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By R. M. Giegerich

"This paper begins with a brief history of Madawaska Mines, a brief description of the geology, mining methods and equipment, and the historical development of 7/8-in. tapered drilling equipment. It then outlines the performance characteristics and inherent problems of the traditional 12-degree, tapered connection, blade-type insert bits. Service-free (Unipass) button-type insert bits are presented as a possible solution to these problems. The paper concludes with an analysis of button bit performance to date.Brief History of Madawaska MinesMadawaska Mines Limited, near Bancroft, Ontario, is in Faraday Township, Hastings County, approximately 100 miles northeast of Toronto and 100 miles west of Ottawa.The mine re-opened in 1976committed to 1,500 tons per day to provide approximately 600,000 pounds of yellowcake (U3O8) per year to A.G.I.P. (an Italian government agency) under the joint ownership of Federal Resources Corporation, Salt Lake City (51%), and Consolidated Canadian Faraday Limited (49%). At present, the mine is producing approximately 2 pounds per ton (.1% U3O8) at the rate of 60,000 pounds per month. The mine employs about 400 employees.Brief Description of Geology, Mining Methods and EquipmentGeologyThe Grenville metasediments of the mine area are chiefly paragneiss, amphobolite and some carbonate (marble) rocks, which were intruded by a basic rock, altered to a metagabbrometadiorite. These formations are generally concordant, striking east to northeast and dipping 45 to 60 degrees to the south. Locally, the metagabbro is often discordant. The above group of rocks (mixed hybrid gneisses) forms the hanging wall of the south-dipping Faraday granite sheet and was intruded by nepheline syenite, syenite and granite. The ore occurs in the granite-syenite-pegmatite dykes that are probably genetically related to the Faraday granite. The ore shoots are erratically distributed within the pegmatite bodies, mainly on the hanging or footwalls but also medially. Their size varies from 50 to 350 feet in length, 5 to 40 feet in width and 50 to 200 feet in height. The ore occurs most frequently in a medium-grained granite or syenite, well hematized with 10 to 30% mafic crystals of pyroxene, amphibole and/or relics of the host rock."

Jan 1, 1982

By Robert Cameron, Colin Ashton, John MacNeil, Leo Piciacchia

"The in pit dam construction and utilities relocation, known as the East Mine Corridor Relocation (EMCR) project, was developed to extend the life of the east side of the Base Mine pit by two veal's. This will result in the recovery of an additional 80 million barrels of oil and delay expenditures associated with the opening of the North Mine by two years. To accomplish this, a large in pit earth structure was required to provide a new embankment foundation for relocating a public highway, four powerlines, a natural gas back-up pipeline, a substation, and a conveyor train. This structure would also he required as a temporary dam 10 contain mature fine tails on the west side until mining is completed in the east mine corridor area, that will then be filled with fluid.The in pit dam, known as The Highway Berm, is 2.5 km long, 63 m high and has 42 million m3 of engineered soil added to the already existing end-dumped soil volumes. To complete the design and construction of a structure of this magnitude, in the very short time frame of two-and-a-half years, presented many new challenges. The main challenges faced were: designing while construction was ongoing; designing without the use of clay cores or sand filters; using relatively non-select overburden material; proper dewatering and base preparation; changing from construction of 50 m high spoil piles to a high specification construction operation; compacting lifts with heavy haulers; constructing during the winter; and monitoring movement of the structure with satellites."

Jan 1, 1995

By Chr. Krause

Within the scope the collaborative research centre 599 (Medical University of Hanover, University of Veterinary Medicine Hanover, University of Hanover) the behaviour of the degradation of magnesium materials as implants are investigated by using animal experiments (rabbits). Thus extruded cylindrical pins from the magnesium alloys MgCa0.8%, WE43 and LAE 442 were implanted intramedullary in the tibiadiaphyses. The implantation duration was 3 and 6 month. After the explantation 3 point bending tests were carried out to investigate the possible changes of the mechanical properties. Clearly changes in dependence of the implantation duration could be determined. The three magnesium alloys show a decrease of the mechanical resistance with an increasing implantation time. To evaluate the degradation process, wich is the reason for the changes, micrographs and element analyses (EDX) have been accomplished after the 3 point bending tests. The micrographs show for all used magnesium alloys corroded surfaces but no preferred corrosion on the grain boundarys. The element analyses show beside a layer which is rich in calcium and phosphorus an agglomeration of rare earth elements in this layer. With these results a using of magnesium alloys as a material for implants can be announced.

Jan 1, 2006

By L. Xia, B. Hart, J. Nigim, Z. Chen

"Grinding ore is an important step in the flotation process. Not only does grinding reduce particle size and liberate minerals, it also creates conditions for reactions to occur on particle surfaces that can aide or inhibit flotation. There have been numerous studies examining various grinding regiments and the effect on flotation pulp chemistry, including autogenous grinding and using media of variable composition. There have been however, few studies looking at the effect of variability in grinding media size on pulp chemistry and subsequent flotation. This study attempts to link changes in pulp chemistry in response to variations in grinding media size to flotation recovery. It uses probes mounted in the grinding chamber (pH, Eh, DO, and conductivity) to monitor pulp chemistry changes during grinding of a Cu-Zn ore. Surface chemistry analysis by ToF-SIMS was performed on sphalerite from the mill discharge. Activator and depressant species were monitored on the mineral surfaces and their presence was evaluated in the context of variability in pulp chemistry linked to differences in grinding media and its ball size.INTRODUCTIONIt has been widely recognised that not only does grinding reduce particle size and liberate minerals but the grinding environment has a large effect on the flotation of sulphide minerals. This effect is attributed to Eh change, iron hydroxide coating on surfaces, oxygen reduction, precipitation from solution and galvanic coupling (Grano, 2009). As early as 1960, it was reported that after grinding the ores in an iron mill the natural floatability of sphalerite was reduced significantly (Rey and Formanek, 1960). Kocabag and Smith (1985) studied on the industrial circuits showing that the depression of sulphides flotation in a steel mill is possibly due to the coating of iron oxidation products. Peng, Grano, Fornasiero, and Ralston (2003a, 2003b) found that iron contamination from grinding media plays a dominant role in depressing galena and chalcopyrite flotation. Huang, Grano, and Skinner (2006) reported the same observation in the flotation of arsenopyrite."

Jan 1, 2016

By C. F. Gleeson

"I HAVE BEEN ASSIGNED the pleasant task of adding a last word in way of summary to this session. I think that the trend set in having a geochemical session at the CIM Annual General Meeting is a good one and I hope it will continue so that members of the mining fraternity can get together on a regular basis and discuss geochemical problems peculiar to our Canadian scene. A series of interesting papers have been presented on what has been considered by many in the past as not only a problem area for geochemistry but even an impossible one. The papers should help dispel some of these fears. Lack of development of geochemical techniques in the Shield has been due to a variety of factors, many of which have been mentioned. However, I feel that one of the main reasons for this lack of development has been timidness on behalf of many people to get out and do the necessary work which helps produce answers to many of the questions asked. New developments and applications of geochemical methods in the Shield will not be done by the faint of heart but by those who have the curiosity, interest, imagination, drive, resources and, most of all, the intestinal fortitude to stick to it and not give up because results or conditions do not meet with preconceived notions. Another element that will be needed by those who will successfully apply the techniques and who will be responsible for new breakthroughs is the systematic approach to sampling and analysis and the integration of geochemical, geological and geophysical results. Erratic sampling patterns - a sample here and a sample there - generally lead to more problems than solutions."

Jan 1, 1971

By P. K. Kaiser, D. D. Tannant

"A support system for large ground convergence conditions or burst-prone ground must contain holding elements (rockbolts, cable bolts, etc.) that are strong yet capable of sustaining large deformations, i.e., they must absorb as much energy as possible. Steel wire rope anchored in a borehole by a friction bolt provides these desired yield characteristics if the frictional anchorage is placed deep enough into the rockmass, i.e., in non-yielding rock or beyond the expected depth of rock ejected during a rockburst. Pull-out tests were conducted on wire ropes anchored by inflated Swellex bolts to assess the feasibility of this support concept. The test results demonstrate that a Swellex bolt generates a frictional anchorage that allows the wire rope to slide at high loads and to absorb significantly more energy than either a Swellex bolt alone, or a cement-grouted cable.The rope/friction bolt combination can be engineered to provide the desired energy absorption and allowable deformation by varying the installed lengths of the friction bolt and the rope. For yielding rope support, the contact length between the rope and Swellex bolt must be short enough to ensure that the rope can slip well before its tensile capacity is reached. A safe maximum overlap length is about one metre for the wire rope used in this testing. When used as support in the backs of drifts, a swaged button on the ropes end must be used to ultimately mobilize the full rope capacity thereby protecting against gravity-driven falls of ground."

Jan 1, 1995

By V. Cvetkovic, L. Zou, L. Jing

"Sorption process plays a significant role for solute retardation in rock fractures. In this paper, for the aim to investigate the effect of sorption on solute transport in a single rough fracture, a 2D model of representative single rock fracture was built and its roughness was statistically characterized based on the measured data of rock surface topography by laser scanning. A Finite Volume Method (FVM) code was developed to solve the Navier-Stokes (NS) equations and transport equation for numerical modelling the process of fluid flow and solute transport in the rock fracture model. Two groups of simulations were conducted: with and without the consideration of the sorption process with different average flow velocities. The results show that the surface roughness increased the complexities of flow fields, and the non-linear sorption process plays a significant role in the retardation of solute transport through rock fractures. The sorption process caused an obvious lagging time in both the solute concentration fields (plumes) and corresponding breakthrough curves. This lagging time increases with the distance from the inlet boundary, and relatively decreases with the increase of mean velocities. INTRODUCTIONFluid flow and solute transport in fractured rocks is an important research topic for performance and risk assessments for rock engineering projects concerning geo-environment safety, such as radioactive waste disposal, mining, geothermal extraction, reservoir engineering and other contaminant transport processes in geosphere (Berkowitz 2002).The solute transport in the rock fractures mainly involve the advection, surface sorption, matrix diffusion, dispersion, radioactive decay and chemical reactions, governed by general transport equations (e.g. Bodin et al., 2003). Among these transport phenomena, the sorption on the fracture walls can alter solute migration between the fractures, and play an important role in natural retention of solute transport (Weber et al., 1991; Wels et al., 1998; Kumar 2007; Dai et al., 2012). The aim of this study is to investigate the effect of sorption on the solute transport in a single rock fracture with rough surfaces. More complex transport processes, such as matrix diffusion, dispersions, radioactive decay and chemical reactions, are not included in this study."

Jan 1, 2015

By I. H. Redeker

North Carolina is the leading state in the USA in feldspar, mica, and spodumene production. Mixed feldspar, spodumene, mica and quartz are mined from hard rock, open pit deposits and recovered by flotation from the fresh pegmatite type ores. Potash feldspar, mica, clay and quartz are recovered from weathered decomposed pegmatites. The North Carolina State University has a Minerals Research Laboratory in Asheville with trained personnel and flexible pilot plant equipment. The flowsheets for the feldspar, spodumene and mica producing companies and for large phosphate and glass sand flotation plants were developed and tested in Asheville. Examples and problems of pegmatite flotation are demonstrated with flowsheets and slides.

Jan 1, 1981

By M. Walmsley, D. Maynard

"This paper describes the use of terrain and soil information in the planning of mine developments, particularly in satisfying many of the existing provincial regulatory requirements. It is also noted that, if properly used, this will provide a solid data base for cost-efficient and environmentally acceptable land use.IntroductionIn planning the development or expansion of a new or existing mine, engineering alternatives are judged on many factors, one of which is the environmental influence. Ecological investigations, ensuring consideration of a rational approach to managing land use and environmental impacts, should be carried out prior to a final decision being made on mine development. The Pit Slope Manual (CANMET, 1976) suggests that both baseline aquatic and terrestrial data be collected and interpreted in such pre-mining surveys. In British Columbia, planning procedures now exist which incorporate biophysical studies to help identify, assess and manage major environmental impacts associated with mine development.Methods outlined in the Guidelines for Coal Development (E.L.U.C., 1976) have been successfully applied in recent years. Following this example, the Inspection and Engineering Division of the B.C. Mineral Resources Branch prepared guidelines to help expedite the development of new base metal mines (Procedures for Obtaining Approval for Metal Mine Development; Ministry of Energy, Mines and PetroleumResources, 1979).The metal-mine guidelines require the proponent of a new mine development project to prepare a two-stage assessment proposal which systematically moves from a preliminary feasibility study (Stage I) to a final project design (Stage II), including application for regulatory approvals. One purpose of the Stage I report is to provide a description of the existing environmental conditions that could be affected by the proposed development. A preliminary environmental impact assessment should also be reported. The Stage II report will contain detailed assessment and management of environmental impacts."

Jan 1, 1981

By A. Hynes, T. Skulski, D. Francis

The Archean volcano-sedimentary succession in the LG-3 area has undergone two phases of deformation and has been metamorphosed to upper greenschist and amphibolite facies. Marine, fine-grained sediments and mafic pyroclastics comprise the lowest observed stratigraphic unit. These sediments are overlain by a thick sequence of submarine basalts and minor basaltic andesite. The lavas are characterized by high Al/Al+Si, Ti values, low Mg numbers and flat REE profiles (lOx chondrite). A sedimentary prism of coarse elastics which was deposited close to an exposed plutonic highland, overlie the volcanics. Massive lavas of basaltic andesi te and associated volcano-sediments comprise the uppermost stratigraphic unit. These lavas are characterized by high Mg numbers, Ni, Cr, LREE (lOOx chondrite) but low Ti, Al/Al+Si and HRee. The supracrustal rocks were intruded by tonalites and tonalitic gneisses.

Jan 1, 1984

By F. W. Crossland

Losses of metal are often traced to incorrect pH/ORP signals in flotation, leaching, extraction, electrolysis, and precipitation processes, aggravated by pressure changes. IC Controls, a Canadian mining sensor manufacturer, developed a new superior pH/ORP sensor that stops metal losses, reduces environmental footprint and contributes to sustainability. The cause of incorrect pH/ORP signal is rooted in the reference. Reference junctions are designed to allow diffusion of reference chloride ions into the process but also allow process ions to diffuse into the reference. This development is important to mines and hydrometallurgists where sulphide, cyanide, ammonia and other poisoning ions are present in the process. These ions react with reference electrolyte components causing the signal to change, drifting from the correct process value. With fluctuating process pressure, ion in migration dilutes the electrolyte producing similar signal drifts. If process ion in-diffusion could be stopped, the pH/ORP signal would be accurate. IC Controls new pH/ORP sensor stops process ion in-diffusion, and remains accurate over long periods. New processes using higher pressure and fluctuating pressurized reactors will greatly benefit from stable pH readings. Similar to IC Controls' proven model 642 Mining pH sensor, our new model 647 contributes to sustainability through reducing disposal costs from waste reagents, lost metal and fewer used sensors.

Jan 1, 2014

By K. Pienimäki

Boliden Harjavalta Oy has produced copper since 1945. The essential idea has always been continuous development of process efficiency and environmental friendliness by using the Best Available Techniques (BAT). The ongoing development step is to increase the production capacity up to 210 000 tpy of anode copper and 155 000 tpy of copper cathode. One of the focal issues in this action is modernization of the copper refinery to utilize permanent cathode technology. This paper describes the refinery project and the technology used in it.

Jan 1, 2007

By Ross Dimmock

The productivity of a mine has the same goals as the quest to complete a tunnel project both safely and within time. A key aspect to achieving this goal is to excavate and support the working face as quickly as possible, allowing early re-entry to start construction of the next advance in safety. As with tunnels, the use of high performance wet-mix sprayed concrete has increased in mines dramatically over the last few years, and year on year has seen a stepwise increase in shotcrete performance, particularly in the first few hours. Shotcrete early age strength development clearly offers mining teams enormous advantages by allowing early, safe re-entry to the face. This paper illustrates that in the hard rock tunnelling field, modern shotcrete approaches do not cause delays in re-entry, but allow a continuous construction cycle. Furthermore, the paper identifies the most suitable, up-to-date shotcrete admixture and equipment technology available to the mining community to permit early re-entry.

May 1, 2003

By E. Henderson

"This paper outlines the upgrading of a double-drum 2000 hp cage hoist to provide fully-automatic operation from shaft station control panels. The application utilizes programmable controller technology to provide all necessary functions for movement of personnel and material to 22 locations in a 4000 ft shaft.Various functions involving special design considerations such as ""chairing"", ""jogging"", and three modes of ""multi-level calling service"", are outlined. The use of higher level PLC functions to optimize memory utilization and simulate ""elevator service"" required the addition of a comprehensive fault finding software section to aid in troubleshooting.This paper will deal primarily with the automation portion of the project with references made to other pertinent aspects which were prerequisite to automatic operation. It is not intended to deal with every design detail, but rather to provide an overview of what can be done in the area of automation for those considering such an application. INTRODUCTIONEarly hoisting control systems provided only the essential elements of control, leaving many responsibilities with the operator. With advancements in various areas of technology, electromechanical devices were incorporated to enforce slow-down in end zones, control acceleration rates, monitor safety devices, etc. Brake control systems were supplied to allow for ""single-stick"" operator control, regulated deceleration during emergency brake applications, etc.These additions enhanced the over-all performance but were generally confined to speed and current regulation. Some mechanical devices, such as travelling nut limits, etc.; were used to provide ""position"" control to multiple locations within the shaft. These devices, in conjunction with rather extensive relay control panels, did allow for the establislunent of some automatic cage hoists . The hoists were often limited to service from point ""A"" to point ""B""', involving a limited number of levels due to the complexities of the mechanical interfaces employed. Only limited systematic work sequences were possible . .Programmable Logic Controllers (PLCs) were introduced into industry in the mid-70s and have since gained acceptance in mining applications such as pumping, ventilation, ore handling, etc. This technology, being ""software"" based, allows complexities to reside in the program rather than increasing the number of physical control elements. This has opened the door into hoisting systems for automatic loading and hoisting of ore as well as a means to achieve a comprehensive package of automated cage hoisting functions."

Jan 1, 1989

By Reis. E., P. Pino Véliz

"Along the process of defining the fundamentals of a ferronickel project, several questions require proper answers from the very beginning such as the size and characteristics of the laterite deposit (oxide or silicate), the mineralogical variability, and the selection of the most valuable process route. In general, these elements will be defined along the progress of the exploration and feasibility studies, and definitive engineering. Also, from the very preliminary estimates, three questions are very common: what should be the plant capacity (annual tonnes of contained nickel), what will be the probable capital required (CAPEX), and what will be the estimated timeline (schedule) between the initial stage, say the feasibility study and the plant start-up and ramp-up to designed capacity. The accuracy of the capital cost estimates also progresses along the different stages of development from ±50% at the Preliminary Economic Assessment (PEA) stage down to ±5% for the Detailed Engineering and Construction stage. These accuracies of estimates have been, in some ways, accepted by the mining community and investors. The industry accepted benchmark for ferronickel projects in terms of CAPEX are then in the order of US$50,000 per tonne of nickel contained in the FeNi product. In this paper, the authors analyze in some details three ferronickel projects for lateritic ores that have selected the Rotary Kiln - Electric Furnace (RKEF) as the suitable technological route and have started production in the period 2006–2016. Some key aspects of the ferronickel projects are examined: 1) size and type of deposit; 2) flowsheet selection; 3) evolution of capital cost as a function of capacity from the feasibility stage to construction; 4) comparison between planned production scale and actual ramp up; 5) estimated capital expenditure (CAPEX) compared with actual figures; 6) nickel price evolution and timing of the approval for the project to proceed to construction and production start-up. The objective of this paper is to identify key elements that should be addressed in future projects and that are proposed as benchmark figures for similar projects."

Jan 1, 2017

By D. Pérez Escobar

Multiphase steels are quite sensitive to hydrogen embrittlement. Laboratory tests to evaluate this often use electrochemical, charging to introduce hydrogen into the sample, but damage purely caused by hydrogen charging has to be avoided. A ferrite-bainite steel, was charged using various conditions to identify when surface blisters occurred. Samples were also checked for internal, damage by electron microscopy. This study was repeated for three other multiphase steels and pure iron. An HSLA steel, was found to be more resistant whereas pure iron was quite susceptible to internal, hydrogen damage. For al, industrial, steels, cracks concentrated in the middle of the sample were attributed to inclusions and segregations, inherent to production.

Jan 1, 2010

By D. A. Brown, C. Lowe

"Abstract -A multi-sensor (electromagnetics, magnetics, gamma-ray spectrometry, and VLF) geophysical survey was recently conducted in the Purcell Basin of southeastern British Columbia in an area encompassing the world-class Sullivan Sedex deposit. The purpose of the survey was to geophysically characterize the known mineral occurrences and to develop strategies to enhance future mineral exploration in the basin. Follow-up investigations of geology and measurements of rock physical properties helped constrain interpretations of the geophysical data sets.Despite extraction of more than 90% of the ore from the Sullivan deposit, it is clear that the mineralization there, as well as at other Sedex occurrences surveyed, is characterized by high conductivity values, strong bedrock conductors, and elevated magnetic anomaly values. The albite-sericite alteration which accompanies this mineralization yields high potassium and low thorium-potassium ratio values. Associated Moyie gabbro is characterized by low electrical conductivity and radioelement concentrations and by high magnetic anomaly values. The study has also aided exploration for other mineral deposit types including stratabound Cu-Ag, placer gold, vein and disseminated basemetal deposits. In addition, the geophysical data have helped constrain geological interpretations of the basin."

Jan 1, 1998

By Rene Cane, V. I. Lakshmanan, John Starkey, Richard May

"The Agrium Kapuskasing Phosphate Operation mines and processes up to 6,000 t/d of phosphate ore. Run-of-mine crushing to minus 6 inches is done in a toothed roll-crusher, while grinding is done in a SAG/ball mill circuit with no coarse recycle classification of the SAG mill discharge. The primary grinding mill is an 18 ft. diameter x 9 ft. EGL, 1500 HP variable speed SAG mill and the secondary mill is a 13 ft. diameter x 21 ft. long, 2000 HP fixed speed, ball mill. When hard ore was treated, the SAG mill restricted the tonnage that could be ground. When soft ore was treated, the ball mill and spiral classifier overloaded and restricted throughput.Recommendations from a plant benchmark and an ore hardness testing program, on how to better utilize installed energy in the Agrium SAG mill when treating soft ore, and how to obtain best results when treating hard ore, were checked in a pilot plant investigation in the 3 ft. diameter Starkey-PRO Pilot SAG Mill. Correlation between the ore hardness testing and the results from the 3’ Pilot SAG mill was very good. In addition, the work indicated the results that could be expected for the different ore types when using either smaller SAG discharge grates and/or a vibrating screen with 10 mesh square opening cloth.INTRODUCTIONAgrium Kapuskasing Phosphate Operation consists of a 6800 t/d open pit mine and a concentrator, near the Town of Kapuskasing in Northern Ontario. The two major ore types are sandy ore and cemented ore. Sandy ore is fine, soft and easy to grind in the SAG mill while cemented ore is harder, more blocky and difficult to grind in the SAG mill. The ratio of sandy to cemented ore in the deposit is thought to be in the order of 80:20 but can range as high as 5050, so it was important for the grinding circuit to have the ability to treat sandy ore alone."

Jan 1, 2002

By I. G. L. Sinclair

"ABSTRACTTill geochemistry was the principal exploration tool employed by Selco in the investigation of a zinc prospect in Lanark Township, Ontario. The geochemical studies were undertaken after the discovery at surface of marble boulders containing bands of sphalerite and lesser amounts of galena.The source of these mineralized boulders was sought by means of B-horizon soil geochemistry, followed, where appropriate, by back-hoe trenching and till sampling. The thickness of the tiff in this part of Ontario seldom exceeds 3 m or 4 m and it was generally possible to sample complete profiles of the till and thus to obtain detailed information concerning the dispersion of zinc. Drilling and trenching at the up-ice extremity of the zinc dispersion trains showed the source of the float to be sub-economic bands of sphalerite in the Grenville marble. IntroductionTill geochemistry was used extensively by Selco during the period 1975 through 1980. It was the principal exploration technique employed in a program seeking carbonate-hosted lead-zinc deposits of the Balmat-Edwards type in the Grenville rocks of southeastern Ontario. This paper describes the use of the method to locate the bedrock source of a group of sphalerite boulders found at the surface near the village of Hopetown in Lanark Township (Fig. I) . Geochemical investigations at this locality were the subject of a previous publication by the author (Sinclair, 1979).All of the analytical work related to this project was done by Bondar-Clegg & Co. Ltd. in their Ottawa laboratory. In all cases the -80 mesh fraction of the till was analyzed. The total zinc content was determined by atomic ab sorption spectrometry after hot aqua regia digestion; readily extractable zinc was determined by atomic absorption after samples had been cold-leached for 18 hours in an ammonium citrate hydroxylamine hydrochloride solution, the pH of which was adjusted to 8.5"

Jan 1, 1986

By C. Ayora

The Iberian Pyrite Belt (SW Spain and Portugal) contains one of the largest reserves of pyrite in the world with mining activities dating back to prehistoric times. About one hundred abandoned mine wastes and galleries release a huge acidity and metal load to the Tinto and Odiel rivers. Once the mining activity is over, polluting discharges can persists for decades or even centuries with no specific responsible entity. In-situ passive remediation technologies are especially suitable for these orphan sites. The concept is to insert a reactive porous material in the natural flow path of contaminated surface and ground waters, and it is implemented through infiltration ponds and reactive barriers, respectively. Calcium carbonate pea-size gravel is the common alkalinity supplier to neutralize acidity and precipitate metals. These remediation systems have been traditionally implemented in coal mines. However, the acid drainages from the Iberian Pyrite Belt contain metal concentrations one to two orders of magnitude higher than those from coal mines and require special designs to avoid quick clogging or passivation (coating) of the grains of reactive material. To overcome these problems, a Dispersed Alkaline Substrate (DAS) mixed from fine-grained limestone sand and a coarse inert matrix (e.g. wood chips) was developed. The small grains provide a large reactive surface and dissolve almost completely before the growing layer of precipitates passivates the substrate. The high porosity and the dispersion of nuclei for precipitation on the inert surfaces retard clogging. However, limestone dissolution only raises pH to values around 6.5, which is sufficient to precipitate the hydroxides of trivalent metals (Al, Fe), but it is not alkaline enough to remove divalent metals. Magnesium oxide, which hydrates to Mg hydroxide upon contact with water, buffers the solution pH between 8.5 and 10. A DAS system replacing limestone with caustic magnesium oxide has been tested to be very efficient to remove divalent metals (Zn, Cd, Mn, Cu, Co, Ni, Pb) from drainage previously treated with limestone.

Aug 1, 2013