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By T. Sugawara, H. Sekimoto

Electrorefining of low-grade copper alloys containing various amounts of nickel, lead, antimony, bismuth, arsenic, selenium, silver, and gold in sulfamic acid media was demonstrated. The copper concentration of the alloys used as an anode was 70–90 wt%. The electrolyte contained 100 g L-1 of free sulfamic acid and 40 g L-1 of cupric ion. Galvanostatic electrolysis was conducted at 200–300 A m-2 in the electrolyte using a low-grade copper alloy anode and a stainless steel cathode at 25C. The terminal voltage was approximately 0.8 V at the start of the electrolysis, although it increased periodically to approximately 2.0 V and then shortly returned to its initial value. Nickel, lead, and arsenic from the anode dissolved in the electrolyte and were removed. Antimony, bismuth, selenium, and silver were removed as solids. Consequently, a dense copper cathode was obtained, and the concentration of copper was evaluated by inductively coupled plasma – optical emission spectrometry to be 99.82–99.99 wt%. INTRODUCTION Electrorefining of copper is conventionally carried out in a sulfuric acid electrolyte using crude copper assaying at 99.5 wt% Cu as the anode (Biswas & Davenport, 1994). Elements more noble than copper do not react anodically, and consequently, they are distributed in anode slimes. Elements less noble than copper dissolve from the anode. Nickel and arsenic are stabilized as aqueous species. Lead, antimony, and bismuth react with water, sulfuric acid, or arsenic acid to form barely soluble compounds; thus, they are distributed in anode slimes. An emerging issue in the electrolytic refining of copper is an increase of impurities in crude copper used as the anode (Moats et al., 2013). This is due to an increase in the content of impurities in copper concentrates as well as an increase in the types of secondary copper feedstocks (e.g., E-Scraps, automotive shredder residues, and smelting residues) treated in the copper pyrometallurgical process. An extreme case is a copper smelter that does not use copper concentrates as feedstocks. In such a process, copper-bearing feedstocks are smelted in a top submerged lance furnace to prepare low-grade copper alloys assaying at 80– 90 wt% Cu (Sekimoto et al., 2013). Such low-grade copper is not acceptable as an anode in the conventional copper electrolytic refining process because it is easily passivated during electrolysis. Consequently, electrolytic copper is produced by leaching the atomized low-grade copper in a sulfuric acid solution with oxygen, followed by electrowinning. However, electrowinning should be avoided whenever possible because the electrical energy consumed in electrowinning is 5–10 times higher than that consumed in electrorefining. Therefore, the development of technologies for electrorefining of low-grade copper alloys is desirabl.

Jan 1, 2019

By A. G. Slade

"This paper deals with the direct application of rock mechanics in the underground mines at the Sudbury Operations of Falconbridge Nickel Mines Ltd. It covers mining methods, the use of photoelastic models, the fore-casting of rock strains and their elimination, closure methods and other common methods of ground control.INTRODUCTIONROCK MECHANICS IS A STUDY IN ROCK BEHAVIOUR and, although it is being termed a new science, it has been practiced since the industry began. Every person involved with rock excavations, from the mine superintendent to the stope driller, is actually practising rock mechanics. They probably call it by another name -experience, and applications of this knowledge are in evidence throughout the Falconbridge operations. Only in recent years have formal rock mechanics studies been employed to provide technical assistance to the mine operators in their primary objective of producing ore safely."

Jan 1, 1968

By S. Masambi, S. M. Bradshaw, C. Dorfling

The presence of iron in base metal leach solutions complicates nickel and copper recovery processes. Leach solutions are commonly purified by precipitating iron as hematite, jarosite or goethite. Fast oxidation of ferrous to ferric is an important step to remove iron by precipitation at low pH values. This study reviews the ferrous oxidation mechanism and reaction rates in chloride media using molecular oxygen. This work contributes to the development of a better understanding of iron precipitation processing steps, which continues to be an important matter in hydrometallurgy. The specific objectives were to investigate (1) the effect of key process variables (acid concentration, copper concentration, and temperature) on the rate and extent of ferrous oxidation by dissolved oxygen and (2) the oxidation mechanism by varying chloride and hydrogen ion concentrations separately. Batch oxidation tests were performed using synthetic chloride solutions containing 45 g/L Fe and 3 g/L Ni at 50 and 80°C, dissolved Cu concentrations (0.3 to 3 g/L) and HCl concentrations (2 to 4.6 M). Regression analysis indicated that the significance of the effect of different variables on the extent of oxidation achieved after five hours decreased in the following order: HCl concentration > Cu concentration > temperature. Increasing the HCl concentration from 4 M to 4.6 M caused the degree of oxidation achieved after two hours to increase from 58.3% to 98.1%. The catalytic effect of dissolved copper on ferrous oxidation was more significant at low acid concentrations. Experimental data suggest that rapid oxidation of ferrous is possible at high HCl concentrations for two main reasons. First, the formation of ferrous chloride complexes allows ferrous oxidation to proceed without the formation of superoxide as an intermediate product (the rate limiting step in dilute acid solutions). Second, the formation of ferric chloride complexes stabilises the oxidation product.

Jan 1, 2016

By G. C. Weatherly, L Beitelman, M Gray, M. W. Bates, R Hadden

"A program of evaluation of in-mould electromagnetic stirring on the product of a straight-mould, billet continuous casting machine has been carried out. The effects on macrostructure, surface and internal quality, chemistry segregation and mechanical properties on carbon, low-alloy and resulphurized, free-machining steel billets and rolled bars are discussed. Operational aspects as a result of in-mould stirring are highlightedIntroductionA development program on electromagnetic stirring (EMS) in the mould of a continuous caster was started by Ferrco Engineering Limited in 1979, with the first experimental device being developed and installed at Lake Ontario Steel Company. As a result of these initial trials, new designs of in-mould EMS systems have been developed and are currently being used in continuous casters in North America and Europe. The rapid progress which has been made is in large measure due to the fruitful cooperation which has existed between the various parties, including Ferrco, the EMS equipment manufacturer, several operating plants and the University of Toronto.A brief review of some of the basic ' principles of electromagnetic stirring action on solidifying metal, and the landmarks of this process development, will explain the philosophy of this cooperation.From casting practice, it is well known that an equiaxed dendritic structure provides better' material properties than a columnar dendritic structure. Homogeneity of the equiaxed structure leads to better control of material properties, such as strength and ductility. Therefore, many efforts are being made to obtain this structure in continuous casting.The extent of the equiaxed zone is determined to a large degree by convective flow in the liquid. Fluid flow can fragment dendrites in the columnar zone, which then act as nuclei for grains in the equiaxed zone farther down the sump. This process is referred to as dendrite or grain multiplication."

Jan 1, 1982

By Marcel Laflamme

Underground mine workers are continuously exposed to many sources of noise and vibration in carrying out their tasks. Even though the vibration and sound level of some mining equipment is documented, it was found that this information is not readily available for many pieces of equipment and that it is not considered when choosing equipment or planning tasks. As well, health problems related to vibration and noise are among the main causes of work-related compensations in mines. Considering those facts and although no Canadian regulations could force employers to limit the exposure of their workers to vibration, the Société de recherche et développement minier (SOREDEM) decided to address the problem by including vibration among their research priorities. In order to characterize noise and vibration sources of different mining equipment used for underground mining, the authors have performed a study in 8 different mines in Québec on 28 different mining equipments. The paper will present the procedure that was followed to select the list of equipment to be evaluated and the low cost acquisition system developed to perform multichannel time domain acquisition in harsh environments. It will also present the results obtained for the noise level produced by the equipment as well as for the hand-arm and whole-body vibration exposures.

Aug 1, 2013

By M. Connell, S. Bedrossian

Alkali cracking followed by chloride-based leaching is one of the prominent methods for rare earth element processing. Regeneration of the leach lixiviant, namely hydrochloric acid, is a critical operation in the process. A number of different process routes are available for recovery of hydrochloric acid from chloride solutions. The objective of this paper is to discuss various recovery routes and analyze the impact of several input variables on the variable operating cost.

Jan 1, 2014

By B. M. Das, F. Claridge, V. K. Garga

Coal, as well as a large part of other minerals in Canada, is produced by surface mining methods. This has resulted in short and long-term accumulation of waste rock in dumps. Two main problems arise from the flow of water through these dumps: stability of dumps and the impact on stream flows. In recent years, a number of mines have started placing waste rock in valleys for general disposal or far constructing mine access road ways. All these have created challenges in the following areas: effective design of dumps and flow-through dams; stability monitoring of the structures; environmental impacts downstream by way of increased amount of fines in suspension, sedimentation, and toxic substances; and long-term status of flow and flood. Similar situations also exist in many civil engineering structures. This paper discusses the status of rock drains and the immediate and future research needs.

Jan 1, 1990

By Robert B. Parsons

"As the 1981 annual reports of Canadian mining companies one by one see the light of day, it becomes clear that softer metal prices and rising costs are the main problems which beset the industry today. These problems are certainly not lightened by that familiar monster lurking in the shadows-taxation! Recent taxation trends in Canada, and the existing tax regimes for the mining industry, continue to be a major bugaboo.This examination by ""Tax Notes"" of the impact of current taxation trends on the mining industry is based on a speech delivered recently by Robert D. Brown, senior tax partner of Price Waterhouse, Canada, to the annual meeting of the American Institute of Mining, Metallurgical and Petroleum Engineers in Dallas.IntroductionThe purpose of this paper is to tell a story-and it is a story with a moral. The first thing to recognize is that, with depressed metal prices and weakening western economies, high taxes, in and of themselves, are not really the cause of the Canadian mining industry's present doldrums. However, the character and level of mining taxes in Canada has had a profound influence on the development of the industry over the past decade, and the expectations of what the future holds for mining men in Canada will equally play an important role in the future development of the Canadian industry. Our tax system has, in the past, served as a negative and destabilizing influence in the mining industry: it has contributed to a major short-fall in investment commitments and hence in the contribution which the mining industry can make to the Canadian economy, and the adverse effect on the industry of previous high marginal tax rates was made far worse by the confusing, contradictory and perverse nature of the tax system itself."

Jan 1, 1982

By Rita Michael

"The Marmara Ironworks was not the earliest ironworks in Ontario, but it was distinguished from other early works in a number of ways. It was established on an ambitious scale as a self-sufficient and, for the time, sophisticated community. In effect it was an iron plantation on the scale and scope of those at Hopewell, Pennsylvania and Saugus, Massachusetts(1). It was, besides, the only one of the few early ironworks in Upper Canada which operated almost to the end of the nineteenth century, albeit in fits and starts, and which used magnetic ores rather than bog iron ores (limonite). Furthermore it is the only works which has produced archaeological interest over a number of years. The ironworks is on the east bank of the Crowe River near Highway 7, on Lots 7 and 8, Concession 4, Marmara Township, Hastings County, Ontario. It is the property of the Village of Marmara, and the extant remains encompass about 2. 5 acres of the original 2000 or so which made up the original grant. The mineral riches of the Canadian Shield had been known since the days of the Jesuit missionary-explorers. A consortium headed by Alexander Henry and the Duke of Gloucester planned to exploit the copper near Sault Ste. Marie during the last part of the eighteenth century, but nothing came of the venture(2). This attempt may have grown out of Lord Dorchester's suggestion that private enterprise be encouraged in order that the iron ore which ""abounds"" in Canada might be exploited(3). John Graves Simcoe, the first Lieutenant Governor of Upper Canada was also anxious to see iron working develop. Simcoe was eager to encourage many enterprises, among which ""the development of iron mines""(4) - Governor Gore had been approached by John Mason for help with his ironworks in Norfolk County (5). Three Americans had applied for permission and support to erect an ironworks on the Gananoque River at the falls to become known as Furnace Falls. They were granted 1000 acres of land in fee simple to encourage their endeavor(6). Sir Peregrine Maitland, only a few months after taking up his duties as Lieutenant Governor in 1818, intended to visit the ""bed of iron ore on the Crow River"" (7) - Maitland was to provide a good deal of support, both moral and substantive, to Charles Hayes when he came to Canada in 1820."

Jan 1, 1999

By J. J. Barakso, S. J. Horsky, H. V. Warren

"A review of past and present biogeochemical studies is given. Early and more recent analytical procedures are described and compared. Tables 1-5 give silver concentrations in various organs of some plant species at different localities. Table 6 and conclusions provide guidelines for exploring for silver using biogeochemistry.IntroductionBiogeochemistry has been shown to be a useful tool in the search for gold deposits, especially those of the disseminated type (Warren and Barakso 1982). The purpose of this paper is to demonstrate that biogeochemistry can also be of assistance in searching for silver concentrations buried by as much as twenty feet of overburden without inflicting any damage on the environment."

Jan 1, 1984

By R. W. Zeindler, D. A. Fawcett

"A summary is presented of the report completed by the Coal Mining Research Centre in 1980. This report was of a cross-pit conveyor system applied as an auxiliary mining complement to the major stripping unit, a dragline. The purpose of the CMRC report was to evaluate selective mining and replacement of the upper horizons of the strata as an aid in reclamation. These strata were the topsoil, subsoil and glacial till.Past utilization of cross-pit conveyor systems and related engineering studies were assessed. The parameters of the study were based on the mining and geological conditions of the Alberta prairie coal mines. The principal excavator for stripping was a dragline. Excavation of the upper horizons was done by a bucket-wheel excavator discharging onto the crosspit conveyor. Alternative equipment applications were economically compared. Four cases or geological sections were evaluated in detail. The economics of the alternative mining systems for each of the cases were determined. In all instances, the most economical solution was a tandem system utilizing a dragline with a bucket-wheel excavator/ cross-pit conveyor system."

Jan 1, 1981

By Jorge Blanco, Joaquin Gotor, Enrique Delgado, Carlos Frias

Since 2009 Cobre las Cruces (CLC) has successfully operated a sustainable mining business near Seville, Spain, applying the most advanced hydrometallurgical technologies to process secondary copper sulphide ores through atmospheric leaching in ferric sulphate media and using oxygen sparging in a cascade of ten reactors. In comparison to conventional copper smelters, the CLC hydrometallurgical process does not generate SO2 gas, airborne emissions or slags. The copper ore is ground and sent directly to atmospheric leaching reactors; flotation is not required, and consequently, copper extraction is maximized at 93-95%, while producing 72,000 t/y copper cathodes of the highest purity (99.999 wt.% Cu, Grade A). Reserves for the CLC deposit were estimated at 16 million tonnes of ore averaging over 6 wt.% Cu and containing principally a chalcocite mineralization. Other copper bearing species include digenite, covellite, chalcopyrite, bornite and enargite. Pyrite represents over 70 wt.% of the ore. In the CLC leaching process, chalcocite reacts with ferric sulphate at approximately 90 ºC and copper is released into solution while ferric ions are reduced to ferrous ions. The ferric sulphate leachant is regenerated continuously by oxygen injection and consumes sulphuric acid. It is remarked that pyrite plays a crucial role to yield high copper leaching rates. When pyrite is oxidized, a small proportion of iron is co-leached and some sulphuric acid is generated. The CLC leaching technology has been designed to allow a certain level of pyrite oxidation, which is positive in many ways: (i) to maintain a Fe/Cu ratio in solution; (ii) to facilitate Fe(II) oxidation; (iii) to produce a high redox potential; and (iv) to counterbalance a bleed solution that removes some iron. Moreover, galvanic interaction between pyrite (cathode) and chalcocite (anode) can substantially increase atmospheric leaching kinetics and efficiency (copper recovery).

Jan 1, 2016

By MacKenzie Dickson

"INTRODUCTIONGold is found in many natural states, native nuggets, loose grain in river sands, veins in rock, as well as associated with sulphides, oxides, etc., disseminated more or less minutely.Its high value in recent years has spawned new technologies to win values from sources once considered too lean for commercial recovery. Cyanide leaching from fine milled ore or tailings, from upstream recovery operations, coupled with adsorption onto relatively coarse granules of activated carbon, concentrate the gold enough to be converted to bullion by time-honoured methods.The carbon granules are fragile. Size degradation in handling must be minimized not only to prevent loss of gold on fine fragments of carbon that could pass with the barren tailings, but to maintain adsorption efficiency. Besides, the granulated carbon itself is costly. Circular Vibroscreens are winning acceptance for dewatering carbon granules thanks to their gentle yet effective performance in gold recovery systems around the world. The system at Equity Silver is illustrative.BackgroundEquity Silver Mines Ltd., Houston, British Columbia, first began production in September 1980. In 1984, a feasibility study showed that additional gold and silver could be economically recovered through cyanide leaching of the flotation tailing.Although the carbon-in-pulp (ClP) or carbon-in-leach (CIL) process is commonly used for extracting precious metals from slurries, the use of circular vibrating screens, and Vibroscreens in particular, for the carbon circuit is an innovation that cuts costs.Rectangular vibrating screens have been the conventional separation mechanism of choice across North America. In contrast, the use of Vibroscreens has been proven to be less costly for the initial purchase and installation. Also, these circular vibrating screens require less power and less space. A description of Equity Silver Mines' process shows how these screens have been successfully integrated into the system."

Jan 1, 1989

Induced microseismicity monitoring is: ?Essential tool in improving the geotechnical understanding about a mine and its inaccessible surrounding rock masses. It helps to determine: -Event timing, location, and magnitude - identification of highly stressed areas -Event source mechanism - the physics of fracturing in its seismic source region -Seismic strain-rate distribution in 5D - identification of stress concentration or migration patterns -Geomechanical interpretation - identification of hidden geological structures or weaknesses in the ground -Strategy for mining e.g. by a block caving method - maximization of mine production and to optimize ground support design -Potential of future seismic hazards -Large event re-entry protocol, to improve mine safety ?The norm as part of mine safety maintenance and long-term mine design practices

Aug 1, 2013

By Hongyan Qu, Lihui Zheng

"Horizontal wells in coal seams, Qinshui basin, China are prone to wellbore instability problems induced by drilling, completion and production operations due to the presence of natural cleat network, anisotropy with regard to permeability, brittleness and mechanically weak property of the coal rock. The mechanism of wellbore instability in coal seams is very different from that in conventional formations, the traditional wellbore stability study methods therefore, are not proper for wellbore stability analysis in coal.In this study, the mechanism and controlling of wellbore stability of coal seams in the Qinshui basin was investigated through theoretical modeling, laboratory experiment and field operation. Firstly, a new physical model of wellbore stability for highly-cleated coalbed was proposed, considering the combined effect of mechanical mechanism and reservoir characteristics, specifically, taking the effect of reservoir pore pressure in the vicinity of the wellbore on the wellbore stability into account. Then experiments on the triaxial stress evaluation were conducted at laboratory where rock mechanical parameters such as Poisson's ratio, Young's modulus, compressive strength, tensile strength, angle of internal friction and cohesion ability were measured respectively. The in situ stress at different depths in four wells of Zheng 1-303, Zheng 1-308, Zheng 1-309, and Zheng 1-310 in the Zhengzhuang were calculated, and the collapse pressure and formation breakdown pressure were predicted through the theoretical model we developed. Finally, by comparing the maximum collapse pressure and minimum breakdown pressure of the four wells in the coal as well as in the roof and floor of the coal seams, the fluid weight window for safe drilling in each coal seams was determined, and appropriate approaches against anti-sloughing in coal seams, Qinshui basin were applied in the field operation.The wellbore stability was found not only related to the wellbore pressure, but also affected by the pressure in the reservoir through the theoretical model. The fluid weight window for safe drilling in each coal seams varies with the coefficient of wellbore stability in the model. The laboratory experiment results indicate that the roof and floor of 3 # coal in Qinshui basin has high breaking strength, high heterogeneity, and are easy to collapse and breakdown. In addition, the whole rock mineral analysis shows that 3 # coal in the Duanshi block has high clay content, resulting in the phenomenon of hydration swelling as clay encountered water, and leading to unstable coal and extreme large drilling uncertainties. Due to the effect of the unstable rock mechanical properties of the roof and floor formation on the wellbore stabilizing, drilling parameters, drilling fluid performance and BHA were optimized during the drilling process according to the formation properties, rock mechanical properties and drilling techniques in the field operation."

Jan 1, 2015

By D. Tetsuka, H. Okamoto

The amount of impurities to be processed in a copper smelting process has increased for recent years because of an increase in the electronic scrap amount. It has been found that Sb and Ni effect on the operation of our copper electrorefining process. It is found that the current efficiency of the copper electrorefining tended to be decreased as the Ni concentration in the electrolyte increased. The passivation of the process seemed to be more related to SO4 concentration in the electrolyte rather than the Ni concentration in it. The current efficiency decreased when the Sb content in the anode was high. A high Sb content in the anode caused easy passivation by forming a gel-like film in the slime layer. We have developed a method to for see the anode passivation in a short time while generating a slime layer. We confirmed the tendency of passivation through the experiment of changing Pb content in anode. Passivation was easily occur with an increase in Pb content in the anode. The amount of slime increased as the Pb content in the anode increased. This suggests that passivation was facilitated because liquid diffusion near the anode was inhibited. INTRODUCTION The amount of impurities to be processed in copper smelting has been growing in recent years because the amount of electronic scrap has increased. Figure 1 shows that the contents of Sb and Ni in copper anodes have increased since 2007.High Sb and Ni contents in the copper anode decreased the current efficiency of the process and made the quality of copper cathode poor because of the anode passivation and the formation of floating slime in the electrolyte during electrorefining. If these influences of impurities are suppressed, it would be possible to make copper electro-refining current density higher and to process much amount of electronic scrap. We examined the components of our copper electro-refining process like anode composition, slime properties and electrolyte composition, and investigated the mechanism by which Sb and Ni affect passivation and current efficiency. When examining the influence of Ni, we noticed that the SO4 important. The effect of SO42 – was also discussed

Jan 1, 2019

By S. Zador

"IntroductionIn the past decade, metallurgical and mining companies have shown an increased interest in the licensing of technology. When licensing technology, it is usually to the benefit of the parties, to have at least some of the technology to be licensed protected by a patent.This paper is intended to bridge the gap between the engineer in the field of mining, metallurgy and mineral processing who is interested in exploiting an invention commercially, and the patent agent or intellectual property lawyer whom he/she might retain to prepare a patent application and then prosecute the application to obtain a granted patent. It is also intended to encourage the inventor or a small business concern to consider the value of patents in the sale and licensing of technology. The lawyer may subsequently advise and assist the inventor in licensing his/her invention.A brief outline of some of the basic features of the patent system follows. The nature of the information, which the patent professional requires from the inventor to enable him/her to draft a patent application, will also be considered in general terms. Furthermore, various types of licenses which may be drawn up between a licensor of specific technical information and a licensee, will be listed and briefly discussed. No attempt, however, will be made to give a comprehensive and detailed account of the above aspects; the interested reader should consult legal publication and reference books, and patent professionals for further specific information.A granted patent is a document which describes an invention and how to practise it. The claims of the granted patent, figuratively speaking, fence off the intellectual property the inventor regards as his invention. The Commissioner of Patents, representing the Government, grants to the inventor or his assignee the exclusive right of making, constructing and using the invention, and selling it to others to be used, for a limited period of time, in exchange for disclosing the invention to the public. Thus, a patent prevents others from practising the claimed invention but it does not, necessarily, bestow the right to the patentee to practise his own invention. The term of a patent now in Canada and in most of the developed countries of the world, is 20 years from the date of filing the patent application. In the United States the patent term is still 17 years from the date of issuance of the patent. In Canada, the term was changed to 20 years in the new Canadian Patent Act which came into force on October 2, 1989. Any patent application filed prior to that date or granted before it, retains a 17 year life, commencing at the time of grant."

Jan 1, 1991

By Greg Johnson

Maintenance needs information about assets to optimize availability and production needs information about performance and consumption to maximize output. In considering both these needs together as, ?Asset Optimization?, the information systems that support them are critical. The theory of Asset Optimization derives from the Lean Manufacturing concepts developed by Toyota, but some changes are required to apply this to mining operations. In particular, mining operations require automated systems due to their geographic spread and they need a strong emphasis on capturing under-performance losses as well as delays and stoppages in production. Leading metal miners and coal miners alike have applied these systems to good effect in the last 10 years. The concepts developed initially in minerals processing plants are now being applied to the mines themsleves as well as the mining logistics chain. Production increases of 5?10% are achievable with the right implementation and consideration of the some key lessons learnt in the last 10 years. Putting these lessons into action is one key step in the goal of optimizing asset performance and thus utilizing the resource at lowest cost.

Aug 1, 2013

By F. P. Hassani, J. F. Boily, A. M. O. Mohamed, M. Hossein

The optimal geochemical parameters required to form ellringite in a lime-remediated site have been investigated with the use of thermodynamic modelling. The speciation of sulphate and 10 metals analyzed in samples of a mine tailing from northern Quebec was calculated with a computer model. The model also includes calcium, which would result from the addition of lime to the system. Two speciation calculations were done. The first one is a hypothetical speciation before the onset of precipitation and was used to devise the stability fields of minerals susceptible of forming in high pHs. The stability fields were determined by building activity ratio diagrams with sulphate, aluminum and calcium species concentrations for pHs ranging from 4 to 14. The investigation was carried out for a 25°C solution with an ionic strength less than 0.12. Thermodynamics predict that an optimal stability field for ettringite in the mine tailing samples containing 10-3 mol/L SO4-2,10-2 mol/L of AI(OH)4 requires at least 10-2mol/L of Ca+2 and a pH larger than 11.6. The sulphate contents of the mine tailing samples, however, limit the precipitation of ettringite and monosulphate could be an end-precipitate. The second speciation is in equilibrium with precipitates and provides information on the speciation of the residual metals. If ellringite could be precipitated as a stable form, it could serve as a sorptive agent for residual metals, and, due to its binding properties, consolidate tailings.

Jan 1, 1995

By L. C. Bird, A. I. A. Salama, M. W. Mikhail

"A program of sampling in Canadian washeries was carried out by the Coal Research Laboratory (CRL) over a period of two years to evaluate the performance of various density separators in these operations(1). Operating data on quality and recovery of products, separation efficiencies and cutpoints for each separator type are compared with data predicted using computer models developed from previously existing data.The Heavy Medium Cyclone (HMC), Heavy Medium Bath (HMB) and jig models give predictions of recoveries and qualities of products for sizes coarser than 10mm with absolute value of error mean less than 7 per cent, whereas predictions of the Water Only Cyclone (WOC) model for -10mmfine coal are with absolute value of error mean less than 8 per cent. Although less accurate for -10 mm fine coal, the HMC and jig models produce predictions of recoveries with absolute value of error mean less than 2 per cent and quality of products predictions with absolute value of error mean less than 28per cent which are generally acceptable because more liberation in the fine fractions appears to compensate for any difference in the accuracy of separation, resulting in good prediction of the clean product. However, ash content of the actual fine refuse was lower than predicted. The difference is attributed to the highly friable nature of Canadian coals which tends to cause an excessive loss of coal fines to the fine refuse.A comparison study based on quality and recovery of products is made between the Dutch State Mines (DSM) models and the recently modified models, both produced comparable predictions."

Jan 1, 1985