine planning there is very little in the way of commercially available systems for integrating geotechnical data into the mine planning and design process. Sirovision is a new technology developed by the CSIRO (Commonwealth Scientific and Industrial Research Organization) in Australia for automated, safe and accurate 3D mapping of geological and geotechnical features. Datamine has integrated this capability into its product range so that Sirovision has become an integral part of the day-to-day mapping, mine geology and geological / geotechnical modeling in both open pit and underground mine environments. This is the first integrated underground application of Sirovision from Datamine collaboration with Xstrata Nickel at the Nickel Rim South Project. This paper discusses the role of Sirovision in collecting the raw data required for geological and geotechnical analysis and the interpretation in a quick, safe, auditable and reproducible manner.

May 1, 2009

By M. Nagamori, A. J. Plumpton

"A low-grade concentrate from the Crevier Township, Quebec, containing 1.8% Ta205 and 13.7% Nb205 was reduced with carbon at 1600°C, and niobium and tantalum were selectively absorbed in liquid iron. To slag off the zirconia-rich gangue, some silica and lime were added as flux. Metallic iron was added in such a way that the combined contents of TaC and NbC did not exceed 20% in the ferroalloy . Up to 95% of the niobium, and up to 80% of the tantalum contained in the concentrate were recovered in the metal. The ferroalloy was ground finely and dissolved in 2 wt % sulphuric acid to leach out iron and silicon preferentially. The insoluble residue consisted principally of NbC and TaC, the calcination of which yielded an enriched concentrate comprising 80% Nb2O5 and 8% Ta2O5. The insoluble residue could also be chlorinated to obtain an impure liquid of Nb2Cl5 and TaCl5. Process variables and their effects are discussed in terms of higher metal recoveries in the smelting.IntroductionPresently, about one-third of the world production of tantalum comes from the pyrometallurgical reprocessing of tin slag, a by-product of tin smelting, containing sometimes 2 to 10% Ta205 and about the same amount of Nb205. Upon heating tin slags with carbon at about 1600°C in an electric furnace, tantalum and niobium oxides are converted to TaC and NbC, which are absorbed by the coexisting phase of molten metallic iron(1,2). The Fe-Nb-Ta-C melts cannot be decarburized by oxidation because of the preferential formation of Nb and Ta oxides over CO gas(3). So, the ferroalloys containing tantalum and niobium carbides are commercially treated by acid-leaching and I or chlorination to eliminate iron and thus permitting the eventual recovery of purified tantalum and niobium oxides(2).Absorbing Ta and Nb carbides in molten iron was first proposed and demonstrated by Zimmerley and Back(4) in 1957 in order to recover selectively tantalum and niobium from lowgrade concentrates. The process was successfully applied to the electric furnace smelting of tin slags by Hunter and Fursmant(5) over a period preceding 1965."

Jan 1, 1985

By Corby G. Anderson

"Laboratory testing using industrial electrowinning solutions was performed to determine the best Faradic cell efficiency for copper cathode recovery. The variables tested were solution flow rate, recycle ratio, reagent addition combinations of guar and thiourea, and addition amount of acid mist suppressant CAL FAX DBA-70. The ideal flow rate was determined to be 37.85 litre/min. Additionally, the ideal recycle ratio was determined to be 10:1. The reagent addition scheme from testing which showed the highest efficiency was with 680 g/tonne guar of cathode copper won and with 135 g/tonne thiourea of cathode copper won. These values for reagent addition only reflect the best efficiency and should not be assumed to be the best reagent concentration for copper purity. The amount of foaming agent that showed the best efficiency was the test with 2 ppm of foaming agent. Again this amount of reagent is based on efficiency and should not be taken as the amount of reagent that does the best acid mist suppression. Additional proprietary surface characterization work indicates these additives may have enhanced the cathodic reduction surface morphology of some noble minor impurities. Subsequently, these operating parameters were introduced into the plant operation and proved successful after their implementation.BACKGROUNDCopper electrowinning has become a dominant technology for the production of marketable high grade copper cathode products. The literature is robust with applications, optimizations, additives and developments in this field (e.g., Classens & Harris, 1990; Pfalzgraff, 1999; Tozawa, Su, & Umetsu, 2003; San Martin, Otero, & Cruz, 2005; Houlachi, Edwards, & Robinson, 2007; Romero, Avila, Fester, & Yacher, 2007; Marsden, 2008; Beukes & Badenhorst, 2009; Vainio & Weatherseed 2009; Bender, 2010; Joy, Staley, Moats, Perkins, Uhrie, & Robinson, 2010; Khouraibchia & Moats, 2010; Moats, 2010; Rutledge & Anderson, 2015).Tests of forty hours duration and at room temperature were performed for this project using samples of actual industrial electrowinning solutions. These industrial solutions were comprised of 60 g/L Cu plus 65 g/L Ni, 3 g/L Fe, and 30 g/L free sulfuric acid. Other confidential minor impurities were also present including some solubilized precious metals. The testing apparatus utilizing stainless steel anodes and cathodes is illustrated in Figures 1 and 2."

Jan 1, 2016

By J. Peck, M. J. Scobie, M. D. Pollitt

"IntroductionOne aspect of current research in the Canadian Centre for Automation and Robotics in Mining (CCARM) involves the automatic identification of different rock types based on particular drill performance parameter responses. In this paper, the four drill performance parameters of torque, pulldown pressure, rotary speed and penetration rate, were measured from an instrumented rotary blasthole drill during field investigations undertaken at the Fording River Mine, Elkford, British Columbia. The variations in these parameters were subsequently correlated with the corresponding rock types using the results from gamma, neutron and core logs in the same or adjacent boreholes. Work to date has sought to understand the relationships between drilling performance parameter variation and rock properties. Using the results of these studies, the present research is aimed at developing techniques whereby classical statistical pattern recognition methods are applied to drill data to permit the discrimination of different rock units. A monitoring system incorporating such a capability would greatly enhance the quality and amount of geological information on a per borehole basis while drilling. This data in tum could be used economically and directly towards explosive loading, geological exploration and reserve estimation. Background and PhilosophyThis work is an extension of equipment monitoring studies at the Fording River Mine. At this site over a two-year period, 5180 m of data was acquired on an instrumented Bucyrus-Erie 60R drill during routine production blasthole drilling. Throughout these studies, a 311mm diameter S8M Security tungsten-carbide tricone bit was used. The mine, located in southeast British Columbia, is a large-scale, open pit coal operation. The means of excavation revolves around a drill-blast-muck cycle and employs a standard shovel-truck system of transport. Four main rock types are present: sandstone, siltstone, mudstone and coal, with average compressive strengths ranging from 10 MPa to 150MPa respectively (peck 1989). However, based on the field studies, very few differences in terms of strength and compositional properties were seen between the sandstones and siltstones at the site. Therefore, they are referred to as sandstone/siltstone in all further discussions."

Jan 1, 1991

By J. C. Hampton, L. A. Matzar, C. R. Gamwell

In geomechanics, conducting uniaxial or triaxial compression tests require samples to be prepared to a certain length-to-diameter ratio. This ratio is typically defined as 2:1 (length to diameter) and is accepted as a common standard for all materials on which mechanical properties testing is performed. Variations in sample length can cause changes in measured strength properties across multiple material types, such as cement, rock, or soil. Within the oil and gas industry, it is not uncommon to receive samples for technical services work that are slightly under or exactly the length requirement before surface grinding and sample preparation. Many of these samples are discarded from uniaxial and triaxial compression tests and used in another manner; therefore, it is necessary to study the length-to-diameter ratio in efforts to understand the limits and validity of testing samples that are slightly out of the 2:1 ratio. This paper discusses uniaxial compression tests performed using Berea sandstone and a standard cement mixture of 2.54-cm diameter to study changes in rock strength and properties. Compressive strength for each lengthto- diameter ratio over a range of 0.5:1 to 2.2:1 was measured. The investigation was extended to study near-end effects, where the sample length is near, but not exactly twice the diameter. It was discovered that the cement samples conformed reasonably well to the suggested ASTM correction factors. The sandstone did not conform to the correction factors and further analysis is required to develop a correction factor unique to the material. Near end effects, in both the cement and Berea, were found to increase compressive strengths, especially when the L/D of the samples was increased slightly over a 2:1 L/D.

Jan 1, 2015

By B. E. Jones

"The area of uranium deposition is situated within the Churchill Province on the western edge of the Wollaston Iithostructural domain where it underlies the eastern edge of the Helikian Athabasca Formation. The Collins Bay deposit is 6 miles north-northeast of the Rabbit Lake mine. Two principal zones of uranium mineralization are described.The ""A"" zone is a partly eroded, high-grade pod of metal oxide and arsenides sheathed by clay-like minerals. It trends north-northeast and lies under 25 to 40feet of water. Uranium mineralization is localized at or adjacent to the unconformity between the Athabasca Formation and the basement rocks. The basement comprises a granitoid Archean terrain overlain by paragneisses of the Aphebian Wollaston Group. ""A "" zone ore contains phyllosilicates, quartz, pitchblende, rammelsbergite, pararammelsbergite, carbonaceous material, galena, gersdorffite, niccolite, carbonate and a trace of sphalerite.The ""B "" zone lies 6,000 ft south of the ""A "", and subcrops under till cover. It is a partly eroded zone composed of metal oxide and arsenides which occur within variably altered Athabasca Formation. Minerals recognized are phyllosilicates, pitchblende, niccotite, gersdorffite, millerite, carbonaceous material, pyrrhotite, skutterudite and a trace of galena. The Athabasca Formation varies from 90 to 160ft thick. Granitoid gneisses of probable Archean age and paragneisses of the Wollaston Group underlie the deposit. An easterly dipping thrust fault transects its length.The deposit is typical of the ""unconformity-type"" uraniumnickel deposits of the Athabasca Basin. Observed features fit well with the ""diagenetic-hydrothermal"" model for such deposits, as envisioned by Hoeve and Sibbald (/978)."

Jan 1, 1980

By Stephan Day

Comments on Robust M3 to Protect Water Quality ?Regulatory and philosophical thinking have tended to evolve at decade scale since 1970s. ?Mines typically last more than a decade. ?Robustness is defined by the ability to adapt to new realities. Managing Water Quality in BC ?1973 ?BC Pollution Control Objectives ?1977 ?Federal Metal Mine Liquid Effluent Regulation (Fisheries Act) ?Late 1980s ?Philosophy of ?Designing for Closure? ?1990s ?Designing for Acid Rock Drainage Management ?2000s ?Awareness of need for water quality management in general, regardless of acidity

May 1, 2010

By Yoginder P. Chugh

This paper discusses an ongoing field study in southern Illinois (USA) that focuses on: 1) Identifying mechanisms of instability in the set-up rooms (SR) and their T-junctions with headgate and tailgate entries, 2) Developing alternate 3-entry and 4-entry set-up rooms geometry using 3-D numerical analyses, 3) Implementing developed geometries in cooperation with mining professionals and regulatory agencies, and 4) Demonstrating performance of implemented geometries through field monitoring. Illinois longwall mining operations typically experience ground control problems (roof falls, rib sloughing, floor heave, etc.) within SR layouts and around the T-junctions of SR. These occur around the areas where the SR for adjacent longwall face (to be mined) connect with the SR of the previously mined face, and around the tail-gate entries of the mined-out longwall face and around the T-junctions of SR. The problems manifest as highly fractured immediate roof strata, major shear zones in the roof, horizontal displacements within the excavations that result in shearing off the heads of the bolts, floor heave and severe rib sloughing. Similar observations have also been made in longwall mining in Utah.

Aug 1, 2013

By S. M. Bulataovic, D. M. Wyslouzil

"The Martison Lake phosphate-niobium deposit is composed of unconsolidated residuum containing clay and silt-size particles of phosphate, niobium, iron and clay minerals. This paper deals with the laboratory and pilot plant development of the flowsheet and the reagent scheme to treat the Martison Lake ore. The ore, in addition to the complex gangue composition, contained several phosphate minerals including fluorapatite, francolite and florencite. The detailed laboratory and pilot plant evaluation resulted in the development of an effective flowsheet and reagent scheme for the selective flotation of phosphate minerals using a fatty acid circuit, followed by niobium flotation using amine collectors at acid pH. The developed flowsheet included des liming of ore, magnetic separation, and selective P 2 O 5 -Nb 2Os flotation. The main aspects discussed include characterization of the ore, step by step development of flowsheet and evaluation of dfferent modifiers and collectors for P20s and Nb20s flotation.INTRODUCTIONMartison Lake phosphate-niobium ore deposit, located 75 km north of Hearst, Ontario was discovered in the early 70's and has been the subject of extensive technical-economic evaluation in the late 70's and early 80's.The deposit is covered completely by 30 m to 90 m of glacial overburden and is composed entirely of unconso1idated material called residuum, that lies on top of a precambrian age carbonatite intrusive from which the residuum was derived by weathering and natural leaching in situ. The residuum is and irregularly-shaped horizontal lens, 2 km by 3 km in area, and up to 100 m thick, composed mostly of unconsolidated clay and silt-size particles of phosphate, niobium, iron, mica and clay minerals."

Jan 1, 1986

By V. G. Papangelakis, T. Clark, G. Kolliopoulos

Sustainability of the hydrometallurgical industry requires the development of processes for effective water recovery; if process water is recovered and recycled, fresh water intakes will be reduced. Forward osmosis (FO) is an innovative membrane process that promises to recover water from industrial process aqueous streams or seawater with less energy input compared to reverse osmosis (RO) and evaporation; the energy efficiency relies on the spontaneity of the process (no energy input required). The driving force of the process is the osmotic pressure gradient between a dilute feed solution (process water) and a concentrated draw solution. The draw solution is an engineered aqueous solution that contains a highly soluble chemical reagent that is able to osmotically "draw" only water from the dilute stream, through a semi-permeable membrane, leaving behind a small volume of concentrated brine. The draw solute is separated and recovered for reuse, leaving behind water. The main energy requirements of the FO process arise from the separation and the regeneration of the solute chemicals from the diluted draw solution. This work focuses on the evaluation of aqueous carbonated trimethylamine (TMAH:HCO3) as the draw solution and reports recent findings on the separation efficiency of TMA and CO2 from the solution.

Jan 1, 2015

By H. Kolcz, G. S. Dobby, R. Stratton-Crawley, S. W. Wilson

"The Matte Separation plant at Inco's Copper Cliff Smelter Complex is described. The continuing implementation of flotation column technology in the flowsheet in various applications is reviewed. Comparative studies on 0.038, 0.10, 1.1 and 1.8 m diameter columns have been carried out. It was demonstrated that consistent metallurgical performance was obtained with both pilot- and plant-scale units. Grade-recovery relationships for plant columns can be predicted with confidence from data obtained from test equipment. The work indicates further areas of the flowsheet in which columns present an attractive alternative to conventional cells. INCO’s MATTE SEPARATION PROCESSNickel concentrate from Inco’s Sudbury area mills has been processed in the Copper Cliff smelter for sixty years. Prior to that, Sudbury ores had been smelted directly. Historically, copper-nickel separation from smelter converter matte was achieved by the classical Orford process. In the mid-1940s Inco developed an improved separation scheme based on mineral processing methods, the Matte Separation Process. A generalized Copper Cliff Smelter Complex flowsheet is shown in Figure 1.Iron sulfide and gangue contained in the nickel concentrate are rejected in the smelting-converting process. The molten product, typically containing 50% Ni, 25% CU and 22% s, is cast at about 1000 ºC, into floor moulds and allowed to slowly cool for four days. During this period nickel sulfide (heazlewoodite, Ni,S,), copper sulfide (chalcocite, cu,S) and a copper-nickel metallic alloy precipitate and form a coarse grain structure that is amenable to separation by physical means. The phase chemistry of this system has been described previously by Sproule et al (1). This matte then becomes the feed to the Matte Separation Process.A simplified block flowsheet of the Matte Separation Process is shown in Figure 2. Matte ingots, typically weighing 20 tonnes each, are broken and crushed in a three stage crushing plant to approximately minus 0.01 m and conveyed to the Matte Separation building. Grinding is carried out in two parallel circuits each consisting of a rod and ball mill in series producing a flotation feed which is 65% minus 44 microns. Typical throughput of each grinding circuit is 650 tonnes/day. The metallic fraction of the feed is recovered by magnetic separation. This product, containing about 66% Ni and 15% CU, is a major component of the feed to the Copper Cliff Nickel Refinery."

Jan 1, 1990

By B. A. Peppley

The current most common method of hydrogen production for fuel cell systems, including SOFC systems, is autothermal reforming. Autothermal reformers have a number of advantages including fast start up and load following and ease of control. However, there are a number of problems inherent with the addition of air into a system connected to the anode feed such as dilution of the fuel with nitrogen and the potential for oxygen to reach the anode chamber directly. Pure steam reforming, which does not involve air addition, provides a richer fuel mixture to the SOFC anode and is inherently safer than autothermal reforming. Although in theory pure steam reforming can be shown to provide these advantages, a number of technical problems need to be overcome before such a system can be practical. In particular, issues such as catalyst degradation due to poisoning and thermal sintering, coking, as well as fuel-steam mixing need to be addressed. Experimental results from a prototype reformer will be presented to illustrate a number of these points. This paper will compare differences in system efficiency, safety and complexity between autothermal/SOFC systems versus a steam reformer/SOFC system. A system simulation will be utilized that is able to account for material and energy balances for a SOFC power generator operating on diesel fuel. The requirements for improved catalysts will be discussed and an analysis of the potential benefits of sulfur tolerance and lower temperature activity will be considered.

Jan 1, 2005