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By Robert D. McKellar, Luke Frawley, Okrasa. Richard

"The resource industries in Canada are facing increasing global competition and stringent environmental regulations. This has made it essential for companies to lower operating costs wherever possible. Electrical energy rep-resents one variable cost that may be better managed and utilized, providing the user with lower operating costs, improved productivity and better yields.The utility industry is also facing changes in the way it must do business. Utilities in North America are facing the prospect of deregulation that will eliminate the monopoly they have traditionally held. This will force them to strive for lower operating costs, to maintain a competitive position and to improve customer ser-vice so as to maintain their customer base.Ontario Hydro has been working with industry for several years. Many opportunities for cost savings have been identified involving energy efficiency, process improvements and the use of new electro technologies. One useful service that the utility can offer industry is to increase the awareness of potential opportunities suited to their operations. This paper will provide an overview of some of the projects that have been implemented and those that are presently being evaluated. An electronic data-base of electro technology applications that is under development will also be described."

Jan 1, 1996

By Robert D. McKellar, Luke Frawley, Richard Okrasa

"The resource industries in Canada are facing increasing global competition and stringent environmental regulations. This has made it essential for companies to lower operating costs wherever possible. Electrical energy rep-resents one variable cost that may be better managed and utilized, providing the user with lower operating costs, improved productivity and better yields.The utility industry is also facing changes in the way it must do business. Utilities in North America are facing the prospect of deregulation that will eliminate the monopoly they have traditionally held. This will force them to strive for lower operating costs, to maintain a competitive position and to improve customer ser-vice so as to maintain their customer base.Ontario Hydro has been working with industry for several years. Many opportunities for cost savings have been identified involving energy efficiency, process improvements and the use of new electro technologies. One useful service that the utility can offer industry is to increase the awareness of potential opportunities suited to their operations. This paper will provide an overview of some of the projects that have been implemented and those that are presently being evaluated. An electronic data-base of electro technology applications that is under development will also be described."

Jan 1, 1996

By N. Ginouse, S. Reny

"In the mining industry time is critical as production depends on the speed of the mining cycle. During the mining process, the time required to re-open access for the next phase of an underground heading is a key point that strongly depends on the ability of the selected ground support technique to promptly ensure the safety of workers. Fiber reinforced dry-mix shotcrete has been proven to be an efficient and well adapted technique, able to produce a ground support material with the required energy absorption or flexural toughness in a single application phase. In this context, this paper demonstrates the possibility of significantly speeding up the mining process by using a new fiber reinforced dry-mix shotcrete. The new fiber reinforced dry-mix shotcrete is capable of developing flexural toughness in only 24 hours that is equivalent to what is typically achieved after 28 days using current fiber reinforced drymix shotcrete technology.INTRODUCTIONShotcrete is often used for ground support when using the drill and blast method or other tunnelling methods. But before re-opening access for the next phase of the underground heading, the applied shotcrete is required to reach a minimum compressive strength and in case of fiber reinforced shotcrete, a minimum flexural toughness (energy absorption) in order to ensure the safety of the workers going into the heading. Combined with bolts, the use of conventional fiber reinforced shotcrete becomes an interesting method for ground support as it is applied very soon after excavation and works to stabilize ground movements (Bernard E. S., 2009). In this case, the toughness development of fiber reinforced shotcrete becomes an important feature of the material when looking to speedup the mining cycle. However, early re-entry criteria in underground openings are difficult to ascertain as the load carrying capacity of fiber reinforced shotcrete is usually assessed after 7 or 28 days. For this reason, re-entry criteria varies from one mining area to another and are usually based on compressive strength requirements. For example, in northern Ontario, Canada, one of the current practices in the mining industry consists of allowing safe re-entry once fiber reinforced shotcrete has developed a compressive strength of higher than 4 MPa (Dufour, O’Donnell, & Ballou, 2003). Flexural toughness requirements on fiber reinforced shotcrete are also typically based on evaluation after 28 days."

Jan 1, 2015

By R. Marleau, R. Assad, J. Dugas

"A study of the geological features of known occurrences of mineralization in Gaspe is the basis for a classification. Nickel, chromite, asbestos and some copper are pre-or syn-Taconic, whereas the most important deposits are tied to granitic post-Taconic stocks. Most occurrences are clearly related to igneous rocks: nickel, chromium and asbestos to Ordovician serpentinite; copper to volcanic rocks of different ages; and copper, zinc and lead to acidic intrusions with apparent zoning. Some lead-zinc deposits lying between the Grande Greve and York Lake formations are stratigraphically controlled. Some occurrences are tied to faults; e.g., the nickel-copper mineralization along the North Grand Pabos fault. Northerly-trending transverse structures appear to coincide with the Gaspe Copper, Mount McGerrigle (Tabletop) granite and Lemieux dome areas of mineralization. JEAN DUGAS, after graduating"

Jan 1, 1969

By Mingxia Liu, Hao Li, Qi Liu

"Laboratory batch flotation tests were carried out on fine (-20 µm) hematite to investigate the non-polar oil’s influences when sodium oleate, octyl hydroxamic acid, or oleyl hydroxamic acid were used as a collector. Batch flotation tests were performed with artificial mixed minerals (hematite:quartz = 1:1) under natural pH condition and kerosene was utilized as the model oil. The experimental results showed that kerosene emulsion behaved differently when used in conjunction with the three collectors. Kerosene helped improve the flotation when sodium oleate or oleyl hydroxamic acid was used as a collector. Nevertheless, it reduced concentrate weight yield, grade and recovery to a noticeable extent when octyl hydroxamic acid was used as a collector, especially at low dosages. In addition, single hematite batch flotation kinetics tests coupled with water recovery measurement were carried out to study the role of kerosene at different collector dosages. It was observed that water drainage and the resulting froth destabilization by kerosene was dominant at low collector dosages, especially in the flotation using octyl hydroxamic acid. At higher collector dosages, the water drainage and froth destabilization effect by kerosene was possibly counter-balanced by the higher hematite hydrophobicity and bubble surface tension gradient, which led to more stable froth layer.INTRODUCTION The minerals industry is facing a steady decline in ore grade, compounded by increasing complexity of mineral dissemination. As a result, the ore has to be ground sufficiently fine to have a suitable degree of mineral liberation, which produces large percentages of fine and ultrafine particles outside of optimal size range for ore dressing. Due to the unique characteristics of fine particles, i.e., small mass, high specific surface area, and problems such as increased solubility of complex minerals (Finkelstein, 1997; Finkelstein & Allison, 1976; Fornasiero & Ralston, 2005), high reagent consumption, fast surface oxidation in the case of sulfides (Collins & Read, 1971; Klassen & Mokrousov, 1963), severe particle entrainment (Subrahmanyam & Forssberg, 1988; Warren, 1984), low flotation rates (Glembotsky, 1953; Philippoff, 1952; Ye & Miller, 1988), slime coating (T. K. Mitchell et al., 2005; Parsonage, 1984), etc., flotation performance of these finely ground ores is very poor in terms of low concentrate grade and recovery."

Jan 1, 2017

"In developing a backfill system handling tailings feed to and from the storage silo, it is necessary to establish a slurry laboratory to develop the technology and silo design criteria. This paper presents the principles involved in such development and the importance of testing principles for optimizing the slurry system. Evaluation procedure based on experiments is applicable to a wide range of materials and allows silo design by scaling up the data gained from model tests. Silo simulation has been successful to design and operation, so becomes an effective approach to backfill applications. IntroductionThe silo is a device comprising specialized equipment and operating with related procedures for storing and handling the mill rejects as backfill slurry. It provides a steady supply of the solids slurry, prepared at desired pulp density under the continuous feed conditions. Because the silo system is designed to accomplish specific objectives when dealing with a particular mill tailings slurry, it is necessary to characterize certain slurry properties, behaviour of the solids slurry and understand the silo performance to establish design criteria. Bench-scale, pilot-scale and dewafull- scale experiments were employed in developing the load-storage-discharge system, and routine procedures are now available for pre-design testing. Silo model experiments and full-scale tests were conducted to define the design parameters and evaluate the silo performance. A silo can be designed by scaling up the silo model geometry and data obtained during tests.Since the early 1960s, silo backfill systems have been widely established. The shape and size of the silo and the operation procedure, as practised, all appear to be relevant to successful operation. Understanding the basic material properties and behaviour of solids slurry retained in the silo will help perfect the silo design, operation procedure and, consequently, improve the silo performance."

Jan 1, 1997

By I. Nakatsugawa

Chemical conversion coating is a process to create thin oxide/hydroxide film containing several inorganic/organic compounds by way of chemical deposition reaction. In case of the application to Mg mobile electronic housings, the film should possess a good electric conductivity while keeping adequate corrosion resistance and working as a paint base. The use of toxic/hazardous chemicals is strictly prohibited from the environmental aspects. This paper describes the recent trend of conversion coating used for Mg electronic housings and analyzes critically from the point of surface technology. The importance of cleaning process and understanding of surface microstructure are particularly emphasized with several experimental results.

Jan 1, 2006

By R. R. Culbert

Several thousand parts per billion of uranium are present in some alkaline lake and ground waters of the Okanagan region, British Columbia. To a major extent the uranium content of these highly anomalous waters is controlled by their levels of dissolved bicarbonate. In lakes, dissolved bicarbonate and the organic content of the sediment largely control the partitioning of uranium between sediment and water. This relationship is found to a lesser extent in alkaline creeks, and transported geochemical anomalies in soils appear where uranium-bearing alkaline ground waters have encountered organic materials. There is a possibility that young, near-surface deposits (with very low radioactivity) are forming from these uraniferous waters.

Jan 1, 1978

By A. Fischersworring-Bunk

The new inline six spark-ignition engine is the realization of BMW's concept of efficient dynamics at high technological level to achieve the attributes of low weight and high efficiency, The paper presents different aspects of the development and manufacturing of BMW's inline six-cylinder engine magnesium-aluminium composite crankcase, Reference will be made on the AJ magnesium alloy optimization approach to balance between mechanical properties and the high pressure die cast ability requirements, Next to this aspect some mechanical design issues will be covered, with CAE methods playing an instrumental role in the early project stage for the assessment of the compound concept, Due to the compound design chosen, the interface posed challenges to both design and productions, A set of novel techniques has been used to cope with these tasks.

Jan 1, 2006

By S. Auger, S. McDonald, K. Ward

"This preliminary paper provides a summary of lab and mill flotation investigations into the copper collector at two Canadian operations. The orebodies illustrated in these studies both contain mainly copper and zinc with uneconomic quantities of lead. Silver is also present as a secondary precious metal.Each mill has advanced to the extended mill trial stage with Uniflot SP129 as the sole copper collector. The preliminary metallurgical results have indicated higher copper circuit zinc and lead rejection is possible as shown in Case Study #2. In Case Study #1, improved zinc circuit metallurgy has been realized during all the Uniflot copper circuit collector trials. A slight increase in silver recovery has also been observed in the extended trials at both operations. INTRODUCTIONThe Canadian base metal industry is presently going through a rationalization period in response to low metal prices and low grade ore bodies. The response from flotation mills has been to reduce costs by incorporating new technologies such as energy efficient large cells, low moisture pressure filters and low steel consumption SAG mills. Other optimization strategies have been incorporated to get better metallurgical performance such as improved process control and monitoring techniques.The newer flotation plants have embraced many of the latest equipment innovations but they continue to incorporate off-the shelf reagents like xanthate and methylisobutylcarbinol (MIBC) . New collector chemistries have been mostly unsuccessful. Our approach incorporates the best of the old and new chemistry into proprietary formulations that match the application. We have found most single chemical formulations cannot meet the demands of the optimized modern flotation plant."

Jan 1, 1992

By Frederic Benard

THE Ontario Refining Company, Limited, wholly-owned subsidiary of The International Nickel Company of Canada, refines the entire blister copper output of the latter's Copper Cliff smelter. Prior to 1936, the blister was cast in 460-lb. cakes at the smelter, loaded on open cars, and transported by rail to the refinery, a distance of approximately 1 1/4 miles. Here the cakes were transferred to the plant narrow-gauge system, charged to furnaces, and re-melted. This procedure necessitated the operation of holding furnaces and casting machines at the smelter -extensive re-handling-and melting down of a cold charge at the refinery. Transfer of the copper in molten form direct from converters to anode furnaces promised a considerable reduction in costs, and this possibility was investigated. As a result, a portable holding furnace, or hot-metal car, was designed and constructed. It was placed in operation in July, 1936, to be followed a year later by three additional units of slightly modified design. Figure 1 shows the original car, and Figure 2 the lacer type. With four cars in service, operations were placed on an all 'hot-metal' basis.

Jan 1, 1938

By M. Holm

Coal is an important fuel for energy generation, and since there are no adequate alternatives it will also be for the next decades. The deep lying hard coal is important in particular because of its high energy content. Automation of underground mining has led to major improvements in productivity and safety. A fully mechanized longwall shearer workface has already reached a high degree of automation and provides a high productivity for example utilizing the memory cut. Current researches and developments in longwall mining are focused on extending this method by adaptive cutting drum height adjustment. The so-called horizon control is often based on memory cut methods. Horizon control in this way requires information of the environment, which can be provided by models (seam model, cut model) and coal interface detection (CID). Available CID systems only provide an optimal output under specific conditions. The authors propose the shield-data-based horizon control (SDHC) system as an alternative approach. SDHC does not require information from a CID system or an environmental model. All necessary information is provided by roof supports, shearer and process monitoring. The SDHC system was tested in simulation under different seam conditions and yielded promising results which will be presented in this paper. In cooperation with the German mining company RAG the SDHC has already reached an experimental stage. A test assembly was built up at the surface and the SDHC system was implemented on real mining equipment. To make the test scenario as realistic as possible, the SDHC system was only connected to the monitoring system, not to the simulation model. The aim of these tests was to establish the cooperation between all subsystems, find appropriate controller parameters, locate and address safety critical aspects and finally to achieve an automatic cutting drum height adjustment. An introduction of SDHC for shearer guidance is given in this paper. The experimental tests are described and the control results of the realized SDHC system on the test assembly are shown.

Aug 1, 2013

By Magdy Ibrahim

This paper presents experimental design and development of a low-cost remote sensing hardware designed to support automated site data acquisition for near real-time progress reporting of construction operations. The developed hardware utilizes open source microcontroller equipped with multiple sensors that include 3D accelerometer, GPS, Data logger and Bluetooth. The use of open source microcontroller makes the developed design cost effective; freeing it from the need for costly license fees. Its platform configuration is flexible; enabling the addition of temperature, weight and other sensors, Wi-Fi and Xbee capabilities to suit individual field applications. Pilot tests have been carried out in laboratory and outdoor environments. The results prove effectiveness and robustness of the developed configuration. The paper provides description of the individual components used in the development of this prototype hardware. It also describes the technical characteristics, capabilities and limitations of the developed hardware. The findings of comparison with alternative technologies used for outdoor tracking of construction operations are presented. The comparison is carried out with respect to range, cost and suitability for outdoor environment. The developed hardware is expected to support a wide range of applications including tracking of earthmoving operations, highway construction and onsite resources. As well, it is expected to enhance safety on construction jobsites.

Aug 1, 2013

By E. Barsky

"Theoretical notions of mass transfer processes in cascade separation of bulk materials have not been adequately developed as yet (Barsky M.D. 1980). In this paper we have derived linear difference equation of the second order for a cascade with initial feeding top any stage proceeding from mass exchange regularities. The solution of these equations has allowed us to determine quantitative dependences of the material distribution over the cascade stages, which serve the basis of the method of predictive estimate of the process results. We have also examined the model of the material distribution coefficient formation at individual cascade stages.We have checked the adequacy of this model to experimental data. It is noteworthy that the obtained theoretical results are phenomenological, i.e. they can be applied to the processes of separation of different physical nature, e.g. of isotopes, liquid media, gases, etc.INTRODUCTIONRecently, the processes of cascade separation of bulk materials have found broad application in various industries. They ensure a high separation efficiency and high-quality composition of final products. Although specialized literature gives serious attention to cascade processes [1], their theory is not sufficiently developed yet. To achieve optimal organization of this process, we examine mass transfer in a cascade gravitational classifier with stages of identical design."

Jan 1, 2016

By Jose Alberto Gonzalez, Said Sharif Mahboob, Jeffrey L. Shepherd

"During the industrial electrowinning of zinc, uneven growth can cause short-circuits and make the deposits more sensitive to the presence of impurities that can significantly impact current efficiency. To produce levelled zinc deposits, additives such as glue, licorice and sodium silicate are often added to the electrolyte. Even in the presence of additives, uneven zinc growth still takes place because of the combination of hydrodynamic and electrolysis conditions in the cell house. Recent advancements in imaging spectroscopy and scaling analysis have opened an avenue to further study the effects of additives on zinc growth morphology. In this study, Atomic Force Microscopy (AFM) and scaling analysis have been used to monitor zinc growth characteristics including roughness, periodicity, aspect ratios and growth mechanisms as a function of electrolyte composition as well as deposition time. Zinc was electrodeposited from an industrial electrolyte containing a host of additives onto an aluminum cathode with a platinum wire serving as the anode. AFM images of the samples were collected to obtain 3D topographical information on which scaling analysis was performed to extract details on root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. This analysis provided information on the mechanism by which the previously mentioned variables can impact short term growth and also provided a prediction of expected growth at long deposition times.INTRODUCTIONElectrowinning is one of the final stages in the industrial production of zinc metal. It is during this process where dissolved zinc ions undergo electro-reduction from an acidic electrolyte onto an aluminum cathode and are later recovered by stripping the zinc metal from the substrate. However, due to the nature of zinc growth as well as the various operating conditions, zinc deposition may occur unevenly, sometimes causing short-circuits that can cause electrode damage and reduced zinc production."

Jan 1, 2016

By Hasini Wijayaratne

Anode cover material, a mixture of crushed electrolyte and alumina, is a crucial part of an aluminium reduction cell because of its important role in maintaining overall heat balance. However, until recently little attention has been given to understanding or controlling its composition and quality. The thermal conductivity of anode cover material determines the extent of the heat loss from the top of the cell. This will change as a function of the granulometry and composition of the applied cover as well as over time as the cover material consolidates on top of the cell. The ability to measure or predict the thermal conductivity of fresh and ageing cover is an important tool for managing cell heat balance. Recent studies have shown that granulometry or more correctly, voidage is likely to be the predominant determinant of thermal conductivity of anode cover materials. We have developed equipment to measure the thermal conductivity of granular cover material and tested the relative importance of composition (ratio of alumina to crushed electrolyte) and granulometry/voidage on cover thermal conductivity. In general, our results confirm that granulometry is the dominating factor. Generally, high voidages contribute to lowering the thermal conductivity especially when particles are mostly fine. However the relationships between granulometry, voidage and thermal conductivity are complex due to the varying nature of heat transfer between particles. Aging of granular cover material occur during cell operation forming a consolidated crust due to exposure to heat and fumes over time. Structure and thermal behaviour of this consolidated crust is also important in understanding the overall properties of cover. This paper presents the outcomes of laboratory studies conducted in order to understand the thermochemical behaviour of anode cover material and in particular, the role of fines in anode covers mixtures.

Jan 1, 2011

By A. Gauthier, J .. E. Muir, M. Cormier

Falconbridge's Lac Shortt gold deposit is located in Gand Township, some 25 km north-east of Desmaraisville, The deposit was outlined in i980 by a drilling program me conducted by Falconbridge Ltd. in a joint venture with Corporation Falconbridge Copper after three years of systematic exploration by Falconbridge Ltd. in the Desmaraisville area. The gold bearing structure had previously been drilled by three other exploration companies. As based on an underground development programme conducted by Corporation Falconbridge Copper, the "in-si tu" mineral inventory to a depth of 500 metres at a cut-off grade of 3.0 g/t is estimated at 1 937 605 tonnes at a grade of 6.4 g/t (uncut) and 6.0 g/t (cut). Regionally, the stratigraphy consists of thick sequences of volcanic and volcanosedimentary rocks intruded by numerous and voluminous mafic (gabbro), felsic (granodiorite, syenite) and anorthositic intrusions. Structurally, at least two fold sets and one major fault system (E-NE) are present. Minor fault systems oriented E-NE and N-NW also occur. Mine stratigraphy can be divided into 1) - the hangingwall; 2) - ore zone; 3) - footwall. Hanging wall rocks include: a) green lapilli and blocky tuff b) transition zone c) green mica crystal tuff and d) red dolomitic tuff. Ore zone rocks include: a) bleached mafic tuff b) barren carbonates, c) pyritic dolomitic tuff (?) and d) brick-red syenite. Footwall rocks include: a) magnetic lava (so-called diorite), b) mafic lapilli and blocky tuff and c) alkali basalt, Native gold is the only gold mineral so far identified and it occurs both as free grains in gangue and as micro-inclusions in pyrite. Two geochemical groups were identified in the main rock units: 1) Alkali-rich rocks cons is ting of the ore zone and foot wall rocks and 2) Subalkaline group consisting of the hanging wall rocks. Ore analysis also shows Ba, Sr, W, Zr, REE and F enrichment in the ore zone. Footwall rocks are enriched in Na20. Present geological and geochemical data do not permit a clear interpretation of the formation for the Lac Shortt gold deposit but suggest it is a volcanic-hosted stratabound type. The bulk of the mineralization is associated with an exhalative phase following alkalic, carbonic, hydrothermal activity and part of the mineralization is associated with a late intrusive phase.

Jan 1, 1984

By P. Simon, G. Falkinger, G. Angerer, B. Gerold

"This contribution presents an investigation of the evolution of shrinkage pores during hot rolling with a special focus on the microscopic mechanism. The reliable closure of pores, which inevitably occur during the casting process, is of crucial technological importance for high-quality hot rolled plate products. Therefore, lab-scale tests were carried out under different typical thermomechanical loadings. Extensive data from optical microscopy was collected before and after deformation. The analysis shows that the average volume of pores evolves similar to the volume of an idealized arrangement of voids in an ideally plastic matrix. The average shape of the shrinkage pores, however, was found to be almost constant during deformation. Even though individual pores exhibit complex morphologies far from any idealized geometries, the overall evolution of a large number of pores is well captured by simple assumptions. In addition to the quantitative analysis, a schematic representation of this counter-intuitive behavior is provided. A simple ‘Gurson’-type void evolution equation was implemented in a three-dimensional Finite-Element model of the industrial hot rolling process. With the help of this mechanism-based process simulation the thermomechanical closure of shrinkage pores during the rolling process has been optimized for a variety of plate products.INTRODUCTION Aluminum alloys of the 7xxx series are widely used in the aircraft industry. They have to meet high quality standards regarding microstructure as well as mechanical properties. For hot-rolled aircraft plates, one of the most important quality requirements is that they are free from pores. Pores, however, are inevitably created during the casting process either due to shrinkage or due to the dissolution of gas from the melt. The pores have to be closed mechanically during the hot-rolling process. Therefore, the mechanism of so-called pore closure or void closure has a high technological relevance for the production of aircraft plates. The behaviour of voids in a ductile matrix subjected to mechanical deformation has been extensively studied, especially in the context of damage mechanics. A recent review (Besson et al., 2010) on modeling methods for ductile damage gives a good impression on how much experimental as well as theoretical effort has been dedicated to the problem of void evolution under mechanical loadings. Although void closure has been studied to a far lesser degree, it obeys to the same general theoretical evolution laws as void growth. The most basic theoretical result is that hydrostatic pressure drives void closure, while hydrostatic tension leads to void growth. The mechanism of void closure depends on the void shape. This is illustrated by the example of a flat penny-shaped void, which under compression obviously closes much faster than a sphere with the same volume. Theoretical models have been developed for the evolution of simplified void geometries, such as spheres or cylinders (e.g. Gurson, 1977), spheroidal (Gologanu et al., 1997) and ellipsoidal voids (Ponte-Castaneda, 1994). In industrial cast ingots, however, the pores exhibit very complex morphologies, which are far from any idealized geometry. X-ray tomography revealed ‘tortuous’ voids in a 5xxx aluminium alloy (Chaijaruwanich et al., 2006)."

Jan 1, 2018

By G. P. Demopoulos

The solubilities of calcium sulfate in HCl-CaC1z-H20 solutions up to 100°C were successfully modelled with the aid of OLI software after bringing proper modification to it. Modelling, more specifically, was carried out with the help of the Environmental Simulation Program, V-6.6.0.4 (www.olisystems.com). New model parameters were obtained by regressing the solubility data. A private databank was established by adding the newly defined model parameters and the calcium sulfate hemihydrate phase that is not included in the original OLI database. The McGill-modified OLI software was successfully applied not only to modelling solubilities but also the transformation of the various CaS04 phases, namely dihydrate, hemihydrate and anhydrite. In this paper, the modelling methodology will be discussed along with a comparison of the capabilities of the newly developed model vs the original OLI model.

Jan 1, 2005

By C. Bergstrand

"Precipitation of gypsum and the formation of scale may pose a serious challenge in the leaching of several minerals. As an example, precipitated gypsum may form scale in the machines increasing the need for maintenance. Alternatively, it may encapsulate precious elements, i.e. gold and lower the recovery during subsequent leach processes. In this work we explore how different biopolymers modify the rheology of gypsum at three different pH levels at ambient and elevated temperatures. The ability to disperse gypsum vary with temperature, pH and biopolymer. It is also inversely related to the scaling potential. Measurements of the zeta potential as a function of increasing amounts of biopolymer reveals that the magnitude of the zeta potential changes in the presence of biopolymer, and so does the ability to disperse the gypsum suspension. Similar results with hematite will also be discussed. The methodology and results may aid in the selection of additives used in mineral processing applications where scale pose a problem.INTRODUCTION Processing of refractory gold ores normally involve either atmospheric or oxidation under pressure in order to convert sulfides to oxides (Weir, King, & Robinson, 1986; Weir, Robinson, & King, 1986). This conversion facilitates leaching of gold (and silver) in normal CIL processes. During oxidation, sulfides are converted to sulfates. Normally, there is an abundance of calcium ions in the process water, either released from the ore or added as lime to adjust pH for the CIL process. Precipitation of calcium sulfate, or other compounds (calcium carbonate, jarosite, hematite) is a way to remove gangue minerals from the solution entering the CIL circuit (Ji, King, Fleming, & Ferron, 2010). Precipitation may also cause challenges in the process as gold (or other valuable elements) may become encapsulated in gangue. (Beauchamp, Choung, & Xu, 2006). In addition to precipitation, the precipitated gangue minerals may solidify and form scale in the processing equipment. Recently, Lauten and Kluck (2016) found that dispersants used as scale inhibitors to prevent encapsulation of gypsum did not modify the solubility of gypsum. In the utilised model system, similar amounts of gypsum precipitated with and without dispersants. Instead, it was found that the dispersants evaluated as scale inhibitors reduced the yield stress of gypsum suspensions. The reduced yield stress was associated with a reduced tendency for gypsum particles to agglomerate and form scale."

Jan 1, 2017