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By Li. L.

Backfilling has become a popular solution in underground mines around the world. It reduces environmental impact of mining industry and improves ground stability. In most cases, backfill has a high water content so that it can be delivered by pipes from a backfill plant on ground surface to underground stopes. Upon deposition in the stope, the backfill tends to consolidate under its own weight, leading to a generation of excess pore-water pressure. To avoid excessive pressure and protect the backfill barricade installed at the base of the stope, the backfilling of the stopes is usually divided into two stages: plug pour and backfill body pour. The interruption of backfilling operation is undesirable as it slowdowns the mining productivity, and sometimes causes pipe clogging, leading to unexpected increase in manpower cost and further reduction in mining productivity. The backfilling interruption time may be reduced, even eliminated if the drainage of backfilled stopes is sufficiently improved. This paper presents an application of wick drains, a material commonly used in civil engineering, to mine backfilled stopes to help accelerating the drainage. A protocol is proposed for installing the wick drains in a mine stope to be backfilled. Numerical simulations were made, showing that the drainage of the backfill can significantly be improved by the introduction of wick drains. The application of wick drains in mine backfill can thus be considered as a promising technique and merits deeper and more detailed investigation.

Aug 1, 2013

By Ji Wang

Reflective in-seam wave detection has the advantages of a far detection range and wide applicability. It has been successfully used in detection of many abnormal geological structures in work-faces, such as faults and collapse columns. However, a reflective in-seam wave is a dispersion wave. It has weak energy and is always covered by the direct in-seam wave. In the past, underground seismic explorations were not able to image the opposite roadway using reflective in-seam waves. To solve this problem, we propose a new method of reflective in-seam wave imaging based on adaptive dispersion filtering. This method processes the reflective in-seam wave using a filter with the parameter of transmission distance. The degree of similarity of the filtered and the explosion signal is used to estimate the transmission distance and image the reflective objects. We test and verify this method using real underground seismic data. This research is helpful for the detection of coal mine goafs and abandoned roadways in work-faces or in front of tunneling ends.

Aug 1, 2013

By R. C. Hartviksen

"The Drumbo Mine is a new gypsum mine located at exit No. 32 of Highway 401 between Woodstock and Kitchener, Ontario. The flat-lying 6-foot (1.8-metre) bed of gypsum is near the base of the Silurian Salina Formation, about 380 feet (116 metres) below surface. The mine is owned and operated by Westroc Industries Limited. A shaft, 12.5 feet (3.81 metres) in diameter, was drilled and then lined with a liner-sinking technique new to this continent. The shaft was completed in the fall of 1977. Gypsum production was started in December 1978, employing a conventional room - and - pillar method of mining.Historical BackgroundA brief mention of gypsum in the Drumbo area is included in a survey of the Ontario gypsum industry by Guillet. This occurrence was discovered in 1958 when National Gypsum conducted some widespread diamond drilling. Western Gypsum Products Limited acquired leases in 1960 and concentrated a drilling program in Blenheim Township near the village of Drumbo; 79 holes were drilled in an area of 1900 acres (770 hectares). Mining rights were then acquired for 170 0acres (690 hectares). A test shaft, 44 inches (1.1 metres) in diameter, was drilled to obtain a 50-ton (45-tonne) bulk sample. This opening will be used as an emergency escape way and for ventilation.Westroc Industries Limited, a wholly owned subsidiary of BPB Industries, has its head office at Mississauga, Ontario and operates gypsum board plants at Mississauga, Vancouver, Calgary, Winnipeg and Montreal. Other gypsum mines are at Windermere, B.C. and Amaranth, Manitoba."

Jan 1, 1983

By R. W. Guill

"The Apex Mine is currently scheduled to be brought back into production by Hecla in the first quarter of1990. Its projected productivity rate will be exceptionally high for a small underhand cut and fill mine.The ore mined at the Apex Mine occurs within a pipe-like structure as a series of iron oxides containing both gallium and germanium, plus significant amounts of silver, zinc, lead, and copper.Ground conditions in and around the ore zone have dictated that unique approaches be utilized. To date, these have included a prototype 0.5 cu. yd diesel LHD, and the use of fibrous shotcrete in 4ft by 7ft headings, and the first pneumatically-placed cemented backfill in North America. Above all else, it is the combination of new technologies with a small and dedicated workforce which has allowed for the successful development of this ore body.IntroductionThe Apex Mine is an example of the typical small underground project. It has high grade, but low tonnage and is deposited in poor ground. In such cases, conventional planning and thinking generally results in an uneconomical evaluation and negative production decision. Fortunately, some unconventional thinking was allowed to take place during the planning and evolution of the Apex Mine development. The result now serves as an example of how such unconventional thinking can lead to the type of innovations described below.The job necessitated the development and use of new equipment and materials to execute a highly flexible underhand cut and fill mine design/pneumatic backfill concept, that must be constantly modified as different than assumed conditions become evident in and around the ore zone."

Jan 1, 1990

By P. Trudel, M. A. . Cloutier

This lithogeochemical study demonstrates that the Gilman and Blondeau Formations in the Chibougamau area belong to a subalkaline suite of tholeiitic affinity poor in potassium. The Gilman Formation is composed mostly of basalts, with subordinate andesites and rare dacites, while the Blondeau Formation comprises all lithologies of the basalt-andesite-dacite-rhyodacite-rhyolite ensemble. Both AFM and Harker variation diagrams show that all these rocks originated by differentiation from the same magma reservoir, and are related to one volcanic episode, This study did not, however, identify hydrothermal alteration zones useful for regional geochemical prospect ion.

Jan 1, 1984

By Robert W. Plummer

"This paper describes the use of Geographic Information Systems (GIS) as a tool for mineral exploration by using the Eskay Creek area of northern British Columbia as an example. Data entry, analysis and output are discussed. Examples of some of the capabilities of the technology are presented.The main benefit of the technology is being able to perform complex and sophisticated searches of large and diverse data sets to highlight exploration targets. A GIS is a powerful data management tool that can be used in mineral exploration. It is a computer based system that is designed for the collection, storage and analysis of objects and phenomena where geographic location is an important characteristic. The main function of the GIS is to produce information for the geologist from a variety of sources (geology, geophysics, geochemistry, mineral deposits and so forth) quickly and efficiently. This allows the geologist to examine large amounts of data in a fraction of the time than can be done using conventional manual methods."

Jan 1, 1992

By Y. Kocaefe, D. Bhattacharyay, D. Kocaefe

The carbon anodes used in the electrolytic production of aluminum are made of petroleum coke, recycled anodes and butts, and coal tar pitch. Due to technological advances in the aluminum production technology, aimed at increasing production and decreasing energy consumption and greenhouse gas emissions, better quality anodes are required. Presently, the anode quality is evaluated by visual inspection and the analysis of a small core taken from 1.5-2% of the anodes produced. The visual inspection is susceptible to human error and limited to surface imperfections. The analysis of cores takes time, and therefore, it is difficult to determine the existence of a problem and intervene at the right time. In addition, the core does not represent the whole anode due to the non-homogeneity of anodes. A validated online anode quality control system can highly improve the situation. In this article, an electrical resistivity measurement method developed for this purpose is presented.

Jan 1, 2014

By Robert Macdonald, William Coombe, John F. Lewry

Gold occurrences have been known in the La Ronge Domain for many year . Mineable reserves have more recently been outlined and there is every prospect of a major gold camp being established in the domain within this decade. The La Ronge Domain lies in the Lower Proterozoic 'Trans-Hudson Orogen' and is part of a collage of Early Proterozoic crust comprising volcanoplutonic arcs, batholiths, associated volcaniclastics and volcanogenic sediments lying between the Superior Craton to the outheast and the reworked Archean basement/Aphebian cover terrain to the northwest. The domain has several lithostructural subdivisions, the most important of whjch , from a gold exploration point of view, is the Central Metavolcanic Belt. This belt is composed dominantly of a range of metavolcanic rocks and gabbroic to granitic intrusives, which geochemically resemble younger subduction-generated 'primitive' arcs developed on oceanic crust. U-Pb zircon geochronology indicates that the arc volcarusm and pre- to late-kjnematic plutonism occurred about 1890 Ma to 1850 Ma ago. The belt has an attained grade of upper greenschist to amphibolite facies and is relatively undeformed , though high strain zones occur locally. Most gold occurrences in the La Ronge Domain have been found in the Star-Waddy Lakes area of the Central Metavolcanic Belt, and in the Sulprude-MacKay Lakes area to the south which is interpreted as a tectonically dismembered part of the main belt. Both tratiformand vein-type gold occurrences are present in the domain; vein-type predominate and form nearly 90 per cent of the occurrences. The stratiform-type occurrences show a regional lithological a sociation with iron-rich sediments within proximal felsic volcanjc sequences. Some vein-type occurrences appear related to brittle fracturing associated with intrusive emplacement (the magmatic-hydrothermal "syn:' and "subvolcanic" veins) and faulting. However, most of the vein-type occurrences exhibit a spatial association with regionalscale ductile shear and other high strain zones, and were probably formed by metamorphichydrothermal processes.

Jan 1, 1986

By R. G. L. McCready, R. O. van Everdingen, M. Kalin, R. van Everdingen

"This paper is based on data generated between October, 1986 and October, 1989, during the implementation of an Ecological Engineering close-out for a zinc mine in Northern Ontario, where 690000 tonnes of tailings contain 41.1% pyrite and 4.1% pyrrhotite. The objective was to determine rates of sulphide oxidation and iron precipitation in the tailings. Those rates are relevant for the assessment of the long-term effectiveness of biological systems employed in the removal of heavy metals from contaminated drainage issuing from tailings.Data were collected on the topography and stratigraphy of the tailings basin, subsurface temperatures and groundwater levels, and chemical analyses were made of water samples collected from a number of piezometers. The thickness of unsaturated tailings varied widely between individual piezometer locations; annual maxima ranged from 0.67 m to 3.55 m, and annual minima from 0 to 2.68 m. Sulphate concentrations ranged from 36 mg/L to 20180 mg/L; iron concentrations from 0.36 mg/L to 9938 mg/L; and zinc concentrations from 0.33 mg/L to 1123 mg/L.The geochemistry of the piezometer samples suggests that some of the initial Fe content, resulting from metal sulphide oxidation, is subsequently precipitated in the tailings pile and, possibly, in the underlying unconsolidated sediments, probably in the form of iron-hydroxide and Na-jarosite. Other metals such as Zn may be co-precipitated with Fe. The discharge of a portion of these metals to the environment would be delayed by this process. Some of the initial sulphate may also be lost from solution, probably by precipitation of gypsum; approximate saturation degrees for gypsum ranged from -3.27 to +0.47. The precipitated minerals will somewhat decrease the porosity and permeability of the tailings.Sulphide-oxidation rates, calculated using the analytical results and the estimated amount of annual recharge at the tailings site, average 0.0057 mol/kg/yr. Calculated iron-precipitation rates average 0.000386 mol/kg/yr. It is concluded that the characteristics of seepage from mining wastes may change with time, reflecting the solubilization of precipitated secondary minerals."

Jan 1, 1992

By M. J. Dry, G. B. Harris

"This paper presents basic chemistry and operating conditions for the hydrolysis of ferric chloride into solid hematite and gaseous hydrogen chloride, and shows how this unit operation can be applied in chloride hydrometallurgy to regenerate strong hydrochloric acid and reject iron without also rejecting valuable metals such as nickel, copper and cobalt. Two examples are used to illustrate the hydrolysis technology and compare it to existing technology. The first is the regeneration of spent steel pickling acid, comparing hydrolysis to conventional pyrohydrolysis. The second example is the processing of a hypothetical low grade nickel laterite, comparing the novel chloride hydrolysis route to conventional sulphate HPAL technology.INTRODUCTION Whilst, in many respects, the control and removal of dissolved iron from chloride leach solutions can resemble the manner in which it is done in sulphate systems, chloride chemistry additionally offers the ability to achieve the same objectives in different ways (Harris, 2014). Conventionally, iron is oxidised to its ferric state (if necessary) and then precipitated with a base, usually magnesia where the feed is a laterite and lime where it is a sulphide, since calcium will precipitate sulphate formed during leaching. One method for controlling iron is to form FeOOH, either ß-FeOOH (akaganéite), a-FeOOH (goethite), or a mixture thereof (Fillipou and Choi, 2002). However, if akaganéite is formed, the precipitate will contain a significant chloride component (as high as 7% Cl), leading to chloride losses and difficulty in satisfactorily disposing of the residue. Washing chloride from akaganéite is almost impossible due to the propensity of the solids to undergo peptization. The conventional approach requires the addition of a base, but it is based to some extent on controlled supersaturation precipitation (Demopoulos, 2009), which produces a more uniform and crystalline material and is far more attractive than, for example, the turboaeration process proposed by Great Central Mines in their chloride copper process (Raudsepp & Beattie, 1986)."

Jan 1, 2016

By Masaru Kato

The plated gold being used by the electronics industry can be broadly classified into two categories: soft gold and hard gold. Soft gold is used for circuit metallization and for bonding semiconductor chips, while hard gold is indispensable as the contact material on electrical connectors, electromechanical relays, and printed circuit boards. The traditional baths from which to plate soft gold as well as hard gold contain the cyanide complex, [Au(CN)2]-, as the source of gold, which liberates free cyanide ions during the plating. The free cyanide is not only highly toxic but also attacks photoresists used to delineate circuit patterns and bonding pads. For these reasons, non-cyanide baths are in use to plate soft gold, whereas hard gold can be plated only from cyanide baths at present. In this presentation, the current status of both electrolytic and electroless non-cyanide processes for plating soft gold will be reviewed.

Oct 1, 2003

By M. Phylli Bray

"Concurrent with the continuing demise of many Canadian mining towns is the rise of a new method of providing remote mine sites with a workforce. This is the Long Distance Commute (LDC) which uses commuter labour and requires no permanent settlements to support the mine operation. It provides a flexible and cost effective method of operation to the industry and relieves both governments and industry of the expense of building and maintaining mining towns. However, little attention has been paid to the effect on workers or their families of the LDC work schedule whereby workers spend a fixed number of days at the site followed by a fixed number of days at home. Off-shore oil rig experience would indicate that negative social impacts may be expected. Research leading to an understanding of the problems involved seems to be indicated. One innovative suggestion has been to use already established but dying mining towns as workforce pick-up points for new LDC operations further north.BackgroundUntil recently, mine towns were considered as a necessary component of mine development. This was a natural symbiosis resulting from the need to provide workforce accommodation close to isolated mine sites. The early mine communities in Canada were often just a huddle of shacks around a head frame. Gradually mining companies began to provide housing which varied from basic duplexes and quads in grid pattern layout to professionally planned and designed towns, either model company towns or the more recent suburbs-in-the-bush, the so-called ""instant towns"" of the postWorld War II era of resource development. The improvement in accommodation reflected the need to attract a stable workforce as mine operations became more sophisticated. City amenities were expected and offered in these mine towns as a way of encouraging a permanent community of mining families. Indeed in towns like Manitouwdage, Schefferville, and others, it was not unusual to find a significant percentage of two- and three-generation families apparently providing the permanent mining communities so desired by mine operators."

Jan 1, 1991

By M. A. N. Rosa, L. C. R. Machado, R. A. Fonseca, A. M. Mendonça

"Sossego Mine was the first Vale SAG mill operation to process copper-gold ore. It is located in the state of Para, in the south-eastern Amazon region of Brazil. In the first six years of continuous operation, Vale investigated different alternatives for improving circuit performance by investigating operating conditions, mainly focusing on the SAG mill.Today, after a steady increase over five years the annual production rate seems to have stabilized. It is hoped this work will show how the SAG operating practice have been perfected with time and as new data are collected. Historical data of mill grind-outs and crash stops helped create operation curves depending on the ball charge volume and total charge volume. Also noted were impacts on throughput due to the effect of reducing liner weight and the ore type characteristics."

Jan 1, 2012

By M. Marchese

It is no secret that scarcity of fresh water is an issue that at a global level in the years to come will have a major impact on the business landscape. A number of projects, beyond the mining sector, could remain on paper only due to this. At the same time, this situation is seeing the rise of new business opportunities, such as development of technologies for more efficient usage of water, water recycling, and desalinization of sea water. Despite that most of Chilean mining facilities are located in the driest area of the world, business has developed strongly and actively for more than a century. However, the negative effect on the water reservoirs and the environment is, lately, resulting in the reduction of the authorized water rights. Holding Water Rights for any given volume does not guarantee that the resource will be available when needed. A recent report from the United Nations on global climate change indicates that global warming can be directly related to changes in the natural and human environment. Chile would not be an exception. The reduction in snow levels in the high Andes and reduced rainfall during the so called "Bolivian winter", have directly affected the replenishing of the underground water reservoirs in the lower parts of the valleys, where most of the extraction of the resource takes place. Mining facilities shall be designed to reduce potential environmental effects, using proven technologies, and considering the best practices available. These measures shall constitute a complete structural framework for the environmental impact assessment (EIA) of the Project. The measures to prevent and mitigate the impacts on the water resources shall be considered during the design stage of a mining project. Current and future mining projects in Chile are conscious that the increasing pressure on the limited water resources is becoming unsustainable, and are already facing the water scarcity and social pressure by implementing sea water desalination plants, including long pressurized pipelines to the mine sites (e.g. Escondida, Candelaria, El Morro, Regalito). This paper presents, in summary, an analysis of the present and potential future scenarios.

Jan 1, 2007

By R. T. Erskine

"IntroductionIn this paper it will not be possible to cover all details of the reagent systems at Brunswick Mining and Smelting but it is hoped that a description of the evolution of these systems will be of some benefit. The concentrator of Brunswick Mining and Smelting located near Bathurst, New Brunswick was originally designed as a 3,000 ton per day operation but before construction commenced was uprated, with 4,500 tons per day being treated by the summer of 1964. Development of the open pit at another ore body five miles away was initiated in 1965 and additional concentrator and crusher facilities went into operation in September, 1966. Present total daily throughput is over 8,000 tons per day. The ore at Brunswick is very high grade but mineralization is very fine grained and requires grinds generally over 75% minus 400 mesh for liberation. The amount of surface exposed using grinds of this order understandably requires great quantities of reagents, Reagent mixing systems for the original concentrator allowed only for batch mixing and were very expensive in labour cost especially.During the first three years of operation total number of men employed in reagent handling reached a peak of four men per shift and six men on dayshift unloading cars for a total of 22 men. At present only one man is employed on shift, and four men on dayshift take care of unloading and mixing reagents, a total of 8 men. The man on shift is almost entirely occupied with checking feeder operation, flow rates, and head tank levels. Most commonly used reagents are tabulated in Fig. 1 showing average monthly and daily requirements in the Brunswick operation as well as pounds per ton of mill feed as found in 1969. It is very obvious that with over seventeen tons each of lime and soda ash and six tons of copper sulphate used each day, opening of bags and mixing batches of solution is an inefficient undertaking."

Jan 1, 1970

By Patrick Mclaren, Peter B. Hale

Canada, with one of the largest continental shelf areas in the world, has done little to evaluate its offshore unconsolidated mineral resources which include heavy minerals (gold, chromite, rutile etc.) and industrial minerals (silica sand and aggregates). During glaciation much of the continental shelf was covered with an ice sheet and later subaerially exposed with the result that glacial, glaciomarine and fluvial processes deposited sediments that may contain heavy minerals derived from onland locations. With rising sea-levels, beach and nearshore processes may have served to concentrate heavy minerals by winnowing and removing the lighter mineral components. These potentially valuable resources can be found with suitable exploration techniques such as seismic profiling and bottom sampling. Gold deposits are known to exist off the coast of Nova Scotia, and on the basis of form er beach mining, gold deposits probably occur off Vancouver Island and the Queen Charlotte Islands. Large deposits of silica sand occur near the Madeleine Islands and it appears likely that supplies of marine aggregates are present close to urban markets or sites of future mega-projects such as oil field developments. This paper, which is based upon a review of literature and consultation with members of the Department of Energy, Mines and Resources' Coordinating Committee on Ocean Mining (DCOM), is the first step in assessing the Canadian offshore f or its resource potential with respect to quantified deposits, known and speculative mineral occurrences. Although this is a subjective evaluation, the potential appears promising. A more detailed resource inventory is required to provide a more certain assessment.

Jan 1, 1984

By D. McConchie

The use of Bauxsol? (physically and chemically modified alumina refinery residues) to treat acid rock drainage (ARD), and sulphidic waste rock and tailings, provides new options for managing some intractable environmental problems at both derelict and active mine sites. Treatment of ARD waters using the Bauxsol technology shows that the effectiveness of raw Bauxsol material can be enhanced by including modest amounts of selected industrial minerals or common chemical additives. The type and amount of additive required and the amount of the blend needed to treat the water depends on the initial composition of the water and the target water quality; for some ARD waters, optimum treatment may require one or more changes in the type or amount of additive used. Maximum treatment efficiency can be achieved only when a balance is maintained between the rate of trace metal binding and the rate of change in water pH; adding treatment reagents faster than can be accommodated by the reaction kinetics will not result in more rapid water treatment. This paper presents the results for treating several ARD waters to illustrate the importance of blend selection and treatment procedure. Although treating ARD water is often necessary, this strategy treats the symptoms rather than the cause. The best permanent solution is to treat the sulphidic waste rock or tailings such that they do not continue to oxidise and produce acidic metal-rich leachates; sulphide oxidation needs to be stopped or slowed to a rate that can be accommodated by normal environmental processes. Capping lined impoundments is not a solution because all caps and linings will inevitably fail some time in the future creating a nasty surprise for some future generation. Adding lime is also less than ideal because the lime leaches from the treated material; treatment often appears to be effective for a few years and then fails. Bauxsol technology offers effective alternatives to conventional liming and capping procedures and Bauxsol blend application rates and procedures can be planned to ensure that no acidic or metal-rich water can ever escape from the site. Bauxsol can be physically mixed with the sulphidic mine wastes or it can used to form subsurface permeable reactive barriers, or both. Bauxsol treated waste rock and tailings can be immediately and effectively revegetated. In this paper we present leachate quality and plant growth rate data for several sulphidic waste rock and tailings deposits treated using the new technology.

May 1, 2003

By Boyd Davis, Vladimiros Papangelakis, Douglass Duffy, Michael Carlos

"The processing of lateritic saprolite in hyper-concentrated magnesium chloride brines offers several potential advantages for the hydrometallurgical production of nickel. An aggressive HCl-MgCl2 leach at atmospheric pressure can significantly reduce magnesium dissolution, and offers the ability to recover HCl and MgO by a less energy intensive process than conventional techniques via the formation of magnesium hydroxychlorides. Inevitably, the high chloride concentration renders iron fully soluble during leaching and thus requires subsequent iron control and disposal steps. Experimental measurements coupled with OLITM modeling were conducted to investigate the behaviour of iron in concentrated magnesium chloride brines, in terms of chemistry (nature of iron species) and solubility limits. The solubility of ferric chloride in magnesium chloride solutions of concentrations and temperatures relevant to this process was controlled by a previously unreported solid phase: 2.5FeCl3·MgCl2·7.5H2O. Iron precipitation tests on synthetic leach solutions without seeding indicate a metastable akaganeite precipitate which transitions to hematite upon equilibration. Magnesium chloride solubility in ferric chloride solutions was also investigated to allow the simulation of a ternary phase diagram for the MgCl2-FeCl3-H2O system, in order to determine process conditions that avoid unwanted chloride precipitation.INTRODUCTION In the search for more economical processes to treat lateritic saprolite for nickel production, chloride hydrometallurgy has been increasingly investigated. While High Pressure Acid Leaching (HPAL) can frequently economically treat lateritic limonite, the presence of saprolite negatively affects process economics. The higher magnesium content of saprolite increases acid consumption, because magnesium sulphate, unlike iron and aluminum sulphates, does not hydrolyze in HPAL. This soluble magnesium decreases the sulphuric acid strength by an amount greater than the amount of acid stoichiometrically required to leach magnesium, which must also be disposed of or recovered (Jankovic, Papangelakis, & Lvov, 2009). Due to these issues, pyrometallurgy is most commonly employed to treat lateritic saprolite, via the Rotary Kiln-Electric Furnace (RKEF) process; this process uses a rotary kiln to dry and partially reduce nickel and iron oxides before sending the calcine to an electric furnace for smelting to produce a ferronickel product for the stainless steel market. Although the problems encountered during hydrometallurgical processing are avoided and nickel recoveries are high, high capital and energy costs prevent the application of this process to lower grade lateritic saprolite deposits (De Bakker, 2011)."

Jan 1, 2016

By F. F. Roberto

Sulfuric acid has been demonstrated to be an efficient lixiviant for in situ extraction of copper in the past. It has also been proposed that microbial production (by iron-oxidizing acidophilic bacteria) of acidic ferric solution either in situ or ex situ could provide an economic strategy to generate an effective lixiviant for secondary copper sulfides like chalcocite and covellite. Copper heap bioleaching also takes advantage of this approach. One of the major environmental challenges for in situ copper recovery projects is the containment of acidic solution within the ore deposit, and ultimate restoration of the depleted ore body to its original state. A perhaps overlooked aspect of projected site operations is the possibility that transient acidic conditions and pumping of solutions from surface reservoirs into the subsurface could stimulate the growth of iron- or sulfur-oxidizing species of acidophilic microbes in the ore body, leading to additional generation of sulfate, acid, and ferric iron. This outcome would benefit extraction of copper in mixed oxide/sulfide deposits in the near term, but could complicate restoration activities. Possible impacts of pumping acidic solutions into the subsurface on microbes resident in, or introduced into the extraction zone will be discussed in the context of our understanding of copper heap bioleaching and acid rock drainage. INTRODUCTION As high-grade deposits of metals such as copper continue to decline, conventional mining methods have evolved to mine and process larger and larger quantities of ore. What is currently defined as ore today often contains less metal than the tailings of past operations. The throughput of current-day mines also leads to tremendous amounts of waste rock and tailings that may threaten the environment and communities around the mines, as has recently been experienced by 3 major tailings disposal facility (TSF) dam failures in the past 5 years. Community acceptance of large mine operations thus becomes more difficult to achieve—loss of the social license to operate. In response, the mining industry urgently pursues innovations that can fundamentally change the way in which metals are mined. In situ recovery (ISR) of metals represents one approach to a more sustainable mining industry, by virtually eliminating the need for a pit or underground excavation, eliminating the excavation and transportation of ore to a process plant and the ensuing noise and dust that is generated, and any need for waste rock dumps or TSFs. An ISR mine could have very little visible footprint beyond a network of wells, pumps, and piping to transport pregnant solution to a recovery facility, such as a solvent extraction- electrowinning (SX-EW) plant for copper. Some solid waste streams and/or storage ponds may still be necessary to treat and store bleed streams, PLS and raffinate, or as part of groundwater restoration activities. Thus capital and operating investments would be potentially much lower than that required for a conventional mine. In theory production could also be controlled to adjust to subsurface ore grade and match market demand. A not insignificant challenge of in situ recovery is the requirement for an efficient, low-toxicity, and ideally selective lixiviant for the metal that is targeted.

Jan 1, 2019

By I. M. Santos Moraes

The control of minor impurities (mainly As, Sb and Bi) in copper refineries has been a great challenge. Caraiba Metais' copper refinery produces a very high quality copper, registered in LME as grade A, and recognized as amongst the top ten in the copper world. At Caraiba's Tankhouse Bi and Sb are controlled by means of electrolyte bleed-stream removal after partial decopperizing in a set of electro-winning cells (liberators). Another way of reducing the Sb and Bi content in the electrolyte is by means of the arsenate precipitation chemistry. It is well known that the use of high arsenic concentrations in copper refinery electrolyte has the advantage of causing most of the bismuth and antimony to report in the anode slimes. However, the use of such mechanism of control may contribute to other undesired problems such as antimony and bismuth precipitation in the bulk of the electrolyte, what may cause severe contamination problems. This paper describes a period when some cathode contamination with Sb occurred at Caraiba Metais' Copper Refinery. It also presents an analysis of several process parameters related to the problem, the possible causes for the contaminations as well as the actions taken to correct the problem.

Jan 1, 2007