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By R. A. Sullivan

I T IS one of the unwritten policies at Preston Mines that we examine closely any method or tool that will help us in our constant battle against rising costs. It is our personal conviction that most work methods can be improved. Therefore even though the job went well yesterday, it does not necessarily follow that it should be done by the same method today. With the arrival of the natural gas pipe line in the Porcupine area it was obvious that we would have to take a good look at the possibilities of using this source of fuel for plant heating. • Steam presently generated at Preston is for heating purposes only, no process steam being required. Prior to the fall of 1960, the heating plant consisted of two low pressure, coal-fired, fire-tube boilers, operating at an approximate pressure of 14 pounds per square inch. These boilers were underfed by stokers and could be operated either singly or together. ~o. 1 unit was a horizontal return tubular boiler, registered at 100 h.p. No. 2 unit was a fire-box boiler, registered at 75 h.p.

Jan 1, 1962

By Rocky (Yaokun) Wu

This paper introduces the development and application of a new cable anchor - Cable-Lok for pre-stressed cable bolting in mines. Cable-Lok is a spring-loaded cable anchor suitable for the drill hole diameter of 50 and 65 mm (2" and 2.5") in medium soft rock to hard rocks. The cable anchor is automatically set on installation and the cable can be tensioned immediately to provide active and primary support throughout its length. Post-grouting can be conducted independently. In comparison with the conventional cable bolting, Cable-Lok anchor will greatly speed-up the cable bolting circle and decreases the cost of cable bolting. Cable bolting anchored with Cable-Lok anchor has wide application in mines, e.g. pre-stressed cable bolting in large span drifts and intersections for permanent rock support, or in hanging walls or stopes for temporary support, or cable lace anchoring etc. This paper introduces the principle of pre-stressed cable bolting and the specifications of the Cable-Lok anchor, presented the testing results in laboratory and the application cases in mines.

Oct 1, 2010

By Rachel S. Prudhomme, Michael L. Jeremic

"The consolidation of mine backfill by free zing is a concept which has been under study in the mining engineering laboratories at Laurentian University during the past three years. The proposed underground application of freezing involves the artificial freezing of in-situ backfill by means of a refrigerated brine solution which would be circulated through a circuit off freeze pipes. The most interesting findings to date are: (I) The uniaxial compressive strength off frozen fill is considerably higher than that of cemented fill in a ratio of 20:1 (aggregate to cement), and (2) load deformation characteristics of the frozen fill suggest that a higher ice content results in more brittle failure and that samples which have initially failed can still support up 10 one-half the ultimate load without additional failure.Although at this early stage a derailed economic analysis of the procedure has not been possible, a general evaluation of the costs involved suggests that the method could be competitive with the hydraulic placement of cemented backfill. Results obtained from laboratory investigations indicate that the freezing of backfill is a structurally feasible option .IntroductionGround consolidation by freezing is based on the principle of transformation o f water contained in an aggregate-slurry into ice, which act s as a binding agent between the bulk particles, and which results in the transformation of a granular soil into a ""rock -type"" material. The abrasive nature of the particles enhance s the strength o f the ice by providing internal friction. As a result of this internal friction, the chances of plastic flow of the frozen mass when in a loaded condition are reduced(1). T he strength of a frozen aggregate is al so dependent on the grain shape of the aggregate particles which may or may not promote particle interlocking(2) and on the temperature since, below the freezing point of the water/aggregate mixture, the strength of the frozen mass increase s with decreasing temperatures.In the shaft sinking industry, artificial freezing of loose , unconsolidated soils has been in practice for several decades. Shafts for Saskatchewan 's potash industry have been sun k to depths of 3000 feet by employing artificial freezing to stabilize the Blairmore Formation(3). The common procedure for freezing ground for shaft sinking is summarized as follows(4,5): I) 150 mm diameter bore holes spaced on 1.5 m centres are drilled in a circular pattern with a radius of 1.5 m outside the periphery of the proposed shaft."

Jan 1, 1985

By Mani Manimaran, Inna Dymov, Mariam Melashvili, Chris Fleming, Joe O’Day

This paper presents experimental evidence that supports the use of bromine/bromide as a potential alternative to conventional cyanidation for gold leaching. The study evaluated a brominebased lixiviant, Stabilized Bromine, with considerably lower vapour pressure than liquid bromine. Using a rotating device, the rate of gold dissolution was determined at various concentrations of this reagent. The reactivity of pure pyrite, arsenopyrite and chalcopyrite minerals was also evaluated in stabilized bromine reagent. Furthermore, bromine leaching of gold in a number of gold bearing ores was undertaken. Results showed that significantly higher gold recovery can be achieved with bromine than with cyanide when leaching gold encapsulated in sulphides, but bromine consumption was high owing to simultaneous oxidation of the sulphides. The greatest promise for the bromine leach process was with oxidized gold ores. The recovery of gold from oxide ores with bromine was comparable to that achievable with cyanide and bromine consumption was reasonable when leaching was conducted at a near neutral pH of ~6. In the case of oxidized gold ores containing copper mineralization, it is possible that bromine consumption may be lower than cyanide consumption, since there is evidence to suggest that bromine is less reactive than cyanide with copper minerals.

Jan 1, 2014

By H. Link

"The extremely low permeability of the water-carrying beds in the nevonian formation of the potash district of Saskatchewan does not permit the injection of cement or chemicals to seal off sufficient water from the shafts to guarantee the safety of the mine. Based on many years of experience with wet shafts in the German and French potash mining industry, Alwinsal Potash of Canada Ltd. decided to have their potash mine shaft near Lanigan, Sask., which was completed in September of 1967, lined by means of an absolutely watertight lining of combined concrete and steel-plate construction.This shaft lining, consisting of two steel shells of welded construction with concrete filled in between, has proved itself before in the German coal mining industry. It guarantees a permanently dry shaft. With this type of lining, time-robbing and very often abortive injections are superfluous and the regular repair and adjusting work as well as the corrosion of conveyances and ropes can be avoided. Above all, however, the danger of a water inrush into the shaft is abolished completely."

Jan 1, 1971

By Diankun Lu, Ganfeng Tu, Edouard Asselin, Feng Xie

A novel separation process for detoxifying cadmium-containing residues arising from zinc hydrometallurgical processes has been developed. An initial investigation indicated that a high concentration of zinc in the sulfate solution can be effectively separated from cadmium by solvent extraction with P204 (di(2-ethylhexly)phosphoric acid, D2EHPA). The mixture of sulfuric acid and ammonium citrate ((NH4)3C6H5O7) is thus used to extract metals from the residue at room temperature. Copper in the leachate is recovered by solvent extraction (SX) with LIX 973. Cobalt in the raffinate from the copper SX process is recovered by precipitation with a-nitroso-ß-naphthol. The results show that more than 50% of the copper and virtually all the zinc, cadmium and cobalt in the residue can be leached under the experimental conditions used here. Virtually all dissolved copper and cobalt can be recovered in the subsequent solvent extraction and precipitation processes. The presence of (NH4)3C6H5O7 could significantly facilitate the extraction of zinc by D2EHPA in the subsequent separation of zinc and cadmium. More than 97% of the dissolved zinc can be recovered through a two-stage counter current solvent extraction process. After separating copper, cobalt and zinc, cadmium can easily be recovered from the solution either by cementation with zinc powder or by electrowinning, while the purified solution can be recycled back to the leaching process.

Jan 1, 2014

The dissolution of chalcopyrite has received a significant amount of attention. The predominant paradigm of investigation is that its rate of dissolution is limited or passivated by a surface coating or film of material. The common candidates for such a passivating coating are numerous: polysulfide coating, metal deficient layers, copper sulfide coating, bornite layers, jarosite precipitates, and elemental sulfur films. While this line of explanation, that is, the explanation based on passivation, seems to have won some form of consensus with researchers, there is another explanation for the results that can account for all the results observed. Crundwell (1988) proposed that the solid state properties of chalcopyrite, in particular, the semiconducting properties, are responsible for the observed behaviour of chalcopyrite. The purpose of this paper is to outline the semiconductor mechanism of dissolution, and to show how this mechanism accounts for all the observed phenomena recently reported in the literature. The paper outlines the semiconductor mechanism of dissolution, shows how this mechanism accounts for the dissolution

Jan 1, 2014

The influence of joint orientation and joint persistence, on the mechanical behaviour of jointed rock masses under uniaxial compression, has been studied systematically. The joint inclination angle ß was varied from 0° to 90° with an increment of 15°. The joint continuity factor k was taken as 0.2, 0.4, 0.6 and 0.8. The peak strength, Young’s modulus, the complete axial stress-axial strain curves, the cracking process and the characteristic of the fragments, were investigated. It was found that the anisotropic response of the jointed specimens was governed by the micro-mechanism, such as crack initiation, propagation and coalescence, crack opening or closing, and frictional slip of cracks or joints. With the increase of joint continuity factor, the axial stress-axial strain curves change from single-peak to multipeak, the peak strength and Young’s modulus decrease. The specimens with medium joint inclination angle (30°,45° and 60°) has lower energy dissipation and strength due to stepped or shear failure, while specimens with small and large joint inclination angle (0°, 15°, 75° and 90°) has higher energy dissipation and strength due to axial cleavage or crushing failure.

Jan 1, 2015

By R. M. Berry

A brief outline of refining methods used to (1) upgrade yellowcake to nuclear purity and (2) convert the uranium to the chemical and physical forms required by the fuel fabricators is presented. The uranium hexafluoride (UF6) production facility now under construction at Eldorado, Port Hope, is discussed. Technological improvements in uranium refining are considered.

Jan 1, 1969

By S. Fuentes, J. Cáceres

"During the past fifteen years, mines utilizing the block caving method have improved performance and systematically reduced total mining costs.This paper describes improvements in mine design, mine planning, and mine management, including methods enabling the Chilean and international mining industry to ensure cost savings and productivity growth while using the block caving method. These improvements have encouraged the re-evaluation of underground operations at operating and closed open pits, and challenge surface mining applications as the only low-cost mining method. This paper describes a strategy to estimate the optimum open pit to underground transition time during the life of a mine. IntroductionDuring the last fifteen years, block caving mines have experienced huge changes in designs, planning and administration. These changes have permitted operators to drastically reduce costs, improve equipment productivity, and improve overall business performance. As a consequence of this situation, the block/panel caving mining system is challenging actual open pit operations to maximize the net present value (NPV)."

Jan 1, 2004

By K. Krishnapisharody, S. Clark, M. Barati

Different gas purging methods to metallurgical baths have been applied to date, among which are top lancing and bottom blowing through tuyeres or porous plugs. Among these, the porous plug bottom blowing technique has shown higher efficiency in gas utilization than tuyeres and top blowing, due to smaller bubble size and lower liquid velocity. However, the studies related to bottom stirring of metallurgical baths are limited to slag-less or thin slag-covered melts. In particular, there is no examination of stirring ability in conditions similar to Falconbridge's Slag Make Converter, where the bath is covered with a thick slag layer and a stream of solids is charged on the bath from top. This study was undertaken to investigate the application of gas purging through a porous plug in stirring in and melting of the solid feeds. The spreading behaviour and melting time of a solid layer forming on a plume created by stirring were calculated using the existing models. The results show that formation of a thick solid layer, specifically in areas beyond the plume region is very likely. Nevertheless, the thickness of the layer and melting time do not appear unreasonably high. It is predicted that by proper controlling of gas flowrate and plug configurations, successful solid charging through the mouth can be practiced.

Jan 1, 2007

By Xiu-Xiang Tao

This study investigated bio-liquefaction of lignite and its model compounds of thymol, bezioc acid and quinoline by a fungus, Hypocrea lixii AH. It analyzed, during bio-liquefaction, enzyme activity of oxidase, LiP, Lac, MnP and polyphenol oxidase, and degradation products by UV-Vis, FTIR, 13C NMR and GC-MS. The results showed that the bio-liquefaction percentage (by mass) of lignite was up to 44.86 %. The bio-liquefaction products of lignite were mainly aniline, amide, ether, carboxylic acid ketone and ester. The aromatic ring number was 1-3 with an aromatic carbon ratio of 0.328, which indicated rings opening, bonds breaking and oxidation reaction. By considering with the enzyme activity analysis results, it showed that LiP and Lac catalyzed reactions to open aromatic cycles and to break bonds; esterase to break ester bond; and peroxidase in oxidation reaction.

Aug 1, 2013

By K. Nikkhah, N. Dhadli, G. Freeman

Ammoniacal pressure leaching operations have been in commercial use at the Fort Saskatchewan refinery of Sherritt International Corporation since 1954. Recent improvements have significantly increased the capacity of this circuit. The computer modeling of this process has proved to be a valuable tool in facilitating the evaluation of different operating scenarios in an effective manner. Reagent response in the ammonia leach of nickel and cobalt sulphides is examined using the dynamic process simulation capabilities of IDEAS(TM) software. The dynamic simulation enables accurate measurement of the sensitivity of the process to variables such as temperature, feed rate and ammonia concentration as well as compartmental analysis of metals concentration, pulp density, vent gas composition, and the formation of specific complexes. The complexity of the ammonia leach process makes it a logical choice for evaluation by computational analysis. The methodology for dynamic modeling of a pressure leach process is presented.

Jan 1, 2005

By C. E. Lancelle, J. T. Volk, H. F. Wang, D. Fratta

"The Main Injector Neutrino Oscillation Search (MINOS) Near Detector Hall at Fermilab and the Lafarge – Conco Mine are located approximately 100 meters underground in the Galena-Platteville dolomite just below its contact with the overlying Maquoketa shale in Northeastern Illinois, USA. A new cavern was excavated adjacent to the MINOS Near Detector Hall at Fermilab to house the near detector for the Off-axis Neutrino Appearance Experiment (NOvA) program. During this excavation approximately 1150 cubic meters of shale rock were removed. Tiltmeter arrays consisting of a series of hydrostatic leveling sensors (HLS), which are spaced regularly over a total distance of 50-to-100 meters, were used to monitor subsurface deformations. The tiltmeter response in the MINOS Near Detector Hall due to the NOvA cavern excavation is approximately thirteen times the estimated response based on using laboratorydetermined properties. The discrepancy between modeled and measured tilt is likely due to differences in Young’s Modulus in the rock mass versus in a small laboratory sample. Amplitudes of measured solid earth tides differ from the amplitudes of theoretical solid earth tides by up to 40 percent for both arrays. This is likely due to a local heterogeneity or discontinuity.INTRODUCTIONLong baseline tiltmeters have been used to record small earth movements since the early 1900s. One of the first studies using long baseline tiltmeters to measure earth tides was published by Michelson (1914). He used a leveled 152-meter long, 0.15-meter diameter tube half-filled with water connecting two concrete-lined pits. The pipe was trenched 1.75 meters underground in Williams Bay, Wisconsin in a sandy-clay soil. Initially only an east-west line was used, though a north-south line was added after it was seen that viable results were obtained. Measurements were made by hand either hourly or once every two hours depending on the time of day. When compared to 0.7 times the calculated earth tides, the tiltmeter signal matched almost exactly. This excellent result began the use of long baseline tiltmeters to measure small earth movements."

Jan 1, 2015

By M. Phylli Bray

"Mining has the reputation of being a very ""macho"" industry. Recently, wider educational opportunities for women in nontraditional occupations and changes in mine technology have combined to make mining a viable career choice for women also. To benefit from this new resource, the mining industry faces the challenge of developing a different work environment from the one now burdened with sexism. Management supported initiatives are needed to facilitate such a transformation. The same rethinking of gender attitudes might also be extended to mining women in their traditional role as ""wife of"". The assumption that the male worker's wife is an unpaid adjunct is being questioned. It is suggested that women's separate concerns both as helpmate and as part of the mining workforce should be considered when planning for mining into the 21st century.IntroductionI must confess that, during the preparation of this paper, there have been many moments when I questioned my temerity. After all, I am not male, I am not an engineer, and I have never had a position in mine management. But as the wife of a mining engineer and a long-time resident of Northern Ontario mining towns, I do have an interest in the mining industry. This interest has had little to do with the technical and management aspects of the industry. Instead my research has been concerned with the impact the mining industry has on the people involved, particularly women, whether directly as employees or indirectly as wives. As I look toward the 21st century, I believe that the whole question of gender relations in the mining industry is one of the critical management issues smouldering below the surface."

Jan 1, 1995

By M. A. Halim, V. I. Lakshmanan

Recycling is one of the key elements for sustainable process development for the recovery of value-added products and reducing environmental impact. Process Research ORTECH Inc. has developed several innovative and sustainable technologies, which minimizes the use of water, and chemicals for the recovery of gold, vanadium and gallium from secondary sources by maximizing the recycling of reagents, and reuse of water from process effluents.

Jan 1, 2015

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By M. S. King

"A simple method is proposed for determining the long-term deformation behaviour of evaporites. The theory developed can be tested by measuring the change in diameter as a function of time of a vertical mine shaft opposite evaporite strata. Ultimate shaft closures predicted by the theory agree well with those calculated with the very much more complex theory of Serata (1968), provided that sufficiently high octahedral shear strengths are used in the former.An analysis of measurements made in an isolated opening in a Saskatchewan potash mine shows that the octahedral shear strength of the surrounding potash and halite was approximately 500 psi several years after the opening was mined. This value is less than that deter-mined experimentally for halite by Serata. The same data indicate, furthermore, that the in-situ octahedral shear strength is decreasing slowly with time.The current controversy regarding the actual deformation of evaporites will only be resolved by the cooperation of potash producing companies in releasing data on the long-term deformation of their mine shafts."

Jan 1, 1971

By G. T. Lapidus, R. M. Luna-Sánchez

In the present study, a series of cyanidation experiments were performed on a bulk sulfide concentrate which contained silver in four distinct phases, to determine its extraction rate, varying the oxygen concentration. The results showed that three of the four phases were refractory, aguilarite (Ag,iSeS) being the only leachable phase, and that the effect of the oxidant concentration is minimal. Mathematical simulations were performed, adjusting only the Damkohler number to adequately fit the experimental data. This model, and the mechanism implied, was compared with that found for acanthite (Ag2S) in a previous study, and the differences between the two discussed.

Jan 1, 2005